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EP1323809A2 - Réacteur à lit descendant à co-courant - Google Patents

Réacteur à lit descendant à co-courant Download PDF

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Publication number
EP1323809A2
EP1323809A2 EP02027458A EP02027458A EP1323809A2 EP 1323809 A2 EP1323809 A2 EP 1323809A2 EP 02027458 A EP02027458 A EP 02027458A EP 02027458 A EP02027458 A EP 02027458A EP 1323809 A2 EP1323809 A2 EP 1323809A2
Authority
EP
European Patent Office
Prior art keywords
shaft
gas
lock
shaft body
feed material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP02027458A
Other languages
German (de)
English (en)
Other versions
EP1323809B1 (fr
EP1323809A3 (fr
Inventor
Jürgen Möser
Manfred Schulz
Thomas Flick
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Smile Beteiligungs GmbH
Original Assignee
Umweltkontor Renewable Energy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Umweltkontor Renewable Energy AG filed Critical Umweltkontor Renewable Energy AG
Priority to SI200230833T priority Critical patent/SI1323809T1/sl
Publication of EP1323809A2 publication Critical patent/EP1323809A2/fr
Publication of EP1323809A3 publication Critical patent/EP1323809A3/fr
Application granted granted Critical
Publication of EP1323809B1 publication Critical patent/EP1323809B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02Fixed-bed gasification of lump fuel
    • C10J3/20Apparatus; Plants
    • C10J3/32Devices for distributing fuel evenly over the bed or for stirring up the fuel bed
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02Fixed-bed gasification of lump fuel
    • C10J3/06Continuous processes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02Fixed-bed gasification of lump fuel
    • C10J3/06Continuous processes
    • C10J3/08Continuous processes with ash-removal in liquid state
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02Fixed-bed gasification of lump fuel
    • C10J3/06Continuous processes
    • C10J3/10Continuous processes using external heating
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02Fixed-bed gasification of lump fuel
    • C10J3/06Continuous processes
    • C10J3/14Continuous processes using gaseous heat-carriers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02Fixed-bed gasification of lump fuel
    • C10J3/20Apparatus; Plants
    • C10J3/22Arrangements or dispositions of valves or flues
    • C10J3/24Arrangements or dispositions of valves or flues to permit flow of gases or vapours other than upwardly through the fuel bed
    • C10J3/26Arrangements or dispositions of valves or flues to permit flow of gases or vapours other than upwardly through the fuel bed downwardly
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • F23G5/027Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
    • F23G5/0276Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage using direct heating
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • F23G5/04Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment drying
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/24Incineration of waste; Incinerator constructions; Details, accessories or control therefor having a vertical, substantially cylindrical, combustion chamber
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/44Details; Accessories
    • F23G5/46Recuperation of heat
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B1/00Shaft or like vertical or substantially vertical furnaces
    • F27B1/02Shaft or like vertical or substantially vertical furnaces with two or more shafts or chambers, e.g. multi-storey
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B1/00Shaft or like vertical or substantially vertical furnaces
    • F27B1/10Details, accessories or equipment specially adapted for furnaces of these types
    • F27B1/16Arrangements of tuyeres
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B1/00Shaft or like vertical or substantially vertical furnaces
    • F27B1/10Details, accessories or equipment specially adapted for furnaces of these types
    • F27B1/20Arrangements of devices for charging
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D1/00Casings; Linings; Walls; Roofs
    • F27D1/0003Linings or walls
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/30Arrangements for extraction or collection of waste gases; Hoods therefor
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00Charging; Discharging; Manipulation of charge
    • F27D3/0025Charging or loading melting furnaces with material in the solid state
    • F27D3/0032Charging or loading melting furnaces with material in the solid state using an air-lock
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D7/00Forming, maintaining or circulating atmospheres in heating chambers
    • F27D7/06Forming or maintaining special atmospheres or vacuum within heating chambers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2200/00Details of gasification apparatus
    • C10J2200/15Details of feeding means
    • C10J2200/156Sluices, e.g. mechanical sluices for preventing escape of gas through the feed inlet
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0903Feed preparation
    • C10J2300/0909Drying
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/0943Coke
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0956Air or oxygen enriched air
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983Additives
    • C10J2300/0996Calcium-containing inorganic materials, e.g. lime
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/12Heating the gasifier
    • C10J2300/1246Heating the gasifier by external or indirect heating
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1625Integration of gasification processes with another plant or parts within the plant with solids treatment
    • C10J2300/1628Ash post-treatment
    • C10J2300/1634Ash vitrification
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/18Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1861Heat exchange between at least two process streams
    • C10J2300/1869Heat exchange between at least two process streams with one stream being air, oxygen or ozone
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/18Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1861Heat exchange between at least two process streams
    • C10J2300/1884Heat exchange between at least two process streams with one stream being synthesis gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2202/00Combustion
    • F23G2202/20Combustion to temperatures melting waste
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2205/00Waste feed arrangements
    • F23G2205/16Waste feed arrangements using chute
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2205/00Waste feed arrangements
    • F23G2205/18Waste feed arrangements using airlock systems
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2206/00Waste heat recuperation
    • F23G2206/20Waste heat recuperation using the heat in association with another installation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2209/00Specific waste
    • F23G2209/26Biowaste
    • F23G2209/261Woodwaste
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2209/00Specific waste
    • F23G2209/28Plastics or rubber like materials
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2900/00Special features of, or arrangements for incinerators
    • F23G2900/70Incinerating particular products or waste
    • F23G2900/7004Incinerating contaminated animal meals
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2900/00Special arrangements for conducting or purifying combustion fumes; Treatment of fumes or ashes
    • F23J2900/15081Reheating of flue gases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27MINDEXING SCHEME RELATING TO ASPECTS OF THE CHARGES OR FURNACES, KILNS, OVENS OR RETORTS
    • F27M2001/00Composition, conformation or state of the charge
    • F27M2001/05Waste materials, refuse
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27MINDEXING SCHEME RELATING TO ASPECTS OF THE CHARGES OR FURNACES, KILNS, OVENS OR RETORTS
    • F27M2003/00Type of treatment of the charge
    • F27M2003/14Pyrolising

Definitions

  • the present invention relates to a DC shaft reactor for Melting and gasifying feedstocks of different types and Consistency, such as pollutant-free and / or contaminated woods, house and Bulky waste, alternative fuels, pelletized dusts or animal meal, Plastics, industrial and commercial waste.
  • feedstocks of different types and Consistency such as pollutant-free and / or contaminated woods, house and Bulky waste, alternative fuels, pelletized dusts or animal meal, Plastics, industrial and commercial waste.
  • a synthesis gas which is used to generate electrical energy and heat is suitable and / or as a basis for Synthesis processes are used.
  • a solid product creates a non-leachable slag and a materially processable Metal phase or a non-elutable liquid phase, which for a further processing is available.
  • a coke-heated cycle gas cupola is used material and / or energy recovery of waste materials described. It consists of a vertical furnace shaft with below the Facing large volume recycle gas vents through Channels and nozzles are connected to the melting and overheating zone, above which a large volume excess gas extraction level resulting gas from the process.
  • the furnace shaft part between recycle gas and excess gas suction opening queritessverjüngt is the furnace shaft part between recycle gas and excess gas suction opening quer4.000sverjüngt.
  • the heat transfer takes place as in DE 43 17 145 C1 due to the fact that the feedstock rises upwards in the countercurrent principle Process gases.
  • the multiple countercurrent flow of the gas through the moving bed allows despite some modifications by narrowing the cross-section in the shaft and expanding the cross-section in the Gas discharge does not mean processing a wide range of feed.
  • DE 198 16 864 A1 describes a cycle gas cupola, in which an excess gas extraction below the melting and Overheating zone is arranged. This results in a Counterflow gasification and heat transfer in the upper furnace shaft area, where the gas is sucked off through large-volume openings and through Channels / nozzles are directed into the melting and overheating zone. In the Subsequent DC gasification turns the gas at high temperatures reduced and longer-chain hydrocarbons split. Through this The chosen arrangement is the negative influence of short-circuit currents reduced. The spatial proximity of the endothermic processes to the range and the large-volume excess gas extraction removes from the melt necessary heat to the necessary under all operating conditions to ensure liquid discharge of the melt.
  • DE 100 07 115 A1 describes a reactor for gasifying and / or melting Feedstocks with a feed, pyrolysis, melting and Overheating section described.
  • the pyrolysis section has one Cross-sectional expansion as a gas supply space in which at least one Combustion chamber with at least one burner, through which hot Combustion gases are fed to a bulk cone that forms.
  • high-energy media are created using upper and lower Injection agents in the area of the melting and overheating zone as well introduced above the melt by means of oxygen lances and / or nozzles.
  • the disadvantage of this device is that it is enlarged by the cone Reactor surface in the area of the cross-sectional expansion of the pyrolysis, because Heat losses occur.
  • the object of the invention is a DC shaft reactor to create with that even when using different input materials
  • the inventive DC shaft reactor for melting and Gasification of feedstock has a vertical shaft body.
  • the feed material is dried and heated within the shaft body and gasified.
  • the shaft body can therefore usually be divided into the areas Divide the drying zone, degassing zone and gasification zone.
  • To the The shaft body is followed by a receiving body, which is used to hold molten feed. Within that body is the Melting zone of the reactor formed.
  • the shaft body and / or the Receiving bodies are equipped with a gas discharge device for removing the Produced useful gases generated within the reactor.
  • the Discharge device in the area between the shaft body and the Arranged body and designed as a tube.
  • the vertically aligned shaft body on a feed device through which the Feed material is fed to the shaft reactor.
  • a gas supply device for the Supply of gas connected to the manhole body.
  • the gas supplied at which is preferably air or oxygen-enriched air acts to dry the feed.
  • To be good and effective To achieve drying of the feed is the gas supplied preheated according to the invention.
  • To preheat the gas According to the invention, the gas supply device with the gas discharge device connected.
  • the hot gas discharged from the reactor is according to the invention thus used to preheat the gas supplied to the shaft body.
  • a lock arrangement is arranged downstream of the feed opening of the reactor, that controls the feeding of the feed. In the field of Lock arrangement is at least part of the gas supply device with the Lock chamber connected.
  • the use of the invention dissipated gas as an energy source leads to the preheating of the Gases no additional energy is required and the feed already undergoes a first drying in the lock arrangement.
  • the Lock arrangement is thereby in addition to drying the Input material used.
  • Another significant advantage of the invention is that heat is extracted from the gas that is removed. This is the further processing or use of this gas is simplified.
  • Feed material can be processed in the shaft reactor, because the Feed material stronger during his stay in the shaft reactor is heated and thus also with poorly processable materials Degassing and gasification can be achieved. In particular, this also means achieved that better degassing and gasification within the reactor takes place so that the useful gas has fewer particles.
  • inventive design of the DC shaft reactor possible to produce useful gases that have a significantly lower oil and Tar content and a significantly lower pollutant content.
  • the feed material is introduced into the shaft body via the Lock arrangement.
  • the Lock arrangement preferably has at least one lock chamber on. A first lock gate is thus opened in order to insert the feed material in bring in the lock chamber. Then this first lock gate closed so that the lock chamber is closed. In this Condition may contain any air contained in the lock chamber and / or be replaced by another gas. Then the second Lock gate leading towards the interior of the shaft reactor, opened and the feed material comes from the lock chamber into the Reactor.
  • the lock arrangement is advantageously designed such that the Introducing feed material into the DC shaft reactor almost free cone or low cone. This eliminates the danger reduces that larger pieces of the feed materials roll onto the reactor wall and segregation of the feed takes place. The adverse consequences segregation, such as melting of the furnace lining, Creation of flow channels for the entering gases and fluctuating gas qualities due to different reaction zones thereby greatly reduced.
  • a low-cone introduction of material into Shaft reactors can be achieved, for example, by the fact that the Reactor shaft, which follows the lock arrangement, a similar one Has cross-sectional geometry.
  • the drop height of the fed Good things should be as low as possible. In particular, not higher than three times the height of the feed material in the lock arrangement. In addition, that should open the second lock gate as quickly as possible so that the underside of the falling feedstock remains as horizontal as possible.
  • the feed material in the lock arrangement should not be possible itself already contain a cone. This can be done, for example thereby achieve that the lock chamber in the lock arrangement completely filled with feed and with the closing of the first Lock gates the material that does not fit in the lock chamber, is cut off from the feed material to be introduced. This is in advantageously the first lock gate as a slide with a cutting edge educated. As a result, the feed material to be introduced almost corresponds the geometry of the lock chamber and in particular has almost none Cone on.
  • the second lock gate can be opened as quickly as possible advantageously carried out as a flap or slide.
  • the DC shaft reactor has a shaft body 10.
  • the shaft body 10 can be converted into a Lock arrangement 12, one adjoining the lock arrangement 12 subsequent drying zone 14, one adjoining the drying zone 14 subsequent degassing zone 16 and a subsequent one Gasification zone 18 can be divided.
  • a receiving body 20 which is used for receiving of molten feed 22 is used.
  • the cross section of the Receiving body expanded so that a ring-shaped Gas collection chamber 24 is formed, the lower part of the gasification zone 18 surrounds.
  • the gas collecting space 24 is shown in FIG Embodiment designed as a tube gas discharge device 26th connected.
  • the feed material is fed into the shaft body 10 through a feed opening 28 introduced over the lock assembly 12. Feeding the Feed material takes place via the lock arrangement 12 for introduction large amounts of ambient air, through which the melting and Gasification process can be influenced in an uncontrolled manner to prevent.
  • the lock arrangement 12 has two lock devices or Lock gates 30, 32 between which the lock chamber 34 is formed, the lock chamber 34 already a part of the Manhole body 10 is.
  • the drying zone 14 of the A gas supply device 36 is provided in the shaft body 10.
  • the gas supply device 36 has a ring line surrounding the shaft body 10 38, which have a plurality of nozzles 40 distributed evenly around the circumference connected is.
  • About the gas feed device 36 is the feed in Area of the drying zone 14 preferably hot air, possibly with oxygen can be enriched, fed to dry the feed.
  • a further gas supply device 42 which is also a Has shaft body 10 surrounding ring line 44.
  • the ring line 44 is with several nozzles 46, which are preferably evenly distributed over the circumference connected. Energy-rich gases, Oxygen, air or other to control the melting and Gases suitable gases are fed to the feed.
  • nozzles 48 are provided in the gasification zone 18. Over the nozzles 48, in turn, high energy gas or other can melt and Gases or substances controlling the gasification process can be supplied. As well instead of the nozzles 48, burners can also be provided which are located in the Gasification zone 18 immediately supply heat to the feed.
  • the End region of the shaft body 10 which is rotationally symmetrical with respect to the longitudinal axis 50 is slightly tapered, so that the feed material in the Area of the gasification zone 18 is somewhat retained.
  • nozzles 54 are arranged in a side wall 52 of the receiving body 20 in a side wall 52 of the receiving body 20 in a side wall 52 of the receiving body 20 .
  • the nozzles 54 are used for insertion energy-rich gases or similar substances. Through the nozzles 54 is ensures that the melt 22 remains liquid.
  • Nozzles 54 may also be provided to burners.
  • the gas supply device 36 is connected to the gas discharge device 26.
  • the pipe of the gas discharge device 26 leads through the hot ones in gases produced in the reactor are discharged to a heat exchanger 56.
  • the discharged gases or useful gases flow through the heat exchanger 56 and are then preferably from a tube 58 to Further processing carried away.
  • the heat exchanger 56 Pipeline 60 connected. Air or another is passed through the pipeline 60
  • Gas passed into the heat exchanger 56 takes in the heat exchanger 56 Heat from the useful gas and is returned from the pipe 62 Heat exchanger derived.
  • the tube 62 is then over a heater 64 and a pipe 66 with the ring line 38 of the gas supply device 36 connected.
  • Heating the area by the gas supply 36 the drying zone 14 gas supplied to the feedstock is thus in operation preferably exclusively by the heat of the useful gases with the help of Heat exchanger 56 preheated.
  • the heater 64 where it are, for example, an electric heater or a burner can, the gas to be supplied via the gas supply device can additionally be warmed. Especially during the start cycle of the reactor, in no hot useful gases through the gas discharge device 26 be dissipated or the temperature of these groove gases is not yet high enough the heater 64 can be used to heat the gas.
  • part 35 of the Gas supply device 36 connected to the shaft body 10. Through this The feedstock is already connected in the lock arrangement 12 subjected to the first drying.
  • a side wall 68 of the lock arrangement 12 is preferably double-walled. This can cause heating and thus Drying of the feed material can be achieved in the lock chamber 34 by passing a hot medium through the double-walled side wall 68 becomes. It is preferably air or another gas that also by the useful gas, preferably with the help of the heat exchanger 56 is preheated.
  • the ideal material input preferably uses a homogeneous mixture ahead, especially when adding additives such as coke and lime.
  • entry takes place centrally on the axis of the reactor.
  • the reactor should be kept as full as possible during operation.
  • a Level monitoring is therefore preferably directly below the Lock gate 32 attached. Filling takes place at a high cycle rate. Through these measures, the false air entry is simultaneously reduced and improved pressure maintenance in the overall system.
  • the areas are lock arrangement 12, drying zone 14 and degassing zone 16 into the gasification zone 18 preferably cylindrical or slightly tapered downwards.
  • the transition between the zones takes place without step-like or abrupt Cross-sectional expansion, i.e. the transition is the same cross section and without the formation of voids, steps or edges that are free of fill layers.
  • the drying zone 14 can also be used, particularly in the case of larger designs be double-walled. This enables indirect heating of the Good column inside or ensuring an even temperature of the wall and a reduction in condensation on the Inside. Hot air is preferably also used as the heat transfer medium used. The use of the flue gas at the end of the process is also possible.
  • the drying zone 14 takes place Evaporation of the water takes place.
  • the temperature in the goods rises only slightly above 100 ° C.
  • gases such as nitrogen and carbon dioxide are released, which are not have arisen from fission reactions.
  • the temperature sets above 250 to 300 ° C Development of gases and vapors that are distilled off low molecular weight compounds and the first fission products. Another one Rising temperature causes the reactions that lead to formation of methane and hydrogen.
  • the degassing zone 16 can also continue the drying zone 14 be double-walled.
  • the double-walled version can be replaced by a silicate brickwork to be replaced.
  • An execution of the whole Drying and degassing zone 14, 16 with a ramming mass, also at a double-walled design is advantageous. Less wear and tear on the Steel structural shells stand for lower heat transfer and lower Resistance to temperature changes.
  • the gasification zone 18 is the main reaction zone within the Shaft reactor. This takes place at temperatures of 1,200 to 1,400 ° C Material and energetic implementation of the solids. From the solid Gases and solid products from coke to ash are produced as fuel. For the Complete and even response is critical to having a homogeneous Filling with the degassing gas already created and this gasification agent to be introduced is evenly flowed through.
  • the Gasification zone 18 must be of sufficient height for these reasons have. This is achieved in that the gasification zone 18 as a straight cylindrical area with a transition to a conical reduction of the cross section or immediately as an increasing taper. There themselves through the material implementations and related destructive forces reduce the grain of material, the increase Cavities inside the pillar. By reducing the Shaft cross-section in this area, the rate of descent Material column are equalized, flow channels are destroyed and the formation of larger voids in the bed is avoided.
  • the lower cylindrical or tapered area of the Gasification area 18 protrudes into the melting zone 20. On this part the column above it lies at least partially, at the same time the temperatures are high there. For securing the mechanical Strength and protection against excessive temperatures are cooled using indirect water cooling in shaft wall 70.
  • the from the expired degassing and Thermolysis reactions are longer chain hydrocarbons have been thermally split here and were at the same time running out Gasification processes involved.
  • a medium combustible gas is formed Calorific value with the main components carbon monoxide, carbon dioxide, Hydrogen and water vapor without components of condensable Hydrocarbons. Many of the chemical reactions that took place are endothermic. The temperature of the gas and the bed is reduced Consequently.
  • the gas is deflected by about 180 ° and reaches the free bed Room 24. Due to the endothermic processes described above, the Gas a temperature of approximately 1,000 ° C. After a certain calming of the gas and equalization, the gas is sucked out of the reactor above.
  • the gas collecting space 24 is already part of the melting zone 20, which the top is much wider than the protruding gasification zone 18.
  • the cylindrical melting zone 20 shrinks conically downwards and closes with the base plate, above which the melted phase collects.
  • the melting zone 20 is in its entirety with a multilayer Provide ramming compound or equipped with a lining. reason the high temperatures required for this. Only in the area of The gas collecting space may not need bricking.
  • the completely degassed and coked solid is already in places sintered or melted and sinks from the gasification zone 18 into the Melting zone 20.
  • a level with several oxygen nozzles is integrated into the melting zone 20 or injectors and / or oxidizing burners 54, which also are symmetrically distributed on the axis.
  • the supply of gas with a high proportion of oxygen leads to this strong exothermic reactions with the gas and the solid from the Gasification zone 18.
  • There are temperatures which are significantly above the The melting point of the material is usually about 1400 ° C to 1600 ° C. in the In the area of the oxygen nozzles there are even hot temperature zones from 1800 to 2000 ° C. Under these conditions and by adding Slag formers and / or materials that lower the melting point, all inorganic pollutants are melted safely.
  • the melted material collects as a melt at the bottom of the Reactor. This liquid melt is emptied as in the foundry usual via a tap hole and a gutter 72. A type with forehearth or Siphon is possible.
  • a preferred embodiment of the lock arrangement 12 consists in that the second lock gate 32 is designed as a quick-opening slide (Fig. 2).
  • the lock gate 32 is in particular made of several pieces. When the lock gate 32 is opened, this falls into the lock chamber 34 located feed material evenly in the drying zone 14 of the Shaft body 10. Previously, the feed material with the Lock chamber 34 connected part 35 of the gas supply device 36 pre-dried.
  • the second designed as a slide Lock gate 32 is advantageously provided with a cutting edge. As a result, when the second lock gate 32 is closed, Lock chamber 34 projecting part of the feed are cut off, whereby the lock chamber 34 can be closed again.
  • the first lock gate 30 executed as a slide with a cutting edge, the separates the upper part of the feed material from the lock chamber 34.
  • the in this embodiment, the first lock gate 30 can also be in several pieces be carried out.
  • the second is for introducing feed material into the shaft body 10 Lock gate 32 initially closed and the first lock gate 30 opened.
  • feed material gets into the lock chamber 34 Closing the first lock gate 30 becomes the second lock gate 32 opened, whereby the feed material falls into the shaft body 10.
  • additional feed material can already pass through the feed opening 28 be filled, which is provided on the first lock gate 30. Then the filling cycle begins again.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Processing Of Solid Wastes (AREA)
  • Vertical, Hearth, Or Arc Furnaces (AREA)
  • Furnace Charging Or Discharging (AREA)
  • Emergency Protection Circuit Devices (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Gasification And Melting Of Waste (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
EP02027458A 2001-12-14 2002-12-10 Réacteur à lit descendant à co-courant Expired - Lifetime EP1323809B1 (fr)

Priority Applications (1)

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SI200230833T SI1323809T1 (sl) 2001-12-14 2002-12-10 Sotočni jaškasti reaktor

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DE20120189U 2001-12-14
DE20120189U DE20120189U1 (de) 2001-12-14 2001-12-14 Gleichstrom-Schacht-Reaktor

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AT (1) ATE427347T1 (fr)
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1493799A1 (fr) * 2003-07-04 2005-01-05 von Görtz & Finger Technische Entwicklungs Ges.m.b.H. Gazéification à vapeur instantanée de biomasse
WO2008000975A1 (fr) * 2006-06-30 2008-01-03 Jean-Claude Fayard Bruleur pour realiser la combustion de substances reputees difficilement combustibles
WO2009003436A1 (fr) * 2007-07-04 2009-01-08 Dinano Ecotechnology Llc Dispositif de chargement appartenant à une installation de traitement de matières premières contenant du carbone
WO2009040573A3 (fr) * 2007-09-25 2009-08-13 Refgas Ltd Gazéification
WO2015036241A1 (fr) * 2013-09-16 2015-03-19 Sgl Carbon Se Four à cuve et procédé de retraitement d'un déchet contenant du fluor

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DE10226862B3 (de) * 2002-06-15 2004-01-29 Gesellschaft für Nachhaltige Stoffnutzung mbH Verfahren und Vorrichtung zur Erzeugung eines Brenngases aus Biomassen
DE10327178B3 (de) * 2003-06-17 2005-05-04 Hans Ulrich Feustel Anlage zur Herstellung von Metall- und Schlackeschmelzen sowie von Synthesegas

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DE966459C (de) * 1952-06-29 1957-08-08 Paul Hahnel Dr Ing Verfahren zur oxydierenden und reduzierenden Behandlung oxydischer Erze in Schachtoefen
DE2633128C3 (de) * 1976-07-23 1980-06-26 Kernforschungsanlage Juelich, Gmbh, 5170 Juelich Feuerungsrost für eine Einrichtung zum Verbrennen von Abfallstoffen
BR7706858A (pt) * 1976-10-26 1978-07-04 Union Steel Corp South Africa Processo e aparelho para a producao continua de um gas redutor contendo monoxido de carbono e hidrogenio
US4530702A (en) * 1980-08-14 1985-07-23 Pyrenco, Inc. Method for producing fuel gas from organic material, capable of self-sustaining operation
US4584947A (en) * 1985-07-01 1986-04-29 Chittick Donald E Fuel gas-producing pyrolysis reactors
FR2596409B1 (fr) * 1986-04-01 1988-07-08 Distrigaz Sa Procede et appareil de gazeification de charbon en cocourant
FR2610087B1 (fr) * 1987-01-22 1989-11-24 Aerospatiale Procede et dispositif pour la destruction de dechets solides par pyrolyse
DE3734988A1 (de) * 1987-10-15 1989-04-27 Voest Alpine Ind Anlagen Verfahren zum kontinuierlichen betreiben einer waermerueckgewinnungsanlage und vorrichtung zur durchfuehrung des verfahrens
CA2036581C (fr) * 1990-02-23 1998-09-22 Gunter H. Kiss Methode de transport, de stockage intermediaire et de valorisation energetique et materielle de dechets de tous geres et dispositif associe
DE4030554A1 (de) * 1990-09-27 1992-04-09 Bergmann Michael Dr Verfahren und vorrichtung zur thermischen behandlung von abfallstoffen
DE4317145C1 (de) * 1993-05-24 1994-04-28 Feustel Hans Ulrich Dipl Ing Verfahren und Einrichtung zur Entsorgung unterschiedlich zusammengesetzter Abfallmaterialien
DE19640497C2 (de) * 1996-10-01 1999-01-28 Hans Ulrich Dipl Ing Feustel Koksbeheizter Kreislaufgaskupolofen zur stofflichen und/oder energetischen Verwertung von Abfallmaterialien
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DE10007115C2 (de) * 2000-02-17 2002-06-27 Masch Und Stahlbau Gmbh Rolan Verfahren und Reaktor zum Vergasen und Schmelzen von Einsatzstoffen mit absteigender Gasführung
DE10127138C2 (de) * 2000-06-23 2003-12-24 Nachhaltige Stoffnutzung Mbh G Verfahren und Vorrichtung zur Erzeugung eines Brenngases aus Biomassen
JP2002081624A (ja) * 2000-09-05 2002-03-22 Kawasaki Heavy Ind Ltd 廃棄物ガス化溶融炉と同溶融炉の操業方法

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1493799A1 (fr) * 2003-07-04 2005-01-05 von Görtz & Finger Technische Entwicklungs Ges.m.b.H. Gazéification à vapeur instantanée de biomasse
WO2008000975A1 (fr) * 2006-06-30 2008-01-03 Jean-Claude Fayard Bruleur pour realiser la combustion de substances reputees difficilement combustibles
WO2009003436A1 (fr) * 2007-07-04 2009-01-08 Dinano Ecotechnology Llc Dispositif de chargement appartenant à une installation de traitement de matières premières contenant du carbone
GB2463444A (en) * 2007-07-04 2010-03-17 Dinano Ecotechnology Llc Device for loading an installation for treating raw materials containing carbon
WO2009040573A3 (fr) * 2007-09-25 2009-08-13 Refgas Ltd Gazéification
GB2453111B (en) * 2007-09-25 2010-12-08 Refgas Ltd Gasification
AU2008303334B2 (en) * 2007-09-25 2012-09-27 Refgas Limited Downdraft refuse gasification
WO2015036241A1 (fr) * 2013-09-16 2015-03-19 Sgl Carbon Se Four à cuve et procédé de retraitement d'un déchet contenant du fluor

Also Published As

Publication number Publication date
SI1323809T1 (sl) 2009-08-31
EP1323809B1 (fr) 2009-04-01
DE50213409D1 (de) 2009-05-14
EP1323809A3 (fr) 2004-01-02
DE20120189U1 (de) 2003-04-24
ATE427347T1 (de) 2009-04-15

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