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EP1219719A1 - Tôle d'acier inoxydable ferritique avec une bonne aptitude et procédé pour sa fabrication - Google Patents

Tôle d'acier inoxydable ferritique avec une bonne aptitude et procédé pour sa fabrication Download PDF

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Publication number
EP1219719A1
EP1219719A1 EP01129311A EP01129311A EP1219719A1 EP 1219719 A1 EP1219719 A1 EP 1219719A1 EP 01129311 A EP01129311 A EP 01129311A EP 01129311 A EP01129311 A EP 01129311A EP 1219719 A1 EP1219719 A1 EP 1219719A1
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Prior art keywords
mass
stainless steel
steel sheet
ferritic stainless
workability
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EP01129311A
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EP1219719B1 (fr
Inventor
Manabu Stainless Steel Business Div. Oku
Yoshitomo Stainless Steel Business Div. Fujimura
Yoshiaki Stainless Steel Business Div. Hori
Toshirou Stainless Steel Business Div. Nagoya
Yasutoshi Stainless Steel Business Div. Kunitake
Takeo Shunan Works Tomita
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Nippon Steel Nisshin Co Ltd
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Nisshin Steel Co Ltd
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Priority claimed from JP2000392911A external-priority patent/JP4562280B2/ja
Priority claimed from JP2000392912A external-priority patent/JP4562281B2/ja
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Publication of EP1219719A1 publication Critical patent/EP1219719A1/fr
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/26—Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/004—Very low carbon steels, i.e. having a carbon content of less than 0,01%
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/002—Heat treatment of ferrous alloys containing Cr
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0205—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0273—Final recrystallisation annealing
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226—Hot rolling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0236—Cold rolling

Definitions

  • the present invention relates to a ferritic stainless steel good of workability with less anisotropy useful as material worked to sheets for an automobile and other parts.
  • Ferritic stainless steels improved in heat- and corrosion-resistance by stabilization of C and N with Nb or Ti have been used in broad industrial fields.
  • such ferritic stainless steel is used as a member of an exhaust system for an automobile.
  • a steel material such as SUS409L , SUS436L or SUS436J1L , which contains Nb or Ti to suppress sensitization and to improve intergranular corrosion-resistance, is used for a center pipe or muffler good of corrosion-resistance.
  • a steel material such as SUS430LX , SUS430J1L or SUS444 , which contains Nb or Ti more than a stoichiometric ratio of C and N contents to improve high-temperature strength due to dissolution of surplus Nb or Ti in a steel matrix, is used as an exhaust manifold or front pipe good of heat-resistance.
  • ferritic stainless steel shall be deformed with heavier duty as more complicated shape of a product in order to improve function and/or design of the product.
  • JP 51-29694B and JP 51-35369B An alloying design proposed by JP 51-29694B and JP 51-35369B is to reduce C and N contents together with addition of carbonitride-forming elements such as Ti or Nb at a relatively great ratio.
  • Addition of Ti and/or Nb to ferritic stainless steel for use as a member for an exhaust system is meaningful in improvement of workability and performance for system requirements, since the additives Ti and Nb improves workability of the steel as well as corrosion- and heat-resistance necessary for a member for an exhaust system.
  • a value r representing deep drawability is surely improved by addition of Ti and/or Nb, but the additives Ti and Nb unfavorably enlarges in-plane anisotropy ⁇ r of the value r .
  • mere addition of such alloying elements is not enough to bestow ferritic stainless steel with sufficient workability, which meets requirements for severe deformation.
  • Addition of one or more of Al, B and Cu is also known for improvement of workability.
  • a steel material based on SUS430 composition to which alloying elements are alloyed at small ratios, or a steel material based on SUS430 compositions, to which Al and Ti are alloyed, are those steels improved in workability by manufacturing conditions.
  • the present invention aims at provision of a ferritic stainless steel sheet improved in workability by an effect of Nb-containing precipitates on control of crystalline orientation, without reduction of elements harmful on corrosion- or heat-resistance or addition of special elements effective for corrosion- or heat-resistance, further without restrictions on thickness. Presence of fine Nb-containing precipitates in a steel matrix is also effective for improvement of workability with less in-plane anisotropy.
  • the present invention newly proposes two types of ferritic stainless steel sheets good of workability.
  • a first proposal is directed to a ferritic stainless steel sheet, which consists of C up to 0.03 mass %, N up to 0.03 mass %, Si up to 2.0 mass %, Mn up to 2.0 mass %, Ni up to 0.6 mass %, 9-35 mass % Cr, 0.15-0.80 mass % Nb and the balance being Fe except inevitable impurities, comprises metallurgical structure involving precipitates of 2 ⁇ m or less in particle size at a ratio not more than 0.5 mass % and has crystalline orientation on a surface at 1/4 depth of thickness with Integrated Density defined by the formula (a) not less than 1.2.
  • I (211) andI (200) represents diffraction intensities on (211) and (200) planes of a sample of said steel measured by XRD, while I 0(211) and I 0(200) represents diffraction intensities on (211) and (200) planes of a non-directional sample.
  • the ferritic stainless steel sheet may further contain one or more of Ti up to 0.5 mass %, Mo up to 3.0 mass %, Cu up to 2.0 mass % and Al up to 6.0 mass %.
  • the ferritic stainless steel is offered as a hot-rolled steel strip, a hot-rolled steel sheet, a cold-rolled steel strip, a cold-rolled steel sheet or a welded steep pipe on the market. The wording "steel sheet" involves all of these materials in this specification.
  • the ferritic stainless steel sheet is manufactured by a process involving a step of precipitation-treatment at 700-850 °C for 25 hours or shorter in prior to 1 minute or shorter finish-annealing at 900-1100 °C.
  • a second proposal is directed to a ferritic stainless steel sheet good of workability with less in-plane anisotropy.
  • This stainless steel sheet has the same composition as mentioned above, comprises metallurgical structure involving fine precipitates of 0.5 ⁇ m or less in particle size controlled at a ratio not more than 0.5 mass % in a finish-annealed state by dissolving fine precipitates, which have been once generated by heating, in a steel matrix during finish-annealing, and has crystal orientation with Integrated Intensity defined by the formula (b) not less than 2.0.
  • Integrated Intensity [I (222) /I 0(222) ]/[I (200) /I 0(200) ] wherein, I (222) and I (200) represents diffraction intensities on (222) and (200) planes of a sample of said steel sheet measured by XRD, while I 0(222) and I 0(200) represents diffraction intensities on (222) and (200) planes of a non-directional sample.
  • Integrated Intensity defined by the formula (b) is kept at a level not less than 2.0 by controlling Nb-containing fine precipitates, which has been once generated by heat-treatment in prior to finish-annealing, at a ratio in a range of 0.4-1.2 mass %.
  • Such ferritic stainless steel is manufactured by precipitation-heating the steel having the specified composition at a temperature in a range of 450-750 °C for 20 hrs. or shorter at any one of steps in prior to finish-annealing, and then heating at 900-1100 °C for 1 minute or shorter during finish-annealing.
  • Fig. 1 is a graph showing an effect of precipitates distributed in a steel matrix before finish-annealing on average strain ratio of a finish-annealed steel sheet.
  • Fig. 2 is another graph showing an effect of fine precipitates distributed in a steel matrix before finish-annealing on average strain ratio and in-plane anisotropy of a finish-annealed steel sheet.
  • the inventors have researched effects of compositions and manufacturing conditions on workability from various aspects, on the presumption that ferritic stainless steels containing one or both of Nb and Ti at ratios enough to stabilize C and N as carbonitrides are cold-rolled at a reduction ratio of 50-60 %, which is generally regarded as a value insufficient for increase of a value r .
  • the inventors have discovered that Nb-alloyed ferritic stainless steel can be processed to a steel strip or sheet good of workability by heat-treatment to generate precipitates on any stage in prior to finish-annealing.
  • the present invention which is based on the newly discovered effect of precipitates, enables production of a stainless steel sheet good of workability even when its thickness exceeds 1.0mm.
  • Fig. 1 shows a relationship between a total ratio of precipitates of 2 ⁇ m or less in particle size and workability of a ferritic stainless steel sheet, which was manufactured by 30 seconds precipitation-treatment of a 12Cr-0.8Mn-0.5Si-0.6Nb steel sheet of 4.5 mm in thickness to generate precipitates, cold-rolling to thickness of 2.0 mm and then finish-annealing at 1040 °C.
  • Abrupt increase of an average plastic strain ratio r is noted as increase of a total ratio of precipitates of 2 ⁇ m or less in particle size above 1.1 mass %.
  • Integrated Intensity defined by the above-mentioned formula (a) also increases to a level of 1.2 or more, where the ferritic stainless steel sheet is deformed to an objective shape with good workability, in response to increase of the average plastic strain ratio r .
  • Integrated Intensity defined by the formula (a) shall be kept at a value not less than 1.2 in order to provide a ferritic stainless steel good of workability, in other words, an average value r of 1.5 or more.
  • Integrated Intensity of 1.2 or more is realized by generating precipitates of 2 ⁇ m or less in particle size at a total ratio 1.1 mass % or more.
  • a total ratio of precipitates is preferably kept at a relatively low level in the specified range since the precipitates act as starting points of brittle fracture, although a total ratio of precipitates in a finish-annealed state is not necessarily controlled for a stainless steel sheet for use as a member whose toughness is not much valued.
  • Good workability with less in-plain anisotropy is realized by controlling a ratio of fine precipitates of 0.5 ⁇ m or less at a total ratio not more than 0.5 mass % in a finish-annealed steel sheet.
  • 14Cr-1Mn-1Si-0.4Nb-0.1Cu steel was processed to a hot-rolled steel sheet of 4.5 mm in thickness, heated 30 seconds to generate fine precipitates, cold-rolled to thickness of 2.0 mm, and then finish-annealed at 1040 °C. Under such conditions, a temperature for precipitation-treatment was varied in order to investigate an effect of precipitation-treatment on generation of fine precipitates.
  • Results shown in Fig. 2 prove that increase of fine precipitates of 0.5 ⁇ m or less in particle size at a total ratio more than 0.4 mass % causes increase of an average value r and decrease of in-plane anisotropy ⁇ r .
  • Increase of fine precipitates also results in increase of Integrated Intensity.
  • Integrated Intensity is kept at a level not less than 2.0, in a region where the ferritic stainless steel exhibits good workability.
  • a total ratio of fine precipitates above 1.2 mass % causes abrupt increase of in-plane anisotropy and decrease of Integrated Intensity, although an average value r is not reduced regardless the ratio of fine precipitates.
  • Integrated Intensity defined by the formula ( b ) shall be kept at a value not less than 2.0 in order to provide a ferritic stainless steel good of workability, in other words, an average value r of 1.2 or more with in-plane anisotropy ⁇ r of 0.5 or less.
  • Integrated Intensity of 2.0 or more is realized by generating fine precipitates of 0.5 ⁇ m or less in particle size at a total ratio in a range of 0.4-1.2 mass %.
  • a total ratio of fine precipitates is preferably kept at a relatively low level in a range of 0.4-1.2 mass % since the precipitates act as starting points of brittle fracture, although a total ratio of fine precipitates in a finish-annealed state is not necessarily controlled for a stainless steel sheet for use as a member whose toughness is not much valued. Toughness of the ferritic stainless steel sheet is ensured by dissolution of fine precipitates, which were used for controlling growth of aggregate structure, in a finish-annealing step, so as to reduce a total ratio of fine precipitates of 0.5 ⁇ m or less in particle size to 0.5 mass % or less after the finish-annealing.
  • Toughness of the ferritic stainless steel sheet is ensured by dissolution of precipitates, which were used for controlling growth of aggregate structure, in a finish-annealing step, so as to reduce a total ratio of precipitates of 2 ⁇ m or less, preferably 0.5 ⁇ m or less in particle size to 0.5 mass % or less after the finish-annealing.
  • the newly proposed ferritic stainless steel has the composition specified as follows:
  • C and N are elements for improvement of high-temperature strength such as creep strength in general, excessive addition of C and N not only worsens corrosion-resistance, oxidation-resistance, workability and toughness but also necessitates increase of Nb content to stabilize C and N as carbonitrides.
  • C and N contents are preferably adjusted at low levels. In practical, each of C and N contents are controlled not more than 0.03 mass % (preferably 0.02 mass %).
  • Si is an alloying element very effective for improvement of oxidation-resistance at a high temperature. But, excessive addition of Si causes increase of hardness and worsens workability and toughness. In this sense, Si content is adjusted at a level not more than 2.0 mass % (preferably 1.5 mass %).
  • Mn is an alloying element for improvement of oxidation- resistance at a high temperature as well as separability of scale, but excessive addition of Mn puts harmful influences on weldability. Furthermore, excessive addition of Mn, which is an austenite former, promotes generation of martensite phase, resulting in degradation of workability. Therefore, an upper limit of Mn content is determined at 2.0 mass % (preferably 1.5 mass %).
  • Ni is an element which stabilizes austenite phase, so that excessive addition of Ni promotes generation of martensite phase and worsens workability as the same as Mn.
  • Ni is an expensive element, too. In this sense, an upper limit of Ni content is determined at 0.6 mass % (preferably 0.5 mass %).
  • Cr is an essential element for stabilization of ferrite phase, oxidation resistance necessary for high-temperature use, and pitting- and weather-resistance necessary for use in a corrosive environment. Heat- and corrosion-resistance is better as increase of Cr content, but excessive addition of Cr causes embrittlement of steel and increase of hardness, resulting in degradation of workability. Therefore, Cr content is controlled in a range of 9-35 mass % (preferably 12-19 mass %).
  • Nb stabilizes C and N as carbonitrides, and the remaining Nb improves high-temperature strength of steel. Furthermore, the additive Nb is used for controlling re-crystallized aggregate structure in the invented steel. Generation of fine precipitates is ensured by dissolution of Nb in a matrix of a hot-rolled steel sheet.
  • a part of the additive Nb consumed for stabilization of C and N as carbonitrides exists in a form of Nb(C, N), and does not substantially change its form or its ratio from a hot-rolling step to a finish-annealing step.
  • the other part of the additive Nb dissolved in a hot-rolled steel strip or sheet precipitates as Fe 3 Nb 3 C, Fe 2 Nb or the like by precipitation-treatment in prior to finish-annealing, and the precipitates favorably control preferential growth of re-crystallized aggregate structure effective for improvement of workability.
  • a ratio of Nb shall be kept at a level more than a ratio necessary for stabilization of C and N as carbonitrides.
  • a lower limit of Nb content is determined at 0.15 mass % (preferably 0.20 mass %).
  • a ratio of Nb is controlled not more than 0.80 mass % (preferably 0.50 mass %), since excessive addition of Nb causes too-much generation of precipitates harmful on toughness.
  • Ti is an optional element, which stabilizes C and N as carbonitrides as the same as Nb and improves of intergranular corrosion-resistance. But, excessive addition of Ti worsens toughness and workability of steel and puts harmful influences on external appearance of a steel sheet. In this sense, an upper limit of Ti content is determined at 0.5 mass % (preferably 0.3 mass %).
  • Mo is an element for improvement of corrosion-resistance and heat-resistance (including high-temperature strength and oxidation-resistance at a high temperature), so Mo is optionally added to steel for use which needs excellent properties.
  • excessive addition of Mo worsens hot-rollability, workability and toughness of steel and also raises a steel cost.
  • an upper limit of Mo content is determined at 3.0 mass % (preferably 2.5 mass %).
  • Cu is an optional alloying element for improvement of corrosion-resistance and high-temperature strength and also bestows the ferritic stainless steel with anti-microbial property.
  • excessive addition of Cu causes degradation of hot-rollability of the steel and worsens workability and toughness.
  • an upper limit of Cu content is determined at 2.0 mass % (preferably 1.5 mass %).
  • Al is an optional alloying element for improvement of oxidation-resistance of the ferritic stainless steel at a high temperature as the same as Si. But, excessive addition of Al causes increase of hardness and worsens workability and toughness of the steel. In this sense, an upper limit of Al content is determined at 6.0 mass % (preferably 4.0 mass %).
  • Ratios of the other elements are not especially defined in the present invention, but one or more of such other elements may be added as occasion demands.
  • Ta, W, V and Co for high-temperature strength
  • Y and REM for oxidation-resistance at a high temperature
  • Ca for hot-workability and toughness.
  • a ratio of Ta, W, V and/or Co is preferably up to 3.0 mass %
  • a ratio of Y and/or REM is preferably up to 0.5 mass %
  • a ratio of Ca, Mg and/or B is preferably up to 0.05 mass %.
  • Ordinary impurities such as P, S and O are preferably controlled at the lowest possible level. For instance, P not more than 0.04 mass %, S not more than 0.03 mass % and O not more than 0.02 mass %. These impurities may be severely controlled to further low levels in order to improve workability and toughness of the steel.
  • a ferritic stainless steel sheet is heated at 700-850 °C for a time period of 25 hours or shorter to precipitate Nb-containing particles in a steel matrix.
  • Precipitation-treatment is performed on any stage from a steel-making step before a finish-annealing step, using a continuos or a batch-type annealing oven. Conditions of precipitation-treatment are controlled so as to generate a proper ratio of precipitates of 2 ⁇ m or less in particle size effective for workability.
  • a time period t for precipitation-treatment is properly determined in response to a heating temperature T (°C).
  • T heating temperature
  • the time period t and the heating temperature T are determined so as to maintain a value ⁇ defined by the following formula in a range of 19-23.
  • the precipitation-treatment shall be completed in 25 hours; otherwise precipitates would grow up to coarse particles with less productivity due to long-term heating.
  • ⁇ (T+273) ⁇ (20 + log t)/1000
  • a stainless steel sheet of metallurgical structure wherein precipitates of 2 ⁇ m or less in particle size have been distributed at a proper ratio by the precipitation-treatment, is finish-annealed at 900-1100 °C for re-crystallization to diminish a rolling texture.
  • Re-crystallization occurs at an annealing temperature of 900 °C or higher, but over-annealing at a temperature above 1100 °C accelerates generation of coarse crystal grains and worsens toughness of a steel sheet.
  • the finish-annealing is preferably completed in 1 minute, accounting productivity and energy consumption.
  • Conditions of finish-annealing are controlled so as to reduce a total ratio of undissolved precipitates of 2 ⁇ m or less in particle size below 0.5 mass % for improvement of toughness (especially secondary workability). If too-much precipitates remain in a finish-annealed state of a steel product, they act as starting point of brittle fracture.
  • Re-crystallization which occurs during finish-annealing, is affected by Nb-containing precipitates. That is, (211) plane aggregate structure is preferentially grown up, while growth of (100) plane aggregate structure is suppressed. Consequently, Integrated Intensity defined by the above-mentioned formula (a) increases to a level of 1.2 or more. Due to increase of Integrated Intensity, the finish-annealed stainless steel sheet is improved in workability with an average plastic strain ratio r of 1.5 or more.
  • a ferritic stainless steel sheet is heated at 450-750 °C any stage in prior to finish-annealing, in order to precipitate fine Nb-containing particles in a steel matrix.
  • Conditions of precipitation-treatment are controlled so as to distribute fine precipitates of 0.5 ⁇ m or less in particle size in a steel matrix at a total ratio not less than 0.4 mass %. If the steel is heated at a temperature below 450 °C, generation of fine precipitates is scarcely noted. If the steel is heated at a temperature above 750 °C on the contrary, precipitates grow up to coarse particles more than 0.5 ⁇ m in size.
  • the ferritic stainless steel is heated at the specified temperature for a time shorter than 20 hrs. in order to suppress growth of precipitates to coarse particles.
  • the heating conditions are preferably determined so as to keep the above-mentioned value ⁇ in a range of 13-19 in order to stabilize properties of the ferritic stainless steel.
  • the ferritic stainless steel is then finish-annealed at a temperature in a range of 900-1100 °C for a time period of 1 minute or shorter. If a temperature for finish-annealing is below a re-crystallization temperature, the annealed steel comprises a structure wherein rolling texture remains without sufficient dissolution of fine precipitates generated by the precipitation-treatment. The remaining rolling texture unfavorably impedes reduction of in-plane anisotropy, while the remaining precipitates degrade toughness and secondary workability of a steel product. But, over-heating above 1100 °C causes coarsening of crystal grains, resulting in insufficient toughness.
  • Integrated Intensity defined by the above-mentioned formula (b) is to be controlled to a level of 2.0 or more, so as to assure preferential growth of (222) plane aggregate structure for good workability with less anisotropy.
  • a steel strip may be cold-rolled once or more times, but shall not be heated up to a re-crystallization temperature in the steps other than the finish-annealing.
  • stress-relief annealing after a cold-rolling step shall be performed below the re-crystallization temperature so as to inhibit generation of re-crystallized structure.
  • Hot-rolling conditions are not necessarily specified, since re-crystallization is avoided during hot-rolling at an ordinary temperature in a range of 800-1250 °C.
  • fine precipitates are not generated in a steel matrix.
  • precipitation-treatment for generation fine precipitates is performed after the hot-rolling step.
  • fine precipitates may be generated by controlling a cooling speed of a steel strip just after the hot-rolling.
  • heat-treatment for generation of fine precipitates is not necessarily required in the succeeding steps.
  • a hot-rolled steel strip is air-cooled and optionally water-cooled under the conditions that the afore-mentioned conditions of precipitation-treatment are satisfied during cooling of the hot-rolled steel strip.
  • the present invention is typically advantageous for a stainless steel sheet of 1.0 mm or more in thickness, although there are no special restrictions on a shape of a steel product.
  • features of the present invention are realized even in a case of a stainless steel sheet thinner than 1.0 mm or a product made from the stainless steel sheet by working or welding it to a certain shape.
  • Each hot-rolled steel strip was cold-rolled to thickness of 2.0 mm and then finish-annealed under conditions shown in Table 2 .
  • test piece cut off each annealed steel sheet was subjected to a tensile test at a room temperature.
  • test pieces cut off each steel sheet before and after finish-annealing were tested to detect a ratio of precipitates by weighing the residue after electrolytic dissolution of base elements other than precipitates.
  • test pieces for crystalline orientation were prepared by shaving steel sheets to 3/4 of thickness and then polishing the steel sheets. Diffraction intensity of each test piece was measured at (211) and (200) planes by XRD, while diffraction intensity of a non-directional sample prepared from powdery material was measured at (211) and (200) planes in the same way. The measured values were substituted for formula (a) to calculate Integrated Intensity as an index of crystalline orientation.
  • the average plastic strain ratio was obtained by a tensile test as follows: Test pieces regulated as JIS #13B were prepared by cutting each steel strip along a rolling direction L , a traverse direction T rectangular to the direction L and a direction D crossing the direction L with 45 degrees. A uni-directional stretch pre-strain of 15 % was applied to each test piece under the conditions regulated by JIS Z2254 (entitled to " Test For Measuring Plastic Strain Ratio Of Thin Metal Sheet"), and plastic strain ratios r L , r T and r D along the directions L , T and D , respectively were calculated as ratios of thickness strains to horizontal strains.
  • Example Nos. 1-11 were superior of workability to Comparative Example No. 15 due to bigger plastic strain ratios r , since ratios of precipitates before finish-annealing and crystalline orientation represented by Integrated Intensity were both kept in proper ranges.
  • Each steel of Example Nos. 1-11 had a ductility-embrittlement transition temperature below -50 °C, i.e. at the level that brittle fracture does not occur in practical.
  • Example Nos. 12-14 show results of stainless steels having compositions out of the range of the present invention.
  • Example Nos. 15-18 show results of stainless steels, which had compositions defined by the present invention but processed under different manufacturing conditions.
  • Example No. 16 was relatively good of workability but inferior of toughness due to excessive Nb content.
  • the steels of Example Nos. 13 and 14 were good of toughness but inferior of workability, since Integrated Intensity was not kept in the specified range even by precipitation-treatment in prior to finish-annealing due to absence of Nb.
  • the steel of Example No. 15 which was manufactured by a conventional process involving finish-annealing for re-crystallization without precipitation-treatment, was poor of workability.
  • the steel of Example No. 16 was not improved in workability even by precipitation-treatment, since re-crystallized structure was generated during heating a hot-rolled steel strip.
  • Example 17 and 18 were poor of toughness, since precipitates were insufficiently dissolved in a steel matrix due to finish-annealing as a lower temperature in Example No. 17 or since crystal grains were coarsened due to finish-annealing at a higher temperature in Example No. 18 .
  • Each hot-rolled steel strip was cold-rolled to thickness of 2.0 mm and then annealed under conditions shown in Table 5 (inventive examples) and Table 6 (comparative examples).
  • test piece cut off each annealed steel strip was subjected to a tensile test at a room temperature.
  • test pieces cut off steel strips before and after the finish-annealing were tested to detect ratios of fine precipitates and crystalline orientation by the same way as Example 1 , but the crystalline orientation was represented by Integrated Intensity defined by the formula (b).
  • Example Nos. 16-18 show results of the comparative stainless steels.
  • Example Nos. 19-2 6 show results of stainless steels, which had compositions defined by the present invention but processed under different manufacturing conditions.
  • Example No. 16 was relatively good of workability but inferior of toughness due to excessive Nb content.
  • Steels of Example Nos. 17 and 18 were good of toughness but inferior of workability, since Integrated Intensity was not kept in the specified range even by precipitation-treatment in prior to finish-annealing due to absence of Nb.
  • Steels of Example Nos. 19 and 20 were not improved in workability even by precipitation-treatment for generation of fine precipitates, since hot-rolled steel strips were already transformed to re-crystallized structure by heating at 1040 °C above a temperature range specified in the present invention.
  • Steels of Example Nos. 21 and 24 were inferior of in-plane anisotropy with Integrated Intensity out of the range specified by the present invention, since they were heated in hot-rolled or cold-rolled state at a higher temperature so as to excessively generate fine precipitates.
  • Example Nos. 22 and 23 were inferior of workability with Integrated Intensity out of the range specified by the present invention, since they were heated in hot-rolled or cold-rolled state at a lower temperature so as to insufficiently generate fine precipitates.
  • Steels of Example Nos. 25-27 were also inferior of workability, since precipitates were not completely dissolved in a steel matrix of Example No. 25 due to finish-annealing at a lower temperature, and crystal grains were coarsened due to finish-annealing at a higher temperature in Example No. 26 or for a longer time in Example No. 27.
  • Ratios of precipitates (%) Integrated Intensity r ⁇ r toughness Before finish-annealing After finish-annealing 1 1 0.9 0.2 3.0 ⁇ ⁇ ⁇ 2 2 0.8 0.3 2.7 ⁇ ⁇ ⁇ 3 3 0.9 0.3 2.5 ⁇ ⁇ ⁇ 4 3 1.0 0.3 2.4 ⁇ ⁇ ⁇ 5 3 0.9 0.3 2.6 ⁇ ⁇ 6 3 1.1 0.3 2.6 ⁇ ⁇ ⁇ 7 3 1.0 0.3 3.6 ⁇ ⁇ ⁇ 8 3 0.7 0.4 2.1 ⁇ ⁇ 9 3 0.9 0.3 2.3 ⁇ ⁇ ⁇ 10 4 1.0 0.3 2.2 ⁇ ⁇ ⁇ 11 5 0.9 0.3 2.4 ⁇ ⁇ ⁇ 12 6 0.9 0.3 2.1 ⁇ ⁇ ⁇ 13 7 1.2 0.5 2.0 ⁇ ⁇ ⁇ 14 8 0.4 0.1 2.0 ⁇ ⁇ ⁇ 15 9 0.6 0.2 2.0 ⁇ ⁇ ⁇ r : 1.2 or more evaluated as ⁇ , and less
  • the present invention as above-mentioned uses the effect of precipitates, which have been generated on a stage in prior to finish-annealing, on control of crystalline orientation during finish-annealing, and so enables to provide a ferritic stainless steel sheet good of workability. Furthermore, in-plane anisotropy is reduced by severely controlling a ratio of fine precipitates and crystalline orientation.
  • the good workability is ensured, even when the steel sheet is relatively thick of 1-2 mm, without degradation of intrinsic properties such as heat-resistance, corrosion-resistance and toughness.
  • the newly proposed ferritic stainless steel sheet will be used in broad industrial fields such as a member of an exhaust system for an automobile, due to the excellent properties.

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  • Chemical & Material Sciences (AREA)
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  • Mechanical Engineering (AREA)
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  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
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  • Heat Treatment Of Sheet Steel (AREA)
  • Heat Treatment Of Steel (AREA)
EP01129311A 2000-12-25 2001-12-13 Tôle d'acier inoxydable ferritique avec une bonne aptitude et procédé pour sa fabrication Expired - Lifetime EP1219719B1 (fr)

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JP2000392911 2000-12-25
JP2000392912A JP4562281B2 (ja) 2000-12-25 2000-12-25 加工性に優れたフェライト系ステンレス鋼板及びその製造方法
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WO2004053171A1 (fr) * 2002-12-12 2004-06-24 Nippon Steel & Sumikin Stainless Steel Corporation Feuille d'acier resistante a la chaleur contenant du chrome et presentant une excellente aptitude au façonnage et son procede de production
EP1734143A4 (fr) * 2004-04-07 2007-09-26 Nippon Steel & Sumikin Sst Tôle d'acier inoxydable ferritique excellente en termes de capacité au façonnage et procédé de fabrication de celle-ci
WO2011026460A1 (fr) * 2009-09-01 2011-03-10 Thyssenkrupp Vdm Gmbh Procédé de production d'un alliage fer-chrome
EP2915894A4 (fr) * 2012-10-30 2016-10-26 Nippon Steel & Sumikin Sst Feuille d'acier inoxydable ferritique avec une excellente résistance à la chaleur
EP3521471A4 (fr) * 2016-09-28 2019-09-04 Posco Acier inoxydable ferritique présentant une adsorption réduite de boue de carbone pour échangeur de chaleur de système d'échappement et son procédé de fabrication
CN113088654A (zh) * 2021-04-06 2021-07-09 山西太钢不锈钢股份有限公司 一种改善含铌铁素体不锈钢板宏观偏析的生产方法
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US20040156737A1 (en) * 2003-02-06 2004-08-12 Rakowski James M. Austenitic stainless steels including molybdenum
US20060225820A1 (en) * 2005-03-29 2006-10-12 Junichi Hamada Ferritic stainless steel sheet excellent in formability and method for production thereof
WO2007129703A1 (fr) * 2006-05-09 2007-11-15 Nippon Steel & Sumikin Stainless Steel Corporation Acier inoxydable excellent en termes de resistance a la corrosion, acier inoxydable de ferrite excellent en termes de resistance a la corrosion de joints et d'aptitude a la formation, et acier inoxydable de ferrite excellent en termes de resistance a la corrosion de joints
JP5208450B2 (ja) * 2006-07-04 2013-06-12 新日鐵住金ステンレス株式会社 熱疲労特性に優れたＣｒ含有鋼
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JP4948998B2 (ja) * 2006-12-07 2012-06-06 日新製鋼株式会社 自動車排ガス流路部材用フェライト系ステンレス鋼および溶接鋼管
CN101680066B (zh) * 2007-06-21 2011-09-28 杰富意钢铁株式会社 耐硫酸腐蚀性优良的铁素体系不锈钢板及其制造方法
JP5390175B2 (ja) * 2007-12-28 2014-01-15 新日鐵住金ステンレス株式会社 ろう付け性に優れたフェライト系ステンレス鋼
JP4651682B2 (ja) * 2008-01-28 2011-03-16 新日鐵住金ステンレス株式会社 耐食性と加工性に優れた高純度フェライト系ステンレス鋼およびその製造方法
JP4386144B2 (ja) * 2008-03-07 2009-12-16 Ｊｆｅスチール株式会社 耐熱性に優れるフェライト系ステンレス鋼
JP5420292B2 (ja) * 2008-05-12 2014-02-19 日新製鋼株式会社 フェライト系ステンレス鋼
JP5462583B2 (ja) * 2008-10-24 2014-04-02 新日鐵住金ステンレス株式会社 Ｅｇｒクーラ用フェライト系ステンレス鋼板
UA111115C2 (uk) 2012-04-02 2016-03-25 Ейкей Стіл Пропертіс, Інк. Рентабельна феритна нержавіюча сталь
JP2016196019A (ja) * 2015-04-03 2016-11-24 日新製鋼株式会社 フェライト系ステンレス鋼板、カバー部材およびフェライト系ステンレス鋼板の製造方法
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KR102123663B1 (ko) * 2018-09-27 2020-06-17 주식회사 포스코 용접부의 기계적 성질이 향상된 페라이트계 스테인리스강 및 페라이트계 스테인리스 강관
KR102173277B1 (ko) 2018-11-06 2020-11-03 주식회사 포스코 저온 충격인성이 우수한 열연 강판 및 그 제조방법
KR102259806B1 (ko) * 2019-08-05 2021-06-03 주식회사 포스코 고온 내크립 특성이 향상된 페라이트계 스테인리스강 및 그 제조 방법
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WO2004053171A1 (fr) * 2002-12-12 2004-06-24 Nippon Steel & Sumikin Stainless Steel Corporation Feuille d'acier resistante a la chaleur contenant du chrome et presentant une excellente aptitude au façonnage et son procede de production
US7682559B2 (en) 2002-12-12 2010-03-23 Nippon Steel Corporation Cr-bearing heat-resistant steel sheet excellent in workability and method for production thereof
EP1734143A4 (fr) * 2004-04-07 2007-09-26 Nippon Steel & Sumikin Sst Tôle d'acier inoxydable ferritique excellente en termes de capacité au façonnage et procédé de fabrication de celle-ci
US8048239B2 (en) 2004-04-07 2011-11-01 Nippon Steel & Sumikin Stainless Steel Corporation Ferritic stainless steel sheet superior in shapeability and method of production of the same
WO2011026460A1 (fr) * 2009-09-01 2011-03-10 Thyssenkrupp Vdm Gmbh Procédé de production d'un alliage fer-chrome
EP2915894A4 (fr) * 2012-10-30 2016-10-26 Nippon Steel & Sumikin Sst Feuille d'acier inoxydable ferritique avec une excellente résistance à la chaleur
EP3521471A4 (fr) * 2016-09-28 2019-09-04 Posco Acier inoxydable ferritique présentant une adsorption réduite de boue de carbone pour échangeur de chaleur de système d'échappement et son procédé de fabrication
US11634801B2 (en) 2016-09-28 2023-04-25 Posco Co., Ltd Ferritic stainless steel having reduced carbon sludge adsorption for exhaust system heat exchanger and method of manufacturing same
CN113088654A (zh) * 2021-04-06 2021-07-09 山西太钢不锈钢股份有限公司 一种改善含铌铁素体不锈钢板宏观偏析的生产方法
CN113088654B (zh) * 2021-04-06 2022-09-13 山西太钢不锈钢股份有限公司 一种改善含铌铁素体不锈钢板宏观偏析的生产方法
EP4092141A1 (fr) * 2021-05-21 2022-11-23 ThyssenKrupp Steel Europe AG Produit plan en acier doté d'un revêtement al, son procédé de fabrication, composant en acier et son procédé de fabrication

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US20020117239A1 (en) 2002-08-29
KR20020052993A (ko) 2002-07-04
DE60105955D1 (de) 2004-11-04
KR100799240B1 (ko) 2008-01-29
DE60105955T2 (de) 2005-10-06
CN1363710A (zh) 2002-08-14
US20040084116A1 (en) 2004-05-06
CN1172017C (zh) 2004-10-20
US6673166B2 (en) 2004-01-06
ES2230227T3 (es) 2005-05-01
US7094295B2 (en) 2006-08-22

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