EP1116814A1 - Polyolefin coated and printed textile - Google Patents
Polyolefin coated and printed textile Download PDFInfo
- Publication number
- EP1116814A1 EP1116814A1 EP01400069A EP01400069A EP1116814A1 EP 1116814 A1 EP1116814 A1 EP 1116814A1 EP 01400069 A EP01400069 A EP 01400069A EP 01400069 A EP01400069 A EP 01400069A EP 1116814 A1 EP1116814 A1 EP 1116814A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- textile
- coated
- coating layer
- printed
- printed patterns
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000004753 textile Substances 0.000 title claims abstract description 54
- 229920000098 polyolefin Polymers 0.000 title claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 14
- 239000011248 coating agent Substances 0.000 claims abstract description 13
- 238000000576 coating method Methods 0.000 claims abstract description 13
- 238000007639 printing Methods 0.000 claims abstract description 12
- 239000002966 varnish Substances 0.000 claims abstract description 9
- 230000001681 protective effect Effects 0.000 claims abstract description 6
- 229920002943 EPDM rubber Polymers 0.000 claims abstract description 5
- 239000011247 coating layer Substances 0.000 claims description 24
- 239000004744 fabric Substances 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- 229920001971 elastomer Polymers 0.000 claims description 8
- 238000005034 decoration Methods 0.000 claims description 7
- 239000000806 elastomer Substances 0.000 claims description 7
- -1 polyethylene Polymers 0.000 claims description 7
- 239000010410 layer Substances 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 5
- 238000011282 treatment Methods 0.000 claims description 5
- 238000003490 calendering Methods 0.000 claims description 4
- 238000004381 surface treatment Methods 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 238000001125 extrusion Methods 0.000 claims description 2
- 229920001821 foam rubber Polymers 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 241001226611 Allium textile Species 0.000 claims 1
- 238000005234 chemical deposition Methods 0.000 claims 1
- 239000006260 foam Substances 0.000 claims 1
- 239000000758 substrate Substances 0.000 abstract 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- 230000032683 aging Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000007646 gravure printing Methods 0.000 description 3
- 239000000976 ink Substances 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920006124 polyolefin elastomer Polymers 0.000 description 1
- 229920005629 polypropylene homopolymer Polymers 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000004758 synthetic textile Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920002397 thermoplastic olefin Polymers 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/10—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with styrene-butadiene copolymerisation products or other synthetic rubbers or elastomers except polyurethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/045—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyolefin or polystyrene (co-)polymers
Definitions
- Another object of the invention is also to provide a method for the production of such printed coated textiles which is simple and inexpensive.
- the resulting coated printed textile can then be protected with a varnish, especially of acrylic type.
- the protective varnish can be colorless or colored but translucent to reveal the printed motif (s).
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Laminated Bodies (AREA)
- Printing Methods (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
La présente invention concerne des textiles enduits imprimés dans lesquels la couche d'enduction est à base de polyoléfine ainsi qu'un procédé pour leur préparation.The present invention relates to coated textiles printed in which the coating layer is based on polyolefin as well as a process for their preparation.
Les tissus enduits imprimés disponibles actuellement, par exemple pour la réalisation de nappes ou autres articles du domaine de l'art de la table, présentent généralement une couche d'enduction PVC (polychlorure de vinyle) et/ou de polymères halogénés en particulier de polymères fluorés.Printed coated fabrics currently available, for example for the production of tablecloths or other articles in the field of tableware, usually have a PVC (polyvinyl chloride) coating layer and / or halogenated polymers, in particular fluoropolymers.
Ces tissus enduits ne sont néanmoins pas très souples et présentent une résistance au vieillissement insuffisante en devenant raides et cassants mais aussi collants au toucher. Ils ont notamment une très mauvaise résistance aux intempéries et aux rayons ultra-violets.These coated fabrics are however not very flexible and have a insufficient aging resistance by becoming stiff and brittle but also sticky to the touch. In particular, they have very poor resistance to bad weather and ultra-violet rays.
Par ailleurs, ces tissus résistent mal aux taches alimentaires qui restent de plus en plus marquées au fil du temps et deviennent de plus en plus difficiles à retirer. Parallèlement, ils peuvent perdre leurs couleurs ou leurs motifs d'impression, notamment au fur et à mesure des nettoyages ou sous l'effet de la lumière, ou encore donner lieu à un jaunissement.Furthermore, these fabrics have poor resistance to food stains that remain more and more marked over time and become more and more difficult to remove. At the same time, they may lose their colors or print patterns, especially as and when cleaning or the effect of light, or give rise to yellowing.
En outre, ces tissus enduits ne sont généralement pas recyclables du fait de la présence en particulier de composants halogénés.In addition, these coated fabrics are generally not recyclable because the presence in particular of halogenated components.
L'objectif de la présente invention est de fournir des textiles enduits pouvant présenter des motifs ou décors imprimés, utilisables notamment dans le domaine de l'art de la table, et ne présentant pas les inconvénients mentionnés ci-dessus.The objective of the present invention is to provide coated textiles may have printed patterns or decorations, usable in particular in the field of tableware, and not having the drawbacks mentioned above.
Un autre objectif de l'invention est de fournir des textiles enduits particulièrement souples et conservant leur souplesse lors de leur utilisation ou de leur stockage, ainsi que lors de leurs nettoyages successifs.Another object of the invention is to provide coated textiles particularly flexible and retaining their flexibility during use or during their storage, as well as during their successive cleaning.
Un autre objectif de l'invention est encore de fournir un textile enduit présentant des caractéristiques « d'imprimabilité » satisfaisantes permettant en particulier l'impression de motifs ou décors placés résistant au vieillissement en particulier dans le temps, vis-à-vis des rayons lumineux, des nettoyages, de la chaleur, etc...Another objective of the invention is also to provide a coated textile having satisfactory "printability" characteristics allowing particularly the printing of patterns or decorations placed resistant to aging in particular over time, with regard to light rays, cleaning, heat, etc ...
Un autre objectif de l'invention est aussi de fournir un procédé pour la production de tels textiles enduits imprimés qui soit simple et peu coûteux. Another object of the invention is also to provide a method for the production of such printed coated textiles which is simple and inexpensive.
A cette fin, l'invention a pour objet un textile enduit à motifs imprimés, caractérisé en ce qu'il comprend une sous-couche textile formant support associée à une couche d'enduction formée d'un film à base d'un composant polyoléfinique et d'un élastomère, ladite couche d'enduction présentant des motifs imprimés sur sa surface non liée à la sous-couche textile.To this end, the invention relates to a coated textile with printed patterns, characterized in that it comprises a textile underlay forming a support associated with a coating layer formed of a film based on a component polyolefinic and an elastomer, said coating layer having patterns printed on its surface not linked to the textile underlay.
L'invention fournit également un procédé pour la préparation du textile enduit imprimé ci-dessus, caractérisé en ce que
- on prend une sous-couche textile formant support,
- on dépose sur ladite couche support, une couche d'enduction à base d'un composant polyoléfinique et d'un élastomère,
- on réalise un traitement de surface sur la couche d'enduction,
- on imprime des motifs ou décors, et
- on dépose éventuellement un vernis de protection.
- we take a textile underlay forming a support,
- a coating layer based on a polyolefinic component and an elastomer is deposited on said support layer,
- a surface treatment is carried out on the coating layer,
- we print patterns or decorations, and
- a protective varnish may be deposited.
Le textile enduit imprimé selon l'invention est décrit plus en détail ci-après.The coated textile printed according to the invention is described in more detail below.
Selon l'invention, par « imprimé » on entend l'application de motifs ou décors à la surface de la couche d'enduction du textile enduit, de manière discontinue et variée, généralement à l'aide d'encres de type acrylique et/ou polyuréthane modifié, par opposition à une coloration homogène dans la masse conduisant à des matériaux colorés de façon relativement uniforme.According to the invention, by "printed" means the application of patterns or decorations on the surface of the coating layer of the coated textile, so discontinuous and varied, generally using acrylic type inks and / or modified polyurethane, as opposed to homogeneous coloring in the mass leading to relatively uniformly colored materials.
Les inventeurs ont découvert de manière tout à fait surprenante qu'en appliquant une enduction à base de composants polyoléfiniques et d'élastomère polyoléfinique sur un textile, on pouvait alors réaliser l'impression de motifs par héliogravure.The inventors have discovered quite surprisingly that applying a coating based on polyolefin components and polyolefinic elastomer on a textile, we could then print of rotogravure patterns.
Par « composant polyoléfinique », on désigne conformément à l'invention un ou un mélange de polymère(s) ou copolymère(s) oléfinique(s), en particulier des polymères ou copolymères thermoplastiques oléfiniques (TPO) comme par exemple le polyéthylène, le polypropylène, leurs mélanges ou copolymères.By “polyolefinic component” is meant according to the invention one or a mixture of olefinic polymer (s) or copolymer (s), in particular olefinic thermoplastic polymers or copolymers (TPO) such as for example polyethylene, polypropylene, their mixtures or copolymers.
Selon l'invention, le composant polyoléfinique présente une dureté shore A allant de 30 à 50, de préférence 40 shore A.According to the invention, the polyolefin component has a shore hardness A ranging from 30 to 50, preferably 40 shore A.
La couche d'enduction comprend également un composant de type élastomère polyoléfinique de préférence de type EPDM (monomère éthylène-propylène-diène). The coating layer also includes a component of the type polyolefin elastomer preferably of EPDM type (ethylene-propylene-diene monomer).
La couche d'enduction comprend typiquement 15 à 25 parties en poids (par rapport au poids total de la composition) de composant polyoléfinique et 65 à 80 parties en poids d'élastomère de type EPDM (par rapport au poids total de la composition).The coating layer typically comprises 15 to 25 parts by weight (relative to the total weight of the composition) of polyolefinic component and 65 to 80 parts by weight of EPDM type elastomer (relative to the weight total of the composition).
Cette couche d'enduction peut par ailleurs contenir divers additifs notamment pour améliorer / modifier les propriétés mécaniques du textile enduit imprimé final, sa résistance aux U.V., etc. tels que des plastifiants, agent de protection vis-à-vis des U.V. ...This coating layer can also contain various additives in particular to improve / modify the mechanical properties of the textile final printed coating, resistance to UV rays, etc. such as plasticizers, agent protection against U.V. ...
La composition de la couche d'enduction est typiquement telle
qu'indiquée ci-dessous :
La couche textile formant support peut comprendre ou être constituée d'un tissu, d'un non-tissé ou d'une maille, le tissu et le non-tissé étant préférés. Il peut s'agir indifféremment de textile naturel, artificiel ou synthétique.The textile layer forming a support may comprise or be made up a fabric, a nonwoven or a mesh, the fabric and the nonwoven being preferred. It can be either natural, artificial or synthetic textile.
Selon un autre mode de réalisation de l'invention, le support textile peut être doublé d'une sous-couche en mousse caoutchouc sur sa face opposée à celle portant l'enduction.According to another embodiment of the invention, the textile support can be lined with a foam rubber underlay on its face opposite to the one with the coating.
La composition de la couche d'enduction selon l'invention permet son application sur le support textile par calandrage ou extrusion. L'enduction est ainsi réalisée au moment de cette étape.The composition of the coating layer according to the invention allows its application to the textile support by calendering or extrusion. The coating is thus performed at the time of this step.
Pour permettre l'impression de motifs sur le textile enduit précité, on réalise de préférence un traitement de surface afin de faciliter l'accrochage et l'adhérence des impressions ultérieures sur la surface de la couche d'enduction qui n'est pas liée au support textile. To allow the printing of patterns on the aforementioned coated textile, preferably performs a surface treatment to facilitate attachment and the adhesion of subsequent prints on the surface of the layer coating which is not linked to the textile support.
A cet effet, on peut réaliser un traitement électrique pour rendre polaire la surface d'impression de la couche d'enduction, à savoir la surface de la couche d'enduction qui n'est pas liée au textile.To this end, an electrical treatment can be carried out to make the printing surface of the coating layer, namely the surface of the coating layer which is not linked to the textile.
On peut également réaliser un traitement chimique par dépôt d'un primaire d'impression. Celui-ci est du type couramment utilisé préalablement à la mise en oeuvre de la technique d'héliogravure. Il s'agit généralement d'un vernis à base de polyoléfines chlorées.It is also possible to carry out a chemical treatment by depositing a printing primer. This is of the type commonly used prior to the implementation of the gravure technique. It is usually a varnish based on chlorinated polyolefins.
Selon les cas, on réalise l'un ou l'autre de ces traitements ou on les met en oeuvre successivement.Depending on the case, we carry out one or the other of these treatments or we put them implemented successively.
Ensuite, on réalise l'impression proprement dite des motifs souhaités, par héliogravure, sur la surface ainsi préparée.Then, the actual printing of the desired patterns is carried out, by photogravure, on the surface thus prepared.
La technique d'héliogravure est mise en oeuvre de manière classique, généralement avec des encres de type acryliques et/ou polyuréthanes éventuellement modifiés.The gravure printing technique is implemented in a conventional manner, generally with acrylic and / or polyurethane inks possibly modified.
Le textile enduit imprimé résultant peut ensuite être protégé par un verni, notamment de type acrylique. Selon l'effet désiré, le vernis de protection peut être incolore ou coloré mais translucide pour laisser apparaítre le ou les motif(s) imprimé(s).The resulting coated printed textile can then be protected with a varnish, especially of acrylic type. Depending on the desired effect, the protective varnish can be colorless or colored but translucent to reveal the printed motif (s).
Le textile enduit imprimé selon l'invention présente notamment une grande souplesse ainsi qu'une bonne résistance au vieillissement, aux intempéries, au rayonnement ultra-violet ainsi qu'aux taches alimentaires.The coated textile printed according to the invention notably has a high flexibility and good resistance to aging, weather, ultraviolet radiation and food stains.
Des additifs « anti-taches » de type connu peuvent être introduits par exemple dans le vernis final de protection pour augmenter le pouvoir anti-taches du textile enduit, par exemple vis-à-vis des taches alimentaires.Anti-stain additives of known type can be introduced by example in the final protective varnish to increase the anti-stain power coated textiles, for example against food stains.
Les motifs désirés peuvent être imprimés avec le matériel classiquement utilisé dans l'impression par héliogravure.The desired patterns can be printed with the material conventionally used in rotogravure printing.
Les impressions appliquées présentent une bonne adhérence au support et une bonne résistance au vieillissement, notamment lors d'intempéries, des lavages ...Applied prints have good adhesion to the support and good resistance to aging, especially during bad weather, washes ...
On n'observe pas de toucher collant à mesure de son utilisation.No sticky feel is observed as it is used.
Par ailleurs, le textile enduit imprimé selon l'invention est imperméable aux liquides. Furthermore, the coated textile printed according to the invention is waterproof liquids.
De plus, la composition de la couche d'enduction ne mettant pas en jeu de composés halogénés, ceci ouvre la possibilité de recyclage du textile enduit.In addition, the composition of the coating layer does not involve halogenated compounds, this opens up the possibility of recycling textiles coated.
L'invention concerne également des articles contenant un textile enduit imprimé tel que précité. Elle s'applique plus particulièrement à la fabrication de nappes enduites imprimées ou autres articles destinés à l'art de la table ou encore à des articles destinés à la décoration d'intérieur, en particulier le textile mural.The invention also relates to articles containing a coated textile. printed as above. It applies more particularly to the manufacture of printed coated tablecloths or other articles intended for tableware or still to articles intended for interior decoration, in particular textiles wall.
L'invention va maintenant être illustrée à l'aide d'un exemple qui ne doit pas être considéré comme limitatif.The invention will now be illustrated by means of an example which should not not be considered limiting.
Les différentes phases de production d'une nappe enduite imprimée sont
les suivantes :
Composition d'enduction utilisée :
- Polyoléfine thermoplastique de dureté 40 shore A 70 parties en poids
- Polyoléfine élastomérique 25 parties en poids
- Polypropylène homopolymère 5 parties en poids
- Antioxydant type phosphate 0,2 parties en poids
- Absorbeur UV 0,1 parties en poids
- Stabilisant UV type Hals 0,1 parties en poids
Coating composition used:
- Thermoplastic polyolefin of hardness 40 shore A 70 parts by weight
- Elastomeric polyolefin 25 parts by weight
- Polypropylene homopolymer 5 parts by weight
- Antioxidant phosphate type 0.2 parts by weight
- UV absorber 0.1 parts by weight
- UV stabilizer type Hals 0.1 parts by weight
Claims (21)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0000360A FR2803606B1 (en) | 2000-01-12 | 2000-01-12 | PRINTED COATED TEXTILE BASED ON A POLYOLEFINIC COMPONENT |
| FR0000360 | 2000-01-12 | ||
| CA002351922A CA2351922A1 (en) | 2000-01-12 | 2001-06-29 | Coated textile fabric with polyolefin compound based print |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP1116814A1 true EP1116814A1 (en) | 2001-07-18 |
Family
ID=25682638
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP01400069A Withdrawn EP1116814A1 (en) | 2000-01-12 | 2001-01-11 | Polyolefin coated and printed textile |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP1116814A1 (en) |
| CA (1) | CA2351922A1 (en) |
| FR (1) | FR2803606B1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1348799A1 (en) * | 2002-03-28 | 2003-10-01 | Pennel Industries S.A. | Method for producing an expanded and coated textile |
| FR2890085A1 (en) * | 2005-08-29 | 2007-03-02 | Veninov Soc Par Actions Simpli | Coated and expanded textile for table cloth, comprises alveolar layer, textile support layer, colorless film for protecting and sealing of the textile, and adhesive layer inserted between the textile support layer and the colorless film |
| WO2010125295A3 (en) * | 2009-04-27 | 2010-12-23 | Chomarat Textiles Industries | Method for producing a textile complex including decorative patterns, and complex thus produced |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DD127408A1 (en) * | 1976-09-14 | 1977-09-21 | ||
| JPH05147173A (en) * | 1991-11-29 | 1993-06-15 | Tonen Chem Corp | Composite sheet for building material |
| EP0554896A1 (en) * | 1992-02-06 | 1993-08-11 | Montell North America Inc. | Bonded articles comprising a nonwoven fabric and a polyolefin film and the process for their preparation |
| FR2702416A1 (en) * | 1993-03-10 | 1994-09-16 | Lecomte Roger | PVC-based printed material and production process |
| JPH11255911A (en) * | 1998-03-11 | 1999-09-21 | Towa:Kk | Soft resin sheet and method for producing the same |
-
2000
- 2000-01-12 FR FR0000360A patent/FR2803606B1/en not_active Expired - Fee Related
-
2001
- 2001-01-11 EP EP01400069A patent/EP1116814A1/en not_active Withdrawn
- 2001-06-29 CA CA002351922A patent/CA2351922A1/en not_active Abandoned
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DD127408A1 (en) * | 1976-09-14 | 1977-09-21 | ||
| JPH05147173A (en) * | 1991-11-29 | 1993-06-15 | Tonen Chem Corp | Composite sheet for building material |
| EP0554896A1 (en) * | 1992-02-06 | 1993-08-11 | Montell North America Inc. | Bonded articles comprising a nonwoven fabric and a polyolefin film and the process for their preparation |
| FR2702416A1 (en) * | 1993-03-10 | 1994-09-16 | Lecomte Roger | PVC-based printed material and production process |
| JPH11255911A (en) * | 1998-03-11 | 1999-09-21 | Towa:Kk | Soft resin sheet and method for producing the same |
Non-Patent Citations (2)
| Title |
|---|
| DATABASE WPI Section Ch Week 199328, Derwent World Patents Index; Class A17, AN 1993-223932, XP002148701 * |
| PATENT ABSTRACTS OF JAPAN vol. 1999, no. 14 22 December 1999 (1999-12-22) * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1348799A1 (en) * | 2002-03-28 | 2003-10-01 | Pennel Industries S.A. | Method for producing an expanded and coated textile |
| FR2837847A1 (en) * | 2002-03-28 | 2003-10-03 | Pennel Ind Sa | COATED AND EXPANDED TEXTILE |
| FR2890085A1 (en) * | 2005-08-29 | 2007-03-02 | Veninov Soc Par Actions Simpli | Coated and expanded textile for table cloth, comprises alveolar layer, textile support layer, colorless film for protecting and sealing of the textile, and adhesive layer inserted between the textile support layer and the colorless film |
| WO2010125295A3 (en) * | 2009-04-27 | 2010-12-23 | Chomarat Textiles Industries | Method for producing a textile complex including decorative patterns, and complex thus produced |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2351922A1 (en) | 2002-12-29 |
| FR2803606B1 (en) | 2002-04-05 |
| FR2803606A1 (en) | 2001-07-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2245219C (en) | Film appropriate for printing | |
| KR101888708B1 (en) | Decorative sheet and decorative molded product | |
| EP0122656B1 (en) | Ornamented coated textile structure and process for its manufacture | |
| EP0595706B1 (en) | Laminates of a compatibilised polyamide/polyolefin blend and a tie layer, and articles therefrom | |
| KR20140045996A (en) | Structure integrated by vacuum pressure forming or vacuum forming, and manufacturing method thereof | |
| KR20150100820A (en) | Decorative laminated sheet, structure including the decorative laminated sheet, and method of manufacturing the same | |
| CN102369109A (en) | Durable in-mold decoration laminates using semi-crystalline polymer as top film | |
| FR2608645A2 (en) | RESILIENT RESAFFLE COATING RESISTANT TO STAINS AND SCRATCHES AND PROCESS FOR MOUNTING WEAR SURFACE | |
| TW200904629A (en) | Method for producing a radio wave-transmitting transfer material | |
| CA2004765C (en) | Method for fabrication of wall or floor coverings, and products obtained therefrom | |
| EP1116814A1 (en) | Polyolefin coated and printed textile | |
| US20130048211A1 (en) | Method for protecting surfaces | |
| JP2004074442A (en) | High brightness decorative film | |
| FR2881149A1 (en) | Flocking patch material in automobile industries, comprises a support on which a flocking fibers are deposited by an adhesive, where the support is formed from a flexible thermoplastic elastomer and a flexible adhesive | |
| KR102289177B1 (en) | Molding film and molding transfer foil using same | |
| US6716487B1 (en) | Decorative stickers from inkjet printing and method therefor | |
| US3922399A (en) | Dual surface textiles | |
| US3608298A (en) | Pearlescent yarn | |
| EP1116815B1 (en) | Textile coated with epichlorohydrin rubber and printed | |
| JP4918019B2 (en) | Decorative body and method for producing the same | |
| US20010021614A1 (en) | Printed coated textile based on a polyolefin component | |
| WO2021099822A1 (en) | Multilayer film and use thereof as a barrier effect for textile applications | |
| JP2005153430A (en) | Decorative sheet and method for producing the same | |
| WO2017182408A1 (en) | Method for obtaining a metallized surface having a design | |
| EP1336476A1 (en) | Printed coating comprising two polyolefin layers |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR |
|
| AX | Request for extension of the european patent |
Free format text: AL;LT;LV;MK;RO;SI |
|
| 17P | Request for examination filed |
Effective date: 20010714 |
|
| AKX | Designation fees paid |
Free format text: AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR |
|
| AXX | Extension fees paid |
Free format text: SI PAYMENT 20010714 |
|
| 17Q | First examination report despatched |
Effective date: 20041102 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN WITHDRAWN |
|
| 18W | Application withdrawn |
Effective date: 20051221 |