EP1268874A1 - Cible de pulverisation cathodique a base d'un metal ou d'un alliage metallique, et son procede de production - Google Patents
Cible de pulverisation cathodique a base d'un metal ou d'un alliage metallique, et son procede de productionInfo
- Publication number
- EP1268874A1 EP1268874A1 EP01929445A EP01929445A EP1268874A1 EP 1268874 A1 EP1268874 A1 EP 1268874A1 EP 01929445 A EP01929445 A EP 01929445A EP 01929445 A EP01929445 A EP 01929445A EP 1268874 A1 EP1268874 A1 EP 1268874A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- sputtering target
- particles
- melt
- granules
- target according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 14
- 238000000034 method Methods 0.000 title claims abstract description 14
- 239000002184 metal Substances 0.000 title claims abstract description 13
- 229910001092 metal group alloy Inorganic materials 0.000 title claims abstract description 9
- 229910052751 metal Inorganic materials 0.000 claims abstract description 12
- 238000002844 melting Methods 0.000 claims abstract description 8
- 230000008018 melting Effects 0.000 claims abstract description 8
- 239000002245 particle Substances 0.000 claims description 35
- 238000005477 sputtering target Methods 0.000 claims description 31
- 239000008187 granular material Substances 0.000 claims description 26
- 229910045601 alloy Inorganic materials 0.000 claims description 25
- 239000000956 alloy Substances 0.000 claims description 25
- 239000000155 melt Substances 0.000 claims description 18
- 239000000843 powder Substances 0.000 claims description 16
- 238000007711 solidification Methods 0.000 claims description 10
- 230000008023 solidification Effects 0.000 claims description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- 229910052797 bismuth Inorganic materials 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 239000002826 coolant Substances 0.000 claims description 4
- 230000029142 excretion Effects 0.000 claims description 4
- 229910052714 tellurium Inorganic materials 0.000 claims description 4
- 229910052718 tin Inorganic materials 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 229910001215 Te alloy Inorganic materials 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 3
- 229910052787 antimony Inorganic materials 0.000 claims description 3
- 229910052738 indium Inorganic materials 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 2
- 238000010309 melting process Methods 0.000 claims description 2
- 238000010791 quenching Methods 0.000 claims description 2
- 230000000171 quenching effect Effects 0.000 claims description 2
- 238000005266 casting Methods 0.000 description 7
- 238000000227 grinding Methods 0.000 description 7
- 239000007789 gas Substances 0.000 description 5
- 230000001681 protective effect Effects 0.000 description 5
- 238000004544 sputter deposition Methods 0.000 description 5
- 230000006835 compression Effects 0.000 description 4
- 238000007906 compression Methods 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 238000005204 segregation Methods 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- 229910001152 Bi alloy Inorganic materials 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 238000000889 atomisation Methods 0.000 description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 2
- 239000011362 coarse particle Substances 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000009689 gas atomisation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 229910005728 SnZn Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000012864 cross contamination Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 229910000743 fusible alloy Inorganic materials 0.000 description 1
- 239000008190 ground granulate Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
- C23C14/3407—Cathode assembly for sputtering apparatus, e.g. Target
- C23C14/3414—Metallurgical or chemical aspects of target preparation, e.g. casting, powder metallurgy
Definitions
- the primary structure being able to have grain sizes or sizes of individually separated phases, which are preferably at least 70%, in particular 80% ⁇ 30 ⁇ m.
- the size especially in the case of precipitations, can also be less than 10 ⁇ m.
- the oxygen content of the alloys can typically be in the range from 200 to 300 ppm, with an increase in the oxygen content only resulting, for example, to 600 ppm even after subsequent pulverization using the primary structure. In any case, the oxygen content can be kept well below 1000 ppm.
- Figure 1 shows several granules, with 1 being a granulate, which here is approximately in the form of a round structure and has several cracks. During further processing, these granules can shatter into particles.
- the granulate itself or the particles have a fine structure as shown in Figure 2 as the primary structure, whereby Figure 2 clearly shows the coarse structure of the particles and the fine structure within these particles.
- Figure 2 clearly shows the somewhat broader boundary lines between three to four larger particles, which in turn are structured much more finely in the context of a primary structure.
- a scale of 50 ⁇ m is given in the drawing figure. It can be clearly seen that the primary structure has a structuring which has significantly smaller area sizes within the fine structure.
- Figure 1 shows a granulate of Ge Sb 2 Te 5 alloy poured into water at a magnification of 50: 1 and Figure 2 particles of an AglnSbTe alloy at a magnification of 200: 1.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physical Vapour Deposition (AREA)
- Powder Metallurgy (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
Abstract
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10017414 | 2000-04-07 | ||
| DE10017414A DE10017414A1 (de) | 2000-04-07 | 2000-04-07 | Sputtertarget auf der Basis eines Metalls oder einer Metalllegierung und Verfahren zu dessen Herstellung |
| PCT/EP2001/003310 WO2001077403A1 (fr) | 2000-04-07 | 2001-03-23 | Cible de pulverisation cathodique a base d'un metal ou d'un alliage metallique, et son procede de production |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP1268874A1 true EP1268874A1 (fr) | 2003-01-02 |
Family
ID=7637982
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP01929445A Withdrawn EP1268874A1 (fr) | 2000-04-07 | 2001-03-23 | Cible de pulverisation cathodique a base d'un metal ou d'un alliage metallique, et son procede de production |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20030168333A1 (fr) |
| EP (1) | EP1268874A1 (fr) |
| JP (1) | JP2003530485A (fr) |
| DE (1) | DE10017414A1 (fr) |
| WO (1) | WO2001077403A1 (fr) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10159398A1 (de) | 2001-12-04 | 2003-06-12 | Giesecke & Devrient Gmbh | Speichern von und Zugreifen auf Daten in einem Mobilgerät und einem Benutzermodul |
| DE102004055228B4 (de) * | 2004-11-17 | 2010-09-30 | Daimler Ag | Thermisch gespritzte Lagerschalen für Pleuel |
| CN101103134B (zh) * | 2005-01-18 | 2010-07-07 | 日矿金属株式会社 | 烧结用Sb-Te系合金粉末及其制造方法和烧结该粉末得到的烧结体溅射靶 |
| JP4061557B2 (ja) * | 2005-07-11 | 2008-03-19 | 三菱マテリアル株式会社 | 相変化膜形成用スパッタリングターゲットおよびその製造方法。 |
| DE102005050424B4 (de) * | 2005-10-19 | 2009-10-22 | W.C. Heraeus Gmbh | Sputtertarget aus mehrkomponentigen Legierungen |
| JP2009197310A (ja) * | 2008-02-25 | 2009-09-03 | Kobe Steel Ltd | スパッタリングターゲット |
| EP2626443A1 (fr) * | 2010-10-08 | 2013-08-14 | Kabushiki Kaisha Kobe Seiko Sho | Cible de pulvérisation en alliage à base d'al et son procédé de production |
| US10889887B2 (en) * | 2016-08-22 | 2021-01-12 | Honeywell International Inc. | Chalcogenide sputtering target and method of making the same |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3791955A (en) * | 1972-12-11 | 1974-02-12 | Gte Laboratories Inc | Preparation of chalcogenide glass sputtering targets |
| JPS63188920A (ja) * | 1987-02-02 | 1988-08-04 | Nkk Corp | 強磁性体スパツタリングタ−ゲツトの製造方法 |
| JP2909108B2 (ja) * | 1989-10-24 | 1999-06-23 | 日立金属株式会社 | ターゲット部材およびその製造方法 |
| US5534712A (en) * | 1991-01-18 | 1996-07-09 | Energy Conversion Devices, Inc. | Electrically erasable memory elements characterized by reduced current and improved thermal stability |
| US5171411A (en) * | 1991-05-21 | 1992-12-15 | The Boc Group, Inc. | Rotating cylindrical magnetron structure with self supporting zinc alloy target |
| DE4410114A1 (de) * | 1993-12-20 | 1995-06-22 | Leybold Materials Gmbh | Target für Magnetron-Kathodenzerstäubungsanlage aus einer Kobalt-Basislegierung |
| DE4407774C1 (de) * | 1994-03-09 | 1995-04-20 | Leybold Materials Gmbh | Target für die Kathodenzerstäubung zur Herstellung transparenter, leitfähiger Schichten und Verfahren zu seiner Herstellung |
| US5590389A (en) * | 1994-12-23 | 1996-12-31 | Johnson Matthey Electronics, Inc. | Sputtering target with ultra-fine, oriented grains and method of making same |
| US5736657A (en) * | 1995-03-31 | 1998-04-07 | Ricoh Company, Ltd. | Sputtering target |
| US6033620A (en) * | 1995-04-18 | 2000-03-07 | Tosoh Corporation | Process of preparing high-density sintered ITO compact and sputtering target |
| DE19715806A1 (de) * | 1997-04-16 | 1998-10-22 | Leybold Materials Gmbh | Verfahren zur Herstellung eines Sputtertargets auf der Basis von Zinksulfid sowie das Sputtertarget selbst |
| DE19735734B4 (de) * | 1997-08-18 | 2008-01-03 | W.C. Heraeus Gmbh | Pulvermetallurgisches Sputtertarget auf der Basis von Wismut und Verfahren zu seiner Herstellung |
| JPH11293454A (ja) * | 1998-04-14 | 1999-10-26 | Hitachi Metals Ltd | Al系スパッタリング用ターゲット材及びその製造方法 |
-
2000
- 2000-04-07 DE DE10017414A patent/DE10017414A1/de not_active Withdrawn
-
2001
- 2001-03-23 EP EP01929445A patent/EP1268874A1/fr not_active Withdrawn
- 2001-03-23 JP JP2001575252A patent/JP2003530485A/ja not_active Withdrawn
- 2001-03-23 WO PCT/EP2001/003310 patent/WO2001077403A1/fr not_active Ceased
- 2001-03-23 US US10/257,118 patent/US20030168333A1/en not_active Abandoned
Non-Patent Citations (1)
| Title |
|---|
| See references of WO0177403A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| US20030168333A1 (en) | 2003-09-11 |
| DE10017414A1 (de) | 2001-10-11 |
| WO2001077403A1 (fr) | 2001-10-18 |
| JP2003530485A (ja) | 2003-10-14 |
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Legal Events
| Date | Code | Title | Description |
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| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
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| AK | Designated contracting states |
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| 17P | Request for examination filed |
Effective date: 20021028 |
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| GRAH | Despatch of communication of intention to grant a patent |
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| GRAS | Grant fee paid |
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| STAA | Information on the status of an ep patent application or granted ep patent |
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| 18W | Application withdrawn |
Effective date: 20031105 |