[go: up one dir, main page]

EP1295967A3 - Process for depositing a zinc-nickel alloy from an electrolyte - Google Patents

Process for depositing a zinc-nickel alloy from an electrolyte Download PDF

Info

Publication number
EP1295967A3
EP1295967A3 EP02020926A EP02020926A EP1295967A3 EP 1295967 A3 EP1295967 A3 EP 1295967A3 EP 02020926 A EP02020926 A EP 02020926A EP 02020926 A EP02020926 A EP 02020926A EP 1295967 A3 EP1295967 A3 EP 1295967A3
Authority
EP
European Patent Office
Prior art keywords
zinc
electrolyte
derivatives
salts
carboxylic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP02020926A
Other languages
German (de)
French (fr)
Other versions
EP1295967A2 (en
Inventor
Wilhelmus Maria Johannes Verberne
Karl-Heinz Wandner
Thomas Helden
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MacDermid Enthone Inc
Original Assignee
Enthone Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Enthone Inc filed Critical Enthone Inc
Publication of EP1295967A2 publication Critical patent/EP1295967A2/en
Publication of EP1295967A3 publication Critical patent/EP1295967A3/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00—Electroplating: Baths therefor
    • C25D3/02—Electroplating: Baths therefor from solutions
    • C25D3/56—Electroplating: Baths therefor from solutions of alloys
    • C25D3/565—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of zinc
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02—Anodisation
    • C25D11/04—Anodisation of aluminium or alloys based thereon
    • C25D11/06—Anodisation of aluminium or alloys based thereon characterised by the electrolytes used
    • C25D11/10—Anodisation of aluminium or alloys based thereon characterised by the electrolytes used containing organic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electroplating And Plating Baths Therefor (AREA)

Abstract

Die Erfindung betrifft ein Verfahren zur Abscheidung einer Zink-Nickel-Legierung aus einem Zink-Nickel-Elektrolyten, welches dadurch gekennzeichnet ist, das dem Elektrolyten zur Erweiterung des anwendbaren Stromdichtebereichs wenigstens eine aromatische Carbonsäure, deren Salze und/oder deren Derivate oder wenigstens eine aliphatische Carbonsäure, deren Salze und/oder deren Derivate, oder wenigstens eine aromatische und/oder aliphatische Carbonsäure, deren Salze und/oder deren Derivate zugegeben werden. Ferner wird ein für dieses Verfahren geeigneter Elektrolyt angegeben. Das erfindungsgemäße Verfahren ermöglicht es in vorteilhafter Weise, daß brauchbare Zink-Nickel-Legierungen über einen weiten Stromdichtebereich abgeschieden werden können, so daß auch die Beschichtung von profilierten Werkstücken möglich ist. Dabei kann mit einem ammoniumfreien Elektrolyten gearbeitet werden, was in vorteilhafter Weise die Belastung der Abwässer verringert.The invention relates to a method for depositing a zinc-nickel alloy from a zinc-nickel electrolyte, which is characterized in that the Electrolytes for extending the applicable current density range at least an aromatic carboxylic acid, its salts and / or their derivatives or at least one aliphatic carboxylic acid, its salts and / or derivatives thereof, or at least one aromatic and / or aliphatic carboxylic acid, the Salts and / or their derivatives are added. Furthermore, one for this Method specified suitable electrolyte. The inventive method allows advantageously that useful zinc-nickel alloys over a wide current density range can be deposited, so that the Coating of profiled workpieces is possible. It can with a ammonium-free electrolytes are worked, which advantageously the Reduced load on the wastewater.

EP02020926A 2001-09-21 2002-09-19 Process for depositing a zinc-nickel alloy from an electrolyte Withdrawn EP1295967A3 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10146559A DE10146559A1 (en) 2001-09-21 2001-09-21 Process for the deposition of a zinc-nickel alloy from an electrolyte
DE10146559 2001-09-21

Publications (2)

Publication Number Publication Date
EP1295967A2 EP1295967A2 (en) 2003-03-26
EP1295967A3 true EP1295967A3 (en) 2005-05-11

Family

ID=7699793

Family Applications (1)

Application Number Title Priority Date Filing Date
EP02020926A Withdrawn EP1295967A3 (en) 2001-09-21 2002-09-19 Process for depositing a zinc-nickel alloy from an electrolyte

Country Status (6)

Country Link
US (1) US20030085130A1 (en)
EP (1) EP1295967A3 (en)
JP (1) JP4307810B2 (en)
KR (1) KR100556604B1 (en)
CN (1) CN1291068C (en)
DE (1) DE10146559A1 (en)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060266438A1 (en) * 2005-05-26 2006-11-30 Pavco, Inc. Trivalent chromium conversion coating and method of application thereof
WO2007002070A2 (en) * 2005-06-20 2007-01-04 Pavco, Inc. Zinc-nickel alloy electroplating system
ES2553730T3 (en) * 2006-07-13 2015-12-11 Enthone, Incorporated Electrolyte composition and procedure for the deposition of a layer of zinc-nickel alloy on a cast iron or cast steel substrate
DE102006035233A1 (en) * 2006-07-26 2008-01-31 Mahle International Gmbh Galvanic surface coating of a component
US20100096274A1 (en) * 2008-10-17 2010-04-22 Rowan Anthony J Zinc alloy electroplating baths and processes
DE102008056776A1 (en) 2008-11-11 2010-05-12 Enthone Inc., West Haven Galvanic bath and method for the deposition of zinciferous layers
DE202008014947U1 (en) 2008-11-11 2009-03-12 Enthone Inc., West Haven Galvanic bath for the separation of zinciferous layers
DE102008058086B4 (en) * 2008-11-18 2013-05-23 Atotech Deutschland Gmbh Method and device for cleaning electroplating baths for the deposition of metals
KR101183255B1 (en) 2012-04-13 2012-09-14 서영호 Tin-zinc alloy plating solution
JP5740616B1 (en) 2014-09-25 2015-06-24 ユケン工業株式会社 Additive for acidic zinc alloy plating bath, acidic zinc alloy plating bath, and method for producing zinc alloy plated member
PL3015571T3 (en) 2014-10-27 2018-10-31 Atotech Deutschland Gmbh Acidic zinc and zinc-nickel alloy plating bath composition and electroplating method
PT3461933T (en) 2017-09-28 2019-12-09 Atotech Deutschland Gmbh Method for electrolytically depositing a zinc-nickel alloy layer on at least a substrate to be treated
EP3666929A1 (en) * 2018-12-12 2020-06-17 Dr.Ing. Max Schlötter GmbH & Co. KG Boric acid and ammonium-free zinc electrolyte for the galvanic deposition of zinc coverings

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4388160A (en) * 1980-02-20 1983-06-14 Rynne George B Zinc-nickel alloy electroplating process
US4515663A (en) * 1984-01-09 1985-05-07 Omi International Corporation Acid zinc and zinc alloy electroplating solution and process
DE3534147A1 (en) * 1985-09-25 1987-04-02 Elektro Brite Gmbh Chloride-containing bath for the electrodeposition of a zinc-nickel alloy on iron
US4861442A (en) * 1988-02-26 1989-08-29 Okuno Chemical Industries Co., Ltd. Zinc-nickel alloy plating bath and plating method
US4889602A (en) * 1986-04-14 1989-12-26 Dipsol Chemicals Co., Ltd. Electroplating bath and method for forming zinc-nickel alloy coating
JPH0949097A (en) * 1994-08-31 1997-02-18 Kawasaki Steel Corp Method for producing electrolytic zinc-nickel alloy plating solution and plated steel sheet
US5700362A (en) * 1994-04-15 1997-12-23 Fukuda Metal Foil And Powder Co., Ltd. Method of treating copper foil for printed circuits
DE19941765A1 (en) * 1998-09-15 2000-03-16 Lpw Chemie Gmbh Electroplating process for high-gloss zinc coatings on metal involves using aqueous acid electrolyte containing zinc salt and heterocyclic aromatic, especially N-alkyl-pyridine compound, as brightener

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4543166A (en) * 1984-10-01 1985-09-24 Omi International Corporation Zinc-alloy electrolyte and process
US4832802A (en) * 1988-06-10 1989-05-23 Mcgean-Rohco, Inc. Acid zinc-nickel plating baths and methods for electrodepositing bright and ductile zinc-nickel alloys and additive composition therefor
KR100276701B1 (en) * 1994-08-31 2001-01-15 에모토 간지 Electrolytic zinc-nickel alloy plating solution and method for producing steel sheet using the alloy plating solution
US6238542B1 (en) * 1998-09-15 2001-05-29 Thomas Helden Water soluble brighteners for zinc and zinc alloy electrolytes

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4388160A (en) * 1980-02-20 1983-06-14 Rynne George B Zinc-nickel alloy electroplating process
US4515663A (en) * 1984-01-09 1985-05-07 Omi International Corporation Acid zinc and zinc alloy electroplating solution and process
DE3534147A1 (en) * 1985-09-25 1987-04-02 Elektro Brite Gmbh Chloride-containing bath for the electrodeposition of a zinc-nickel alloy on iron
US4889602A (en) * 1986-04-14 1989-12-26 Dipsol Chemicals Co., Ltd. Electroplating bath and method for forming zinc-nickel alloy coating
US4889602B1 (en) * 1986-04-14 1995-11-14 Dipsol Chem Electroplating bath and method for forming zinc-nickel alloy coating
US4861442A (en) * 1988-02-26 1989-08-29 Okuno Chemical Industries Co., Ltd. Zinc-nickel alloy plating bath and plating method
US5700362A (en) * 1994-04-15 1997-12-23 Fukuda Metal Foil And Powder Co., Ltd. Method of treating copper foil for printed circuits
JPH0949097A (en) * 1994-08-31 1997-02-18 Kawasaki Steel Corp Method for producing electrolytic zinc-nickel alloy plating solution and plated steel sheet
DE19941765A1 (en) * 1998-09-15 2000-03-16 Lpw Chemie Gmbh Electroplating process for high-gloss zinc coatings on metal involves using aqueous acid electrolyte containing zinc salt and heterocyclic aromatic, especially N-alkyl-pyridine compound, as brightener

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 1997, no. 06 30 June 1997 (1997-06-30) *

Also Published As

Publication number Publication date
KR100556604B1 (en) 2006-03-06
CN1410602A (en) 2003-04-16
EP1295967A2 (en) 2003-03-26
JP4307810B2 (en) 2009-08-05
US20030085130A1 (en) 2003-05-08
JP2003105585A (en) 2003-04-09
KR20030025876A (en) 2003-03-29
DE10146559A1 (en) 2003-04-10
CN1291068C (en) 2006-12-20

Similar Documents

Publication Publication Date Title
EP1295967A3 (en) Process for depositing a zinc-nickel alloy from an electrolyte
DE102008038653A1 (en) Successive anti-corrosive pretreatment of metal surfaces in a multi-stage process
WO2011067094A1 (en) Multi-stage pre-treatment method for metal components having zinc and iron surfaces
EP2092090A1 (en) Zr-/ti-containing phosphating solution for passivation of metal composite surfaces
WO2011012443A1 (en) Multistage method for treating metal surfaces prior to dip painting
WO2005061761A1 (en) Two-stage conversion treatment
EP0056881A1 (en) Method of phosphating metals
DE102019134298A1 (en) Method for producing a flat steel product with a metallic protective layer based on zinc and a phosphate layer produced on a surface of the metallic protective layer and such a flat steel product
DE60319209T2 (en) PLATED FASTENING INSERTS AND METHOD FOR THE PRODUCTION THEREOF
EP0410497B1 (en) Process for the passivate rinsing of phosphate coatings
DE10322446A1 (en) Pretreatment of metal surfaces before painting
EP3931895B1 (en) Aluminium foil for battery electrodes and production method
DE102007057185A1 (en) Zirconium phosphating of metallic components, in particular iron
WO1995004842A1 (en) Phosphate treatment process for steel strip with one galvanised surface
EP0264811B1 (en) Process for producing phosphate coatings
EP0219779A2 (en) Phosphatizing process for electrolytically galvanized metal objects
DE2447482A1 (en) METHOD OF FORMING A GLASS FILM ON THE SURFACES OF GRAIN ORIENTED STEEL SHEETS
DE3227755A1 (en) METHOD FOR PRODUCING ELECTROLYTICALLY GALVANIZED STEEL SHEET
EP1531012B1 (en) Supplementary corrosion protection for pieces of organic pre-coated metal sheets
EP3201281B1 (en) Method for the wet chemical polishing and deburring of moulded parts made of zinc
EP0866888B1 (en) Method of phosphating metal surfaces
EP3728693B1 (en) Method for the corrosion protection and cleaning pretreatment of metallic components
DE102016206417A1 (en) PROMOTION TREATMENT FOR SUPPRESSING PLANT-ORIENTED PHOSPHATOR TRANSPORT IN A PROCESS FOR DIVING LACQUER
DE4317819A1 (en) Method for producing length measuring devices, and a length measuring device
DE3537658A1 (en) METHOD FOR PRODUCING A HARDENED, UNMAGNETIZABLE ROLLER BEARING COMPONENT, MADE OF AN AUSTENITIC MATERIAL, AND ROLLER BEARING COMPONENT PRODUCED BY THIS METHOD

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR IE IT LI LU MC NL PT SE SK TR

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR IE IT LI LU MC NL PT SE SK TR

AX Request for extension of the european patent

Extension state: AL LT LV MK RO SI

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Kind code of ref document: A3

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR IE IT LI LU MC NL PT SE SK TR

AX Request for extension of the european patent

Extension state: AL LT LV MK RO SI

17P Request for examination filed

Effective date: 20050617

AKX Designation fees paid

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR IE IT LI LU MC NL PT SE SK TR

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION HAS BEEN WITHDRAWN

18W Application withdrawn

Effective date: 20100924