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EP1276375B1 - Combinaisons de principes actifs fongicides - Google Patents

Combinaisons de principes actifs fongicides Download PDF

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Publication number
EP1276375B1
EP1276375B1 EP01933807A EP01933807A EP1276375B1 EP 1276375 B1 EP1276375 B1 EP 1276375B1 EP 01933807 A EP01933807 A EP 01933807A EP 01933807 A EP01933807 A EP 01933807A EP 1276375 B1 EP1276375 B1 EP 1276375B1
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EP
European Patent Office
Prior art keywords
formula
compounds
active compound
plants
fungicidal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP01933807A
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German (de)
English (en)
Other versions
EP1276375A2 (fr
Inventor
Ulrike Wachendorff-Neumann
Thomas Seitz
Herbert Gayer
Ulrich Heinemann
Bernd-Wieland Krüger
Wolfgang Krämer
Lutz Assmann
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Bayer CropScience AG
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Bayer CropScience AG
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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N2300/00—Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48

Definitions

  • the present invention relates to novel drug combinations that are known from Methoximinoessigklamid derivatives on the one hand and other known drugs On the other hand exist and very well for the control of phytopathogenic Mushrooms are suitable.
  • alkoximinoacetamide derivatives have fungicidal properties have (see WO 96/23763). The effectiveness of these substances is good, lets but at low rates in some cases to be desired.
  • the fungicidal action of the active ingredient according to the invention combinations significantly higher than the sum of the effects of the individual active ingredients. So there is an unpredictable, true synergistic effect not just an effect supplement.
  • the compound may be present as E or Z isomer.
  • the product can therefore be used as a mixture of different isomers or in the form of a single isomer. Preference is given to compounds of the formula (I) in which the compounds of the formula (I) are present as E-isomer.
  • R 1 represents phenyl which is unsubstituted or substituted by fluorine, chlorine, bromine, methyl or ethyl, 2-naphthyl, 1,2,3,4-tetrahydronaphthyl, indanyl, 2-thienyl or 2 -Furanyl stands.
  • R 1 represents phenyl which is unsubstituted or substituted by fluorine, chlorine, bromine, methyl or ethyl, 2-naphthyl, 1,2,3,4-tetrahydronaphthyl or indanyl.
  • the active compound combinations according to the invention contain, in addition to an active substance of formula (I) at least one active ingredient of the compounds of the group 45 In addition, you can also use other fungicidal admixing components contain.
  • the active ingredients in the active compound combinations according to the invention are present in certain weight ratios, the synergistic effect is particularly pronounced.
  • the weight ratios of the active ingredients in the drug combinations can be varied within a relatively wide range. In general, 1 part by weight of active compound of the formula (I) 0.1 to 150 parts by weight, preferably 1 to 100 parts by weight of active compound from the group (45).
  • the active compound combinations according to the invention have very good fungicidal properties and can be used to combat phytopathogenic fungi, such as Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes, Deuteromycetes etc. use.
  • phytopathogenic fungi such as Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes, Deuteromycetes etc. use.
  • the active compound combinations according to the invention are particularly suitable for controlling Phytophthora infestans and Plasmopara viticola.
  • the good plant compatibility of the drug combinations in the fight Concentrations required by plant diseases allow treatment of aboveground plant parts, of planting and seed, and of the soil.
  • the Active compound combinations according to the invention can be used for foliar application or else be used as a mordant.
  • the active compound combinations according to the invention are also suitable for increasing the Crop yield. They are also low in toxins and have good plant tolerance on.
  • plants and parts of plants can be treated.
  • Plants are understood to mean all plants and plant populations, such as desirable and undesirable wild plants or crops (including naturally occurring crops).
  • Crop plants can be plants that by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods can be obtained, including transgenic plants and including the plant varieties that can be protected or not protected by plant variety rights.
  • Under plant parts are all aboveground and underground parts and organs the plants such as shoot, leaf, flower and root are understood, by way of example Leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds as well as roots, tubers and rhizomes. Part of the plant parts also crop as well as vegetative and generative propagation material, for example Cuttings, tubers, rhizomes, offshoots and seeds.
  • plants and their parts be treated.
  • wild-occurring or by conventional biological breeding methods such as crossing or Protoplastenfusion obtained plant species and plant varieties and parts thereof treated.
  • transgenic plants and plant varieties obtained by genetic engineering, optionally in Combination with conventional methods were obtained (Genetic Modified Organisms) and their parts treated.
  • the term “parts” or “parts of plants” or “plant parts” has been explained above.
  • Particularly preferred according to the invention are plants of the respective commercial ones or plant varieties in use. Under plant varieties understands one plants with certain characteristics ("Traits"), which by both conventional Breeding, by mutagenesis or by recombinant DNA techniques have been obtained. These can be varieties, biotypes and genotypes.
  • transgenic plants or plant varieties belong to all plants, by the genetic modification received genetic material containing this Gives plants particularly advantageous valuable properties ("traits").
  • traits are better plant growth, increased tolerance high or low temperatures, increased tolerance to dryness or against water or soil salt content, increased flowering efficiency, easier harvest, Acceleration of maturity, higher yields, higher quality and / or higher Nutritional value of the harvested products, higher shelf life and / or workability the harvest products.
  • Further and especially highlighted examples of such Properties are an increased defense of plants against animal and microbial Pests, such as insects, mites, phytopathogenic fungi, Bacteria and / or viruses as well as an increased tolerance of the plants against certain herbicidal active ingredients.
  • transgenic plants are the important crops, such as cereals (wheat, rice), corn, soy, potato, cotton, rapeseed as well as fruit plants (with the fruits apples, pears, citrus fruits and grapes) with maize, soy, potato, cotton and rape particularly highlighted become.
  • Traits are particularly emphasized the increased defense of the plants against insects caused by the plants Toxins, especially those produced by the genetic material from Bacillus thuringiensis (for example, by the genes CryIA (a), CryIA (b), CryIA (c), CryIIA, CryIIIA, CryIIIB2, Cry9c Cry2Ab, Cry3Bb and CryIF and their combinations) in the Plants are produced (hereinafter "Bt plants”).
  • Traits are also especially emphasized the increased defense of plants against Mushrooms, Bacteria and Viruses by Systemic Acquired Resistance (SAR), Systemin, Phytoalexins, elicitors and resistance genes and expressed accordingly Proteins and toxins.
  • SAR Systemic Acquired Resistance
  • Phytoalexins Phytoalexins
  • properties are further highlighted the increased tolerance of plants to certain herbicides Active ingredients, for example imidazolinones, sulfonylureas, glyphosate or Phosphinotricin (e.g., "PAT” gene).
  • PAT Phosphinotricin
  • Bt plants are maize varieties, Cottons, soybean and potato varieties, which are under the trade names YIELD GARD® (e.g., corn, cotton, soy), KnockOut® (e.g. Corn), StarLink® (e.g., corn), Bollgard® (cotton), Nucotn® (cotton), and NewLeaf® (potato).
  • YIELD GARD® e.g., corn, cotton, soy
  • KnockOut® e.g. Corn
  • StarLink® e.g., corn
  • Bollgard® cotton
  • Nucotn® cotton
  • NewLeaf® potato
  • Roundup Ready® to glyphosate
  • the listed plants can be particularly advantageous according to the invention with the Compounds of general formula I or the active substance mixtures according to the invention be treated.
  • the above for the active ingredients or mixtures specified ranges also apply to the treatment of these plants.
  • Particularly emphasized is the plant treatment with the in the present text specifically listed compounds or mixtures.
  • the treatment according to the invention of the plants and plant parts with the active ingredients takes place directly or by acting on their environment, habitat or Storage room according to the usual treatment methods, e.g. by diving, spraying, Vaporizing, atomizing, spreading, spreading and propagating material, in particular in seeds, further by single or multi-layer wrapping.
  • the active compound combinations according to the invention can be converted into the customary formulations such as solutions, emulsions, suspensions, powders, foams, Pastes, granules, aerosols, microencapsulations in polymeric substances and in Envelopes for seeds, as well as ULV formulations.
  • formulations are prepared in a known manner, e.g. by mixing the active substances or the active compound combinations with extenders, ie liquid Solvents, pressurized liquefied gases and / or solid carriers, optionally using surface-active agents, ie Emulsifiers and / or dispersants and / or foam-forming agents.
  • extenders ie liquid Solvents
  • surface-active agents ie Emulsifiers and / or dispersants and / or foam-forming agents.
  • organic Solvent can be used as auxiliary solvent.
  • liquid solvents are essentially in question: aromatics, such as xylene, toluene or alkylnaphthalenes, chlorinated aromatics or chlorinated aliphatic hydrocarbons, such as Chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, e.g. Petroleum fractions, alcohols, such as butanol or Glycol and their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strong polar solvents such as dimethylformamide and dimethyl sulfoxide, as well as water.
  • aromatics such as xylene, toluene or alkylnaphthalenes
  • chlorinated aromatics or chlorinated aliphatic hydrocarbons such as Chlorobenzenes, chloroethylenes or methylene chloride
  • liquids which are normal Temperature and under normal pressure are gaseous, e.g. Aerosol propellants, such as Butane, propane, nitrogen and carbon dioxide.
  • Aerosol propellants such as Butane, propane, nitrogen and carbon dioxide.
  • solid carriers come in Question: e.g. ground natural minerals, such as kaolins, clays, talc, chalk, Quartz, attapulgite, montmorillonite or diatomaceous earth and ground synthetic minerals, such as fumed silica, alumina and silicates.
  • solid carriers granules are suitable: e.g.
  • emulsifier and / or foaming agents are suitable: e.g. nonionic and anionic Emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, e.g. Alkylaryl polyglycol ethers, alkyl sulfonates, alkyl sulfates, aryl sulfonates as well as protein hydrolysates.
  • Suitable dispersants are: e.g. Lignin liquors and methylcellulose.
  • adhesives such as carboxymethylcellulose, natural and synthetic powdery, granular or latex-shaped polymers are used, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, as well as natural phospholipids, such as cephalins and lecithins, and synthetic phospholipids.
  • Other additives can be mineral and vegetable oils.
  • Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients, such as salts of iron, manganese, boron, copper, cobalt, Molybdenum and zinc are used.
  • inorganic pigments e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients, such as salts of iron, manganese, boron, copper, cobalt, Molybdenum and zinc are used.
  • the formulations generally contain between 0.1 and 95% by weight of active ingredients, preferably between 0.5 and 90%.
  • the active compound combinations according to the invention can be used as such or in their own Formulations also in mixture with known fungicides, bactericides, Acaricides, nematicides or insecticides may be used, e.g. the To widen spectrum of activity or to prevent development of resistance. In many Cases are obtained thereby synergistic effects, i. the effectiveness of the mixture is greater than the effectiveness of the individual components.
  • the active substance combinations can be used as such, in the form of their formulations or the application forms prepared from it, such as ready-to-use solutions, emulsifiable Concentrates, emulsions, suspensions, wettable powders, soluble powders and Granules are applied.
  • the application is done in the usual way, e.g. by casting, spraying, spraying, scattering, spreading, dry pickling, Wet pickling, wet pickling, slurry pickling or encrusting.
  • the application rates be varied within a larger range depending on the type of application.
  • the application rates of drug combination In the treatment of parts of plants are the application rates of drug combination generally between 0.1 and 10,000 g / ha, preferably between 10 and 1000 g / ha.
  • the application rates of active ingredient combination In seed treatment, generally between 0.001 and 50 g per kilogram of seed, preferably between 0.01 and 10 g per kilogram of seed.
  • the soil In the treatment the treatment the soil are the application rates of drug combination in general between 0.1 and 10,000 g / ha, preferably between 1 and 5,000 g / ha.
  • the good fungicidal action of the active compound combinations according to the invention is possible from the examples below. While the individual active ingredients in the fungicidal activity, the combinations have an effect which goes beyond a simple sum of effects.
  • a synergistic effect is always present in fungicides when fungicidal Effect of drug combinations is greater than the sum of the effects of individually applied active ingredients.
  • SR Colby Calculating Synergistic and Antagonistic Responses of Herbicide Combinations, Weeds 15 (1967), 20-22) as follows:
  • the efficiency is determined in%. It means 0% an efficiency that corresponds to that of the control, while an efficiency of 100% means that no infestation is observed.
  • 0% means one Efficiency, which corresponds to that of the control, while an efficiency of 100% means that no infestation is observed.
  • SR Colby Calculating Synergistic and Antagonistic Responses of Herbicide Combinations, Weeds 15 (1967), 20-22) as follows:
  • the efficiency is determined in%. It means 0% an efficiency that corresponds to that of the control, while an efficiency of 100% means that no infestation is observed.

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  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Agronomy & Crop Science (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Zoology (AREA)
  • General Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Furan Compounds (AREA)
  • Heterocyclic Compounds Containing Sulfur Atoms (AREA)
  • Plural Heterocyclic Compounds (AREA)

Claims (12)

  1. Combinaisons de substances actives, contenant au moins un composé de formule (I),
    Figure 00320001
       dans laquelle
    R1
    est un reste phényle non substitué ou portant un substituant fluoro, chloro, bromo, méthyle, éthyle, n-propyle, isopropyle, n-butyle, isobutyle, tertiobutyle, méthoxy, éthoxy ou phénoxy, un reste 2-naphtyle, 1,2,3,4-tétrahydronaphtyle, indanyle, 2-benzofurannyle, 2-benzothiényle, 2-thiényle ou 2-furannyle,
    et
    (45)
    a) de l'oxychlorure de cuivre (XXXXVIa) et/ou
    b) de l'hydroxyde de cuivre (XXXXVb).
  2. Mélanges fongicides suivant la revendication 1, contenant des composés de formule (I) dans lesquels R1 est un reste phényle non substitué ou substitué par un radical fluoro, chloro, bromo, méthyle ou éthyle, un reste 2-naphtyle, 1,2,3,4-tétrahydronaphtyle ou indanyle.
  3. Mélanges fongicides suivant la revendication 1, contenant comme composés de formule (I) des composés de formule (Ia)
    Figure 00330001
  4. Mélanges fongicides suivant la revendication 1, contenant comme composés de formule (I) des composés de formule (Ib)
    Figure 00330002
  5. Mélanges fongicides suivant la revendication 1, contenant comme composés de formule (I) des composés de formule (Ic)
    Figure 00330003
  6. Mélanges fongicides suivant la revendication 1, contenant comme composés de formule (I) des composés de formule (Id)
    Figure 00340001
  7. Mélanges fongicides suivant la revendication 1, contenant comme composés de formule (I) des composés de formule (Ie)
    Figure 00340002
  8. Mélanges fongicides suivant la revendication 1, contenant comme composés de formule (I) des composés de formule (If)
    Figure 00340003
  9. Compositions suivant au moins l'une des revendications 1 à 8, caractérisées en ce que dans les combinaisons de substances actives, le rapport en poids de la substance active de formule (I) à la substance active du groupe (45) se situe entre 1:0,1 et 1:150.
  10. Procédé pour combattre des champignons, caractérisé en ce qu'on épand des combinaisons de substance active suivant au moins l'une des revendications 1 à 9 sur les champignons et/ou sur leur milieu.
  11. Utilisation de combinaisons de substances actives suivant au moins l'une des revendications 1 à 9, pour combattre des champignons.
  12. Procédé de préparation de compositions fongicides, caractérisé en ce qu'on mélange des combinaisons de substances actives suivant au moins l'une des revendications 1 à 9, avec des diluants et/ou des agents tensioactifs.
EP01933807A 2000-04-20 2001-04-09 Combinaisons de principes actifs fongicides Expired - Lifetime EP1276375B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10019758A DE10019758A1 (de) 2000-04-20 2000-04-20 Fungizide Wirkstoffkombinationen
DE10019758 2000-04-20
PCT/EP2001/004042 WO2001080641A2 (fr) 2000-04-20 2001-04-09 Combinaisons de principes actifs fongicides

Publications (2)

Publication Number Publication Date
EP1276375A2 EP1276375A2 (fr) 2003-01-22
EP1276375B1 true EP1276375B1 (fr) 2005-07-20

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Application Number Title Priority Date Filing Date
EP01933807A Expired - Lifetime EP1276375B1 (fr) 2000-04-20 2001-04-09 Combinaisons de principes actifs fongicides

Country Status (18)

Country Link
US (2) US6787567B2 (fr)
EP (1) EP1276375B1 (fr)
JP (1) JP2003531154A (fr)
KR (1) KR20020087985A (fr)
CN (1) CN1436044A (fr)
AT (1) ATE299648T1 (fr)
AU (1) AU2001260189A1 (fr)
BR (1) BR0110116A (fr)
DE (2) DE10019758A1 (fr)
ES (1) ES2243496T3 (fr)
HU (1) HUP0302686A2 (fr)
IL (1) IL152009A0 (fr)
MX (1) MXPA02010331A (fr)
PL (1) PL358279A1 (fr)
PT (1) PT1276375E (fr)
RU (1) RU2265331C2 (fr)
WO (1) WO2001080641A2 (fr)
ZA (1) ZA200207474B (fr)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL369028A1 (en) * 2001-01-16 2005-04-18 Basf Aktiengesellschaft Fungicidal mixture
TWI243164B (en) * 2001-02-13 2005-11-11 Aventis Pharma Gmbh Acylated indanyl amines and their use as pharmaceuticals
EP1482798B1 (fr) 2002-03-01 2006-05-24 Basf Aktiengesellschaft Melange fongicide a base de prothioconazole et de trifloxystrobin
EP2289321B1 (fr) * 2002-03-07 2013-05-29 Basf Se Mélanges fongicides à base de triazoles
UA77507C2 (en) * 2002-03-21 2006-12-15 Basf Ag Fungicidal mixture
DE10228102A1 (de) * 2002-06-24 2004-01-15 Bayer Cropscience Ag Fungizide Wirkstoffkombinationen
JP2008510820A (ja) * 2004-08-24 2008-04-10 バイエル・クロツプサイエンス・エル・ピー イネ科植物又は芝草における菌類病原体を防除する方法
PE20060796A1 (es) * 2004-11-25 2006-09-29 Basf Ag Procedimiento para intensificar la eficiencia de etaboxam
DE102005058838A1 (de) * 2005-12-09 2007-06-14 Bayer Cropscience Ag Fungizide Wirkstoffkombination
CA2647878C (fr) * 2006-04-06 2014-10-14 Ulrich Johannes Haas Compositions fongicides synergetiques ternaires
AU2007295516B2 (en) * 2006-09-12 2010-09-23 Nippon Soda Co., Ltd. Pest control agent in form of stable suspension
CN101658177B (zh) * 2009-07-22 2013-06-12 深圳诺普信农化股份有限公司 一种含有氰霜唑的复配杀菌组合物
CN104322521B (zh) * 2012-11-15 2016-03-16 江苏扬农化工股份有限公司 一种含有氟啶胺的复配杀菌组合物
EP3047731A1 (fr) 2015-01-21 2016-07-27 Basf Se Procédé de lutte contre la rouille du soja comprenant le traitement du soja avec des (2E)-2-[3-substitués-2 [[(E)-[(2E)-2-alkoxyimino-1-méthyl-2-phényl-ethylidene]amino]oxyméthyl]phényl]-2-méthoxy-imino-N-méthyl-acétamides
JP2018503676A (ja) 2015-01-27 2018-02-08 ボード・オブ・リージエンツ，ザ・ユニバーシテイ・オブ・テキサス・システム 病原真菌に感染した植物を処理するのに有効な殺菌剤促進剤
CN117343154B (zh) * 2022-08-24 2025-01-07 西北农林科技大学 快速鉴定荔枝霜疫霉病菌对噁唑菌酮抗药性的方法

Family Cites Families (71)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1972961A (en) 1931-05-26 1934-09-11 Du Pont Disinfectant
CA500788A (fr) 1948-05-18 1954-03-16 R. Kittleson Allen Preparation de n-trichloromethylethioimides
NL129620C (fr) 1963-04-01
NL157191C (nl) 1966-12-17 Schering Ag Werkwijze voor het bereiden van een preparaat met fungicide en fungistatische werking.
SU267245A1 (ru) * 1968-12-23 1973-09-17 Фунгицидный состав
US3903090A (en) 1969-03-19 1975-09-02 Sumitomo Chemical Co Novel n-(3,5-dihalophenyl)-imide compounds
US4009278A (en) 1969-03-19 1977-02-22 Sumitomo Chemical Company, Limited Antimicrobial composition and method containing N-(3,5-dihalophenyl)-imide compounds
US3745170A (en) 1969-03-19 1973-07-10 Sumitomo Chemical Co Novel n-(3,5-dihalophenyl)-imide compounds
FR2148868A6 (fr) 1970-10-06 1973-03-23 Rhone Poulenc Sa
US3823240A (en) 1970-10-06 1974-07-09 Rhone Poulenc Sa Fungicidal hydantoin derivatives
US4048318A (en) 1972-01-11 1977-09-13 Bayer Aktiengesellschaft 1-Substituted-1,2,4-triazole fungicides
US4147791A (en) 1972-01-11 1979-04-03 Bayer Aktiengesellschaft 1-Substituted-1,2,4-triazole fungicidal compositions and methods for combatting fungi that infect or attack plants
US3912752A (en) 1972-01-11 1975-10-14 Bayer Ag 1-Substituted-1,2,4-triazoles
DE2324010C3 (de) 1973-05-12 1981-10-08 Bayer Ag, 5090 Leverkusen 1-Substituierte 2-Triazolyl-2-phenoxyäthanol-Verbindungen, Verfahren zu ihrer Herstellung und ihre Verwendung zur Bekämpfung von Pilzen
GB1469772A (en) 1973-06-21 1977-04-06 Boots Co Ltd Fungicidal imidazole derivatives
US4079062A (en) 1974-11-18 1978-03-14 Janssen Pharmaceutica N.V. Triazole derivatives
US4160838A (en) 1977-06-02 1979-07-10 Janssen Pharmaceutica N.V. Antimicrobial and plant-growth-regulating triazole derivatives
BG28977A3 (en) 1978-02-02 1980-08-15 Montedison Spa Fungicide means and method for fungus fighting
BE884661A (fr) 1979-08-16 1981-02-09 Sandoz Sa Nouvelles 3-amino-oxazolidine-2-ones, leur preparation et leur utilisation comme agents fongicides
JPS6052146B2 (ja) 1979-12-25 1985-11-18 石原産業株式会社 Ｎ−ピリジルアニリン系化合物、それらの製造方法及びそれらを含有する有害生物防除剤
US4347253A (en) 1980-04-25 1982-08-31 Sandoz Ltd. Fungicides
AU542623B2 (en) 1980-05-16 1985-02-28 Bayer Aktiengesellschaft 1-hydroxyethyl-azole derivatives
US4432989A (en) 1980-07-18 1984-02-21 Sandoz, Inc. αAryl-1H-imidazole-1-ethanols
US5266585A (en) 1981-05-12 1993-11-30 Ciba-Geigy Corporation Arylphenyl ether derivatives, compositions containing these compounds and use thereof
US4510136A (en) 1981-06-24 1985-04-09 E. I. Du Pont De Nemours And Company Fungicidal 1,2,4-triazole derivatives
US4496551A (en) 1981-06-24 1985-01-29 E. I. Du Pont De Nemours And Company Fungicidal imidazole derivatives
US4608385A (en) 1981-10-29 1986-08-26 Sumitomo Chemical Company, Limited Fungicidal N-phenylcarbamates
CH658654A5 (de) 1983-03-04 1986-11-28 Sandoz Ag Azolderivate, verfahren zu ihrer herstellung und mittel die diese verbindungen enthalten.
US4920139A (en) 1983-11-10 1990-04-24 Rohm And Haas Company Alpha-alkyl-alpha-(4-halophenyl)-1H-1,2,4-triazole-1-propanenitrile
IL78175A (en) 1985-03-29 1989-10-31 Basf Ag Azolylmethyloxiranes,their preparation and their use as fungicide crop protection agents
US4705800A (en) 1985-06-21 1987-11-10 Ciba-Geigy Corporation Difluorbenzodioxyl cyanopyrrole microbicidal compositions
EP0219756B1 (fr) 1985-10-09 1994-01-05 Shell Internationale Researchmaatschappij B.V. Amides de l'acide acrylique
IT1204773B (it) 1986-01-23 1989-03-10 Montedison Spa Azolilderivati fungicidi
US5087635A (en) 1986-07-02 1992-02-11 Rohm And Haas Company Alpha-aryl-alpha-phenylethyl-1H-1,2,4-triazole-1-propanenitriles
DE3623921A1 (de) 1986-07-16 1988-01-21 Basf Ag Oximether und diese enthaltende fungizide
USRE33989E (en) 1986-07-16 1992-07-07 Basf Aktiengesellschaft Oxime ethers and fungicides containing these compounds
JPH0784445B2 (ja) 1986-12-03 1995-09-13 クミアイ化学工業株式会社 ピリミジン誘導体および農園芸用殺菌剤
DE3889345T2 (de) 1987-02-09 1994-09-01 Zeneca Ltd Schimmelbekämpfungsmittel.
DE3735555A1 (de) 1987-03-07 1988-09-15 Bayer Ag Aminomethylheterocyclen
CA1339133C (fr) 1987-03-13 1997-07-29 Rikuo Nasu Derives de l'imidazole et compositions a base de ces derives pour l'elimination d'organismes nuisibles
ES2052772T3 (es) 1987-08-21 1994-07-16 Ciba Geigy Ag Procedimiento y agente contra enfermedades de plantas.
DE3881320D1 (de) 1987-09-28 1993-07-01 Ciba Geigy Ag Schaedlingsbekaempfungsmittel.
US5153200A (en) 1987-09-28 1992-10-06 Ciba-Geigy Corporation Pesticides
IL89029A (en) 1988-01-29 1993-01-31 Lilly Co Eli Fungicidal quinoline and cinnoline derivatives, compositions containing them, and fungicidal methods of using them
DE3814505A1 (de) 1988-04-29 1989-11-09 Bayer Ag Substituierte cycloalkyl- bzw. heterocyclyl-carbonsaeureanilide
DE3815728A1 (de) 1988-05-07 1989-11-16 Bayer Ag Stereoisomere von n-(r)-(1-aryl-ethyl)-1-alkyl-2,2-dichlor- cyclopropancarbonsaeureamiden
US5264440A (en) 1989-02-10 1993-11-23 Imperial Chemical Industries Plc Fungicides
US5223523A (en) 1989-04-21 1993-06-29 E. I. Du Pont De Nemours And Company Fungicidal oxazolidinones
US5356908A (en) 1989-04-21 1994-10-18 E. I. Du Pont De Nemours And Company Fungicidal oxazolidinones
US4957933A (en) 1989-04-21 1990-09-18 E. I. Du Pont De Nemours And Company Fungicidal oxazolidinones
PH11991042549B1 (fr) 1990-06-05 2000-12-04
US5453531A (en) 1990-08-25 1995-09-26 Bayer Aktiengesellschaft Substituted valinamide derivatives
JPH06504538A (ja) 1991-01-30 1994-05-26 ゼネカ・リミテッド 殺菌剤
DE4117371A1 (de) 1991-05-28 1992-12-03 Basf Ag Antimykotische mittel, die phenylessigsaeurederivate enthalten
IL103614A (en) 1991-11-22 1998-09-24 Basf Ag Carboxamides for controlling botrytis and certain novel such compounds
US6002016A (en) 1991-12-20 1999-12-14 Rhone-Poulenc Agrochimie Fungicidal 2-imidazolin-5-ones and 2-imidazoline-5-thiones
FR2706456B1 (fr) 1993-06-18 1996-06-28 Rhone Poulenc Agrochimie Dérivés optiquement actifs de 2-imidazoline-5-ones et 2-imidazoline-5-thiones fongicides.
JP2783130B2 (ja) 1992-10-02 1998-08-06 三菱化学株式会社 メトキシイミノ酢酸誘導体およびこれを有効成分とする農園芸用殺菌剤
US5304572A (en) 1992-12-01 1994-04-19 Rohm And Haas Company N-acetonylbenzamides and their use as fungicides
ZW8594A1 (en) 1993-08-11 1994-10-12 Bayer Ag Substituted azadioxacycbalkenes
US5514643A (en) 1993-08-16 1996-05-07 Lucky Ltd. 2-aminothiazolecarboxamide derivatives, processes for preparing the same and use thereof for controlling phytopathogenic organisms
RU2162075C2 (ru) 1994-02-04 2001-01-20 Басф Акциенгезельшафт Производные фенилуксусной кислоты и средство борьбы против насекомых и паукообразных и против вредоносных грибов
DE4423612A1 (de) 1994-07-06 1996-01-11 Basf Ag 2-[(Dihydro)pyrazolyl-3'-oxymethylen]-anilide, Verfahren zu ihrer Herstelung und ihre Verwendung
DE19528046A1 (de) 1994-11-21 1996-05-23 Bayer Ag Triazolyl-Derivate
BR9606814A (pt) 1995-01-30 1997-12-30 Bayer Ag Amidas de ácido alcoximinoacético
DE19528651A1 (de) 1995-08-04 1997-02-06 Basf Ag Hydroximsäurederivate, Verfahren zu ihrer Herstellung und sie enthaltende Mittel
IL122944A (en) 1995-08-10 2001-11-25 Bayer Ag Halogenobenzimidazoles, their preparation and microbicidal compositions containing them
DE19539324A1 (de) 1995-10-23 1997-04-24 Basf Ag Phenylessigsäurederivate, Verfahren und Zwischenprodukte zu ihrer Herstellung und sie enthaltende Mittel
DE19602095A1 (de) 1996-01-22 1997-07-24 Bayer Ag Halogenpyrimidine
DE19646407A1 (de) 1996-11-11 1998-05-14 Bayer Ag Halogenpyrimidine
DE19716257A1 (de) * 1997-04-18 1998-10-22 Bayer Ag Fungizide Wirkstoffkombination

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ZA200207474B (en) 2003-09-18
PL358279A1 (en) 2004-08-09
WO2001080641A3 (fr) 2002-03-28
US6787567B2 (en) 2004-09-07
HUP0302686A2 (hu) 2003-11-28
KR20020087985A (ko) 2002-11-23
AU2001260189A1 (en) 2001-11-07
US20030158151A1 (en) 2003-08-21
US20040266850A1 (en) 2004-12-30
MXPA02010331A (es) 2003-05-23
WO2001080641A2 (fr) 2001-11-01
CN1436044A (zh) 2003-08-13
ES2243496T3 (es) 2005-12-01
RU2002131167A (ru) 2004-03-27
ATE299648T1 (de) 2005-08-15
DE50106790D1 (de) 2005-08-25
EP1276375A2 (fr) 2003-01-22
PT1276375E (pt) 2005-11-30
JP2003531154A (ja) 2003-10-21
BR0110116A (pt) 2003-02-11
DE10019758A1 (de) 2001-10-25
RU2265331C2 (ru) 2005-12-10

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