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EP1392891B1 - Enceintes d'electro-extraction d'aluminium comprenant un fond de cathode draine et un reservoir de collecte d'aluminium - Google Patents

Enceintes d'electro-extraction d'aluminium comprenant un fond de cathode draine et un reservoir de collecte d'aluminium Download PDF

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Publication number
EP1392891B1
EP1392891B1 EP02726381A EP02726381A EP1392891B1 EP 1392891 B1 EP1392891 B1 EP 1392891B1 EP 02726381 A EP02726381 A EP 02726381A EP 02726381 A EP02726381 A EP 02726381A EP 1392891 B1 EP1392891 B1 EP 1392891B1
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Prior art keywords
aluminium
cell
cathode
anodes
drained
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Expired - Lifetime
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EP02726381A
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German (de)
English (en)
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EP1392891A1 (fr
Inventor
Vittorio De Nora
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Moltech Invent SA
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Moltech Invent SA
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
    • C25C3/08—Cell construction, e.g. bottoms, walls, cathodes

Definitions

  • This invention relates to a cell for the electrowinning of aluminium from alumina dissolved in a fluoride-containing molten electrolyte having an aluminium-wettable drained cathode surface and an aluminium reservoir, and a method to produce aluminium in such an aluminium electrowinning cell.
  • the technology for the production of aluminium by the electrolysis of alumina, dissolved in molten cryolite, at temperatures around 950°C is more than one hundred years old and still uses carbon anodes and cathodes.
  • US Patent 5,683,559 (de Nora) proposed a new drained cathode design for aluminium production cells, where grooves or recesses were incorporated in the surface of blocks forming the cathode surface in order to channel the drained product aluminium.
  • a specific embodiment provides an enhanced anode and drained cathode geometry where aluminium is produced between V-shaped anodes and cathodes and collected in recessed grooves.
  • WO98/53120 (Berclaz/de Nora) discloses an aluminium production cell provided with a cathode mass supported on a cathode shell or plate, the cathode mass having a horizontal drained cathode surface and a central channel extending along the cell for draining molten aluminium.
  • WO00/63463 discloses an aluminium production cell in which the drained cathode bottom is divided into four drained cathode sections by a longitudinally extending central aluminium evacuation groove and a central aluminium collection reservoir extending centrally across the cell on a spacer body located between and parallel to cathode blocks placed across the cell.
  • An object of the invention is to provide an aluminium electrowinning cell bottom and an aluminium electrowinning cell having an aluminium-wettable drained cathode which is made of conventional cell blocks which can be easily retrofitted in existing cells.
  • a further object of the invention is to provide an aluminium electrowinning cell having an aluminium collection reservoir from which molten aluminium can be tapped without the risk of aluminium freezing in the reservoir, and which can be easily retrofitted in existing cells.
  • a major object of the invention is to provide a modular assembly of an aluminium collection reservoir and cathode blocks for an aluminium production cell.
  • Yet another object of the invention is to provide a method to produce aluminium in an aluminium electrowinning cell provided with such a cell bottom.
  • the invention provides a cell for the electrowinning of aluminium from alumina.
  • This cell comprises a plurality of anodes, in particular oxygen-evolving anodes, facing a series of pairs of cathode blocks with aluminium-wettable drained cathode surfaces placed across the cell and a longitudinal aluminium collection recess which is located between the cathode blocks and which extends along the cell and is at a lower level than the drained cathode surfaces so that during use aluminium produced on the drained cathode surfaces drains into the aluminium collection recess.
  • the aluminium collection recess is defined between the cathode blocks by a separate reservoir body which is placed between the blocks of each pair of cathode blocks spacing them apart across the cell and which extends along the cell.
  • the cathode blocks can be made of graphite and/or have an aluminium-wettable upper part.
  • the cathode blocks are coated with an aluminium-wettable layer.
  • the cathode blocks are made of aluminium-wettable material.
  • Suitable aluminium-wettable materials and carbon materials for cathode blocks are disclosed in US Patent 5,651,874 (de Nora/Sekhar), and PCT applications WO98/17842 (Sekhar/Duruz/liu), WO01/42168 (de Nora/Duruz) and WO01/42536 (Nguyen/Duruz/de Nora).
  • the cathode blocks may be covered with porous ceramic-based plates filled with molten aluminium whose surfaces serve as aluminium-wettable drained cathode surfaces on which aluminium is produced and from which aluminium drains into the collection reservoir.
  • the ceramic-based plates are preferably made of materials which are resistant and inert to molten aluminium.
  • the inert and resistant ceramic material may comprise at least one oxide selected from oxides of aluminium, zirconium, tantalum, titanium, silicon, niobium, magnesium and calcium and mixtures thereof, as a simple oxide and/or in a mixed oxide, for example an aluminate of zinc (ZnAlO 4 ) or titanium (TiAlO 5 ).
  • suitable inert and resistant ceramic materials can be selected amongst nitrides, carbides and borides and oxycompounds thereof, such as aluminium nitride, AlON, SiAlON, boron nitride, silicon nitride, silicon carbide, aluminium borides, alkali earth metal zirconates and aluminiumates, and their mixtures.
  • the ceramic-based plates contain an aluminium-wetting agent.
  • Suitable wetting agents include metal oxides which are reactable with molten aluminium to form a surface layer containing alumina, aluminium and metal derived from the metal oxide and/or partly oxidised metal, such as manganese, iron, cobalt, nickel, copper, zinc, molybdenum, lanthanum or other rare earth metals or combinations thereof.
  • the aluminium-filled ceramic-based plates may extend from the cathode blocks over part of the aluminium collection recess, thereby the surface area of the aluminium-wettable drained cathode surface is increased.
  • the reservoir body may be made of anthracite or other carbonaceous material.
  • the reservoir body can be made of a plurality of sections assembled end-to-end longitudinally along the cell and/or side-by-side across the cell.
  • the reservoir body has a generally U-shaped cross-section across the cell.
  • the aluminium collection recess can have a triangular, rectangular or curved cross-section or a variation thereof which is suitable for the collection of aluminium.
  • the aluminium collection recess is generally U-shaped with rounded lower corners and/or an outwardly curved upper part in cross-section
  • the reservoir body has a rectangular cross-section with a planar upper surface which is at a level below the drained cathode surfaces and which constitutes the bottom surface of the aluminium collection recess.
  • Upper parts of end faces of the cathode blocks may form the lateral surfaces of the aluminium collection recess.
  • the bottom part of the aluminium collection recess may be horizontal or sloping longitudinally along the cell down towards one end of the cell or the centre of the cell.
  • the anodes are oxygen-evolving anodes, such as metal-based anodes, in particular metal-based anodes having an oxide-based outer part.
  • anodes can be made of an iron alloy comprising nickel and/or cobalt whose surface may be oxidised.
  • Suitable metal-based anodes are disclosed in WO00/06802, WO00/06803 (both in the name of Duruz/de Nora/Crottaz), WO00/06804 (Crottaz/Duruz), WO01/42535 (Duruz/de Nora), WO01/42534 (de Nora/Duruz) and WO01/42536 (Duruz/Nguyen/de Nora).
  • Oxygen-evolving anodes may have an electrochemically active part coated with a slowly soluble protective layer, or a protective layer made of one or more cerium compounds, in particular cerium oxyfluoride, as disclosed in US Patents 4,614,569 (Duruz/Derivaz/Debely/ Adorian), 4,680,094 (Duruz), 4,683,037 (Duruz) and 4,966,674 (Bannochie/Sheriff), which can be continuously replenished by in-situ electrodeposition thereon of the cerium compound(s).
  • a slowly soluble protective layer or a protective layer made of one or more cerium compounds, in particular cerium oxyfluoride, as disclosed in US Patents 4,614,569 (Duruz/Derivaz/Debely/ Adorian), 4,680,094 (Duruz), 4,683,037 (Duruz) and 4,966,674 (Bannochie/Sheriff), which can be continuously replenished by in-sit
  • the invention also relates to a method of producing aluminium in a cell as described above.
  • This method comprises passing an electrolysis current between the anodes and facing drained cathode surfaces in an electrolyte containing dissolved alumina to evolve gas, such as oxygen, at the anodes and produce aluminium on the drained cathode surfaces.
  • gas such as oxygen
  • the anodes may be oxygen-evolving and can be coated with a protective layer, such as a layer of one or more cerium compounds, in particular cerium oxyfluoride, in which case an amount of cerium species is preferably maintained in the electrolyte to maintain the protective cerium-based layer.
  • a protective layer such as a layer of one or more cerium compounds, in particular cerium oxyfluoride, in which case an amount of cerium species is preferably maintained in the electrolyte to maintain the protective cerium-based layer.
  • a further aspect of the invention relates to a bottom of a cell for the electrowinning of aluminium from alumina.
  • This cell bottom comprises a series of pairs of cathode blocks with aluminium-wettable drained cathode surfaces placed thereacross and a longitudinal aluminium collection recess which is located between the cathode blocks and which extends along the cell bottom and is at a lower level than the drained cathode surfaces so that during use aluminium produced on the drained cathode surfaces drains into the aluminium collection recess.
  • the aluminium collection recess is defined between the cathode blocks by a separate reservoir body which is placed between the cathode blocks spacing them apart across the cell bottom and which extends along the cell bottom.
  • the cell bottom may comprise any of the above cell bottom-related features or any combination thereof.
  • Another aspect of the invention relates to a method of producing aluminium in a cell comprising a cell bottom as described above.
  • This method comprises passing an electrolysis current between anodes and the drained cathode surfaces of the cell bottom in an electrolyte containing dissolved alumina to evolve gas at the anodes and produce aluminium on the drained cathode surfaces.
  • the produced aluminium drains from the drained cathode surfaces into the aluminium collection recess defined by the separate reservoir.
  • Figure 1 illustrates a drained-cathode cell having an aluminium collection reservoir in accordance with the invention.
  • the cell shown in Figure 1 comprises a plurality of pairs of oxygen-evolving anodes 10 dipping in a molten electrolyte 5 and facing a series of pairs of cathode blocks 25 with aluminium-wettable drained cathode surfaces 20 spaced apart across the cell and a separate longitudinal reservoir body 30 which is located between the spaced apart blocks 25.
  • the reservoir body 30 has an upper surface which defines a central aluminium collection recess 35. This recess 35 extends along and is at a lower level than the drained cathode surfaces 20 so that during use aluminium produced on the drained cathode surfaces 20 drains into the aluminium collection recess 35.
  • the cathode blocks 25 are made of graphite and have a reduced height, e.g. 30 cm, and are coated with an aluminium-wettable layer 22 which protects the graphite from erosion and wear.
  • Suitable aluminium-wettable layers are disclosed in the above mentioned US Patent 5,651,874, WO98/17842, WO01/42168 and WO01/42531.
  • the reservoir body 30 is generally U-shaped and the aluminium collection recess 35 has rounded lower corners and an outwardly curved upper part.
  • the reservoir body 30 is made of two generally L-shaped sections 31 assembled across the cell.
  • the reservoir sections 31 are made of anthracite-based material.
  • the aluminium-wettable layer 22 extends in the recess 35 to protect the reservoir body 30 during use against wear and sodium intercalation.
  • the reservoir body 30 extends below the cathode blocks 25 into the refractory and insulating material 26 of the cell bottom permitting a maximisation of the capacity of the aluminium collection recess 35.
  • the reservoir body 30 has a solid base 32 which extends from above to below the bottom face of the cathode blocks 25 and provides sufficient mechanical resistance to keep the blocks 25 properly spaced apart across the cell when exposed to thermal expansion during start-up of the cell and normal operation.
  • a solid base 32 which extends from above to below the bottom face of the cathode blocks 25 and provides sufficient mechanical resistance to keep the blocks 25 properly spaced apart across the cell when exposed to thermal expansion during start-up of the cell and normal operation.
  • longitudinally spaced apart spacer bars 33 placed across the reservoir body 30 may provide additional mechanical strength to the reservoir body 30.
  • Such spacer bars 33 can be made of carbon material coated with an aluminium-wettable protective layer.
  • the cathode blocks 25 are covered with porous ceramic-based plates 21 which are filled with molten aluminium and which form the aluminium-wettable drained active cathode surfaces 20 on the cathode blocks 25.
  • the aluminium-filled ceramic-based plates 21 extend from the cathode blocks 25 over part of the aluminium collection recess 35.
  • projecting parts of the aluminium-wettable drained active cathode surfaces 20 are located above the aluminium collection recess 35.
  • the openly porous plates 21 are spaced apart over the aluminium collection recess 35 to leave an access for the tapping of molten aluminium 60 through a conventional tapping tube.
  • the spacing between the openly porous plates 21 over the aluminium collection recess 35 can be much smaller along the remaining parts of the recess 35, thereby maximising the surface area of the active cathode surfaces 20.
  • the cell shown in Figure 1 comprises a series of corner pieces 41 made of the openly porous material of the plates 21 and filled with aluminium and placed at the periphery of the cell bottom against sidewalls 40.
  • the sidewalls 40 and the surface of the electrolyte 5 are covered with a ledge and a small crust of frozen electrolyte 6.
  • the cell is fitted with an insulating cover 45 above the electrolyte crust 6. Further details of suitable covers are disclosed in WO99/02763 (de Nora/Sekhar), WO01/31086 (de Nora/Duruz) and WO02/070784 (de Nora/Berclaz).
  • the cell is also provided with exhaust pipes (not shown) that extend through the cover 45 for the removal of gases produced during electrolysis.
  • the cell comprises alumina feeders 15 with feeding tubes 16 that extend through the insulating cover 45 between the anodes 10.
  • the alumina feeders 15 are associated with a crust breaker (not shown) for breaking the crust 6 underlying the feeding tube 16 prior to feeding.
  • the insulating material of the sidewalls 40 and cover 45 may be sufficient to prevent formation of any ledge and crust of frozen electrolyte.
  • the sidewalls 40 are preferably completely shielded from the molten electrolyte 5 by a lining of the aforesaid openly porous material filled with aluminium.
  • the anodes 10 are preferably made of electrolyte resistant inert metal-based material.
  • Suitable metal-based anode materials include iron alloys comprising nickel and/or cobalt which may be heat-treated in an oxidising atmosphere.
  • the lifetime of the anode may be increased by a protective coating made of cerium compounds, in particular cerium oxyfluoride.
  • a protective coating made of cerium compounds in particular cerium oxyfluoride.
  • the cell may be operated with an electrolyte 5 at reduced temperature, typically from about 850° to 940°C, preferably from 880° to 930°C.
  • an electrolyte 5 at reduced temperature typically from about 850° to 940°C, preferably from 880° to 930°C.
  • Operating with an electrolyte at reduced temperature reduces the solubility of oxides, in particular of alumina. For this reason, it is advantageous to enhance alumina dissolution in the electrolyte 5.
  • Enhanced alumina dissolution may be achieved by utilising an alumina feed device which sprays and distributes alumina particles over a large area of the surface of the molten electrolyte 5.
  • Suitable alumina feed devices are disclosed in greater detail in WO00/63464 (de Nora/Berclaz).
  • the cell may comprise means (not shown) to promote circulation of the electrolyte 5 from and to the anode-cathode gap to enhance alumina dissolution in the electrolyte 5 and to maintain in permanence a high concentration of dissolved alumina close to the active surfaces of anodes 10, for example as disclosed in WO00/40781 (de Nora).
  • alumina dissolved in the electrolyte 5 is electrolysed to produce oxygen on the anodes 10 and aluminium 60 on the drained cathode surfaces 20.
  • the product aluminium 60 drains from the cathode surfaces 20 into the reservoir 30 from where it can be tapped.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
  • Secondary Cells (AREA)

Claims (20)

  1. Cuve pour l'électro-obtention d'aluminium à partir d'alumine comprenant une pluralité d'anodes, en particulier des anodes dégageant de l'oxygène, faisant face à une série de paires de blocs cathodiques avec des surfaces cathodiques de drainage mouillables par l'aluminium placées en travers de la cuve et un évidement de collecte d'aluminium qui est situé entre des blocs cathodiques à un niveau inférieur aux surfaces cathodiques de drainage de sorte que, pendant l'utilisation, l'aluminium produit sur les surfaces cathodiques de drainage s'écoule dans l'évidement de collecte d'aluminium,
    caractérisée en ce que l'évidement de collecte d'aluminium est un évidement longitudinal qui s'étend le long de la cuve et qui est défini entre les blocs cathodiques par un corps de réservoir séparé qui est placé entre les blocs en les espaçant en travers de la cuve et qui s'étend le long de la cuve.
  2. Cuve selon une quelconque revendication précédente, dans laquelle les blocs cathodiques sont réalisés en graphite.
  3. Cuve selon une quelconque revendication précédente, dans laquelle les blocs cathodiques ont une partie supérieure mouillable par l'aluminium.
  4. Cuve selon la revendication 3, dans laquelle les blocs cathodiques sont revêtus d'une couche mouillable par l'aluminium.
  5. Cuve selon la revendication 1, 2 ou 3, dans laquelle les blocs cathodiques sont réalisés en une matière mouillable par l'aluminium.
  6. Cuve selon une quelconque revendication précédente, qui comprend des plaques poreuses à base de céramique placées sur les blocs cathodiques et remplies d'aluminium en fusion.
  7. Cuve selon la revendication 6, qui comprend des plaques à base de céramique remplies d'aluminium qui s'étendent à partir des blocs cathodiques sur une partie du réservoir de collecte d'aluminium.
  8. Cuve selon une quelconque revendication précédente, dans laquelle le corps du réservoir est réalisé en anthracite.
  9. Cuve selon une quelconque revendication précédente, dans laquelle le corps du réservoir est réalisé en une pluralité de sections assemblées bout à bout longitudinalement le long de la cuve.
  10. Cuve selon une quelconque revendication précédente, dans laquelle le corps du réservoir est réalisé en au moins deux sections assemblées côté à côte en travers de la cuve.
  11. Cuve selon une quelconque revendication précédente, dans laquelle le corps du réservoir a une section transversale généralement en forme de U en travers de la cuve.
  12. Cuve selon la revendication 11, dans laquelle l'évidement de collecte d'aluminium a des coins inférieurs arrondis.
  13. Cuve selon la revendication 11 ou 12, dans laquelle l'évidement de collecte d'aluminium a une partie supérieure courbée vers l'extérieur.
  14. Cuve selon une quelconque revendication précédente, dans laquelle les anodes sont des anodes à dégagement d'oxygène, telles que des anodes à base de métal.
  15. Cuve selon la revendication 14, dans laquelle les anodes sont à base de métal et ont une partie externe à base d'oxyde électrochimiquement active.
  16. Cuve selon la revendication 14 ou 15, dans laquelle les anodes à dégagement d'oxygène sont revêtues d'une couche protectrice, telle qu'une couche réalisée à partir d'un ou de plusieurs composés de cérium, en particulier de l'oxyfluorure de cérium.
  17. Procédé pour produire de l'aluminium dans une cuve telle que définie dans une quelconque revendication précédente, ledit procédé consistant à faire passer un courant d'électrolyse entre les anodes et les surfaces cathodiques de drainage en vis-à-vis dans un électrolyte contenant de l'alumine dissoute pour dégager du gaz, en particulier de l'oxygène, au niveau des anodes et produire de l'aluminium sur les surfaces cathodiques de drainage, l'aluminium produit s'écoulant à partir des surfaces cathodiques de drainage dans l'évidement de collecte d'aluminium défini par le corps du réservoir séparé.
  18. Procédé selon la revendication 17, dans lequel les anodes sont revêtues d'une couche protectrice à dégagement d'oxygène, telle qu'une couche réalisée à partir d'un ou de plusieurs composés de cérium, en particulier de l'oxyfluorure de cérium, qui peut être maintenue en conservant une quantité d'espèce de cérium dans l'électrolyte.
  19. Fond d'une cuve pour l'électro-obtention d'aluminium à partir d'alumine, comprenant une série de paires de blocs cathodiques avec des surfaces cathodiques de drainage mouillables par l'aluminium placées en travers de celui-ci et un évidement de collecte d'aluminium qui est situé entre des blocs cathodiques à un niveau inférieur aux surfaces cathodiques de drainage de sorte que, pendant l'utilisation, l'aluminium produit sur les surfaces cathodiques de drainage s'écoulent dans l'évidement de collecte d'aluminium,
    caractérisé en ce que l'évidement de collecte d'aluminium est un évidement longitudinal qui s'étend le long du fond de la cuve et qui est défini entre les blocs cathodiques par un corps de réservoir séparé qui est placé entre les blocs cathodiques en les espaçant en travers du fond de la cuve et qui s'étend le long du fond de la cuve.
  20. Procédé pour produire de l'aluminium dans une cuve comprenant un fond de cuve tel que défini dans la revendication 19, ledit procédé consistant à faire passer un courant d'électrolyse entre des anodes et les surface cathodiques de drainage du fond de la cuve dans un électrolyte contenant de l'alumine dissoute pour dégager du gaz au niveau des anodes et produire de l'aluminium sur les surfaces cathodiques de drainage, l'aluminium produit s'écoulant des surfaces cathodiques de drainage dans l'évidement de collecte d'aluminium défini par le réservoir séparé.
EP02726381A 2001-05-30 2002-05-28 Enceintes d'electro-extraction d'aluminium comprenant un fond de cathode draine et un reservoir de collecte d'aluminium Expired - Lifetime EP1392891B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
WOPCT/IB01/00956 2001-05-30
IB0100956 2001-05-30
PCT/IB2002/001883 WO2002097168A1 (fr) 2001-05-30 2002-05-28 Enceintes d'electro-extraction d'aluminium comprenant un fond de cathode draine et un reservoir de collecte d'aluminium

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Publication Number Publication Date
EP1392891A1 EP1392891A1 (fr) 2004-03-03
EP1392891B1 true EP1392891B1 (fr) 2004-10-06

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EP (1) EP1392891B1 (fr)
AT (1) ATE278822T1 (fr)
CA (1) CA2448311A1 (fr)
DE (1) DE60201534T2 (fr)
ES (1) ES2225783T3 (fr)
NO (1) NO20035303L (fr)
NZ (1) NZ529849A (fr)
WO (1) WO2002097168A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101368282B (zh) * 2007-08-14 2012-07-11 北京有色金属研究总院 下阴极稀土金属电解槽及采用该电解槽的电解工艺

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2007226245B2 (en) * 2006-03-10 2011-05-12 Rio Tinto Alcan International Limited Aluminium electrowinning cell with enhanced crust
RU2482224C2 (ru) * 2011-04-18 2013-05-20 Общество с ограниченной ответственностью "Объединенная Компания РУСАЛ Инженерно-технологический центр" Катодное устройство алюминиевого электролизера с рельефной подиной
NO347208B1 (en) * 2012-11-13 2023-07-03 Obshchestvo S Ogranichennoy Otvetstvennostyu Obedinennaya Kompaniya Rusal Inzhenerno Tekh Tsenter Lining for an aluminum electrolyzer having inert anodes
RU2509830C1 (ru) * 2012-12-18 2014-03-20 Общество с ограниченной ответственностью "Легкие металлы" Электролизер для производства алюминия
RU2518029C1 (ru) * 2013-03-11 2014-06-10 Общество с ограниченной ответственностью "Легкие металлы" Электролизер для производства алюминия

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Publication number Priority date Publication date Assignee Title
DE1251962B (de) * 1963-11-21 1967-10-12 The British Aluminium Company Limited, London Kathode fur eine Elektrolysezelle zur Herstellung von Aluminium und Verfahren zur Herstellung derselben
US4602990A (en) * 1983-02-17 1986-07-29 Commonwealth Aluminum Corporation Low energy aluminum reduction cell with induced bath flow
DE69526264T2 (de) * 1994-09-08 2002-10-24 Moltech Invent S.A., Luxemburg/Luxembourg Aluminium Elektrolysezelle mit drainierfähige Kathode
ATE244324T1 (de) * 1999-04-16 2003-07-15 Moltech Invent Sa Aluminium-elektrogewinnungszelle mit v-förmigem kathodenboden

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101368282B (zh) * 2007-08-14 2012-07-11 北京有色金属研究总院 下阴极稀土金属电解槽及采用该电解槽的电解工艺

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CA2448311A1 (fr) 2002-12-05
EP1392891A1 (fr) 2004-03-03
NO20035303D0 (no) 2003-11-28
DE60201534T2 (de) 2005-10-20
NZ529849A (en) 2005-01-28
WO2002097168A1 (fr) 2002-12-05
ATE278822T1 (de) 2004-10-15
DE60201534D1 (de) 2004-11-11
NO20035303L (no) 2003-11-28
ES2225783T3 (es) 2005-03-16

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