EP1582295A1 - Method and apparatus for cleaning, with a low environment impact, stony surfaces and the like - Google Patents
Method and apparatus for cleaning, with a low environment impact, stony surfaces and the like Download PDFInfo
- Publication number
- EP1582295A1 EP1582295A1 EP05004420A EP05004420A EP1582295A1 EP 1582295 A1 EP1582295 A1 EP 1582295A1 EP 05004420 A EP05004420 A EP 05004420A EP 05004420 A EP05004420 A EP 05004420A EP 1582295 A1 EP1582295 A1 EP 1582295A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cleaning
- sodium bicarbonate
- solution
- mixture
- product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 35
- 238000004140 cleaning Methods 0.000 title claims abstract description 26
- 239000000463 material Substances 0.000 claims abstract description 12
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims abstract description 10
- 230000009471 action Effects 0.000 claims abstract description 10
- 239000002245 particle Substances 0.000 claims abstract description 10
- 239000000126 substance Substances 0.000 claims abstract description 8
- 239000003973 paint Substances 0.000 claims abstract description 7
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims abstract description 5
- 235000017557 sodium bicarbonate Nutrition 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims description 16
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 230000001681 protective effect Effects 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 7
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 6
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 6
- 239000001095 magnesium carbonate Substances 0.000 claims description 6
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 6
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 5
- 239000011737 fluorine Substances 0.000 claims description 5
- 229910052731 fluorine Inorganic materials 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical compound O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 2
- 239000011707 mineral Substances 0.000 claims description 2
- 235000010755 mineral Nutrition 0.000 claims description 2
- 239000010453 quartz Substances 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 239000004575 stone Substances 0.000 claims 1
- 230000015556 catabolic process Effects 0.000 description 5
- 238000006731 degradation reaction Methods 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000004291 sulphur dioxide Substances 0.000 description 2
- 235000010269 sulphur dioxide Nutrition 0.000 description 2
- 238000004078 waterproofing Methods 0.000 description 2
- 208000012641 Pigmentation disease Diseases 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229940043430 calcium compound Drugs 0.000 description 1
- 239000011538 cleaning material Substances 0.000 description 1
- 230000005757 colony formation Effects 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000000254 damaging effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002939 oilproofing Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000019612 pigmentation Effects 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- -1 silicas Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- 230000005068 transpiration Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24C—ABRASIVE OR RELATED BLASTING WITH PARTICULATE MATERIAL
- B24C7/00—Equipment for feeding abrasive material; Controlling the flowability, constitution, or other physical characteristics of abrasive blasts
- B24C7/0046—Equipment for feeding abrasive material; Controlling the flowability, constitution, or other physical characteristics of abrasive blasts the abrasive material being fed in a gaseous carrier
- B24C7/0076—Equipment for feeding abrasive material; Controlling the flowability, constitution, or other physical characteristics of abrasive blasts the abrasive material being fed in a gaseous carrier the blasting medium being a liquid stream
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24C—ABRASIVE OR RELATED BLASTING WITH PARTICULATE MATERIAL
- B24C1/00—Methods for use of abrasive blasting for producing particular effects; Use of auxiliary equipment in connection with such methods
- B24C1/003—Methods for use of abrasive blasting for producing particular effects; Use of auxiliary equipment in connection with such methods using material which dissolves or changes phase after the treatment, e.g. ice, CO2
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24C—ABRASIVE OR RELATED BLASTING WITH PARTICULATE MATERIAL
- B24C11/00—Selection of abrasive materials or additives for abrasive blasts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/14—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas designed for spraying particulate materials
- B05B7/1404—Arrangements for supplying particulate material
- B05B7/1431—Arrangements for supplying particulate material comprising means for supplying an additional liquid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/14—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas designed for spraying particulate materials
- B05B7/1481—Spray pistols or apparatus for discharging particulate material
- B05B7/149—Spray pistols or apparatus for discharging particulate material with separate inlets for a particulate material and a liquid to be sprayed
Definitions
- the present invention relates to a method for cleaning stony surfaces and the like, with a low or small environment impact.
- sulphur dioxide is the main responsible of urban and historical degradation.
- microcracks are generated which, during icing and thawing cycles, because of an expansion and shrinking action, increase the thickness and depth of the mentioned microcracks.
- the atmospheric environment further comprises solid particle materials such as silicas, crystal sands and so on, subjecting the surfaces to an abrading action, with a consequent erosion of the exposed materials, which loose their surface resistance starting characteristics.
- solid particle materials such as silicas, crystal sands and so on
- the cleaning is conventionally performed by mechanical or chemical types of methods.
- a mechanical cleaning method provides to use abrasive wheels, sanding machines, hydrosanding devices, hydrocleaners, carbon dioxide apparatus.
- Chemical cleaning systems or methods conventionally provide to use interacting paint removing and cleaning materials, mainly consisting of solvents and surface active agent mixtures, which, mainly because the presence of the solvent, make difficult to properly control the environment ejection, thereby they cannot be used in a free environment and without a recovery possibility.
- the presence of organic compounds can originate undesired actions inside the stony object, thereby changing the original composition thereof.
- the aim of the present invention is to overcome the above mentioned problem, by providing a method for cleaning stony surfaces and the like, with a low environment impact, allowing to associate mechanical and chemical activities, thereby preventing any environment impact deriving from an use of dangerous volatile products.
- a main object of the present invention is to provide such a cleaning method which does not mechanically damage the surfaces being processed because of abrasion phenomena.
- Another object of the present invention is to provide such a cleaning method requiring a small operating power with a very reduced environment impact deriving from noise and used products, thereby said method can be carried out without the need of taking specific application protective measurements.
- Another object of the present invention is to provide such a cleaning method which, owing to its specifically designed features, is very reliable and safe in operation.
- Yet another object of the present invention is to provide such a cleaning method which can be easily carried out and which, moreover, is very competitive from a mere economic standpoint.
- a method for cleaning stony surfaces and the like with a low environment impact characterized in that said method comprises the step of ejecting, at a low pressure, on a surface to be processed a water and sodium bicarbonate solution to provide a physical-chemical action suitable to remove atmospheric particle materials, paint layers and mass deposits, such as alimentary gums.
- the method for cleaning stony surfaces and the like, with a low environment impact comprises the step of ejecting, at a low pressure, on the surface to be processed, a water and sodium bicarbonate solution, thereby providing a physical and chemical action suitable to remove atmospheric particle materials, paint layers and mass deposits such as alimentary gums and the like.
- Another mixture which could be used would comprise sodium bicarbonate, calcium carbonate, magnesium carbonate and silica oxide in an amount less than 0-1%.
- a further mixture which could be used, and having a controlled particle size, would comprise mineral materials free of silica and quartz, in particular calcium and magnesium compounds.
- a taking nozzle 2 is provided, forming a Venturi element, thereon is coupled an air delivery branch 3, having a main branch 4 communicating with a delivery nozzle 10 to which is further connected the powder inlet duct 11.
- a mouth or inlet 12 Downstream of the Venturi tube formed by the nozzle 10, a mouth or inlet 12 is moreover provided for supplying water at a hydraulic system pressure, so as to provide a solution or mixture, depending on the type of the used material.
- the oversaturated solution or mixture, at the outlet of the nozzle, will immediately loose the acquired propelling power, with a comparatively high reduction of the stony matrix, on which the cleaning product is ejected.
- Said protecting products are generally based on paraffins or fluorine resins and are typically made depending on their particular application.
- an anti-wording protective product i.e. a fluorine resin aqueous solution, suitable to facilitate the removal of the vandalic wordings.
- the product does not form films, does not change the color of the processed surface and allow the support to transpire with respect to the water steam, and moreover it also has good waterproofing characteristics.
- the product would be of a sacrificial type, since, in removing the wordings, also a protective layer is removed which, however, could be reapplied after the cleaning operation.
- Another protective product would comprise a paraffinic wax aqueous emulsion which, after application, will form a film on the coating surface, and, upon drying the film, will allow to obtain very good waterproofness properties without altering the transpiration capability.
- This product would allow to achieve a better water resistance and, moreover, will prevent atmospheric powder or dirt to adhere, which would frequently deteriorate the film aspect.
- the latter is also adapted to greatly facilitate the removal of the vandalic wordings.
- Yet another specific protective product, for horizontal surfaces would comprise fluorine resin dissolved in a solvent.
- Such a product does not form films and change the support color, and moreover has very good waterproofing and oilproofing characteristics, and is adapted to greatly facilitate the removal of alimentary gums and soil in general.
- a paint removal product for removing paints from the surfaces being processed, a paint removal product will be used, comprising a biodegradable cleaning component, to be applied by spraying or by padding and which could be reapplied in a case of a difficult to be removed wording.
- the invention provides a method for cleaning stony surfaces and the like with a low environment impact which, by combining a mechanical action and chemical action, allows to overcome all the drawbacks of the prior art, by providing a very satisfactory cleaning of the surfaces being processed, without abrading them, but carrying out a very efficient and delicate removal.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Cleaning By Liquid Or Steam (AREA)
- Processing Of Stones Or Stones Resemblance Materials (AREA)
- Devices For Post-Treatments, Processing, Supply, Discharge, And Other Processes (AREA)
- Cleaning In General (AREA)
- Road Signs Or Road Markings (AREA)
Abstract
Description
- The present invention relates to a method for cleaning stony surfaces and the like, with a low or small environment impact.
- As is known, the interaction of chemical compounds or elements, as generated by modern activities, and discharged into the atmosphere, provides conditions favoring degradation phenomena, of a sulphation and/or carbonation type, depending on the active principles comprising sulphur dioxide and carbon dioxide, in combination with oxygen of air and rainwater.
- Of the air-conveyed particle material depositing on exposed surfaces, both of a horizontal or of a vertical arrangement, sulphur dioxide is the main responsible of urban and historical degradation.
- Moreover, it is also known that all stony materials have a specific porosity.
- Because of mechanical stresses, such as, for example, urban traffic, microcracks are generated which, during icing and thawing cycles, because of an expansion and shrinking action, increase the thickness and depth of the mentioned microcracks.
- Thus, it should be pointed out that the above mentioned continuous action in a nearly unstoppable manner, thereby producing degradation phenomena, such as darkenings, non natural pigmentations, plaster and reinforcing iron explosions, vegetable colony formations and chalking.
- Moreover, the atmospheric environment further comprises solid particle materials such as silicas, crystal sands and so on, subjecting the surfaces to an abrading action, with a consequent erosion of the exposed materials, which loose their surface resistance starting characteristics.
- Another cause of the above mentioned degradation is that of social situations such as wordings, murales and soilings, which, because of different reasons, cause serious consequences, such as artistic work damagings and a consequent decay of urban zones in general.
- At present, the cleaning is conventionally performed by mechanical or chemical types of methods.
- In particular, a mechanical cleaning method provides to use abrasive wheels, sanding machines, hydrosanding devices, hydrocleaners, carbon dioxide apparatus.
- The above mentioned prior systems, if properly used, achieve the objective of properly cleaning the affected surface, but they are affected by intrinsic operation defects, such as an abrasion of the stony matrix which, very frequently, for common stoning materials used for coating facades, would increase natural porosity and microcrackings, thereby accelerating a degradation of the surface to be protected.
- Chemical cleaning systems or methods, on the other hand, conventionally provide to use interacting paint removing and cleaning materials, mainly consisting of solvents and surface active agent mixtures, which, mainly because the presence of the solvent, make difficult to properly control the environment ejection, thereby they cannot be used in a free environment and without a recovery possibility.
- Moreover, the presence of organic compounds can originate undesired actions inside the stony object, thereby changing the original composition thereof.
- Thus, the aim of the present invention is to overcome the above mentioned problem, by providing a method for cleaning stony surfaces and the like, with a low environment impact, allowing to associate mechanical and chemical activities, thereby preventing any environment impact deriving from an use of dangerous volatile products.
- Within the scope of the above mentioned aim, a main object of the present invention is to provide such a cleaning method which does not mechanically damage the surfaces being processed because of abrasion phenomena.
- Another object of the present invention is to provide such a cleaning method requiring a small operating power with a very reduced environment impact deriving from noise and used products, thereby said method can be carried out without the need of taking specific application protective measurements.
- Another object of the present invention is to provide such a cleaning method which, owing to its specifically designed features, is very reliable and safe in operation.
- Yet another object of the present invention is to provide such a cleaning method which can be easily carried out and which, moreover, is very competitive from a mere economic standpoint.
- According to one aspect of the present invention, the above mentioned aim and objects, as well as yet other objects, which will become more apparent hereinafter, are achieved by a method for cleaning stony surfaces and the like with a low environment impact, characterized in that said method comprises the step of ejecting, at a low pressure, on a surface to be processed a water and sodium bicarbonate solution to provide a physical-chemical action suitable to remove atmospheric particle materials, paint layers and mass deposits, such as alimentary gums.
- Further characteristics and advantages of the present invention will become more apparent hereinafter from the following detailed disclosure of a preferred, though not exclusive, embodiment of a method for cleaning stony surfaces and the like, with a low environment impact, which is illustrated, by way of an indicative but not limitative example, in the accompanying drawings, where:
- Figure 1 shows a diagram of the system used
for carrying out the cleaning method according to the
present invention;
and - Figure 2 schematically shows the delivery nozzle for delivering the cleaning product.
-
- With reference to the number references of the above mentioned figures, the method for cleaning stony surfaces and the like, with a low environment impact, comprises the step of ejecting, at a low pressure, on the surface to be processed, a water and sodium bicarbonate solution, thereby providing a physical and chemical action suitable to remove atmospheric particle materials, paint layers and mass deposits such as alimentary gums and the like.
- More specifically, it is possible to use, in addition to very pure sodium bicarbonate, at 99%, of suitable particle size, a sodium bicarbonate, calcium carbonate and magnesium carbonate mixture or blend.
- According to a further approach, it is possible to use a sodium bicarbonate, iron oxide mixture including an amount less than 0.16% of F2O3, calcium carbonate and magnesium carbonate.
- Another mixture which could be used would comprise sodium bicarbonate, calcium carbonate, magnesium carbonate and silica oxide in an amount less than 0-1%.
- A further mixture which could be used, and having a controlled particle size, would comprise mineral materials free of silica and quartz, in particular calcium and magnesium compounds.
- As is shown in figure 1, for conveying and ejecting the powders, which are held in a powder tank 1, a taking
nozzle 2 is provided, forming a Venturi element, thereon is coupled an air delivery branch 3, having amain branch 4 communicating with adelivery nozzle 10 to which is further connected thepowder inlet duct 11. - Downstream of the Venturi tube formed by the
nozzle 10, a mouth orinlet 12 is moreover provided for supplying water at a hydraulic system pressure, so as to provide a solution or mixture, depending on the type of the used material. - The oversaturated solution or mixture, at the outlet of the nozzle, will immediately loose the acquired propelling power, with a comparatively high reduction of the stony matrix, on which the cleaning product is ejected.
- Thus, with the above disclosed arrangement, the decreasing cleaning effect typical of bicarbonate will be held up to the end of the final washing and, at the end of the cleaning operations, on the cleaned and dried surface two layers of protecting product will be applied.
- Said protecting products are generally based on paraffins or fluorine resins and are typically made depending on their particular application.
- In particular, on vertical surfaces it would be possible to use an anti-wording protective product, i.e. a fluorine resin aqueous solution, suitable to facilitate the removal of the vandalic wordings.
- The product does not form films, does not change the color of the processed surface and allow the support to transpire with respect to the water steam, and moreover it also has good waterproofing characteristics.
- The product would be of a sacrificial type, since, in removing the wordings, also a protective layer is removed which, however, could be reapplied after the cleaning operation.
- Another protective product would comprise a paraffinic wax aqueous emulsion which, after application, will form a film on the coating surface, and, upon drying the film, will allow to obtain very good waterproofness properties without altering the transpiration capability.
- This product would allow to achieve a better water resistance and, moreover, will prevent atmospheric powder or dirt to adhere, which would frequently deteriorate the film aspect.
- Moreover, the latter is also adapted to greatly facilitate the removal of the vandalic wordings.
- Yet another specific protective product, for horizontal surfaces would comprise fluorine resin dissolved in a solvent.
- Such a product does not form films and change the support color, and moreover has very good waterproofing and oilproofing characteristics, and is adapted to greatly facilitate the removal of alimentary gums and soil in general.
- For removing paints from the surfaces being processed, a paint removal product will be used, comprising a biodegradable cleaning component, to be applied by spraying or by padding and which could be reapplied in a case of a difficult to be removed wording.
- From the above disclosure it should be apparent that the invention fully achieves the intended aim and objects.
- In fact, the invention provides a method for cleaning stony surfaces and the like with a low environment impact which, by combining a mechanical action and chemical action, allows to overcome all the drawbacks of the prior art, by providing a very satisfactory cleaning of the surfaces being processed, without abrading them, but carrying out a very efficient and delicate removal.
- The invention, as discloses, is susceptible to several modifications and variations, all of which will come within the scope of the invention.
Claims (14)
- A method for cleaning stony surfaces and the like, with a low environment impact, characterized in that said method comprises the step of ejecting, at a low pressure, on the surface being processed, a mixture comprising a water and sodium bicarbonate solution, thereby providing a physical-chemical action suitable to remove atmospheric particle materials, paint layers and mass deposits, such as alimentary gums.
- A method according to the preceding claim, characterized in that said mixture comprises a sodium bicarbonate solution, having a 99% very high pureness, and a set particle size.
- A method according to the preceding claims, characterized in that said mixture comprises a sodium bicarbonate, calcium carbonate and magnesium carbonate solution.
- A method according to one or more of the preceding claims, characterized in that said mixture comprises a sodium bicarbonate, iron oxide, calcium carbonate and magnesium carbonate solution.
- A method according to the preceding claim, characterized in that said iron oxide is present in an amount less than 0.016% as F2O3,
- A method according to one or more of the preceding claims, characterized in that said mixture comprises a sodium bicarbonate, calcium carbonate, magnesium carbonate and Si oxide solution.
- A method according to the preceding claim, characterized in that said Si oxide is present in an amount less than 0.1%.
- A method according to one or more of the preceding claims, characterized in that said mixture comprises mineral materials free of silica and quartz, in particular of calcium and magnesium type.
- A method according to one or more of the preceding claims, characterized in that said method further comprises the step of applying, after the processing by said solution, a protective product.
- A method according to the preceding claim, characterized in that said protective product comprises a fluorine resin aqueous emulsion.
- A method according to one or more of the preceding claims, characterized in that said protective product comprises a paraffinic wax aqueous emulsion.
- A method according to one or more of the preceding claims, characterized in that said method provides to apply a protective product for horizontal surfaces, comprising fluorine resins dissolved in a solvent.
- An apparatus for applying a mixture comprising a water and bicarbonate solutions of specifically designed particle size, characterized in that said apparatus comprises a granular product storing tank, at an outlet thereof a taking Venturi element is arranged, which is supplied with air delivered by an air inlet duct coupled to a delivery nozzle at a conveying tube for conveying to the outlet said granular product, downstream of said Venturi element for conveying said granular product a water inlet being moreover provided.
- A method for cleaning stone surfaces and the like, with a low environment impact, according to one or more of the preceding claims, and substantially as broadly disclosed and illustrated and for the intended aim and objects.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT000421A ITMI20040421A1 (en) | 2004-03-04 | 2004-03-04 | PROCEDURE FOR CLEANING STONE AND SIMILAR SURFACES WITH REDUCED ENVIRONMENTAL IMPACT |
| ITMI20040421 | 2004-03-04 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1582295A1 true EP1582295A1 (en) | 2005-10-05 |
| EP1582295B1 EP1582295B1 (en) | 2010-04-28 |
Family
ID=34878845
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP05004420A Expired - Lifetime EP1582295B1 (en) | 2004-03-04 | 2005-03-01 | Method and apparatus for cleaning, with a low environment impact, stony surfaces and the like |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP1582295B1 (en) |
| AT (1) | ATE465845T1 (en) |
| DE (1) | DE602005020871D1 (en) |
| IT (1) | ITMI20040421A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT201600097204A1 (en) * | 2016-09-28 | 2018-03-28 | Cristanini Spa | APPARATUS FOR SPRAYING AN ABRASIVE MIX TOWARDS A DELICATE SURFACE FOR THE REMOVAL OF WRITINGS, DRAWINGS OR GRAFFITI FROM THE SAME. |
| CN112691971A (en) * | 2020-12-10 | 2021-04-23 | 深圳信息职业技术学院 | Deep cleaning device and method for microporous resin |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT202200003008A1 (en) | 2022-02-17 | 2023-08-17 | Andrea Macchia | Cleaning system for cleaning vandalized painted surfaces of public art |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4583329A (en) * | 1984-02-09 | 1986-04-22 | Water Research Centre | High pressure jets |
| US4731125A (en) * | 1984-04-19 | 1988-03-15 | Carr Lawrence S | Media blast paint removal system |
| US5509971A (en) * | 1992-03-20 | 1996-04-23 | Church & Dwight Co., Inc. | Process for removing coatings from hard surfaces |
| US5527203A (en) * | 1992-08-28 | 1996-06-18 | Cook; Jack R. | Method for removal of surface contaminants from metal substrates |
| US5588901A (en) * | 1993-09-03 | 1996-12-31 | Yelapa Corporation | Cleaning method and apparatus utilizing sodium bicarbonate particles |
-
2004
- 2004-03-04 IT IT000421A patent/ITMI20040421A1/en unknown
-
2005
- 2005-03-01 AT AT05004420T patent/ATE465845T1/en not_active IP Right Cessation
- 2005-03-01 DE DE602005020871T patent/DE602005020871D1/en not_active Expired - Lifetime
- 2005-03-01 EP EP05004420A patent/EP1582295B1/en not_active Expired - Lifetime
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4583329A (en) * | 1984-02-09 | 1986-04-22 | Water Research Centre | High pressure jets |
| US4731125A (en) * | 1984-04-19 | 1988-03-15 | Carr Lawrence S | Media blast paint removal system |
| US5509971A (en) * | 1992-03-20 | 1996-04-23 | Church & Dwight Co., Inc. | Process for removing coatings from hard surfaces |
| US5527203A (en) * | 1992-08-28 | 1996-06-18 | Cook; Jack R. | Method for removal of surface contaminants from metal substrates |
| US5588901A (en) * | 1993-09-03 | 1996-12-31 | Yelapa Corporation | Cleaning method and apparatus utilizing sodium bicarbonate particles |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT201600097204A1 (en) * | 2016-09-28 | 2018-03-28 | Cristanini Spa | APPARATUS FOR SPRAYING AN ABRASIVE MIX TOWARDS A DELICATE SURFACE FOR THE REMOVAL OF WRITINGS, DRAWINGS OR GRAFFITI FROM THE SAME. |
| EP3300836A1 (en) * | 2016-09-28 | 2018-04-04 | Cristanini Spa | Apparatus for spraying an abrasive mixture towards a delicate surface for removing writings, drawings or graffiti therefrom |
| CN112691971A (en) * | 2020-12-10 | 2021-04-23 | 深圳信息职业技术学院 | Deep cleaning device and method for microporous resin |
| CN112691971B (en) * | 2020-12-10 | 2022-08-05 | 深圳信息职业技术学院 | Deep cleaning device and method for microporous resin |
Also Published As
| Publication number | Publication date |
|---|---|
| ATE465845T1 (en) | 2010-05-15 |
| ITMI20040421A1 (en) | 2004-06-04 |
| EP1582295B1 (en) | 2010-04-28 |
| DE602005020871D1 (en) | 2010-06-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5827114A (en) | Slurry blasting process | |
| US5575705A (en) | Slurry blasting process | |
| US5384990A (en) | Water blasting process | |
| EP0316264A2 (en) | Method and device for stripping enamel and for removing layers from surfaces | |
| EP1582295B1 (en) | Method and apparatus for cleaning, with a low environment impact, stony surfaces and the like | |
| JP6206898B2 (en) | Member surface blasting method | |
| JP2632141B2 (en) | Cleaning method | |
| JP2015016959A (en) | Automatic roller inclination type water washing device for falling object backing plate of endless belt conveyor | |
| HK1042668B (en) | Method for removing surface coatings | |
| JPS63156661A (en) | Wafer polishing device | |
| JP7025770B2 (en) | Blast treatment method to remove lichen on the surface of the member | |
| JP2006326819A (en) | Blast gun for peeling aging coating film | |
| KR20070000369A (en) | Substrate cleaning apparatus and substrate cleaning method | |
| JP5416461B2 (en) | Method for removing rust from steel structures | |
| JP7641615B2 (en) | Well cleaning method using dry ice | |
| JP4317114B2 (en) | Method of jet blasting steel structure or steel material | |
| JP6563099B1 (en) | Cutting method of steel fiber reinforced concrete | |
| JP2007007780A (en) | Blade part surface treatment method for cutting tool | |
| CN106738358A (en) | A kind of clearing up and processing method of preserved egg stone | |
| JP2002001249A (en) | Surface-treating system for concrete structure | |
| US20120298138A1 (en) | Process for cleaning surfaces using dry ice | |
| JPH10138141A (en) | Method and device for accelerating spraying dry ice in spraying device to peel and clean paint film by spraying dry ice | |
| CN114144281B (en) | Jet media and surface treatment method using the jet media | |
| JP2006326821A (en) | Aging coating film peeling method | |
| AU784029B2 (en) | A process for surface cleaning |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU MC NL PL PT RO SE SI SK TR |
|
| AX | Request for extension of the european patent |
Extension state: AL BA HR LV MK YU |
|
| 17P | Request for examination filed |
Effective date: 20051222 |
|
| AKX | Designation fees paid |
Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU MC NL PL PT RO SE SI SK TR |
|
| RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: BERTIN, ALESSANDRO |
|
| 17Q | First examination report despatched |
Effective date: 20080314 |
|
| GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
| GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
| GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
| AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU MC NL PL PT RO SE SI SK TR |
|
| REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
| REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: NV Representative=s name: BOVARD AG PATENTANWAELTE |
|
| REF | Corresponds to: |
Ref document number: 602005020871 Country of ref document: DE Date of ref document: 20100610 Kind code of ref document: P |
|
| REG | Reference to a national code |
Ref country code: NL Ref legal event code: VDEP Effective date: 20100428 |
|
| LTIE | Lt: invalidation of european patent or patent extension |
Effective date: 20100428 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100808 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100428 Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100428 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100428 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100428 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100428 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100828 Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100428 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100428 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100729 Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100428 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100830 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100428 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100428 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100428 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100428 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100428 Ref country code: BE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100428 |
|
| PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100428 |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: PFA Owner name: DEKOS S.R.L. Free format text: DEKOS S.R.L.#VIA RIVOLI, 2#20121 MILANO (IT) -TRANSFER TO- DEKOS S.R.L.#VIA RIVOLI, 2#20121 MILANO (IT) |
|
| 26N | No opposition filed |
Effective date: 20110131 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CH Payment date: 20110331 Year of fee payment: 7 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20110331 |
|
| GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20110301 |
|
| REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST Effective date: 20111130 |
|
| REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20110301 Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20111001 Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20110331 |
|
| REG | Reference to a national code |
Ref country code: DE Ref legal event code: R119 Ref document number: 602005020871 Country of ref document: DE Effective date: 20111001 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20110301 |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20120331 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20120331 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20110301 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100428 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100728 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100428 |