EP1221869A1 - Filtre a cigarette hautes performances - Google Patents
Filtre a cigarette hautes performancesInfo
- Publication number
- EP1221869A1 EP1221869A1 EP00972837A EP00972837A EP1221869A1 EP 1221869 A1 EP1221869 A1 EP 1221869A1 EP 00972837 A EP00972837 A EP 00972837A EP 00972837 A EP00972837 A EP 00972837A EP 1221869 A1 EP1221869 A1 EP 1221869A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cigarette filter
- filter
- filter according
- cellulose
- performance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 63
- 239000000835 fiber Substances 0.000 claims abstract description 61
- 229920002678 cellulose Polymers 0.000 claims abstract description 28
- 239000000463 material Substances 0.000 claims abstract description 20
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229920002301 cellulose acetate Polymers 0.000 claims description 33
- 239000004014 plasticizer Substances 0.000 claims description 28
- 230000014759 maintenance of location Effects 0.000 claims description 23
- 239000000654 additive Substances 0.000 claims description 20
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 claims description 17
- 229920001169 thermoplastic Polymers 0.000 claims description 15
- 239000004416 thermosoftening plastic Substances 0.000 claims description 15
- 239000001913 cellulose Substances 0.000 claims description 9
- 238000012360 testing method Methods 0.000 claims description 9
- 229960002622 triacetin Drugs 0.000 claims description 9
- 239000000853 adhesive Substances 0.000 claims description 8
- 235000013773 glyceryl triacetate Nutrition 0.000 claims description 8
- 230000000996 additive effect Effects 0.000 claims description 7
- 239000001087 glyceryl triacetate Substances 0.000 claims description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 230000001070 adhesive effect Effects 0.000 claims description 6
- 230000000694 effects Effects 0.000 claims description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 3
- 150000002170 ethers Chemical class 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 230000004580 weight loss Effects 0.000 claims description 3
- OVOUKWFJRHALDD-UHFFFAOYSA-N 2-[2-(2-acetyloxyethoxy)ethoxy]ethyl acetate Chemical compound CC(=O)OCCOCCOCCOC(C)=O OVOUKWFJRHALDD-UHFFFAOYSA-N 0.000 claims description 2
- DQEFEBPAPFSJLV-UHFFFAOYSA-N Cellulose propionate Chemical compound CCC(=O)OCC1OC(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C1OC1C(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C(COC(=O)CC)O1 DQEFEBPAPFSJLV-UHFFFAOYSA-N 0.000 claims description 2
- 229920000881 Modified starch Polymers 0.000 claims description 2
- 229920002472 Starch Polymers 0.000 claims description 2
- 230000002378 acidificating effect Effects 0.000 claims description 2
- 150000001733 carboxylic acid esters Chemical class 0.000 claims description 2
- 229920001727 cellulose butyrate Polymers 0.000 claims description 2
- 229920006218 cellulose propionate Polymers 0.000 claims description 2
- 235000019426 modified starch Nutrition 0.000 claims description 2
- 150000007524 organic acids Chemical class 0.000 claims description 2
- 235000005985 organic acids Nutrition 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
- 150000008442 polyphenolic compounds Chemical class 0.000 claims description 2
- 235000013824 polyphenols Nutrition 0.000 claims description 2
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 150000004033 porphyrin derivatives Chemical class 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- 238000006467 substitution reaction Methods 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- KGYXYKHTHJPEBX-UHFFFAOYSA-N 5-ethoxy-3-ethoxycarbonyl-3-hydroxy-5-oxopentanoic acid Chemical compound CCOC(=O)CC(O)(CC(O)=O)C(=O)OCC KGYXYKHTHJPEBX-UHFFFAOYSA-N 0.000 claims 1
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 238000002788 crimping Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 description 23
- 238000004519 manufacturing process Methods 0.000 description 21
- 230000008901 benefit Effects 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 12
- 230000008569 process Effects 0.000 description 12
- 238000001914 filtration Methods 0.000 description 11
- 229920000642 polymer Polymers 0.000 description 11
- 239000000047 product Substances 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- 229910000831 Steel Inorganic materials 0.000 description 6
- 238000004132 cross linking Methods 0.000 description 6
- 238000001704 evaporation Methods 0.000 description 6
- 230000008020 evaporation Effects 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 239000000779 smoke Substances 0.000 description 6
- 239000010959 steel Substances 0.000 description 6
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 5
- 229960002715 nicotine Drugs 0.000 description 5
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 241000208125 Nicotiana Species 0.000 description 4
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 4
- 238000010276 construction Methods 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000004745 nonwoven fabric Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 229920003043 Cellulose fiber Polymers 0.000 description 3
- 229920000433 Lyocell Polymers 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000002657 fibrous material Substances 0.000 description 3
- 230000000391 smoking effect Effects 0.000 description 3
- 238000009987 spinning Methods 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- NXQMCAOPTPLPRL-UHFFFAOYSA-N 2-(2-benzoyloxyethoxy)ethyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCCOCCOC(=O)C1=CC=CC=C1 NXQMCAOPTPLPRL-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000006065 biodegradation reaction Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000003490 calendering Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 150000004005 nitrosamines Chemical class 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 1
- QBBTZXBTFYKMKT-UHFFFAOYSA-N 2,3-diacetyloxypropyl acetate Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O.CC(=O)OCC(OC(C)=O)COC(C)=O QBBTZXBTFYKMKT-UHFFFAOYSA-N 0.000 description 1
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 1
- 229920013683 Celanese Polymers 0.000 description 1
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 102000008192 Lactoglobulins Human genes 0.000 description 1
- 108010060630 Lactoglobulins Proteins 0.000 description 1
- 102000015636 Oligopeptides Human genes 0.000 description 1
- 108010038807 Oligopeptides Proteins 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 229920006221 acetate fiber Polymers 0.000 description 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 239000002592 antimutagenic agent Substances 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 125000000609 carbazolyl group Chemical class C1(=CC=CC=2C3=CC=CC=C3NC12)* 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 206010061592 cardiac fibrillation Diseases 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical class OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical group CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- -1 fatty acid esters Chemical class 0.000 description 1
- 230000002600 fibrillogenic effect Effects 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 1
- 239000004312 hexamethylene tetramine Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920005606 polypropylene copolymer Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920001289 polyvinyl ether Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 238000002411 thermogravimetry Methods 0.000 description 1
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 1
- 238000000870 ultraviolet spectroscopy Methods 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 230000003442 weekly effect Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/067—Use of materials for tobacco smoke filters characterised by functional properties
- A24D3/068—Biodegradable or disintegrable
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/04—Tobacco smoke filters characterised by their shape or structure
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/08—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent
- A24D3/10—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent of cellulose or cellulose derivatives
Definitions
- the advantages of the overall process lie in the high efficiency of the filter tow production, the low transport costs from the filter tow manufacturer to the end customer and in particular the high productivity in the filter production, which is not insignificantly determined by the length of the belts in the bales.
- Filter Tow is processed on commercially available filter rod machines, such as, for example, the KDF 3 / AF 3 from Körber AG, Hamburg. Production speeds of currently 600 m / min are state of the art.
- the productivity of filter production can be increased significantly when using the double-strand technology described in DE-A-43 40 029 and when using the twin-tow technology shown in DE-A-43 20 303.
- the invention is therefore based on the object of providing surface filters based on endless cellulose ester fibers which do not have the disadvantages of the prior art explained above, in particular of the filter described in US Pat. No. 4,007,745. Even without three-dimensional crosslinking, these should have sufficient hardness, and their mechanical disintegration capability should correspond to that of surface filters which were produced from nonwovens with short-cut fibers.
- the Filtrona hardness should be based on the market requirements.
- the area filters are to retain the advantageous properties known from the prior art or, in individual cases, improved properties.
- a filter plug can be heated in an inert gas stream and the evaporation kinetics can be verified by combustion in a commercially available flame ionization detector (FID).
- FID flame ionization detector
- the evaporation rate one in the Fiber evenly applied plasticizer differs sustainably from that of a superficially applied plasticizer. Since the evaporation is diffusion-controlled, the evaporation kinetics are significantly slower with even distribution than with surface application. Another possibility is to display the evaporation kinetics using differential thermogravimetry. Thirdly, the uniform distribution can be determined by short-term extraction methods in solvents suitable for the polymer with subsequent quantitative analysis of the plasticizer.
- the ratio of fiber weight / tensile resistance S based on the filament titer according to the formula described above is greater than approximately 0.7. If this value is undershot, this leads to retention values as are customary in conventional cellulose acetate feeds.
- the fiber weight / tensile resistance ratio S based on the filament titer is preferably at most about 2, and is in particular in the range from about 0.8 to 1.3. If the preferred value of about 2 for the ratio S is exceeded, then this product no longer meets the desired economic requirements.
- the following general conditions preferably apply:
- cellulose acetate flakes were introduced into a double-walled universal mixer with a total volume of 615 liters and a cooling / heating device.
- the mixing tool 1 is in one piece with three blades all the way around the bottom and placed vertically on the drive shaft.
- a one-piece, four-bladed chopper tool 2 is attached horizontally to the drive shaft, which prevents agglomerate formation during the addition and diffusion of plasticizer and is operated at a peripheral speed of 21 m / sec (2890 rpm).
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biodiversity & Conservation Biology (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Nonwoven Fabrics (AREA)
- Filtering Materials (AREA)
- Paper (AREA)
Abstract
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SI200030331T SI1221869T1 (en) | 1999-10-22 | 2000-10-20 | High performance cigarette filter |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19951062A DE19951062C2 (de) | 1999-10-22 | 1999-10-22 | Hochleistungs-Zigarettenfilter |
| DE19951062 | 1999-10-22 | ||
| PCT/EP2000/010389 WO2001028369A1 (fr) | 1999-10-22 | 2000-10-20 | Filtre a cigarette hautes performances |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1221869A1 true EP1221869A1 (fr) | 2002-07-17 |
| EP1221869B1 EP1221869B1 (fr) | 2004-01-21 |
Family
ID=7926613
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP00972837A Expired - Lifetime EP1221869B1 (fr) | 1999-10-22 | 2000-10-20 | Filtre a cigarette hautes performances |
Country Status (26)
| Country | Link |
|---|---|
| US (1) | US6776168B1 (fr) |
| EP (1) | EP1221869B1 (fr) |
| JP (1) | JP3726061B2 (fr) |
| KR (1) | KR100505177B1 (fr) |
| CN (1) | CN1221193C (fr) |
| AT (1) | ATE258017T1 (fr) |
| AU (1) | AU764251B2 (fr) |
| BR (1) | BR0015000B1 (fr) |
| CA (1) | CA2387487C (fr) |
| CZ (1) | CZ296610B6 (fr) |
| DE (2) | DE19951062C2 (fr) |
| DK (1) | DK1221869T3 (fr) |
| EA (1) | EA003238B1 (fr) |
| ES (1) | ES2216978T3 (fr) |
| GE (1) | GEP20043215B (fr) |
| HU (1) | HUP0203081A3 (fr) |
| IL (1) | IL149234A0 (fr) |
| MX (1) | MXPA02003968A (fr) |
| NZ (1) | NZ518131A (fr) |
| PL (1) | PL202497B1 (fr) |
| PT (1) | PT1221869E (fr) |
| SI (1) | SI1221869T1 (fr) |
| SK (1) | SK285134B6 (fr) |
| UA (1) | UA67876C2 (fr) |
| WO (1) | WO2001028369A1 (fr) |
| ZA (1) | ZA200202967B (fr) |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004048651A1 (de) * | 2004-10-06 | 2006-04-13 | Rhodia Acetow Gmbh | Tabakrauchfilter oder -filterelemente mit einem Gehalt an Zusatzstoffen |
| US8646463B2 (en) * | 2005-08-15 | 2014-02-11 | Philip Morris Usa Inc. | Gravure-printed, banded cigarette paper |
| GB0517551D0 (en) * | 2005-08-27 | 2005-10-05 | Acetate Products Ltd | Process for making filter tow |
| US20080035163A1 (en) * | 2006-08-10 | 2008-02-14 | Shaahin Cheyene | Magnetic Advanced Cigarette Filtration System |
| DE102007061932A1 (de) * | 2007-12-21 | 2009-06-25 | Rhodia Acetow Gmbh | Filtertowstreifen, Filterstabmaschine, Verfahren zum Herstellen von Filtertowstreifen und Verfahren zum Herstellen von Filterstäben |
| WO2010017989A1 (fr) * | 2008-08-14 | 2010-02-18 | Rhodia Acetow Gmbh | Matière plastique photodégradable et son utilisation |
| DE102008051579A1 (de) | 2008-10-14 | 2010-04-15 | Rhodia Acetow Gmbh | Biologisch abbaubarer Kunststoff und Verwendung desselben |
| US8534294B2 (en) | 2009-10-09 | 2013-09-17 | Philip Morris Usa Inc. | Method for manufacture of smoking article filter assembly including electrostatically charged fiber |
| GB2474694B (en) * | 2009-10-23 | 2011-11-02 | Innovia Films Ltd | Biodegradable composites |
| GB0920397D0 (en) * | 2009-11-20 | 2010-01-06 | Filtrona Int Ltd | Tobacco smoke filter |
| GB0922253D0 (en) * | 2009-12-21 | 2010-02-03 | British American Tobacco Co | Sheet filter materials with additives |
| GB0922254D0 (en) * | 2009-12-21 | 2010-02-03 | British American Tobacco Co | Enhancing the disintegration and/or degradation of a smoking article |
| EP2357277A1 (fr) | 2010-02-12 | 2011-08-17 | Rhodia Acetow GmbH | Papier photodégradable et son utilisation |
| CN101858042A (zh) * | 2010-06-13 | 2010-10-13 | 湖南中烟工业有限责任公司 | 选择性降低烟气中苯酚等有害物卷烟成形纸功能涂料 |
| GB2490727A (en) * | 2011-05-13 | 2012-11-14 | British American Tobacco Co | An arrangement of smoking article additive-containing members for filters |
| US20120325231A1 (en) * | 2011-06-23 | 2012-12-27 | Eastman Chemical Company | Filters having improved degradation and methods of making them |
| CN102499475B (zh) * | 2011-10-16 | 2015-05-13 | 上海华宝生物科技有限公司 | 一种复合固型滤棒及其制备方法 |
| US8967155B2 (en) | 2011-11-03 | 2015-03-03 | Celanese Acetate Llc | Products of high denier per filament and low total denier tow bands |
| CN104411189A (zh) * | 2012-07-13 | 2015-03-11 | 菲利普莫里斯生产公司 | 用于吸烟制品的可降解型过滤嘴 |
| CN103126075B (zh) * | 2013-03-05 | 2014-08-06 | 湖南中烟工业有限责任公司 | 一种可降低卷烟主流烟气中酚类化合物的滤棒纤维基材添加剂及应用 |
| CN103126074B (zh) * | 2013-03-05 | 2014-08-20 | 湖南中烟工业有限责任公司 | 一种可降低卷烟主流烟气中酚类化合物的纸质滤棒滤芯基材添加剂及应用 |
| WO2015007400A1 (fr) | 2013-07-16 | 2015-01-22 | Philip Morris Products S.A. | Filtre d'article à fumer radialement ferme |
| CN103932381B (zh) * | 2014-05-04 | 2015-12-02 | 广东中烟工业有限责任公司 | 一种丰富口腔味觉的利咽卷烟 |
| BR112018003916A2 (pt) * | 2015-08-28 | 2018-09-25 | Jt International S.A. | ?artigo de fumo? |
| WO2017036588A1 (fr) * | 2015-08-28 | 2017-03-09 | Jt International S.A. | Article à fumer |
| JP7109888B2 (ja) * | 2016-06-02 | 2022-08-01 | セラニーズ・インターナショナル・コーポレーション | スピナレットを使用したセルロースアセテートトウを製造する方法 |
| DE102017007455A1 (de) * | 2017-08-08 | 2019-02-14 | Hauni Maschinenbau Gmbh | Maschine der Tabak verarbeitenden Industrie zur gleichzeitigen Herstellung mehrerer Stränge |
| US12484611B2 (en) | 2017-12-28 | 2025-12-02 | Philip Morris Products S.A. | Firm filter for aerosol-generating article |
| CN108606360B (zh) * | 2018-03-16 | 2021-05-18 | 河南中烟工业有限责任公司 | 一种二酯类烟用香料在卷烟中的应用 |
| WO2020115898A1 (fr) * | 2018-12-07 | 2020-06-11 | 日本たばこ産業株式会社 | Article à fumer de type chauffant non combustible et système à fumer de type chauffant électrique |
| CN109813646B (zh) * | 2019-03-21 | 2021-03-30 | 红云红河烟草(集团)有限责任公司 | 一种预测卷烟吸阻的方法 |
| DE202019001738U1 (de) | 2019-04-18 | 2019-05-14 | Wintersun Co., Ltd | Zigarette mit einem aus Polylactid (PLA) aufgebauten Zigaretten-Filter |
| EP4240181B1 (fr) * | 2020-12-18 | 2024-03-20 | Philip Morris Products S.A. | Article de génération d'aérosol comportant un élément tubulaire creux |
| DE102021125415A1 (de) | 2021-09-30 | 2023-03-30 | Cerdia International GmbH | Filterelement für mundstücke zur verwendung mit rauchwaren oder hnb-produkten |
| DE102022102066B4 (de) * | 2022-01-28 | 2025-09-04 | Delfortgroup Ag | Segment für rauchartikel mit kalandrierter faserbahn |
| DE102022102862A1 (de) | 2022-02-08 | 2023-08-10 | Cerdia International GmbH | Filterelement für mundstücke, mundstück zur verwendung mit rauchwaren oder hnb-produkten und zigarettenfilter |
| KR20230147314A (ko) * | 2022-04-14 | 2023-10-23 | 주식회사 케이티앤지 | 라이오셀 토우를 포함하는 담배 필터 및 이의 제조방법 |
| KR102864708B1 (ko) * | 2022-07-28 | 2025-09-29 | 주식회사 케이티앤지 | 생분해도를 가지는 친환경 필터 |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3224453A (en) * | 1959-06-12 | 1965-12-21 | Celanese Corp | Filter cigarettes |
| US3050430A (en) * | 1959-11-12 | 1962-08-21 | Eastman Kodak Co | Jet and method of filter manufacture |
| DE1560800A1 (de) * | 1966-02-10 | 1971-01-07 | Lutravil Spinnvlies | Verfahren und Vorrichtung zur Herstellung von Mischvliesen durch Schmelzspinnen |
| GB1200219A (en) | 1966-12-13 | 1970-07-29 | Mitsubishi Rayon Co | Cigarette filters |
| US3552400A (en) * | 1967-06-08 | 1971-01-05 | American Filtrona Corp | Filter plug of staple fiber filter elements and the like |
| GB1264894A (fr) * | 1968-06-17 | 1972-02-23 | ||
| US4007745A (en) * | 1971-03-23 | 1977-02-15 | Celanese Corporation | Filter |
| AU514462B2 (en) * | 1976-10-06 | 1981-02-12 | Celanese Corporation | Filter material |
| DE2658479C3 (de) * | 1976-12-23 | 1981-10-01 | Rhodia Ag, 7800 Freiburg | Zusatzmittel für Rauchtabakprodukte und deren Filterelemente |
| US5215819A (en) * | 1989-05-17 | 1993-06-01 | Bayer Aktiengesellschaft | Processes for the production of mono- and multifilaments and staple fibers based on kolyarylene sulfides and high-strength polyarylene sulfide fibers |
| US5404890A (en) * | 1993-06-11 | 1995-04-11 | R. J. Reynolds Tobacco Company | Cigarette filter |
| DE4320303C1 (de) * | 1993-06-18 | 1995-02-16 | Rhodia Ag Rhone Poulenc | Mehrfachbreiter Faserstreifen sowie ein Verfahren und eine Vorrichtung zu dessen Herstellung |
| DE4320317C2 (de) * | 1993-06-18 | 1998-04-23 | Rhodia Ag Rhone Poulenc | Verfahren und Vorrichtung zum Herstellen von Fasersträngen |
| DE4322966C2 (de) * | 1993-07-09 | 1995-10-26 | Rhodia Ag Rhone Poulenc | Aus Celluloseacetat geformte Gebilde und ihre Verwendung als Filtertow und Tabakrauchfilterelement |
| DE4322965C1 (de) * | 1993-07-09 | 1994-10-06 | Rhodia Ag Rhone Poulenc | Filtertow und Verfahren zu dessen Herstellung sowie dessen Verwendung als Tabakrauchfilterelement |
| DE4345569B4 (de) * | 1993-11-24 | 2006-06-08 | Hauni Maschinenbau Ag | Anordnung zum Aufbereiten eines Streifens aus Filtermaterial |
| CN1063929C (zh) * | 1993-11-29 | 2001-04-04 | 考脱沃兹纤维控股有限公司 | 香烟过滤嘴和香烟 |
| GB9412311D0 (en) * | 1994-06-20 | 1994-08-10 | Courtaulds Fibres Holdings Ltd | Filter materials |
| JP3390278B2 (ja) * | 1994-12-05 | 2003-03-24 | ダイセル化学工業株式会社 | セルロースエステル組成物および成形品 |
| US5491024A (en) * | 1995-03-14 | 1996-02-13 | Hoechst Celanese Corporation | Photodegradable cellulose ester tow |
| JP3606950B2 (ja) | 1995-05-31 | 2005-01-05 | ダイセル化学工業株式会社 | たばこフィルターおよびその製造方法 |
| JP3576292B2 (ja) | 1995-10-05 | 2004-10-13 | ダイセル化学工業株式会社 | たばこフィルターおよびその製造方法 |
| DE19541873A1 (de) * | 1995-11-09 | 1997-05-15 | Rhodia Ag Rhone Poulenc | Filterzigarette |
| DE19609143C1 (de) * | 1996-03-08 | 1997-11-13 | Rhodia Ag Rhone Poulenc | Melt-blown-Vlies, Verfahren zu dessen Herstellung und dessen Verwendungen |
| US5947126A (en) * | 1997-05-29 | 1999-09-07 | Eastman Chemical Co. | Environmentally disintegratable tobacco smoke filter rod |
| DE19730485C2 (de) | 1997-07-16 | 2003-07-03 | Rhodia Acetow Ag | Celluloseacetatfilamente mit trilobalem Querschnitt |
-
1999
- 1999-10-22 DE DE19951062A patent/DE19951062C2/de not_active Expired - Fee Related
-
2000
- 2000-10-20 AT AT00972837T patent/ATE258017T1/de active
- 2000-10-20 BR BRPI0015000-2A patent/BR0015000B1/pt not_active IP Right Cessation
- 2000-10-20 CZ CZ20021383A patent/CZ296610B6/cs not_active IP Right Cessation
- 2000-10-20 CN CNB008170444A patent/CN1221193C/zh not_active Expired - Fee Related
- 2000-10-20 GE GEAP20006456A patent/GEP20043215B/en unknown
- 2000-10-20 KR KR10-2002-7005166A patent/KR100505177B1/ko not_active Expired - Fee Related
- 2000-10-20 HU HU0203081A patent/HUP0203081A3/hu unknown
- 2000-10-20 IL IL14923400A patent/IL149234A0/xx not_active IP Right Cessation
- 2000-10-20 JP JP2001530972A patent/JP3726061B2/ja not_active Expired - Fee Related
- 2000-10-20 SK SK529-2002A patent/SK285134B6/sk not_active IP Right Cessation
- 2000-10-20 CA CA002387487A patent/CA2387487C/fr not_active Expired - Fee Related
- 2000-10-20 AU AU11429/01A patent/AU764251B2/en not_active Ceased
- 2000-10-20 ES ES00972837T patent/ES2216978T3/es not_active Expired - Lifetime
- 2000-10-20 PT PT00972837T patent/PT1221869E/pt unknown
- 2000-10-20 SI SI200030331T patent/SI1221869T1/xx unknown
- 2000-10-20 NZ NZ518131A patent/NZ518131A/en unknown
- 2000-10-20 PL PL355636A patent/PL202497B1/pl not_active IP Right Cessation
- 2000-10-20 UA UA2002054166A patent/UA67876C2/uk unknown
- 2000-10-20 EP EP00972837A patent/EP1221869B1/fr not_active Expired - Lifetime
- 2000-10-20 EA EA200200482A patent/EA003238B1/ru not_active IP Right Cessation
- 2000-10-20 US US10/110,953 patent/US6776168B1/en not_active Expired - Fee Related
- 2000-10-20 DK DK00972837T patent/DK1221869T3/da active
- 2000-10-20 DE DE50005096T patent/DE50005096D1/de not_active Expired - Lifetime
- 2000-10-20 MX MXPA02003968A patent/MXPA02003968A/es active IP Right Grant
- 2000-10-20 WO PCT/EP2000/010389 patent/WO2001028369A1/fr not_active Ceased
-
2002
- 2002-04-16 ZA ZA200202967A patent/ZA200202967B/xx unknown
Non-Patent Citations (1)
| Title |
|---|
| See references of WO0128369A1 * |
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP1221869B1 (fr) | Filtre a cigarette hautes performances | |
| EP1796488B1 (fr) | Filtre ou element filtrant de fumee de tabac ayant une teneur en additifs | |
| DE69619433T2 (de) | Tabakrauchfilter und Verfahren zur Herstellung derselben | |
| DE69009103T2 (de) | Nichtgewebte Faserbahn für Tabakrauchfilter. | |
| EP3861159B1 (fr) | Matériau filtrant consolidé par hydro-jet pour articles à fumer | |
| EP0859558B1 (fr) | Cigarette filtre | |
| EP4064883B1 (fr) | Matériau filtrant structuré pour produits de délivrance de nicotine | |
| EP4076045B1 (fr) | Procédé de fabrication d'un matériau de filtre et/ou matériau de remplissage pour embouts destinés à être utilisés avec des produits à fumer ou des produits hnb, embouts et filtres de cigarette comprenant un tel matériau de filtre et/ou matériau de remplissage | |
| DE2744796A1 (de) | Filtermaterial, seine herstellung und verwendung | |
| EP4475696B1 (fr) | Élément filtre pour embouts buccaux, embout buccal destiné à être utilisé dans des produits à fumer ou des produits à chauffage sans combustion (hnb), et filtre de cigarette | |
| EP4408205B1 (fr) | Élément filtrant pour embouts buccaux à utiliser dans des produits à fumer ou des produits hnb (à chauffer sans combustion) | |
| EP4240905B1 (fr) | Segment pour un article à fumer comprenant une bande fibreuse calandrée | |
| WO2024170274A1 (fr) | Matériau fibreux destiné à être utilisé en tant que matériau de filtre et/ou matériau de remplissage pour embouts, mèche faite d'un tel matériau fibreux et embouts pour produits à fumer faits d'un tel matériau de mèche | |
| HK1054491B (en) | High performance cigarette filter |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| 17P | Request for examination filed |
Effective date: 20020225 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE |
|
| AX | Request for extension of the european patent |
Free format text: AL;LT PAYMENT 20020225;LV PAYMENT 20020225;MK;RO PAYMENT 20020225;SI PAYMENT 20020225 |
|
| 17Q | First examination report despatched |
Effective date: 20020826 |
|
| GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
| GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
| GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
| AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE |
|
| AX | Request for extension of the european patent |
Extension state: LT LV RO SI |
|
| REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
| REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: GERMAN |
|
| REF | Corresponds to: |
Ref document number: 50005096 Country of ref document: DE Date of ref document: 20040226 Kind code of ref document: P |
|
| GBT | Gb: translation of ep patent filed (gb section 77(6)(a)/1977) |
Effective date: 20040407 |
|
| REG | Reference to a national code |
Ref country code: SE Ref legal event code: TRGR |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: NV Representative=s name: ISLER & PEDRAZZINI AG |
|
| REG | Reference to a national code |
Ref country code: GR Ref legal event code: EP Ref document number: 20040401224 Country of ref document: GR Ref country code: DK Ref legal event code: T3 |
|
| REG | Reference to a national code |
Ref country code: PT Ref legal event code: SC4A Free format text: AVAILABILITY OF NATIONAL TRANSLATION Effective date: 20040420 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20041031 |
|
| REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2216978 Country of ref document: ES Kind code of ref document: T3 |
|
| ET | Fr: translation filed | ||
| PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
| REG | Reference to a national code |
Ref country code: SI Ref legal event code: IF |
|
| 26N | No opposition filed |
Effective date: 20041022 |
|
| REG | Reference to a national code |
Ref country code: PT Ref legal event code: MM4A Effective date: 20050720 |
|
| REG | Reference to a national code |
Ref country code: PT Ref legal event code: NF4A Free format text: RESTITUTIO IN INTEGRUM Effective date: 20061013 |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: PCAR Free format text: ISLER & PEDRAZZINI AG;POSTFACH 1772;8027 ZUERICH (CH) |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DK Payment date: 20081024 Year of fee payment: 9 Ref country code: IE Payment date: 20081028 Year of fee payment: 9 Ref country code: LU Payment date: 20081027 Year of fee payment: 9 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FI Payment date: 20081027 Year of fee payment: 9 Ref country code: PT Payment date: 20081008 Year of fee payment: 9 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: SE Payment date: 20081027 Year of fee payment: 9 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CY Payment date: 20081009 Year of fee payment: 9 |
|
| REG | Reference to a national code |
Ref country code: PT Ref legal event code: MM4A Free format text: LAPSE DUE TO NON-PAYMENT OF FEES Effective date: 20100420 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: BE Payment date: 20091029 Year of fee payment: 10 |
|
| EUG | Se: european patent has lapsed | ||
| REG | Reference to a national code |
Ref country code: DK Ref legal event code: EBP |
|
| REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20100420 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20091020 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20091020 Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20091020 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DK Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20091031 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20101109 Year of fee payment: 11 Ref country code: AT Payment date: 20101020 Year of fee payment: 11 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CH Payment date: 20101025 Year of fee payment: 11 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GR Payment date: 20101020 Year of fee payment: 11 Ref country code: IT Payment date: 20101028 Year of fee payment: 11 Ref country code: GB Payment date: 20101021 Year of fee payment: 11 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20091020 |
|
| BERE | Be: lapsed |
Owner name: *RHODIA ACETOW G.M.B.H. Effective date: 20101031 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20091021 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20101031 |
|
| REG | Reference to a national code |
Ref country code: SI Ref legal event code: KO00 Effective date: 20110728 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: ES Payment date: 20111024 Year of fee payment: 12 Ref country code: NL Payment date: 20111025 Year of fee payment: 12 |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
| REG | Reference to a national code |
Ref country code: GR Ref legal event code: ML Ref document number: 20040401224 Country of ref document: GR Effective date: 20120503 |
|
| REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST Effective date: 20120629 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20111031 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20111031 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20120503 Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20111102 |
|
| REG | Reference to a national code |
Ref country code: AT Ref legal event code: MM01 Ref document number: 258017 Country of ref document: AT Kind code of ref document: T Effective date: 20111020 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20111020 |
|
| REG | Reference to a national code |
Ref country code: NL Ref legal event code: V1 Effective date: 20130501 |
|
| GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20121020 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20121020 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20130501 Ref country code: IT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20121020 |
|
| REG | Reference to a national code |
Ref country code: ES Ref legal event code: FD2A Effective date: 20140116 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20121021 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20161025 Year of fee payment: 17 |
|
| REG | Reference to a national code |
Ref country code: DE Ref legal event code: R082 Ref document number: 50005096 Country of ref document: DE Representative=s name: MEISSNER BOLTE PATENTANWAELTE RECHTSANWAELTE P, DE |
|
| REG | Reference to a national code |
Ref country code: DE Ref legal event code: R119 Ref document number: 50005096 Country of ref document: DE |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20180501 |