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EP1420753A2 - Base de creme pour produire des colorants capillaires - Google Patents

Base de creme pour produire des colorants capillaires

Info

Publication number
EP1420753A2
EP1420753A2 EP02797613A EP02797613A EP1420753A2 EP 1420753 A2 EP1420753 A2 EP 1420753A2 EP 02797613 A EP02797613 A EP 02797613A EP 02797613 A EP02797613 A EP 02797613A EP 1420753 A2 EP1420753 A2 EP 1420753A2
Authority
EP
European Patent Office
Prior art keywords
cream base
amount
base according
surfactants
fatty acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP02797613A
Other languages
German (de)
English (en)
Inventor
Doris Oberkobusch
Horst Höffkes
Udo Erkens
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP1420753A2 publication Critical patent/EP1420753A2/fr
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair

Definitions

  • the present invention relates to a cream base for the production of hair colorants, which can be obtained by cold / cold production processes, as well as a process for the production of the cream bases and the use of these cream bases in hair colorants.
  • Hair dyes are mainly offered in the form of creams which contain the coloring components, eg the dye precursors in the case of oxidation hair dyes or the dyes in the case of substantive dyes.
  • the coloring cream is mixed with an H 2 O 2 -containing emulsion (developer emulsion) before use.
  • the coloring creams usually contain fatty alcohols, fatty alcohol ethoxylates, fatty acids or their esters as so-called consistency agents (fat phase).
  • other components are nonionic, anionic and / or amphoteric surfactants, neutralizing agents, perfume oils, antioxidants and care components such as silicone oils, protein hydrolyzates, cationic polymers etc.
  • the substances used as consistency agents only melt above 50 ° C to 60 ° C. It is therefore necessary that the fat phase is first melted in the production of customary coloring creams before the cream emulsion can be produced. The emulsion produced must then be carefully cooled.
  • Another manufacturing process for hair dye creams is known from WO98 / 51267, in which one first produces a PIT or microemulsion and in this stirs the dye components in the cold. Although this process saves the heating and cooling step directly in the production of coloring cream, the PIT emulsion is produced in the heat.
  • the object of the present invention was to provide cream bases which can be produced using so-called cold / cold processes and into which further components, e.g. coloring components, can be incorporated.
  • the cream base or the finished dye cream should have a sufficiently high viscosity and a suitable flow behavior after mixing with a developer emulsion, so that the mixture can be easily applied to the fibers to be colored and does not drip down. Furthermore, the cream should have a largely constant viscosity in the temperature range between 20 ° C and 45 ° C, so that even when the cream is heated to skin temperature (approx. 32 ° C) there is no dripping and the emulsion remains stable at higher storage temperatures.
  • cream bases which are suitable for the production of coloring creams can be produced by means of cold / cold processes if they contain a combination of fatty alcohols, anionic and / or nonionic surfactants, fatty acids / fatty acid soaps in defined quantity ranges and, if appropriate, further ingredients ,
  • the present invention accordingly relates to a cream base which can be prepared by means of a cold / cold process, comprising a) 1 to 15% by weight of straight-chain or branched C 8 -C 22 alcohols or alcohol mixtures which are liquid at temperatures above 15 ° C. or in the other components of the formulation are soluble, b) 0.1 to 10% by weight of anionic and / or nonionic surfactants, c) 2 to 15% by weight of C 16 -C 22 fatty acid / fatty acid soap, and d) any other usual ingredients and water to 100% by weight.
  • the cream bases according to the invention can be produced by means of cold / cold processes.
  • the coloring components are easy to incorporate and the cream obtained has a sufficient viscosity after mixing with the developer emulsion and maintains its viscosity even at the application temperature and at elevated storage temperatures.
  • the individual starting components are not heated.
  • the components usually have room temperature, which also means slightly elevated temperatures up to 35 ° C.
  • the alcohols or alcohol mixtures used as component a) can be straight-chain or branched and have 8 to 22 carbon atoms. They can be native or synthetic. Those alcohols or alcohol mixtures which, in combination with the compounds of component b), have a thickening effect are preferably used.
  • the alcohols of component a) are preferably present in the cream base according to the present invention in an amount of 1 to 10% by weight and particularly preferably in an amount of 3 to 8% by weight, based on the finished cream base.
  • the anionic surfactants of component b) are preferably selected from C 8 - C 22 -Fettalkoholethersulfaten having 2 to 10 ethylene oxide units in the molecule, salts of C 8 - C 22 -Fettalkoholethercarbonklaren, C 8 -C 22 alkyl sulfates, C 8 -C 22 - Alkyl sulfonates, salts of N-acylated amino acids with 8 to 22 carbon atoms in the acyl radical, such as N-acylated glutamic acid or aspartic acid, and mixtures thereof.
  • the preferred nonionic surfactants used are, in particular, the alkoxylated, preferably ethoxylated, C 8 -C 22 fatty alcohols, alkoxylated, preferably ethoxylated, triglycerides and mixtures thereof.
  • Component b) is preferably used in an amount of 0.1 to 7.5% by weight, particularly preferably 3 to 6% by weight, based on the finished cream base.
  • the cream base according to the invention contains a fatty acid or fatty acid soap or a fatty acid or fatty acid soap mixture, it being possible to use linear or branched, saturated or unsaturated fatty acids or fatty acid soaps.
  • Components c) can be added in the form of the acids which are neutralized in the course of the production process or as neutralized fatty acid soaps.
  • Fatty acids which are preferably used are isostearic acid, oleic acid, elaidic acid or their mixtures or their alkali or ammonium soaps.
  • the fatty acid or fatty acid soap is preferably in an amount of 2 to 10% by weight, particularly preferably in an amount of 3 to 7 wt .-%, based on the finished cream base.
  • the cream base according to the invention contains further surfactants selected from zwitterionic surfactants, ampholytic surfactants, dialkanolamides, amine oxides and / or polyethylene glycol ethers. These components can be present in the cream base according to the invention in an amount of 0.1 to 10% by weight, preferably in an amount of 1.5 to 4.5% by weight, based on the finished cream base.
  • Zwitterionic surfactants are surface-active compounds that contain at least one quaternary ammonium group and at least one -COO () - or -SO 3 H group in the molecule.
  • Particularly suitable zwitterionic surfactants are the so-called betaines such as the N-alkyl-N, N-dimethylammonium glycinate, for example the coconut alkyl dimethylammonium glycinate, N-acylaminopropyl-NN-dimethylammonium glycinate, for example the coconut acylaminopropyl dimethylammonium glycinate, and 2-alkyl -3-carboxymethyl-3-hydroxyethyl-imidazolines each having 8 to 18 carbon atoms in the alkyl or acyl group and the cocoacylaminoethylhydroxyethylcarboxymethylglycinate.
  • a preferred zwitterionic surfactant is the fatty acid amide derivative known under the CTFA name
  • Ampholytic surfactants are surface-active compounds which, in addition to a C 8-18 -alkyl or -acyl group, contain at least one free amino group and at least one -COOH or -SO 3 H group in the molecule and are capable of forming internal salts are.
  • ampholytic surfactants are N-alkylglycine, N-alkylpropionic acid, N-alkylaminobutyric acid, N-alkyliminodipropionic acid, N-hydroxyethyl-N-alkylamidopropylglycine, N-alkyltaurine, N-alkyl sarcosine, 2-alkylaminopropionic acid and alkylaminoacetic acid, each with approximately 8 to 18 carbon atoms in the alkyl group.
  • Particularly preferred ampholytic surfactants are N-coconut alkyl aminopropionate, coconut acylaminoethyl aminopropionate and C 12-18 acyl sarcosine.
  • a combination of fatty alcohol sulfates of component b) and the other surfactants can have a thickening effect on the cream base according to the invention.
  • a combination of C 8 -C 18 fatty alcohol ether sulfates with 2 to 4 EO and zwitterionic surfactants, in particular cocamidopropyl betaine is used.
  • customary thickening additives can additionally be used in amounts of up to 10% by weight, preferably from 0.1 to 10% by weight and particularly preferably from 0.5 to 5% by weight.
  • the viscosity of the agents can be measured using customary standard methods (for example Brookfield RVD-VII viscometer at 20 rpm and 20 ° C., spindle 3) and is preferably in the range from 100 to 5000 mPas.
  • Preferred liquid to gel form agents have viscosities of 200 to 4000 mPas, values between 400 and 2000 mPas being particularly preferred.
  • Suitable thickeners are inorganic or polymeric organic compounds. Mixtures of several thickeners can also be used.
  • the inorganic thickeners include, for example, polysilicic acids, clay minerals such as montmorillonites, zeolites, silicas and clays such as bentonites.
  • the organic thickeners come from the groups of natural polymers, modified natural polymers and fully synthetic polymers.
  • Polymers derived from nature that are used as thickeners are, for example, agar agar, carrageenan, alginates, xanthan gum, karaya gum, tragacanth, gum arabic, alginates, pectins, polyoses, guar flour, locust bean gum, linseed gums, dextrans , Starch fractions and derivatives such as amylose, amylopectin and dextrins, gelatin and casein.
  • Modified natural products mainly come from the group of modified starches and celluloses, examples include carboxymethyl cellulose and other cellulose ethers, such as hydroxyethyl and hydroxypropyl cellulose, and core meal ether.
  • thickeners that are widely used in a wide variety of applications are the fully synthetic polymers such as polyacrylic and polymethacrylic compounds, vinyl polymers such as polyvinyl alcohol, polycarboxylic acids, polyethers, polyimines, polyamides and polyurethanes.
  • Anionic and cationic polymers preferably copolymers of anionic and nonionic monomers, may also be mentioned as further examples of fully synthetic polymers, those consisting of 70 to 55 mol% of acrylamide and 30 to 45 mol% of 2-acrylamido-2-methylpropanesulfonic acid, the sulfonic acid group being whole or partially as sodium, potassium, ammonium, mono- or triethanolammonium salt exist, are particularly preferred.
  • Thickeners from the substance classes mentioned are commercially available and are sold, for example, under the trade names Acusol ® -820 (methacrylic acid (stearyl alcohol-20-EO) ester-acrylic acid copolymer, 30% strength in water, Rohm & Haas), Dapral ® -GT -282-S (alkyl polyglycol ether, Akzo), Deuterol ® polymer 11
  • a further increase in viscosity can also be achieved by adding electrolytes (neutral salts).
  • electrolytes neutral salts
  • alkali halides in particular chlorides, alkali hydrogen carbonates, alkali sulfates and alkali phosphates, sodium chloride and sodium sulfate being particularly preferred.
  • the cream base according to the invention is particularly suitable for the production of coloring creams which can be used for dyeing fibers containing keratin.
  • Keratin-containing fibers are wool, furs, feathers and in particular human hair.
  • the colorants according to the invention can also be used for dyeing other natural fibers, such as, for. As cotton, jute, sisal, linen or silk, modified natural fibers, such as. B. regenerated cellulose, nitro, alkyl or hydroxyalkyl or acetyl cellulose and synthetic fibers such as. B. polyamide, polyacrylonitrile, polyurethane and polyester fibers can be used.
  • any coloring components can be incorporated into the cream base, for example direct dyes or Oxidation dye precursors which, as already explained above, form the oxidation dyes by oxidatively coupling one or more developer components to one another or with one or more coupler components on the hair.
  • M-Phenylenediamine derivatives, naphthols, resorcinol and resorcinol derivatives, pyrazolones, m-aminophenols and substituted pyridine derivatives are generally used as coupler components.
  • coupler substances are ⁇ -naphthol, 1, 5-, 2,7- and 1, 7-dihydroxynaphthalene, 5-amino-2-methylphenol, m-aminophenol, resorcinol, resorcinomino methyl ether, m-phenylenediamine, 2,4 -Diaminophenoxyethanol, 2-amino-4- (2'-hydroxyethylamino) -anisole (Lehmanns Blau), 1-phenyl-3-methyl-pyrazol-5-one, 2,4-dichloro-3-aminophenol, 1, 3-bis (2 ', 4'-diaminophenoxy) propane, 2-chlororesorcinol, 4-chlororesorcinol, 2-chloro-6-methyl-3-aminophenol, 2-methylresorcinol, 5-methylresorcinol, 3-amino-6- methoxy-2-methylamino-pyridine and 3,5-diamino-2,6-dimethoxypyridine.
  • the cream base can be conventional substantive dyes, e.g. B. from the group of nitrophenylenediamines, nitroaminophenols, anthraquinones or indophenols, such as. B. under the international names or trade names HC Yellow 2, HC Yellow 4, HC Yellow 6, Basic Yellow 57, Disperse Orange 3, HC Red 3, HC Red BN, Basic Red 76, HC Blue 2, Disperse Blue 3, Basic Blue 99, HC Violet 1, Disperse Violet 1, Disperse Violet 4, Disperse Black 9, Basic Brown 16 and Basic Brown 17 known compounds as well as picramic acid 2-amino-6-chloro-4-nitrophenol, 4-amino-2-nitrodiphenylamine -2'-carboxylic acid, 6-nitro-1, 2,3,4-tetrahydroquinoxaline, 4-N-ethyl-1, 4-bis- (2-hydroxyethylamino) -2-nitrobenzene hydrochloride and 1- Methyl-3-nitro-4- (2-hydroxyethyl
  • the preparations according to the invention can furthermore also contain naturally occurring dyes, such as those contained in henna red, henna neutral, henna black, chamomile flowers, sandalwood, black tea, rotten bark, sage, blue wood, madder root, catechu, sedre and alkanna root.
  • naturally occurring dyes such as those contained in henna red, henna neutral, henna black, chamomile flowers, sandalwood, black tea, rotten bark, sage, blue wood, madder root, catechu, sedre and alkanna root.
  • cream bases produced according to the invention can contain cationic surfactants as well as active ingredients, auxiliaries and additives.
  • Examples of the cationic surfactants which can be used in the cream bases according to the invention are in particular quaternary ammonium compounds.
  • Ammonium halides such as alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, for.
  • the quaternized protein hydrolyzates are further cationic surfactants which can be used according to the invention.
  • cationic silicone oils such as, for example, the commercially available products Q2-7224 (manufacturer: Dow Corning; a stabilized trimethylsilylamodimethicone), Dow Corning 929 emulsion (containing a hydroxyl-amt ⁇ -mO-modified silicone, which is also referred to as amodimethicone) will), SM-2059 (manufacturer: General Electric), SLM-55067 (manufacturer: Wacker) and Abil ® -Quat 3270 and 3272 (manufacturer: Th. Goldschmidt; diquaternary polydimethylsiloxanes, Quaternium-80).
  • alkylamidoamines especially fatty acid amidoamines such as the stearylamidopropyldimethylamine available under the name Tego Amid ® S 18, are notable for their good biodegradability. Also very good biodegradability are quaternary Estereducatingen, so-called “esterquats”, kyldialkoyloxyalkylammoniummethosulfate such as those sold under the trademark Stepantex ® Methylhydroxyal-.
  • a suitable cationic surfactant quaternary sugar derivative is the commercial product Glucquat ® 100, according to CTFA nomenclature a "lauryl methyl Gluceth-10 Hydroxypropyl Dimonium Chloride”.
  • nonionic polymers such as vinylpyrrolidone / vinyl acrylate copolymers, polyvinylpyrrolidone and vinylpyrrolidone ⁇ inylacetate copolymers and polysiloxanes
  • cationic polymers such as quaternized cellulose ethers, polysiloxanes with quaternary groups, dimethyldiallylammonium chloride, dimethyldioxylammonium chloride, monolamino-dimethylchloride-monolamino-chloride, dimethyldiallylammonium chloride, dimethyldioxylammonium chloride, dimethyldiallylammonium chloride, monomethyl-ammonium chloride, dimethyldiallylammonium chloride, monomethyl-ammonium chloride, dimethyldiallylammonium chloride, monomethyl-ammonium chloride, dimethyldiallylammonium chloride, -methyl-ammonium chloride-dimethyl-monolamyl-ammonium chloride -
  • Protein hydrolyzates in particular elastin, collagen, keratin, milk protein, soy protein and wheat protein hydrolyzates, their condensation products with fatty acids and quaternized protein hydrolyzates, perfume oils, dimethyl isosorbide and cyclodextrins,
  • Solubilizers such as ethanol, isopropanol, ethylene glycol, propylene glycol, glycerin and diethylene glycol,
  • Anti-dandruff agents such as piroctone olamine and zinc omadine, other substances for adjusting the pH value,
  • Active ingredients such as panthenol, pantothenic acid, allantoin, pyrrolidone carboxylic acids and their salts, plant extracts and vitamins, cholesterol, Light stabilizers,
  • Consistency enhancers such as sugar esters, polyol esters or polyol alkyl ethers, fats and waxes such as walrus, beeswax, montan wax, paraffins, fatty alcohols and fatty acid esters, fatty acid alkanolamides,
  • Swelling and penetration substances such as glycerol, propylene glycol monoethyl ether, carbonates, hydrogen carbonates, guanidines, ureas and primary, secondary and tertiary phosphates, imidazoles, tannins, pyrrole, opacifiers such as latex,
  • Pearlescent agents such as ethylene glycol mono- and distearate
  • Blowing agents such as propane-butane mixtures, N 2 O, dimethyl ether, CO 2 and air as well as antioxidants.
  • Suitable metal salts are e.g. B. formates, carbonates, halides, sulfates, butyrates, valerates, capronates, acetates, lactates, glycolates, tartrates, citrates, gluconates, propionates, phosphates and phosphonates of alkali metals, such as potassium, sodium or lithium, alkaline earth metals, such as magnesium, Caicium, strontium or barium, or of aluminum, manganese, iron, cobalt, copper or zinc, with sodium acetate, lithium bromide, calcium bromide, calcium gluconate, zinc chloride, zinc sulfate, magnesium chloride, magnesium sulfate, ammonium carbonate, chloride and acetate being preferred.
  • These salts are preferably present in an amount of 0.03 to 65, in particular 1 to 40, mmol based on 100 g of the ready-
  • the pH of the ready-to-use coloring preparations is usually between 2 and 12, preferably between 4 and 10.
  • Another object of the present invention is a process for the preparation of a cream base, which is suitable as a cream base for hair colorants, in which by means of cold / cold process in a manner known per se an emulsion of components a) 1 to 15 wt .-% straight-chain or branched C 8 -C 22 alcohols or alcohol mixtures which are liquid at temperatures above 15 ° C or are soluble in the other formulation components, b) 0.1 to 10% by weight of anionic and / or nonionic surfactants, c) 2 to 15 wt .-% C ⁇ 6 -C 22 fatty acid / fatty acid soap and d) if necessary, other conventional ingredients and water to 100 wt .-% is produced.
  • the individual components should be liquid at room temperature, preferably at temperatures above 15 ° C., or be soluble in the other recipe components.
  • the viscosity can be adjusted by adding suitable thickeners or by using a special combination of surfactants, such as a combination of anionic or nonionic surfactants with a thickening effect, with zwitterionic surfactants, amphoteric surfactants, alkanolamides or amine oxides. Creams with sufficient viscosity are obtained, the viscosity of which does not decrease or only decreases to a minor extent even when heated.
  • the emulsion was prepared using a toothed disk stirrer at room temperature (1000-2000 rpm).
  • Cetiol ® OE dicapryl ether (commercially available from Cognis Germany
  • Sepigel ® 305 copolymer made from acrylamide and 2-acrylamido-2-methylpropanesulfonic acid (INCI name: polyacrylamide (and)
  • Ci3-C 14 -lsoparaff ⁇ n (and) Laureth-7) (commercially available from

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Abstract

L'invention concerne une base de crème pouvant être produite par un procédé froid/froid et contenant a) 1 à 15 % en poids de mélanges d'alcools ou d'alcools C8-C22 à chaîne droite ou ramifiés, solubles dans les autres composants de la formulation ou liquides à des températures supérieures à 15 DEG C, b) 0,1 à 10 % en poids de tensioactifs anioniques et/ou non ioniques, c) 2 à 15 % en poids de savon d'acide gras / d'acide gras C16-C22 et d) éventuellement d'autres ingrédients classiques et de l'eau dans une proportion telle que la somme de tous les composants représente 100 %. Des composants colorants peuvent être facilement intégrés et la crème obtenue présente une viscosité suffisante après mélange avec l'émulsion de développement et conserve sa viscosité, y compris à la température d'application et en présence de températures de stockage élevées.
EP02797613A 2001-09-01 2002-08-23 Base de creme pour produire des colorants capillaires Ceased EP1420753A2 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10143024 2001-09-01
DE2001143024 DE10143024A1 (fr) 2001-09-01 2001-09-01 Base de creme pour produire des colorants capillaires
PCT/EP2002/009438 WO2003020229A2 (fr) 2001-09-01 2002-08-23 Base de creme pour produire des colorants capillaires

Publications (1)

Publication Number Publication Date
EP1420753A2 true EP1420753A2 (fr) 2004-05-26

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EP02797613A Ceased EP1420753A2 (fr) 2001-09-01 2002-08-23 Base de creme pour produire des colorants capillaires

Country Status (4)

Country Link
EP (1) EP1420753A2 (fr)
AU (1) AU2002333688A1 (fr)
DE (1) DE10143024A1 (fr)
WO (1) WO2003020229A2 (fr)

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US11937602B2 (en) 2017-09-26 2024-03-26 Ecolab Usa Inc. Solid acid/anionic antimicrobial and virucidal compositions and uses thereof
US12329157B2 (en) 2019-12-16 2025-06-17 Ecolab Usa Inc. Anionic surfactant impact on virucidal efficacy

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DE102004025281B4 (de) * 2004-05-19 2008-09-04 Henkel Ag & Co. Kgaa Verfahren zur Herstellung von Mitteln zur Färbung keratinischer Fasern
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EP2277500A1 (fr) * 2009-07-22 2011-01-26 KPSS-Kao Professional Salon Services GmbH Composition et procédé de coloration des cheveux
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BR112015002215B1 (pt) 2012-08-02 2019-10-15 L'oreal Composição para tintura das fibras queratínicas humanas, processo para tintura das fibras queratínicas humanas e dispositivo com compartimentos múltiplos
FR2994091B1 (fr) 2012-08-02 2014-08-01 Oreal Composition de coloration comprenant de la gomme de guar non ionique ou l'un de ses derives non ionique, procede et dispositif
BR112015002202B1 (pt) * 2012-08-02 2019-10-22 Oreal composição para a tintura das fibras queratínicas, processo para a tintura das fibras queratínicas e dispositivo
FR2994085B1 (fr) * 2012-08-02 2014-08-01 Oreal Composition de coloration comprenant au moins un corps gras, au moins un agent oxydant et au moins un tensioactif non ionique, anionique et amphotere
FR2994090B1 (fr) * 2012-08-02 2014-10-17 Oreal Composition de coloration a base de colorants directs comprenant un corps gras, un polymere cationique, un agent oxydant, des tensioactifs anioniques, amphoteres et non ioniques, procede de coloration et dispositif appropries
FR3024359B1 (fr) * 2014-08-01 2016-07-15 Oreal Composition comprenant un copolymere d'amps®, un amidon modifie ou non modifie et un precurseur de colorant d'oxydation

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US11950595B2 (en) 2017-09-26 2024-04-09 Ecolab Usa Inc. Acid/anionic antimicrobial and virucidal compositions and uses thereof
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WO2003020229A3 (fr) 2003-12-18
DE10143024A1 (fr) 2003-03-20

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