EP1220800B1 - Couvercle de recipient a isolation thermique - Google Patents
Couvercle de recipient a isolation thermique Download PDFInfo
- Publication number
- EP1220800B1 EP1220800B1 EP00969364A EP00969364A EP1220800B1 EP 1220800 B1 EP1220800 B1 EP 1220800B1 EP 00969364 A EP00969364 A EP 00969364A EP 00969364 A EP00969364 A EP 00969364A EP 1220800 B1 EP1220800 B1 EP 1220800B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- container
- lid
- thermally insulated
- port
- rotary
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000007789 sealing Methods 0.000 claims abstract description 4
- 238000001816 cooling Methods 0.000 claims description 13
- 239000002826 coolant Substances 0.000 description 26
- 239000000463 material Substances 0.000 description 15
- 235000015243 ice cream Nutrition 0.000 description 12
- 229920005830 Polyurethane Foam Polymers 0.000 description 8
- 239000011496 polyurethane foam Substances 0.000 description 8
- 230000005496 eutectics Effects 0.000 description 5
- 238000009413 insulation Methods 0.000 description 5
- 239000003507 refrigerant Substances 0.000 description 5
- 235000013305 food Nutrition 0.000 description 4
- 238000005057 refrigeration Methods 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 239000000374 eutectic mixture Substances 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000004794 expanded polystyrene Substances 0.000 description 3
- 230000008014 freezing Effects 0.000 description 3
- 238000007710 freezing Methods 0.000 description 3
- 229920000092 linear low density polyethylene Polymers 0.000 description 3
- 239000004707 linear low-density polyethylene Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000003491 array Methods 0.000 description 2
- 239000002775 capsule Substances 0.000 description 2
- 235000011089 carbon dioxide Nutrition 0.000 description 2
- 235000011850 desserts Nutrition 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229920006327 polystyrene foam Polymers 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- 229920002430 Fibre-reinforced plastic Polymers 0.000 description 1
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 1
- 239000005041 Mylar™ Substances 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 230000031018 biological processes and functions Effects 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000004795 extruded polystyrene foam Substances 0.000 description 1
- 239000011151 fibre-reinforced plastic Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 235000013611 frozen food Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011491 glass wool Substances 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 229920001179 medium density polyethylene Polymers 0.000 description 1
- 239000004701 medium-density polyethylene Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000014214 soft drink Nutrition 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/38—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents with thermal insulation
- B65D81/3813—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents with thermal insulation rigid container being in the form of a box, tray or like container
- B65D81/3818—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents with thermal insulation rigid container being in the form of a box, tray or like container formed with double walls, i.e. hollow
Definitions
- the present invention relates to a container cover with port. It particularly relates to the design of a lid assembly suitable for adapting to an insulated container for maintaining the contents below 10°C, even while the container is opened frequently at high ambient temperatures while providing for convenient loading of and easy accessibility to the contents. It also relates to a container equipped with such lid.
- US 5743427 discloses a lid of a container with a discharge aperture in the lid to allow the consumption of a drink through the lid but the discharge aperture area is designed only for fluid food stuffs.
- WO 9925622 provides a container with a reclosable discharge aperture for food stuffs in particular frozen foods and confections. This invention does not solve the problem of prolonged storage of material under conditions of repeated exposure to high temperature e.g. during vending of foodstuff.
- a purpose of the present invention is to design a lid assembly for an insulated container provided with economical amounts of the cooling system that allows convenient loading and easy and frequent retrieval of the contents while maintaining the temperature of the contents below 10°C for long enough time periods.
- It is a first object of the present invention to provide a thermally insulated lid assembly for an insulated container comprising a thermally insulated rotary lid capable of sealing the opening of the inner cavity of the container adapted to hold the objects to be stored therein, the said rotary lid being provided with at least one eccentrically positioned retrieval port and a thermally insulated plug for the said port.
- the rotary lid can rotate around one axis or more than one.
- the rotary lid rotates around one axis.
- the lid assembly is seated on and rotates over a circular opening of the container leading to the inner storage cavity. The rotation of the lid is facilitated by providing advantageous features such as smooth contact surfaces, lubrication, guided ball bearings in a channel, etc.
- the rotary lid is provided with a fixed or detachable cooling arrangement such as one or more eutectic pads etc.
- the face of the rotary lid on the inner cavity side can be provided with cooling means such as eutectic/coolant pads and devices to hold them in place. This allows for a further cooling capacity within the container while, in the prior art, where lids, when opened, show the whole container opening, it is not possible to have additional cooling means beneath the lid.
- the retrieval port provided in the rotary lid is located eccentrically in order to maximise the area swept by the port over the storage cavity and hence provide a better view of the contents and facilitate access to the specific item from the storage cavity.
- the plug of the port is opened to retrieve the contents during vending.
- the port can be of any geometrically regular shape such as circular, oval, square, rectangular, triangular or any other irregular shape.
- the area of the port with respect to the lid is less than 40%, preferably less than 25%, even more preferably less than 10%.
- the plug may be free, hinged, flippable or otherwise fastened to the rotary lid or the outer part of the container.
- the lid is transparent. This allows for seeing the inside of the container and rotating the lid in order to have the port above the product to be taken out.
- the insulated storage container may be designed to have any suitable shape such as a parallelopiped, cube, sphere, cylinder or other attractive geometry.
- the container can be employed in the horizontal position with the major dimension parallel to the ground or in the vertical position with the major dimension perpendicular to the ground.
- the mouth and lid can be placed on top of the container or on any of its sides.
- the container, rotary lid and the plug for the port may be made from any suitable material capable of withstanding low temperatures.
- suitable materials of construction are low carbon steel, stainless steel, galvanised iron, aluminium, polymeric materials such as high/medium/low density polyethylene, linear low density polyethylene, polyvinyl chloride, polycarbonate, polyester, thermally insulating foams such as polyurethane foam and expanded polystyrene foam etc.
- the container, rotary lid and the plug of the port can be thermally insulated using polyurethane foam, expanded polystyrene foam, vacuum superinsulation, glass wool, vacuum panels containing powder or open cell polyurethane foam or any other suitable material known in the art.
- the preferred mode of thermal insulation for the container is multilayer vacuum superinsulation.
- the vacuum in the annular space between the outer envelope and inner cavity is preferably of the order of 500 Pa or lower.
- materials such as open cell polyurethane foam, speciality silica, multi-layered sheets of low thermal emmissivity alternating with low thermal conductivity spacer materials etc. may be provided to enhance structural integrity and/or minimise radiative heat transfer.
- the preferred materials are multi-layered foils of aluminium spaced with thermal insulator or aluminised mylar films.
- the preferred thermal insulation for the outer rotary lid and the plug to the port is by using polyurethane foam, expanded or extruded polystyrene foam.
- the insulated container is provided with additional cooling means and preferably a coolant with a heat absorption capacity of >50 joules/gram in the temperature range of 10°C and -80°C.
- a suitable coolant for the container as well as the rotary lid can be particles of dry ice.
- sealed pads containing different coolants as specified above can be in the form of bags, arrays of ampoules, bottles, blocks, sachets, blister packs etc. to serve as "coolant batteries" for this purpose.
- the coolant within the pads may be partially or fully frozen at a low enough temperature.
- the pads may be loose filled or they can be stacked along the inner surface of the container using a retainer device to improve accessibility of the stored food articles.
- the coolant pads may also be attached to the surface under the rotary lid.
- the cooling surface may be provided in the form of pads or jackets fixed to the inner cavity of the container and cooled/frozen in place using primary refrigeration liquid such as R-12, CARE-30 circulated through conduits of appropriate design attached to the coolant pads/jackets.
- the source of primary refrigerant may be attached to the container or may be located separately and coupled to the container as and when required.
- the sealed jackets/pads fixed to the inner vessel may be cooled using secondary refrigerant brines such as aqueous solutions of freezing point depressants or eutectic mixtures of salts in water circulated through conduits of appropriate design.
- the source of circulating secondary refrigeration brines may be attached to the container or may be located externally and coupled to the container as and when required.
- the inner cavity of the container may be cooled directly employing primary refrigerant liquid such as R-12, CARE - 30 etc. circulated in coils/jackets/conduits of appropriate design.
- the source of primary refrigerant may be attached to the container or may be located separately and coupled to the container as and when required.
- the inner cavity of the container may be cooled using secondary refrigerant brines such as aqueous solutions of freezing point depressants or eutectic mixtures of salts in water circulated through coils/jackets/conduits of appropriate design.
- the source of circulating secondary refrigeration brines may be attached to the container or may be located externally and coupled to the container as and when required.
- the coolant jackets and pads and conduits can be made from suitable material of construction capable of withstanding low temperatures.
- suitable material of construction capable of withstanding low temperatures.
- the examples of such materials have been described above. It can be in the form of single unit packs or as detachable/removable units of varying form, shape and size. They can be in the form of discrete arrays of ampoules, capsules or blister packs which are preferably flexible yet self standing when placed in position. They can also be in the form of continuous mats of interconnected blister packs, ampoules or capsules.
- the container was double walled with walls (wl and w2).
- the inner vessel forming the internal cavity (IC) and the outer envelope (OE) were made from aluminium alloy sheet, 3mm thick.
- the inner vessel had a diameter of 460mm and height of 470mm.
- the outer envelope had a diameter of 540mm and height of 645mm.
- the volume of the inner cavity was 75 litres and the empty weight was 30.0kg.
- the annular space (AS) between the inner vessel and outer envelope was evacuated to a vacuum of - 1.33 X 10 -4 Pa. Additionally, multi-layered sheets of aluminium alternating with paper were provided to minimise radiative heat transfer. Zirconium "getters" to scavenge gases were also provided in the annular space in order to prolong service life, and minimise heat ingress.
- the cooling medium was provided in the form of pads filled with a eutectic coolant at -23°C in the inner storage cavity.
- the freezing/melting temperature of the eutectic coolant was ⁇ -23°C with a heat absorption capacity of - 230 Joules/gram.
- the opening (O) was circular in cross section, located on top of the container and comprised of fibre reinforced plastic neck (N) and a circular aluminium ring (AR) at the top.
- the diameter of the mouth was 450mm.
- FIG 2 shows a schematic view of the rotary lid assembly and plug to the port.
- the rotary lid (RL) forming the lid was constructed of linear low density polyethylene and insulated with polyurethane foam (TI) of density 40kg per cubic metre.
- the top plate (TP) of the rotary lid rests on the aluminium ring (AR as in Figure 1) and can be rotated in place.
- the insulation thickness in the lid was 125mm.
- the lid was provided with a square port (P) of side 180mm.
- the plug (PL) of the port was constructed of linear low density polyethylene and insulated with polyurethane foam (TI) of density 40kg per cubic metre.
- the insulation thickness in the plug was 125mm.
- the rim of the opening of the inner cavity and the lid were polished smoothly to minimise friction and allow easy rotation of the lid.
- Two handles (H1 and H2) were provided on the outer rotary lid and one handle (H3) on the plug to the port.
- the weight of the port plug with handle was 0.5kg and the weight of the entire rotary lid assembly was 3.0kgs.
- the containers were pre-cooled from the ambient temperature of 30°C to a temperature of ⁇ -20°C by loading 2.0kg of pre-frozen pads containing eutectic coolant at -23°C described above.
- Table 2 lists the design features of the lids on the above containers. Design and Constructional features of lid Placement of Coolant Limitations on coolant placement Container 1 1.5kg below lid 1.5kg at bottom of container None Container 2 3.0kg at bottom of container Cannot be placed below lid since the coolant would be exposed to high ambient temperature frequently. Container 3 3.0kg at bottom of container Cannot be placed below lid since there are six ports in the lid.
- the insulated container with a rotating lid and port is convenient to use, provides easy accessibility and clear visibility of the contents and can preserve ice creams below the desired temperature for a longer time as compared to the other containers.
- the proposed lid assembly as described above has several advantages over the conventional designs. These are:
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Packages (AREA)
- Table Devices Or Equipment (AREA)
- Closures For Containers (AREA)
Claims (7)
- Couvercle à isolation thermique pour un conteneur isotherme comprenant un couvercle rotatif à isolation thermique (CR) capable de sceller une ouverture d'une cavité intérieure (CI) du conteneur adapté pour supporter des objets devant y être stockés, ledit couvercle rotatif (CR) étant pourvu au moins d'un orifice d'extraction placé de façon excentrique et d'un bouchon mâle à isolation thermique (BM) pour ledit orifice.
- Couvercle à isolation thermique selon la revendication 1, dans lequel la zone de l'orifice par rapport au couvercle (CR) est inférieure à 40%, de préférence, inférieure à 25%.
- Couvercle à isolation thermique selon la revendication 1, dans lequel le couvercle (CR) est transparent.
- Couvercle à isolation thermique comprenant un couvercle rotatif à isolation thermique (CR) capable de sceller une ouverture d'une cavité intérieure (CI) du conteneur adapté pour supporter des objets devant y être stockés, ledit couvercle rotatif (CR) étant pourvu au moins d'un orifice d'extraction placé de façon excentrique et d'un bouchon mâle à isolation thermique (BM) pour ledit orifice.
- Couvercle à isolation thermique selon la revendication 4, dans lequel la zone de l'orifice par rapport au couvercle (CR) est inférieure à 40%, de préférence, inférieure à 25%.
- Couvercle à isolation thermique selon la revendication 4, dans lequel le couvercle (CR) est transparent.
- Couvercle à isolation thermique selon la revendication 4, dans lequel la face du couvercle rotatif (CR) sur le côté intérieur de la cavité est pourvue de moyens de refroidissement.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IN707BO1999 | 1999-10-15 | ||
| INBO070799 | 1999-10-15 | ||
| PCT/EP2000/009593 WO2001028886A1 (fr) | 1999-10-15 | 2000-09-27 | Couvercle de recipient a isolation thermique |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1220800A1 EP1220800A1 (fr) | 2002-07-10 |
| EP1220800B1 true EP1220800B1 (fr) | 2004-08-11 |
Family
ID=11080263
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP00969364A Expired - Lifetime EP1220800B1 (fr) | 1999-10-15 | 2000-09-27 | Couvercle de recipient a isolation thermique |
Country Status (13)
| Country | Link |
|---|---|
| EP (1) | EP1220800B1 (fr) |
| AT (1) | ATE273203T1 (fr) |
| AU (1) | AU752195B2 (fr) |
| BR (1) | BR0014785A (fr) |
| CA (1) | CA2387448A1 (fr) |
| DE (1) | DE60012955T2 (fr) |
| ES (1) | ES2225232T3 (fr) |
| IL (1) | IL149117A (fr) |
| MX (1) | MXPA02003738A (fr) |
| PT (1) | PT1220800E (fr) |
| TR (1) | TR200201016T2 (fr) |
| WO (1) | WO2001028886A1 (fr) |
| ZA (1) | ZA200202898B (fr) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10314799A1 (de) * | 2003-04-01 | 2004-10-14 | Dieter Kellerstrass | Thermo-Speisetransportbehälter |
| CN107054901B (zh) * | 2017-01-25 | 2018-05-01 | 赵琦 | 一种带有速溶饮料的方便食品 |
| USD839054S1 (en) | 2017-08-17 | 2019-01-29 | Yeti Coolers, Llc | Container |
| USD839055S1 (en) | 2017-08-17 | 2019-01-29 | Yeti Coolers, Llc | Container |
| USD856748S1 (en) | 2017-08-17 | 2019-08-20 | Yeti Coolers, Llc | Lid |
| US10968029B1 (en) | 2017-08-17 | 2021-04-06 | Yeti Coolers, Llc | Container and lid |
| USD839056S1 (en) | 2017-08-17 | 2019-01-29 | Yeti Coolers, Llc | Container |
| USD888509S1 (en) | 2018-04-11 | 2020-06-30 | Yeti Coolers, Llc | Container |
| USD878166S1 (en) | 2018-04-11 | 2020-03-17 | Yeti Coolers, Llc | Container |
| USD878163S1 (en) | 2018-04-11 | 2020-03-17 | Yeti Coolers, Llc | Container |
| USD888508S1 (en) | 2018-04-11 | 2020-06-30 | Yeti Coolers, Llc | Container |
| USD887793S1 (en) | 2018-04-11 | 2020-06-23 | Yeti Coolers, Llc | Container |
| USD885903S1 (en) | 2018-04-11 | 2020-06-02 | Yeti Coolers, Llc | Lid |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR727859A (fr) * | 1931-12-04 | 1932-06-25 | Pot pour le transport du lait | |
| GB770275A (en) * | 1954-06-09 | 1957-03-20 | British Vacuum Flask Company L | Improvements in the construction of jugs |
| US4024731A (en) * | 1975-10-31 | 1977-05-24 | Gott Mfg. Co., Inc. | Insulated container with refreezable lid-mounted bottle |
| US5316193A (en) * | 1991-01-24 | 1994-05-31 | Heiberger Robert A | Bottle with reflective barrier layer for reducing electromagnetic energy transfer |
| NL1002629C2 (nl) * | 1996-03-15 | 1997-09-17 | Maverick B V Projektinrichting | Transportkist voor sublimerende vaste stoffen. |
-
2000
- 2000-09-27 IL IL14911700A patent/IL149117A/xx not_active IP Right Cessation
- 2000-09-27 WO PCT/EP2000/009593 patent/WO2001028886A1/fr not_active Ceased
- 2000-09-27 DE DE60012955T patent/DE60012955T2/de not_active Expired - Fee Related
- 2000-09-27 TR TR2002/01016T patent/TR200201016T2/xx unknown
- 2000-09-27 BR BR0014785-0A patent/BR0014785A/pt not_active IP Right Cessation
- 2000-09-27 ES ES00969364T patent/ES2225232T3/es not_active Expired - Lifetime
- 2000-09-27 MX MXPA02003738A patent/MXPA02003738A/es active IP Right Grant
- 2000-09-27 AT AT00969364T patent/ATE273203T1/de not_active IP Right Cessation
- 2000-09-27 CA CA002387448A patent/CA2387448A1/fr not_active Abandoned
- 2000-09-27 EP EP00969364A patent/EP1220800B1/fr not_active Expired - Lifetime
- 2000-09-27 PT PT00969364T patent/PT1220800E/pt unknown
- 2000-09-27 AU AU79113/00A patent/AU752195B2/en not_active Ceased
-
2002
- 2002-04-12 ZA ZA200202898A patent/ZA200202898B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE60012955D1 (de) | 2004-09-16 |
| ZA200202898B (en) | 2003-04-14 |
| CA2387448A1 (fr) | 2001-04-26 |
| TR200201016T2 (tr) | 2002-06-21 |
| IL149117A0 (en) | 2002-11-10 |
| AU752195B2 (en) | 2002-09-12 |
| AU7911300A (en) | 2001-04-30 |
| WO2001028886A1 (fr) | 2001-04-26 |
| BR0014785A (pt) | 2002-06-11 |
| MXPA02003738A (es) | 2002-08-30 |
| ATE273203T1 (de) | 2004-08-15 |
| DE60012955T2 (de) | 2005-01-20 |
| IL149117A (en) | 2005-12-18 |
| PT1220800E (pt) | 2004-11-30 |
| ES2225232T3 (es) | 2005-03-16 |
| EP1220800A1 (fr) | 2002-07-10 |
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