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EP1585802A2 - Substrat de nettoyage impregne de tensioactifs - Google Patents

Substrat de nettoyage impregne de tensioactifs

Info

Publication number
EP1585802A2
EP1585802A2 EP03766195A EP03766195A EP1585802A2 EP 1585802 A2 EP1585802 A2 EP 1585802A2 EP 03766195 A EP03766195 A EP 03766195A EP 03766195 A EP03766195 A EP 03766195A EP 1585802 A2 EP1585802 A2 EP 1585802A2
Authority
EP
European Patent Office
Prior art keywords
concentration
weight
cleaning
substrate according
substrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP03766195A
Other languages
German (de)
English (en)
Inventor
Petra Koch
Jörg KÜTHER
Kathrin Liste
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beiersdorf AG
Original Assignee
Beiersdorf AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beiersdorf AG filed Critical Beiersdorf AG
Publication of EP1585802A2 publication Critical patent/EP1585802A2/fr
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/049—Cleaning or scouring pads; Wipes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0208—Tissues; Wipes; Patches
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/143—Sulfonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/34—Derivatives of acids of phosphorus
    • C11D1/345—Phosphates or phosphites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives

Definitions

  • the present invention relates to a foamable,. cleaning substrates soaked in surfactants, their production and use.
  • Surfactants are very important as wash-active substances in cosmetic cleaning agents. Due to their specific molecular structure, each with a hydrophilic (water-attracting) and hydrophobic (water-repellent) grouping in the same molecule, they ensure a reduction in the surface tension of the water, wetting of the skin, facilitating dirt removal and foam regulation.
  • the first class are the non-ionic surfactants. These include fatty alcohol ethoxylates, fatty acid monoethanolamides and alkyl polyglycosides (APGs).
  • APGs alkyl polyglycosides
  • amphoteric surfactants are compounds that contain both a cationic function, usually a quaternary nitrogen, and an anionic function, usually a carboxylate group. Their state of charge depends on the pH. These include alkylaminobetaines and alkylamidoglycinates.
  • the group of cationic surfactants consists of compounds which contain at least one quaternary nitrogen atom. These include, for example, alkylamines, alkylimidazoles, ethoxylated amines.
  • the group of anionic surfactants is formed from sulfates, sulfonates and carboxylates i.e. Salts of esters of sulfuric acid, and salts of sulphonic and carboxylic acids, for example sodium lauryl ether sulfates (sodium polyoxyethylene lauryl sulfates).
  • Solid cleaning substrates in particular wipes, represent a special product form for cleaning preparations. These can already be impregnated with the cleaning preparation by the manufacturer and have the advantage that the preparation is already specified in the correct dosage. In addition, they avoid the disadvantage of preparations stored in bottles, the packaging of which can break and the contents can "leak".
  • the other advantages of cleaning substrates / wipes also include the fact that they can be conveniently taken in a counted quantity when traveling and for their own Application usually no longer requires water.
  • Textiles can be woven, knitted or knitted or as a composite (narrow, non-woven textile). Composites are mostly used (for reasons of cost). In the case of composites, the fabric is not formed by warp and weft or stitch formation, but by intertwining and / or cohesive and / or adhesive bonding of textile fibers. Composites can be differentiated according to DIN 61210 T2 into fleece, paper wadding and felt. Nonwovens are loose materials made of spun fibers (ie fibers of limited length) or filaments (continuous fibers), mostly made of polypropylene, polyester or viscose, the cohesion of which is generally given by the fibers' own liability.
  • the individual fibers can have a preferred direction (oriented or cross-layer nonwovens) or non-directional (tangled nonwovens).
  • the nonwovens can be mechanically consolidated by needling, meshing or by swirling using sharp water jets.
  • Adhesively bonded nonwovens are created by gluing the fibers with liquid binders (e.g. acrylate polymers, SBR / NBR, Polyvinyl esters, polyurethane dispersions) or by melting or dissolving so-called binding fibers, which were added to the fleece during manufacture.
  • liquid binders e.g. acrylate polymers, SBR / NBR, Polyvinyl esters, polyurethane dispersions
  • binding fibers which were added to the fleece during manufacture.
  • the fiber surfaces are dissolved by suitable chemicals and connected by pressure or welded at elevated temperatures [J. Falbe, M. Regnitz: Römpp-Chemie-Lexikon, 9th edition. Thieme-Verlag, Stuttgart (1992)].
  • a second variant is the "spray process", in which the preparation is sprayed onto the passing cloth. This process is suitable for all textiles, but no strongly foaming preparations can be applied to the cloth, since the foam development becomes too great during the spraying process.
  • fleece or cloth webs run past scraper plates, beams or nozzles, which are continuously loaded with impregnation solution. Different degrees of impregnation can u. a. divide by varying the contact pressure and the cloth pull speed.
  • a substrate which is impregnated with a cleaning preparation having a viscosity of 1 to 3000 mPas, preferably having a viscosity of 1 to 2500 mPas, particularly preferably having a viscosity of 1 to 2000 mPas, containing a) or several anionic and / or nonionic surfactants in a concentration of 0.1 to 15% by weight, preferably with a concentration of 1 to 10% by weight, b) water in a concentration of 40 to 99% by weight, preferably in a concentration from 50 to 90% by weight, particularly preferably in a concentration of 60 to 90% by weight, c) one or more preservatives in a concentration of 0.01 to 3% by weight, preferably with a concentration of 0.1 to 2 % By weight, in each case based on the total weight of
  • the substrates according to the invention represent an extremely satisfactory, good foaming, ready-to-use cleaning utensil which can be used without further addition of water.
  • the special mildness of the cleaning preparation enables the use of the substrates according to the invention for cleaning the skin and / or the hair. Even use on sensitive and dry skin, for example the skin of babies, the elderly or facial skin, is advantageously possible according to the invention.
  • the surfactant combination of the preparations according to the invention is so mild that it is no longer necessary to rinse off the preparation with water after using the substrate.
  • the concentration is one or more anionic and / or nonionic in a concentration of 0.1 to 15% by weight, preferably in a concentration of 1 to 10% by weight, in each case based on the total weight of the preparation ,
  • water in a concentration of 40 to 99% by weight preferably in a concentration of 50 to 90% by weight, particularly preferably in a concentration of 60 to 90% by weight, based on the total weight of the Preparation is.
  • one or more preservatives is present in a concentration of 0.01 to 3% by weight, preferably in a concentration of 0.1 to 2% by weight, in each case based on the total weight of the preparation.
  • the cleaning preparation according to the invention has a viscosity of 1 to 3000 mPas, preferably a viscosity of 1 to 2500 mPas, particularly preferably a viscosity of 1 to 2000 mPas.
  • the viscosity of the cleaning preparation according to the invention can advantageously be adjusted according to the invention using thickeners.
  • wash-active surfactant or surfactants according to the invention from the group of surfactants which have an HLB value of more than 25, very particularly advantageous are those which have an HLB value of more than 35.
  • anionic surfactants which are advantageous according to the invention are
  • Acylamino acids and their salts such as ⁇ acylglutamates, especially sodium acylglutamate
  • ⁇ sarcosinates for example myristoyl sarcosine, TEA-lauroyl sarcosinate, sodium and sodium,
  • Sulfonic acids and their salts such as ⁇ acyl isethionate, for example sodium / ammonium cocoyl isethionate,
  • ⁇ sulfosuccinates for example dioctyl, Dinatriumlaurethsulfo- succinate, disodium and disodium MEA sulphosuccinate
  • sulfuric acid esters such as
  • alkyl ether sulfate for example sodium, ammonium, magnesium, MIPA, TIPA laureth sulfate, sodium and sodium C ⁇ 2-13 pareth,
  • Alkyl sulfates for example sodium, ammonium and TEA lauryl sulfate. Also
  • ⁇ taurates for example sodium lauroyl taurate and sodium methyl cocoyl taurate
  • Ether carboxylic acids for example sodium laureth-13 carboxylate and sodium PEG-6 cocamide carboxylate, sodium PEG-7 olive oil carboxylate,
  • Phosphoric acid esters and salts such as DEA-Oleth-10 phosphate and dilaureth-4 phosphate
  • Alkyl sulfonates for example sodium cocosmonoglyceride sulfate, sodium C 12 . 14 olefin sulfonate, sodium lauryl sulfoacetate and magnesium PEG-3 cocamide sulfate can be used advantageously according to the invention.
  • anionic surfactants acylamino acid surfactants, sarcosinates, sulfosuccinates, sulfosuccinate citrates,
  • Monoalkyl phosphates, olefin sulfonates are used.
  • acylamino acid surfactants such as sodium cocoyl giutamate (e.g., Aminoft CS-11 from Ajinomoto), sodium lauroyl glutamate, sodium capryloyl glutamate, sodium caprinoyl glutamate and / or di-TEA-palmitoyl aspartate are used as anionic surfactants.
  • Alkanolamides such as Cocamide MEA / DEA / MIPA
  • esters which are formed by esterification of carboxylic acids with ethylene oxide glycerol, sorbitan or other alcohols, ⁇ ethers, for example ethoxylated alcohols, ethoxylated lanolin, ethoxylated polysiloxanes, propoxylated POE ethers and alkyl polyglycosides such as lauryl glucoside, decyl glycoside and cocoglycoside
  • alkyl polyglucosides are used as nonionic surfactants, decylglucoside, laurylglucoside, cocoglucoside being particularly preferred according to the invention. It is advantageous according to the invention to choose a combination of anionic and nonionic surfactants in which the weight ratio of anionic to nonionic surfactants is between 2: 5 to 5: 2. Weight ratios of 5: 3 and 3.5: 4 are preferred, and 2.5: 3 (anionic surfactants to nonionic surfactants) is very particularly preferred.
  • a particularly preferred embodiment according to the invention is the combination of sodium cocoyl glutamate and lauryl and / or decyl glucoside.
  • the substrates according to the invention contain preservatives in the cleaning preparation with which they are impregnated.
  • Advantageous preservatives for the purposes of the present invention are, for example, formaldehyde releasers (such as, for example, DMDM hydantoin, which is available, for example, from Lonza under the trade name Glydant TM), iodopropyl butyl carbamates (for example those under the trade names Glycacil-L, Glycacil -S available from Lonza and / or Dekaben LMB from Jan Dekker), parabens (ie alkyl p-hydroxybenzoate such as methyl, ethyl, propyl and / or butyl paraben), phenoxyethanol, ethanol, benzoic acid and the like.
  • the preservation system usually also advantageously includes preservation aids, such as, for example, octoxyglycerol, glycine soya, etc.
  • preservation aids
  • preservatives or preservation aids such as dibromodicyanobutane (2-bromo-2-bromomethylglutarodinitrile), phenoxyethanol, 3-iodo-2-propynylbutylcarbamate, 2-bromo-2-nitro-propane-1,3-diol, imidazolidinyl - urea, 5-chloro-2-methyl-4-isothiazolin-3-one, 2-chloroacetamide, benzalkonium chloride, benzyl alcohol.
  • dibromodicyanobutane (2-bromo-2-bromomethylglutarodinitrile)
  • phenoxyethanol 3-iodo-2-propynylbutylcarbamate
  • 2-bromo-2-nitro-propane-1,3-diol imidazolidinyl - urea
  • imidazolidinyl - urea 5-chloro-2-methyl-4-isothiazolin-3-one
  • the cleaning preparation of the substrates according to the invention contains further cosmetic and / or dermatological active ingredients, auxiliaries and / or additives.
  • the cleaning preparation according to the invention can preferably contain one or more oil phases in addition to one or more water phases and can be present, for example, in the form of W / O, O W, W / O / W or O / W / O emulsions.
  • Such formulations can preferably also be a microemulsion (e.g. a PIT emulsion).
  • the cleaning preparations according to the invention can optionally contain the additives customary in cosmetics, for example perfume, dyes, antimicrobial substances, lipid-replenishing agents, complexing and sequestering agents, plant extracts, vitamins, active substances, bactericides, UV light protection filters, repellents, Self-tanners, depigmenting agents, pigments that have a coloring effect, softening, moisturizing and / or moisturizing substances, or other usual components of a cosmetic or dermatological formulation such as emulsifiers, polymers, foam stabilizers, electrolytes, organic solvents or silicone derivatives.
  • the additives customary in cosmetics for example perfume, dyes, antimicrobial substances, lipid-replenishing agents, complexing and sequestering agents, plant extracts, vitamins, active substances, bactericides, UV light protection filters, repellents, Self-tanners, depigmenting agents, pigments that have a coloring effect, softening, moisturizing and / or moisturizing substances,
  • the cleaning preparation according to the invention can, as an aqueous solution or aqueous phase of an emulsion, not only water but also other ingredients according to the invention contain, for example alcohols, diols or polyols of low C number, and their ethers, preferably ethanol, isopropanol, propylene glycol, glycerol, ethylene glycol, ethylene glycol monoethyl or monobutyl ether, propylene glycol monomethyl, monoethyl or monobutyl ether, diethylene glycol monomethyl or monoethyl ether and analog products, furthermore low C number alcohols, for example ethanol, isopropanol, 1,2-propanediol and glycerol.
  • alcohols, diols or polyols of low C number, and their ethers preferably ethanol, isopropanol, propylene glycol, glycerol, ethylene glycol, ethylene glycol monoethyl or monobuty
  • moisturizers for the purposes of the present invention are, for example, glycerol, lactic acid and / or lactates, in particular sodium lactate, butylene glycol, propylene glycol, biosaccaride Gum-1, glycine soybean, ethylhexyloxyglycerol, pyrrolidonecarboxylic acid and urea.
  • polymeric moisturizers from the group of water-soluble and / or water-swellable and / or water-gelable polysaccharides.
  • hyaiuronic acid, chitosan and / or a fucose-rich polysaccharide are particularly advantageous.
  • Fucogel®1000 from the company SOLABIA S.A. is available.
  • Advantageous fat-soluble film formers are e.g. B., the film formers from the group of polymers based on polyvinylpyrrolidone (PVP)
  • Copolymers of polyvinylpyrrolidone for example the PVP hexadecene copolymer and the PVP eicosen copolymer, which are commercially available, are advantageous.
  • Drawings Antaron V216 and Antaron V220 are available from the GAF Chemicals Cooperation, as well as the Tricontayl PVP and the like.
  • Suitable film formers with at least one partially quaternized nitrogen group are preferably those which are selected from the group of substances which bear the name “Polyquaternium” according to the INCI nomenclature (International Nomenclature Cosmetic Ingredient), for example:
  • Polyquaternium-2 (Chemical Abstracts No. 63451-27-4, e.g. Mirapol® A-15)
  • Polyquaternium-5 (copolymer of the acrylamide and the ß-methacryloxyethyltrimethylammonium methosulfate, CAS No. 26006-22-4)
  • Polyquatium-6 (homopolymer of N, N-dimethyl-N-2-propenyl-2-propen-1-aminium chloride, CAS No. 26062-79-3, e.g. Merquat® 100
  • Polyquaternium-28 vinyipyrrolidone / methacrylamidopropyltrimethylammonium chloride copolymer e.g. Gafquat® HS-100
  • Polyquaternium-29 e.g. Lexquat® CH
  • Polyquaternium-44 copolymer quaternary ammonium salt consisting of
  • Vinyl pyrrolidones and quaternized imidazoline e.g. Luviquat.RTM
  • polymers polyquaternium-10, polyquaternium-22 and polyquaternium-44 have proven to be preferred and advantageous.
  • a particularly preferred film former according to the invention is Polyquarternium-10 (Ucare Polymer JR-125®, Ucare Polymer JR-400® from Amerchol).
  • the quaternized guar gum derivatives such as e.g. Guar hydroxypropyltrimonium chloride (Jaguar Excel®, Jaguar C 162® from Rhodia) and / or cellulose derivatives.
  • the oil phase of the cleaning preparations according to the invention is advantageously chosen from the group of polar oils, for example from the group of lecithins and fatty acid triglycerides, especially the triglycerol esters of saturated and / or unsaturated, branched and / or unbranched alkane carboxylic acids with a chain length of 8 to 24, in particular 12 to 18 carbon atoms.
  • the fatty acid triglycerides can for example be advantageously selected from the group of synthetic, semi-synthetic and natural oils, such as. B.
  • cocoglyceride olive oil, sunflower oil, soybean oil, peanut oil, rapeseed oil, almond oil, palm oil, coconut oil, castor oil, wheat germ oil, grape seed oil, safflower oil, evening primrose oil, macadamia nut oil and the like.
  • further advantageous polar oil components can also be selected from the group of esters from saturated and / or unsaturated, branched and / or unbranched alkane carboxylic acids with a chain length of 3 to 30 carbon atoms and saturated and / or unsaturated, branched and / or unbranched alcohols with a chain length of 3 to 30 carbon atoms and from the group of esters aromatic carboxylic acids and saturated and / or unsaturated, branched and / or unbranched alcohols with a chain length of 3 to 30 carbon atoms.
  • ester oils can then advantageously be selected from the group octyl palmitate, octyl co-coat, octyl isostearate, octyl dodeceyl myristate, octyl dodecanol, cetearyl isononanoate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl oleate, n-butyl stearate, n-stonolate, n-stonolate, n-stonyl-n-stonate, 2-ethylhexyl palmitate, 2-ethylhexyl laurate, 2-hexyldecyl stearate, 2-octyldodecyl palmitate, stearyl heptanoate, oleyl oleate, olerlerucate, erucyl oleate, erucylerucate
  • the oil phase can advantageously be selected from the group of dialkyl ethers and dialkyl carbonates.
  • pentylglykoldiheptanoat the one or more oil components from the group consisting of isoeicosane, neopentyl, propylene glycol dicaprylate / dicaprate, caprylic / capric / Diglyceryl- succinate, butylene glycol dicaprylate / dicaprate, cocoglycerides (z. B.
  • Myritol® 331 by Henkel 12 C , 13 alkyl lactate, di-C 12 - 13 -Alkyltartrat, triisostearin, Dipentaerythrityl hexa caprylate / Hexacaprat, Propylenglykolmonoisostearat, Tricaprylin, dimethyl isosorbide. It is particularly advantageous if the oil phase of the formulations according to the invention has a content of C 12 -is alkyl benzoate or consists entirely of this.
  • Advantageous oil components are also z.
  • Paraffinum Liquidum can also advantageously be used as an oil component.
  • Embodiments of the substrates according to the invention which are advantageous according to the invention are characterized in that the cleaning preparation oils for skin care and / or contains emulsions. It is preferred according to the invention if the cleaning preparation contains skin-care oils and / or emulsions in concentrations of less than 0.5% by weight.
  • the substrates according to the invention can be smooth or also surface structured. Surface-structured substrates are preferred according to the invention.
  • substrates in the form of cloths which consist of nonwoven, in particular of water-jet bonded and / or water-jet-embossed nonwoven.
  • the substrates can advantageously also be designed as a bulk, perforated fleece or mesh.
  • Such substrates can have macro embossments of any desired pattern.
  • the selection to be made depends on the one hand on the impregnation to be applied and on the other hand on the field of application in which the subsequent cloth is to be used.
  • embossed nonwovens are used, large cavities on the surface of the nonwoven and in the nonwoven make it easier for dirt and impurities to be absorbed if the impregnated cloth is run over the skin.
  • the cleaning effect can be increased many times over compared to non-embossed wipes.
  • the cloth has a weight of 20 to 120 g / m 2 , preferably 30 to 80 g / m 2, particularly preferably 40 to 60 g / m 2 (measured at 20 C C ⁇ 2 ° C and with a ' indoor air humidity of 65% ⁇ 5% for 24 hours).
  • the thickness of the substrate is preferably 0.2 mm to 2 mm, in particular 0.4 mm to 1.5 mm, very particularly preferably 0.6 mm to 0.9 mm.
  • All organic and inorganic fiber materials on a natural and synthetic basis can generally be used as starting materials for the nonwoven fabric of the cloth.
  • Examples include viscose, cotton, cellulose, jute, hemp, sisal, silk, wool, polypropylene, polyester, polyethylene terephthalate (PET), aramid, nylon, polyvinyl derivatives, polyurethanes, polylactide, polyhydroxyalkanoate, cellulose esters and / or polyethylene, as well as mineral fibers such as glass fibers or carbon fibers.
  • PET polyethylene terephthalate
  • aramid nylon
  • polyvinyl derivatives polyurethanes
  • polylactide polyhydroxyalkanoate
  • cellulose esters polyhydroxyalkanoate
  • cellulose esters polyhydroxyalkanoate
  • polyethylene such as glass fibers or carbon fibers.
  • mineral fibers such as glass fibers or carbon fibers.
  • the present invention is not limited to the materials mentioned, but a large number of other fibers can be used
  • the fibers consist of a mixture of 60% to 80% viscose with 40% to 20% PET, in particular 70% viscose and 30% PET.
  • 70% viscose and 30% PET is particularly advantageous.
  • Fibers made of high-strength polymers such as polyamide, polyester and / or highly stretched polyethylene are also particularly advantageous.
  • the fibers can also be colored in order to emphasize and / or increase the visual attractiveness of the fleece.
  • the fibers can additionally contain UV stabilizers and / or preservatives.
  • the fibers used to form the cloth preferably have a water absorption rate of more than 60 mm / [10 min] (measured with the EDANA test 10.1-72), in particular more than 80 mm / [10 min].
  • the fibers used to form the cloth preferably have a water absorption capacity of more than 5 g / g (measured with the EDANA test 10.1-72), in particular more than 8 g / g.
  • Cross direction> 20 preferably> 30 in the impregnated state
  • machine direction> 4 preferably> 60
  • Transverse direction preferably> 20
  • the elasticity of advantageous cloth is preferably 15% to 100%, preferably in the machine direction when dry 20% and 50%
  • Transverse direction 40% to 120%, preferred
  • Transverse direction 40% to 120%, preferred
  • the weight ratio of fleece to cleaning preparation is from 1: 0.5 to 1: 5 and particularly preferably from 1: 0.7 to 1: 3.
  • the process for producing the substrates according to the invention is according to the invention.
  • Impregnation solution is continuously fed to a scraper device (scraper bar, counter-rotating roller system, etc.). This is transferred to a passing substrate by the contact.
  • the liquid impregnation solution is sprayed onto the passing substrate.
  • the cloth material runs through a bath filled with the liquid impregnation solution or a complete roll of cloth is dipped into the impregnation solution.
  • the use of the wipe according to the invention as a cosmetic wipe for cleaning and care of the skin and / or hair is also in accordance with the invention.
  • the use of the cloth for cleaning the face or for “removing make-up” from decorative cosmetics is according to the invention.
  • the cloth according to the invention can be used in particular for cleaning sensitive skin, for example dry skin, the skin of babies or the elderly.

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Dermatology (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne un substrat imprégné d'une préparation de nettoyage présentant une viscosité de 1 à 3000 mPas, de préférence de 1 à 2500 mPas, de préférence de 1 à 2000 mPas. Ladite préparation contient a) un ou plusieurs tensioactifs anioniques et/ou non ioniques à une concentration de 0,1 à 15 % en poids, de préférence de 1 à 10 % en poids, b) de l'eau à une concentration de 40 à 99 % en poids, de préférence de 50 à 90 % en poids, de préférence de 60 à 90 % en poids, et c) un ou plusieurs conservateurs à une concentration de 0,01 à 3 % en poids, de préférence de 0,1 à 2 % en poids, les pourcentages étant respectivement indiqués par rapport au poids total de la préparation de nettoyage.
EP03766195A 2002-07-27 2003-07-16 Substrat de nettoyage impregne de tensioactifs Ceased EP1585802A2 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10234259 2002-07-27
DE10234259A DE10234259A1 (de) 2002-07-27 2002-07-27 Tensidgetränktes Reinigungssubstrat
PCT/EP2003/007735 WO2004013266A2 (fr) 2002-07-27 2003-07-16 Substrat de nettoyage impregne de tensioactifs

Publications (1)

Publication Number Publication Date
EP1585802A2 true EP1585802A2 (fr) 2005-10-19

Family

ID=30010456

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Application Number Title Priority Date Filing Date
EP03766195A Ceased EP1585802A2 (fr) 2002-07-27 2003-07-16 Substrat de nettoyage impregne de tensioactifs

Country Status (5)

Country Link
US (1) US20060128591A1 (fr)
EP (1) EP1585802A2 (fr)
JP (1) JP2006512424A (fr)
DE (1) DE10234259A1 (fr)
WO (1) WO2004013266A2 (fr)

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US20140212464A1 (en) * 2013-01-29 2014-07-31 The Procter & Gamble Company Composition For Wet Wipes That Enhances The Efficacy of Cleansing While Being Gentle To The Skin
JP4299273B2 (ja) * 2005-06-30 2009-07-22 花王株式会社 皮膚洗浄料
JP4299274B2 (ja) * 2005-06-30 2009-07-22 花王株式会社 皮膚洗浄料
JP4676915B2 (ja) * 2006-04-05 2011-04-27 花王株式会社 皮膚洗浄料
PT1985213E (pt) 2007-04-24 2010-10-21 Nestec Sa Método para a preparação de uma bebida cremosa à base de leite a partir de uma cápsula e kit para essa preparação
JP2008295837A (ja) * 2007-05-31 2008-12-11 Daio Paper Corp 湿潤拭取りシート
CA2923519A1 (fr) 2007-08-10 2009-02-19 Little Busy Bodies, Llc Mouchoir salin et procede pour le fabriquer et l'utiliser
US8273514B2 (en) * 2009-05-22 2012-09-25 Xerox Corporation Interfacial layer and coating solution for forming the same
US8278260B2 (en) * 2009-08-21 2012-10-02 S.C. Johnson & Son, Inc. Water-activated “green” cleaning wipe
US8283304B2 (en) * 2009-10-14 2012-10-09 S.C. Johnson & Son, Inc. Green compositions containing synergistic blends of surfactants and linkers
US8541356B2 (en) * 2009-11-23 2013-09-24 S.C. Johnson & Son, Inc. Water-activated “green” multi-functional wipe
DE102010060126A1 (de) * 2010-10-22 2012-04-26 Albaad Deutschland Gmbh Feuchtes Waschmitteltuch
KR101620967B1 (ko) 2015-02-25 2016-05-23 김용전 자동차용 세정제 조성물
WO2020103069A1 (fr) * 2018-11-22 2020-05-28 Beiersdorf Daily Chemical (Wuhan) Co. Ltd. Composition de nettoyage cosmetique
WO2024221216A1 (fr) * 2023-04-25 2024-10-31 3M Innovative Properties Company Composition de nettoyage

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See also references of WO2004013266A3

Also Published As

Publication number Publication date
DE10234259A1 (de) 2004-02-05
WO2004013266A3 (fr) 2006-08-17
US20060128591A1 (en) 2006-06-15
JP2006512424A (ja) 2006-04-13
WO2004013266A2 (fr) 2004-02-12

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