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EP1365069A2 - Papier de sécurité - Google Patents

Papier de sécurité Download PDF

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Publication number
EP1365069A2
EP1365069A2 EP03017392A EP03017392A EP1365069A2 EP 1365069 A2 EP1365069 A2 EP 1365069A2 EP 03017392 A EP03017392 A EP 03017392A EP 03017392 A EP03017392 A EP 03017392A EP 1365069 A2 EP1365069 A2 EP 1365069A2
Authority
EP
European Patent Office
Prior art keywords
coating
paper
security paper
security
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP03017392A
Other languages
German (de)
English (en)
Other versions
EP1365069A3 (fr
Inventor
Reinhard Plaschka
Theo Dr. Burchard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Giesecke and Devrient GmbH
Original Assignee
Giesecke and Devrient GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=7872406&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP1365069(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Giesecke and Devrient GmbH filed Critical Giesecke and Devrient GmbH
Publication of EP1365069A2 publication Critical patent/EP1365069A2/fr
Publication of EP1365069A3 publication Critical patent/EP1365069A3/fr
Withdrawn legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B42BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42DBOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/40Manufacture
    • B42D25/405Marking
    • B42D25/43Marking by removal of material
    • B42D25/445Marking by removal of material using chemical means, e.g. etching
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/40Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B42BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42DBOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/40Manufacture
    • B42D25/45Associating two or more layers
    • B42D25/465Associating two or more layers using chemicals or adhesives
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/20Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds

Definitions

  • the invention relates to a security paper for the production of value documents, such as banknotes, passports, ID cards or the like, that with is provided with a coating that ensures increased fitness for circulation and a method for producing such security paper.
  • Banknotes are usually made from so-called security papers, which consist of cotton fibers and special security features, like a security thread at least partially worked into the paper and have a watermark.
  • the period of circulation of a banknote depends depending on the stress. Certain denominations are preferred in trade used and therefore show due to the greater load Environmental influences a shorter orbital period.
  • AU-PS 488,652 has therefore already proposed banknotes in full to manufacture from a plastic substrate.
  • security elements such as portrait watermarks and window security thread are dispensed with, as well on the special properties, such as the sound and grip of the banknote paper.
  • WO 96/28610 describes a method for producing security paper known in which the paper was glued and then on at least one Page is coated with a paper properties like an improved resistance to dirt, gives good adhesive properties for printing ink, no significant influence on the "handle" of the Paper, resistance to absorption of optical brighteners, and good visibility of security features due to the transparency of the coating.
  • the coating is based on polyurethane. Extenders can be used in the polyurethane be included, for example polyacrylate, styrene-acrylic copolymers, acrylated Vinyl acetate, vinyl chloride-ethylene copolymers or vinyl acetate copolymers. It should be noted that such polymers alone are not are usable, but only as extenders in connection with polyurethane.
  • the Coating can also contain additives, for example fluorescent ones or iridescent pigments, but also numerous other additives, such as catalysts, emulsifiers, defoamers or thickeners.
  • the object of the invention is therefore a further improved security paper to provide, which is dirt-repellent and therefore has a long period of circulation, and that in its other typical properties, such as printability, Sound, color, etc. remains unchanged.
  • the object of the invention is also a value document to provide, which has such a security paper, and to provide a method for manufacturing the security paper.
  • the security paper is at least on one of its Surfaces provided with a coating that consists of a composition exists, which contains only a binder and no fillers Binders in the sense of the invention form all substances that are common Solvents form insoluble films or structures. It is essential that unlike conventional coating materials, the binder does not contain any Fillers, i.e. Contains pigments, such as titanium dioxide, in high concentrations This composition wets the fibers in the surface area of the Paper and forms a closed surface film over the fiber. This minimizes dirt access to the fiber
  • the composition is applied in a layer thickness that on the one hand creates a sufficiently smooth surface and so there are as few possibilities for dirt accumulation as possible.
  • the layer thickness is so small that the other properties of the paper, such as its grip and printability, are not impaired.
  • the weight per unit area of the coating is preferably about 1 to 6 g / m 2 , in particular 2 to 3 g / m 2 .
  • the transmission properties remain due to the low coating thicknesses of the paper unchanged so that the recognizability of possible Portrait watermark in security paper not affected becomes.
  • the coating also has the advantage that it is based on the usual sizing of the paper can be dispensed with. Also the type of security paper there are no conditions attached to it, so usual security papers from fibers of annual plants, in particular cotton fibers Can be used, but also security papers, at least partially made of plastic fibers, preferably polyamide fibers.
  • the binder composition is applied to the paper after it is made doctored or printed. This can be done immediately after the Paper production in the paper machine or in a separate operation, for example, directly before printing on the security paper. If necessary, the smoothness of the surface can then be adjusted accordingly Calendering can still be increased.
  • the coated according to the invention Paper offers an ideal printing surface for high print resolution and very good ink adhesion for physical and / or chemical Attack attempts.
  • the security paper according to the invention is then correspondingly printed on the security to be manufactured and possibly further processed.
  • the imprint with another Binder layer e.g. to cover a layer of lacquer.
  • the paint layer is preferably in its composition to the invention Undercoat layer matched to a good bond between the two Layers. Possibly the network can be replaced by an additional one Networking step can still be improved. This can be done by Exposure to heat or radiation (e.g. with UV radiation).
  • the binder composition of the invention according to the printing process used in addition to the low soiling also improves the adhesion of the printing inks to ensure on the substrate.
  • Another advantage of the invention can be seen in that on another Pretreatment of the security paper according to the invention can be dispensed with can, if optically variable security elements are provided on paper should be.
  • Optically variable elements or printing inks due to of light diffraction or interference a viewing angle dependent Show play of colors need one for good visibility of this effect as smooth a surface as possible.
  • Security elements of this type are, for example Holograms, kinegrams or other diffraction structures, but also printing inks, the interference layer or liquid crystal pigments or contain other effect pigments, such as shiny metallic effect color pigments.
  • liquid crystal pigments and interference layer pigments made only with titanium dioxide coated mica platelets are translucent, so that the color effect not only from the smoothness but also from the color of the Is influenced underground.
  • a black background absorbs that from light transmitted to the pigments and in this way increases the brilliance of the colors reflected by the pigments.
  • security elements which are made up of several thin layers and also show a play of colors based on interference effects. For this and similar Items, it may be necessary to have the security paper in the area of the security element to be applied with a further background layer to provide.
  • a security element machine or visually verifiable authenticity feature such as it is known from WO 97/35732.
  • the coating according to the invention also has an advantageous effect other security elements.
  • Embossed structures for example, are becoming more concise, because the embossing is more pronounced due to the smoother surface.
  • the embossments are also more durable, because not only the paper fibers be shaped.
  • the coating composition contains additionally at least one substance in low concentration with a visually and / or machine-detectable physical property.
  • the material can for example be magnetic, electrically conductive, light diffractive, have light polarizing or light interfering properties and can be evenly distributed over the entire coating are present or applied in the form of patterns.
  • the remaining sample is kept in register with the first sample Part of the surface of the paper with the same composition, which, however, does not contain the detectable additive.
  • additives can be luminescent substances, for example act that can be excited with UV light and in the visual spectral range emit. In the case of a machine check, however, the invisible spectral range, preferably emitting in the IR spectral range Luminescent substances are used. Likewise are photochromic or thermochromic additives conceivable.
  • ком ⁇ онент a component a color reaction system admixed with the binder composition and applied to the paper. Bring it to a later one The second component of the color reaction system, see above a colored area, pattern, lettering or the like visible. This can serve as an authenticity feature or as Revaluation indicator of a check, ticket or the like.
  • Concentration of one or more additives can very easily be any Codings, for example in the form of a barcode, on the security paper be generated.
  • This coding can, for example, be an independent one represent additional security feature or as a comparative feature for other data already provided on the security paper serve. In this way, visually visible information such as for example the denomination, the name of one shown in the portrait Person or the like encrypted and in the form of the invention Coding invisible to the eye on the paper. at , a machine check the coding is read, decrypted and checked for identity with the corresponding, visually visible information.
  • the coating according to the invention can also have recesses.
  • These recesses can be any Shape, e.g. Have stripe shape. They will be before or after Applying the coating according to the invention with an imprint, which has certain effect colors. With these effect colors it can are interference layer pigments, liquid crystal pigments or others Trade glossy pigments. This imprint can show the cutouts cover all or part of it.
  • the security paper according to the invention can also be advantageous, for example used for the production of ID cards and passports. Because it has increased tear resistance and dirt resistance, can under certain circumstances, the usual lamination with plastic films is dispensed with become. If lamination is nevertheless carried out, the invention provides Coating for a firm, inseparable bond between paper and cover layer.
  • a 100% cotton banknote paper with a filler content of 3.0% is used for the coating test.
  • the paper is through Use of commercially available melamine resin (e.g. Madurit MW167) on one Wet strength set at 50% relative to the dry strength.
  • Acronal 320D 400 ml - aqueous dispersion of an acrylic resin - Softened water 600 ml.
  • the mixture is prepared by stirring and applied to the surface of the Paper applied. A rotating pair of rollers is used for this, the lower side in a bowl with the diluted Acronal dispersion dips. The excess of the suspension is pressed through the nip. The paper is then removed using a commercially available photo dryer dried.
  • the treatment gives the paper the following properties: characteristics before treatment after treatment Air permeability 25 ml / min 5 ml / min Water absorption 60 sec 50 g / m 2 20 g / m 2 Oil intake GFL 30 sec 150 sec
  • Neocryl-AC 72 (Zeneca) 900 ml - aqueous dispersion of an acrylate - water 80 ml CX 100 crosslinker (Zeneca) 20 ml
  • the paper can also be coated with the following binder composition: Primal I-545 (Rohm & Haas) 900 ml - aqueous dispersion of an acrylate - water 80 ml Zirconium carbonate (Auer Remy) 20 ml.
  • FIG. 1 shows a section of a security paper web according to the invention 1, as used for example for the production of banknotes becomes.
  • security paper is usually made of cotton fibers or other fibers made from annual plants. For some However, it may also be useful to use some of these natural applications Fibers through plastic fibers, especially polyamide fibers replace. But pure plastic fiber papers are also conceivable.
  • This security thread 2 becomes quasi woven into the paper so that it is in areas 3 directly to the surface of the paper occurs while it is in the dotted areas is completely embedded in the paper pulp.
  • This thread 2 can with any Security features, such as an electrically conductive, metallic Layer, a hologram or the like.
  • the inventive Security paper 1 consists of the base paper 4, as is the paper machine usually leaves, and the binder coating according to the invention 5, which, according to the embodiment shown, covers an entire surface Surface of the security paper 1 was squeegee or printed. Alternatively, however, the coating 5 can also be applied to the security paper on both sides 1 are applied.
  • FIG. 3 and 4 show a further embodiment of the invention Security paper 1.
  • Fig. 4 is a section through this invention Security paper 1 along the dash-dotted line in FIG. 3 Line A - B shown.
  • the security paper 1 also consists of a conventional one Paper web 4 made according to the invention with a pure binder composition is provided without fillers.
  • the binder layer sets but from different areas 6, 9 together.
  • the binder composition is doped with an additive, which can be checked visually and / or by machine, while the remaining areas 9 contain no additive in the binder composition.
  • the also with the Areas 7 shown doped binder composition form a Coding 8 in the form of a bar code.
  • the additive can be, for example, one less than normal Illumination act as transparent luminescent substance when irradiated emitted with UV light in the visual spectral range and thus an intense one Hue shows. In this case, the information is 6.8, as in FIG. 3 shown, only visible under UV lighting.
  • the information 6 can be visualized with the aid of a Spectal region emitting luminescent substance are generated during the barcode 8 with the aid of a substance that can only be detected by machine, e.g. of a luminescent substance emitting in the IR spectral range becomes.
  • the characters 6 that are visually visible under UV illumination can be used for example represent an image, pattern or legible information.
  • the machine readable code 8 could be intended for the individual Information identifying the value document, possibly in encrypted form Represent form. This information could be the Paper material inherent properties, such as the transmission properties, Thickness distribution, etc. act or others for the respective document of value essential information, such as denomination or the like.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Health & Medical Sciences (AREA)
  • Paper (AREA)
  • Credit Cards Or The Like (AREA)
  • Developing Agents For Electrophotography (AREA)
  • Catching Or Destruction (AREA)
  • Control Of Combustion (AREA)
  • Glass Compositions (AREA)
  • Piezo-Electric Or Mechanical Vibrators, Or Delay Or Filter Circuits (AREA)
  • Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
EP03017392A 1998-06-29 1999-06-28 Papier de sécurité Withdrawn EP1365069A3 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19829004 1998-06-29
DE19829004A DE19829004A1 (de) 1998-06-30 1998-06-30 Sicherheitspapier
EP99931205A EP1099024B1 (fr) 1998-06-29 1999-06-28 Papier de securite

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
EP99931205A Division EP1099024B1 (fr) 1998-06-29 1999-06-28 Papier de securite

Publications (2)

Publication Number Publication Date
EP1365069A2 true EP1365069A2 (fr) 2003-11-26
EP1365069A3 EP1365069A3 (fr) 2004-06-09

Family

ID=7872406

Family Applications (2)

Application Number Title Priority Date Filing Date
EP03017392A Withdrawn EP1365069A3 (fr) 1998-06-29 1999-06-28 Papier de sécurité
EP99931205A Revoked EP1099024B1 (fr) 1998-06-29 1999-06-28 Papier de securite

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP99931205A Revoked EP1099024B1 (fr) 1998-06-29 1999-06-28 Papier de securite

Country Status (11)

Country Link
EP (2) EP1365069A3 (fr)
KR (1) KR20010071507A (fr)
CN (1) CN1238603C (fr)
AT (1) ATE259916T1 (fr)
AU (1) AU4779099A (fr)
DE (2) DE19829004A1 (fr)
DK (1) DK1099024T3 (fr)
ES (1) ES2216529T3 (fr)
ID (1) ID27465A (fr)
PT (1) PT1099024E (fr)
WO (1) WO2000000697A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006117804A3 (fr) * 2005-03-22 2007-01-11 Arrow Coated Products Ltd Papier haute sécurité et procédé de fabrication associé
WO2014108331A1 (fr) * 2013-01-11 2014-07-17 Carl Freudenberg Kg Système de revêtement

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003044276A1 (fr) * 2001-11-22 2003-05-30 Landqart Papier infalsifiable et articles infalsifiables
DE10327083A1 (de) * 2003-02-11 2004-08-19 Giesecke & Devrient Gmbh Sicherheitspapier und Verfahren zur Herstellung desselben
CN100432335C (zh) * 2003-02-11 2008-11-12 德国捷德有限公司 防伪纸及其生产方法
US7934752B2 (en) 2004-03-08 2011-05-03 Dai Nippon Printing Co., Ltd. Image forming method and recorded matter
DE102004014778A1 (de) 2004-03-26 2005-10-13 Leonard Kurz Gmbh & Co. Kg Sicherheits- und/oder Wertdokument
ATE335879T1 (de) * 2004-05-14 2006-09-15 Hueck Folien Gmbh Beschichtung zur erhöhung der umlauffähigkeit von dataträgern
DE102005052672A1 (de) * 2005-11-04 2007-05-10 Giesecke & Devrient Gmbh Harzimprägniertes Sicherheitspapier
DK2074260T3 (da) 2006-10-27 2012-05-29 Crane & Co Inc Smuds- og/eller fugtbestandigt sikkerhedsdokument
KR100974099B1 (ko) * 2007-11-29 2010-08-05 양해완 다목적 조립식 운동기구
DE102009024987A1 (de) * 2009-06-16 2010-12-23 Giesecke & Devrient Gmbh Folienverbundbanknote
DE102009054406A1 (de) 2009-11-24 2011-05-26 Giesecke & Devrient Gmbh Wertdokument mit Silikonharzbeschichtung und Verfahren zu seiner Herstellung
DE102010019194A1 (de) 2010-05-04 2011-11-10 Giesecke & Devrient Gmbh Wertdokument mit Ausnehmung
JP5640702B2 (ja) * 2010-12-02 2014-12-17 富士ゼロックス株式会社 用紙
DE102011120063A1 (de) 2011-12-02 2013-06-06 Giesecke & Devrient Gmbh Sicherheitspapier und daraus erhältliches Wertdokument
DE102011120850A1 (de) 2011-12-09 2013-06-13 Giesecke & Devrient Gmbh Sicherheitspapier, daraus erhältliches Wertdokument und Verfahren zum Herstellen derselben
DE202012010037U1 (de) 2012-10-19 2014-01-20 Hueck Folien Ges.M.B.H. Beschichtung für Wertpapiere, insbesondere zur Erhöhung der Umlauffähigkeit
CN107460780B (zh) * 2017-09-29 2020-07-17 温岭市华航电子科技有限公司 一种聚氨酯导电纸及其制备方法
DE102022133075A1 (de) 2022-12-13 2024-06-13 Giesecke+Devrient Currency Technology Gmbh Sicherheitssubstrat, Sicherheitspapier und Herstellungsverfahren

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU488652B2 (en) * 1973-09-26 1976-04-01 Commonwealth Scientific And Industrial Research Organisation Improvements in or relating to security tokens
CA1043193A (fr) * 1975-02-14 1978-11-28 Douglas C. Edwards Couchage du papier
FR2605123B1 (fr) * 1986-10-10 1989-07-07 Bric Objet fiduciaire ou de securite permettant une authentification visuelle ou optique
FR2668507B1 (fr) * 1990-02-09 1996-06-21 Arjomari Europ Feuille pour documents de securite, ayant une imprimabilite elevee en meme temps qu'une resistance a la circulation elevee.
US5182141A (en) * 1990-02-13 1993-01-26 Co-Ex-Tec Industries Bilaminate polymer coated metal strip and method for manufacture thereof
FR2670812B1 (fr) * 1990-12-21 1996-06-21 Arjomari Europ Feuille imprimable pour fabriquer des documents de securite comportant un moyen contre la contrefacon ou d'authentification.
GB2283026B (en) * 1993-09-30 1997-01-08 Portals Ltd Improvement in security features for paper
PL181275B1 (en) * 1995-03-13 2001-07-31 Portals Ltd Paper difficult to counterfeit it
DE19611383A1 (de) * 1996-03-22 1997-09-25 Giesecke & Devrient Gmbh Datenträger mit optisch variablem Element
ES2137805B1 (es) * 1996-04-12 2000-08-16 I D Tec S L Procedimiento de produccion de un nucleo impreso de seguridad para documentos de identidad y nucleo impreso de seguridad.

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006117804A3 (fr) * 2005-03-22 2007-01-11 Arrow Coated Products Ltd Papier haute sécurité et procédé de fabrication associé
RU2409473C2 (ru) * 2005-03-22 2011-01-20 Эрроу Коутид Продактс Лтд Бумага с высокой степенью защиты от подделки и способ ее изготовления
WO2014108331A1 (fr) * 2013-01-11 2014-07-17 Carl Freudenberg Kg Système de revêtement

Also Published As

Publication number Publication date
DE19829004A1 (de) 2000-01-05
DK1099024T3 (da) 2004-06-21
CN1238603C (zh) 2006-01-25
EP1099024B1 (fr) 2004-02-18
CN1307658A (zh) 2001-08-08
WO2000000697A1 (fr) 2000-01-06
KR20010071507A (ko) 2001-07-28
PT1099024E (pt) 2004-06-30
AU4779099A (en) 2000-01-17
DE59908592D1 (de) 2004-03-25
EP1099024A1 (fr) 2001-05-16
ID27465A (id) 2001-04-12
ATE259916T1 (de) 2004-03-15
EP1365069A3 (fr) 2004-06-09
ES2216529T3 (es) 2004-10-16

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