EP1038978A1 - Process and installation for manufacturing hot strip - Google Patents
Process and installation for manufacturing hot strip Download PDFInfo
- Publication number
- EP1038978A1 EP1038978A1 EP00103097A EP00103097A EP1038978A1 EP 1038978 A1 EP1038978 A1 EP 1038978A1 EP 00103097 A EP00103097 A EP 00103097A EP 00103097 A EP00103097 A EP 00103097A EP 1038978 A1 EP1038978 A1 EP 1038978A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- temperature
- strip
- hot strip
- rolling
- cooling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/22—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
- B21B1/24—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a continuous or semi-continuous process
- B21B1/26—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a continuous or semi-continuous process by hot-rolling, e.g. Steckel hot mill
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/22—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
- B21B1/24—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a continuous or semi-continuous process
- B21B1/28—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a continuous or semi-continuous process by cold-rolling, e.g. Steckel cold mill
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/46—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling metal immediately subsequent to continuous casting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B2201/00—Special rolling modes
- B21B2201/04—Ferritic rolling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B45/00—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
- B21B45/02—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for lubricating, cooling, or cleaning
- B21B45/0203—Cooling
- B21B45/0209—Cooling devices, e.g. using gaseous coolants
- B21B45/0215—Cooling devices, e.g. using gaseous coolants using liquid coolants, e.g. for sections, for tubes
- B21B45/0218—Cooling devices, e.g. using gaseous coolants using liquid coolants, e.g. for sections, for tubes for strips, sheets, or plates
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0236—Cold rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0278—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips involving a particular surface treatment
Definitions
- the invention relates to a method for producing a Hot strip based on an unalloyed or low alloy steel with additions of Continuous casting micro alloying elements in the form of reheated or straight from the pouring heat used slabs, thin slabs or cast tape is generated, the hot strip being one of several Rolling stands formed finished series passes. Methods of this type are used to make high-strength Manufacture hot strips of high toughness.
- Such a procedure can also be used for one CSP system is divided into two defined sections Rolling, namely rolling in the recrystallization area of the austenite and the subsequent rolling in the area below the recrystallization stop temperature, carry out.
- This procedure is disadvantageous however, that the rolling performance is at least one of those in the Finishing scale available roll stands not can be used. This leads to a significant one Limitation of the maximum achievable in finish rolling Forming degrees and, associated with it, to a considerable limitation of the variety of products that can be produced with such a method.
- the object of the invention is a method of the type specified at the beginning and one for implementation such a method particularly suitable device to create which enable a high strength Hot strip with excellent toughness inexpensive to manufacture.
- the rolling stock when it is in the Finished season is initiated, a temperature which safely above the recrystallization stop temperature lies.
- This inlet temperature is set so that at least the first forming of the hot strip in the Finished scale in the recrystallization area of austenite is carried out. Through this in Recrystallization area of the austenite rolls grain refinement is achieved.
- Hot strip before it is on between the two rolling stands those below the recrystallization stop temperature lying temperature is cooled, at least once is cooled between previously passed mill stands, without increasing the recrystallization stop temperature fall below.
- This is particularly useful if the hot strip with a high temperature in the Finished relay arrives.
- the hot rolling of the hot strip should take place in the austenite area.
- the final rolling temperature of the hot strip should therefore be greater than Ar 3 + 30 ° C when leaving the finishing train.
- the method according to the invention makes it possible to the method known from DE 197 25 434 A1, in one process carried out continuously to produce particularly good material properties.
- These excellent material qualities can be seen in Procedure according to the invention also for hot strips achieve that from steels with diminished or even not present levels of expensive alloy and Microalloying elements such as Ti, Nb, V have been created are.
- existing steel concepts with new steel qualities higher strength and excellent toughness become.
- alloy contents be saved without becoming a negative Influencing the property spectrum comes.
- the method according to the invention is self-evident not on the use of thin slabs or pre-rolled material is limited as the starting material, which is processed directly from the pouring heat.
- the invention within the conventional Hot strip rolling are used in the Continuous cast slabs are reheated before entering the Rolling mill to be introduced.
- thermo-mechanical hot rolling usually fine-grained Structural structure is the procedure according to the invention refined further. It has been found that a conventionally thermo-mechanically rolled, 12.7 mm thick Hot strip with a set according to API X65 Microstructure with a pearlite-ferrite structure has an average ferrite grain diameter of 5 - 7.5 ⁇ m.
- a comparable hot strip shows after it has undergone a method according to the invention average ferrite grain diameter of 3.5 to 4.5 microns. Ferrite grain inhomogeneities in the strip core become avoided. The same applies to the excretion state, which has a finer dispersion and one Amount of precipitation hardening leads, which over the to be expected for conventionally rolled hot strips goes out.
- the Rolling temperatures taking into account the Recrystallization stop temperature unerringly and very can be set precisely. This enables the rolling in the recrystallization area just above the Carry out recrystallization stop temperature. So can the austenite grain refinement can be optimally used. The subsequent forming below the The recrystallization stop temperature then becomes Solidification of the fine-grained austenite grain structure used. This fine-grained and solidified Austenite structure leads to an optimal, very fine Structural structure after the ⁇ / ⁇ conversion.
- Another advantage of the procedure according to the invention is that the surface condition of the hot strip is positively influenced. Through targeted cooling between the mill stands the scale formation is almost completely suppressed so that little material loss arise and the hot strip in the delivery condition with a small scale layer of less than 10 ⁇ m is occupied. On the one hand, this has advantages in direct use well adhering because thin scale, as expected for example in the manufacture of gas bottles, which painted without descaling after forming become. On the other hand, in cases where the Hot strip is descaled before it is processed, the time required for pickling, for example, is reduced and the capacity of the stain can be increased.
- a cooling device is arranged. This in addition to the usual cooling of the roll stands Cooling device is able to remove the hot strip during the Transition from one to the next mill stand so strong cool that the recrystallization area of the Austenite is completely left after cooling and the subsequent rolling at temperatures below the Recrystallization stop temperature is carried out.
- the cooling device advantageously brings at least a high-pressure water jet whose volume flow is adjustable.
- Cooling device can easily reduce the cooling capacity be adapted to the respective requirements.
- the latter applies in particular if the Cooling device comprises several nozzles, which individually or coolant can be applied in groups. It is also favorable, if not only between one of the a respective cooling device is provided, but if in several of the between two existing stands one each such device is arranged. This gives the Possibility to change the hot strip to a Temperature below the recrystallization stop temperature targeted at that for the respective rolling process optimal position with regard to the desired result perform.
- the finished relay FS from seven roll stands F1, F2, F3, F4, F5, F6, F7 formed by a hot strip W in the direction of conveyance E one after the other. It it goes without saying that the finished relay FS ever according to their design and performance with a fewer or a larger number of roll stands can be equipped.
- This cooling device K1 Upstream of the first roll stand F1 in the conveying direction F. is a first cooling device K1.
- This cooling device K1 has nozzles, not shown, over which water is blasted under high pressure on the hot strip W, before it enters the first mill stand F1.
- the cooling devices K2 - K7 have also nozzles, which via supply lines L are connected to a control device S.
- the control device S are the nozzles of Cooling devices K2 - K7 optionally with high pressure standing cooling water.
- Cooling devices K2 - K7 additionally and independently of the cooling systems with which the respective rolling stands F1 - F7 are equipped as standard.
- the run-out roller table A In the area of the run-out roller table A is at a short distance to the last rolling stand F7 of the FS 1 finishing line conventionally designed cooling device K8, in the manner of a laminar cooling section or a accelerated cooling enabling compact cooling section Cooling water can be applied to the hot strip W.
- a reel device H At the The end of the run-out roller table A is finally a reel device H, in which the hot strip W to Coils C can be wound.
- the hot strip W is cooled in the first cooling device K1 by means of water applied under high pressure to a temperature which is in the range of a little more than 30 ° C above the recrystallization stop temperature T REK STOP des Steel lies from which the hot strip W has been produced.
- a thin slab inserted and pre-rolled directly from the casting heat or a strip produced by casting close to the final dimensions can be introduced into the finished batch. If necessary, the slab or the strip is cooled by the cooling device K1 to the required temperature T 1 above the recrystallization stop temperature.
- the hot strip W cooled in this way is subjected to a first forming in the first roll stand F1. Since the temperature of the hot strip W is above the recrystallization stop temperature T REK STOP during this first forming, this forming takes place within the recrystallization area of the austenite.
- a formal connection for determining the Recrystallization stop temperature depending certain alloying elements is, for example, from the Article "Determination of Recrystallization Stop Temperature from Rolling Mill Logs and Comparison with Laboratory Simulation Results ", T.M. Maccagno et al., ISIJ International, Vol. 34 (1994) No. 11, pp. 917-922, known.
- the hot strip W is cooled, for example, by the cooling water, which is applied by the cooling device K2 between the first and the second roll stands F1, F2 under high pressure, at a cooling rate of more than 10 ° C./s to a temperature which is at least 20 ° C is lower than the recrystallization stop temperature T REK-STOP .
- the hot strip W cooled in this way is finish-rolled in the roll stands F2 to F7 in the non-recrystallized area of the austenite, an overall degree of deformation ⁇ h being achieved in these roll stands F1-F7, which is more than 30%.
- the further cooling devices K3-K7 arranged between the subsequent rolling stands F2-F7 remain inoperative in this case.
- the temperature T 1 with which the hot strip W enters the finishing season FS can be set by a corresponding cooling capacity of the cooling device K1 so that the hot strip W, with a temperature above the recrystallization stop temperature T REK STOP also enters the second roll stand F2 in order to be rolled there in the recrystallization area of the austenite as well.
- the hot strip W can then be cooled by the third cooling device K3 at cooling speeds of more than 10 ° C / s to a temperature T 2 which is at least 20 ° C below the recrystallization stop temperature T REK STOP and in the following roll stands F3 to F7 in the non-recrystallized austenite area with a total degree of deformation of at least 30%.
- the cooling device K2 between the roll stands F1, F2 can be used to lower the temperature of the hot strip W before it enters the second roll stand F2, but without falling below the recrystallization stop temperature T REK STOP (FIG. 2).
- the decisive step of cooling below the recrystallization stop temperature T REK STOP can thus be carried out at the point of the finished scale FS that is most favorable for the properties of the processed hot strip W.
- the cooling devices which have passed through this crucial cooling can be used to cool the hot strip W without falling below the recrystallization stop temperature T REK STOP .
- the need for cooling power in the decisive cooling can be reduced from a temperature above the recrystallization stop temperature T REK STOP to a temperature below the recrystallization stop temperature T REK STOP .
- the hot strip W exiting the finishing season FS with a temperature T 3 above the A r3 temperature enters the fourth cooling device K4 at the latest after 10, but preferably after only 2 seconds. In it, it is cooled at a cooling rate of more than 20 ° C./s to a coiling temperature of not more than 650 ° C., preferably not more than 550 ° C.
- the hot strip W cooled in this way is finally coiled on the reel device H to form a coil C.
- the hot strip W produced in this way becomes more advantageous Way to a cold strip with a thickness of less than 5 mm cold rolled, the during the cold rolling achieved total degree of deformation at least 55% should.
- annealed cold rolled strip with corrosion protection that in the form of hot dip galvanizing or electrolytically applied coating is formed.
- hot strip samples P K1 , P K2 , P K3 produced in a conventional procedure, the respective thickness D in mm, the finish rolling temperature ET in ° C, the reel temperature HT in ° C, the yield strength R e in N / mm 2 , the tensile strength R m in N / mm 2 , the elongation at break A in%, the results of the BDWT test BDWT 0 ° C in% or BDWT 85% in ° C and the respective mean ferrite grain diameter FK m in ⁇ m.
- Table 2 summarizes the same information for six hot strip samples P E1 , P E2 , P E3 , P E4 , P E5 , P E6 produced from the same steel in accordance with the invention.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Metal Rolling (AREA)
- Heat Treatment Of Strip Materials And Filament Materials (AREA)
- Heat Treatment Of Sheet Steel (AREA)
Abstract
Description
Die Erfindung betrifft ein Verfahren zum Herstellen eines Warmbandes, das basierend auf einem unlegierten oder niedrig legierten Stahl mit Zusätzen von Mikrolegierungselementen aus Strangguß in Form von wiedererwärmten oder direkt aus der Gießhitze eingesetzten Brammen, Dünnbrammen oder gegossenem Band erzeugt wird, wobei das Warmband eine aus mehreren Walzgerüsten gebildete Fertigstaffel durchläuft. Verfahren dieser Art werden angewendet, um hochfeste Warmbänder von hoher Zähigkeit herzustellen.The invention relates to a method for producing a Hot strip based on an unalloyed or low alloy steel with additions of Continuous casting micro alloying elements in the form of reheated or straight from the pouring heat used slabs, thin slabs or cast tape is generated, the hot strip being one of several Rolling stands formed finished series passes. Methods of this type are used to make high-strength Manufacture hot strips of high toughness.
Beispielsweise aus dem Aufsatz "Optimierung der Warmwalzbedingungen zur Verbesserung und Vergleichmäßigung der Werkstoffeigenschaften", K. Kaup, W. Haumann, G. Gorges, W. Fabian, Stahl u. Eisen 104 (1984), S. 1017 -1024, sind Verfahren bekannt, bei denen das Warmband im Rekristallisationsbereich vorgewalzt, anschließend abgekühlt und dann bei einer Temperatur, welche unterhalb der Rekristallisationstemperatur liegt, fertig gewalzt wird. Zu diesem Zweck ist es erforderlich, den Walzprozeß beim Vorwalzen so zu führen, daß die Vorbandoberfläche vor dem letzten Umformstich des Vorwalzens auf Temperaturen dicht oberhalb der Rekristallisationstemperatur abgekühlt ist. Dies kann zum einen dadurch erreicht werden, daß eine zusätzliche Kühlstrecke im Bereich der Vorwalzstraße vorgesehen wird.For example from the essay "Optimizing the Hot rolling conditions to improve and Uniformization of the material properties ", K. Kaup, W. Haumann, G. Gorges, W. Fabian, Stahl u. Iron 104 (1984), pp. 1017-1024, methods are known in which the hot strip is pre-rolled in the recrystallization area, then cooled and then at a temperature which is below the recrystallization temperature, is finished rolling. For this purpose it is necessary to guide the rolling process during roughing so that the Supporting surface before the last forming stitch of the Pre-rolling to temperatures just above the Recrystallization temperature has cooled. This can lead to one can be achieved by an additional Cooling section is provided in the area of the roughing mill.
Steht entsprechender Platz nicht zur Verfügung, kann der Walzprozeß für eine für das Abkühlen ausreichende Zeitdauer verzögert werden. Diese Verzögerung, während der das Vorband im Bereich zwischen dem Vorwalzgerüst und der Fertigstaffel hin- und herbewegt wird ("pendelt"), führt zu einer unerwünschten Verlängerung des Produktionsablaufs. Während einer langen Pendelzeit kann es darüber hinaus zu einem unerwünschten Austenitkornwachstum und zu Ausscheidungen kommen, durch welche die Gefügeentwicklung nach dem letzten Umformstich in der Vorwalzstraße und beim anschließenden Fertigwalzen in der Fertigstaffel negativ beeinflußt wird. So können nach dem Fertigwalzen im Warmband Austenit-Mischkornstrukturen vorhanden sein, die einen negativen Einfluß auf die Gefügeentwicklung im Rahmen der γ/α-Umwandlung auf dem Auslaufrollgang und im Coil ausüben.If the corresponding space is not available, the Rolling process for one sufficient for cooling Time can be delayed. This delay while which the supporting strip in the area between the roughing stand and the finished relay is moved back and forth ("commutes"), leads to an undesirable extension of the Production process. Can during a long commute it also becomes an undesirable one Austenite grain growth and excretions come through which the structural development after the last forming stitch in the roughing mill and during the subsequent finishing rolling is negatively influenced in the finished series. So can after finish rolling in hot strip austenite mixed grain structures be present that has a negative Influence on the structure development within the framework of the γ / α conversion Exercise on the exit roller table and in the coil.
Letzteres führt insbesondere bei Warmbanddicken von 8 mm und mehr zu einem unerwünscht inhomogenen Gefüge über den Bandquerschnitt, durch welche insbesondere die Zähigkeit in unerwünschtem Maß herabgesetzt wird. Besonders nachteilig wirkt sich dieser Zähigkeitsverlust bei mikrolegierten Stahlgüten mit hohen Zähigkeitsanforderungen aus, welche beispielsweise für den Öl- oder Gas-Pipeline-Bau verwendet werden.The latter leads in particular to hot strip thicknesses of 8 mm and more to an undesirably inhomogeneous structure over the Belt cross-section, through which in particular the toughness is reduced to an undesirable extent. Especially this loss of toughness has an adverse effect microalloyed steel grades with high Toughness requirements, for example for oil or gas pipeline construction.
Aus der deutschen Offenlegungsschrift DE 197 25 434 A1 ist ein Verfahren zum Walzen von Warmband aus stranggegossenen Dünnbrammen in einer sogenannten "Compact-Strip-Production (CSP)"-Linie bekannt. Bei derartigen CSP-Linien wird das stranggegossene Vormaterial nach dem Unterteilen in Walzlängen über einen Ausgleichsofen direkt dem Walzwerk zugeführt. Dabei besteht eine Besonderheit gegenüber konventionellen Herstellungslinien darin, daß die Dünnbramme mit Gußgefüge in die Fertigstaffel eingeführt wird.From the German patent application DE 197 25 434 A1 is a process for rolling hot strip continuously cast thin slabs in a so-called "Compact-Strip-Production (CSP)" line known. At Such CSP lines become continuous Pre-material after dividing into roll lengths over one Compensation furnace fed directly to the rolling mill. Here there is a peculiarity compared to conventional Production lines in that the thin slab with Casting structure is introduced into the finished series.
In der erwähnten Offenlegungsschrift wird zur Herstellung eines Warmbreitbandes aus einem ferritisch-perlitisch mikrolegierten Baustahl mit einer Mikrolegierung mit Vanadium, Niob und / oder Titan vorgeschlagen, die Gußstruktur des in die Fertigstaffel eingeführten Materials durch Einstellung definierter Temperatur- oder Formänderungsbedingungen bei der ersten Umformung zu verändern. Dabei liegt die Temperatur des Materials während der ersten Umformung oberhalb der Rekristallisationsstop-Temperatur. Die erwähnte Änderung soll derart durchgeführt werden, daß während oder nach der ersten Umformung eine vollständige Rekristallisation des Gußgefüges vor Beginn des zweiten Umformschritts erfolgt. Anschließend soll das Warmband bei einer Temperatur unterhalb der Rekristallisationsstop-Temperatur gewalzt werden. Die dabei erreichte Umformung soll einen Betrag von 30 % nicht unterschreiten. Darüber hinaus soll eine Endwalztemperatur nahe der Ar3-Temperatur erreicht werden.In the aforementioned publication, for producing a hot wide strip from a ferritic-pearlitic microalloyed structural steel with a microalloy with vanadium, niobium and / or titanium, it is proposed to change the casting structure of the material introduced into the finished series by setting defined temperature or shape change conditions during the first forming . The temperature of the material during the first forming is above the recrystallization stop temperature. The change mentioned is to be carried out in such a way that a complete recrystallization of the casting structure takes place before or after the second forming step, during or after the first forming. The hot strip is then to be rolled at a temperature below the recrystallization stop temperature. The deformation achieved should not be less than 30%. In addition, a final rolling temperature close to the Ar 3 temperature is to be achieved.
Um sicherzustellen, daß die Rekristallisation vor der zweiten Umformung vollständig abgeschlossen ist, wird in der genannten Offenlegungsschrift weiter vorgeschlagen, mindestens das zweite Walzgerüst der Fertigstaffel zu öffnen oder allenfalls als Treiber einzusetzen. Auf diese Weise hat das in der ersten Stufe umgeformte Warmband ausreichend Zeit, abzukühlen, bevor es der zweiten Umformung unterzogen wird.To ensure that the recrystallization before second reshaping is completed in furthermore proposes the aforementioned publication, at least the second mill stand of the finishing line open or use as a driver if necessary. To this Way, the hot strip formed in the first stage enough time to cool down before it is the second Forming is subjected.
Durch ein solches Vorgehen läßt sich zwar auch bei einer CSP-Anlage ein in zwei definierte Abschnitte unterteiltes Walzen, nämlich das Walzen im Rekristallisationsbereich des Austenits und das anschließende Walzen im Bereich unterhalb der Rekristallisationsstop-Temperatur, durchführen. Nachteilig an dieser Verfahrensweise ist jedoch, daß die Walzleistung mindestens eines der in der Fertigstaffel zur Verfügung stehenden Walzgerüste nicht genutzt werden kann. Dies führt zu einer erheblichen Beschränkung des beim Fertigwalzen maximal erzielbaren Umformgrades und, damit einhergehend, zu einer erheblichen Einschränkung der Vielfalt an Produkten, die mit einem solchen Verfahren hergestellt werden können.Such a procedure can also be used for one CSP system is divided into two defined sections Rolling, namely rolling in the recrystallization area of the austenite and the subsequent rolling in the area below the recrystallization stop temperature, carry out. This procedure is disadvantageous however, that the rolling performance is at least one of those in the Finishing scale available roll stands not can be used. This leads to a significant one Limitation of the maximum achievable in finish rolling Forming degrees and, associated with it, to a considerable limitation of the variety of products that can be produced with such a method.
Die Aufgabe der Erfindung besteht darin, ein Verfahren der eingangs angegebenen Art und eine zur Durchführung eines solchen Verfahrens besonders geeignete Vorrichtung zu schaffen, welche es ermöglichen, ein hochfestes Warmband mit herausragender Zähigkeit kostengünstig herzustellen.The object of the invention is a method of the type specified at the beginning and one for implementation such a method particularly suitable device to create which enable a high strength Hot strip with excellent toughness inexpensive to manufacture.
Diese Aufgabe wird hinsichtlich des Verfahrens dadurch gelöst, daß ein Verfahren zum Herstellen eines Warmbandes, das basierend auf einem unlegierten oder niedrig legierten Stahl mit Zusätzen von Mikrolegierungselementen aus Strangguß in Form von Brammen, Dünnbrammen oder Band erzeugt wird, wobei das Warmband eine aus mehreren Walzgerüsten gebildete Fertigstaffel durchläuft, die folgenden Schritte umfaßt:
- Einleiten des Warmbandes in das erste Walzgerüst der Fertigstaffel mit einer Temperatur, welche um mindestens 30 °C über der Rekristallisationsstop-Temperatur liegt,
- kontinuierlich erfolgendes Walzen des Warmbandes in einem oder mehreren Stichen im Rekristallisationsbereich des Austenits,
- Abkühlen des Warmbandes zwischen zwei Walzgerüsten mittels einer Kühleinrichtung auf eine Temperatur, welche mindestens 20 °C unterhalb der Rekristallisationsstop-Temperatur liegt, mit einer Abkühlgeschwindigkeit, welche mindestens 10 °C/s beträgt,
- Walzen des unterhalb der Rekristallisationsstop-Temperatur abgekühlten Warmbandes in mehreren Stichen bei einem Gesamtumformgrad von mindestens 30 % im Temperaturbereich unterhalb der Rekristallisationsstop-Temperatur.
- Introducing the hot strip into the first mill stand of the finished batch at a temperature which is at least 30 ° C. above the recrystallization stop temperature,
- continuous rolling of the hot strip in one or more passes in the recrystallization area of the austenite,
- Cooling the hot strip between two roll stands by means of a cooling device to a temperature which is at least 20 ° C. below the recrystallization stop temperature, with a cooling rate which is at least 10 ° C./s,
- Rolling the hot strip cooled below the recrystallization stop temperature in several passes with a total degree of deformation of at least 30% in the temperature range below the recrystallization stop temperature.
Besonders vorteilhaft läßt sich mit dem erfindungsgemäßen Verfahren ein Warmband herstellen, welches aus einem Stahl erzeugt ist, der in Masse-% C: ≤ 0,18 %, Si: ≤ 1,5 %, Mn: ≤ 2,5 %, P: 0,005 - 0,1 %, S: ≤ 0,03 %, N: ≤ 0,02 %, Cr: ≤ 0,5 %, Cu: ≤ 0,5 %, Ni: ≤ 0,5 %, No: ≤ 0,5 %, Al ≤ 2 %, bis insgesamt 0,3 % von einem oder mehreren der Elemente B, Nb, Ti, V, Zr und als Rest Eisen und unvermeidbare Verunreinigungen enthält.Can be particularly advantageous with the invention Process produce a hot strip, which from a Steel is produced which in mass% C: ≤ 0.18%, Si: ≤ 1.5 %, Mn: ≤ 2.5%, P: 0.005 - 0.1%, S: ≤ 0.03%, N: ≤ 0.02 %, Cr: ≤ 0.5%, Cu: ≤ 0.5%, Ni: ≤ 0.5%, No: ≤ 0.5%, Al ≤ 2%, up to a total of 0.3% of one or more of the Elements B, Nb, Ti, V, Zr and the balance iron and contains inevitable impurities.
Gemäß der Erfindung hat das Walzgut, wenn es in die Fertigstaffel eingeleitet wird, eine Temperatur, welche sicher oberhalb der Rekristallisationsstop-Temperatur liegt. Diese Eintrittstemperatur ist so eingestellt, daß mindestens die erste Umformung des Warmbandes in der Fertigstaffel im Rekristallisationsbereich des Austenits durchgeführt wird. Durch dieses im Rekristallisationsbereich des Austenits erfolgende Walzen wird eine Kornfeinung erreicht.According to the invention, the rolling stock when it is in the Finished season is initiated, a temperature which safely above the recrystallization stop temperature lies. This inlet temperature is set so that at least the first forming of the hot strip in the Finished scale in the recrystallization area of austenite is carried out. Through this in Recrystallization area of the austenite rolls grain refinement is achieved.
Nach der ersten oder erforderlichenfalls weiteren Umformung in diesem Temperaturbereich wird das Warmband zwischen zwei der Walzgerüste der Fertigstaffel mit einer geeigneten Kühleinrichtung so stark und schnell abgekühlt, daß seine Temperatur beim Eintritt in das folgende Walzgerüst unterhalb der Rekristallisationsstop-Temperatur liegt.After the first, or if necessary, another Forming in this temperature range becomes the hot strip between two of the mill stands of the finished series with one suitable cooling device so strong and fast cooled that its temperature when entering the following mill stand below the recrystallization stop temperature lies.
In diesem Zusammenhang kann es günstig sein, wenn das Warmband, bevor es zwischen den beiden Walzgerüsten auf die unterhalb der Rekristallisationsstop-Temperatur liegende Temperatur gekühlt wird, mindestens einmal zwischen zuvor durchlaufenen Walzgerüsten gekühlt wird, ohne dabei die Rekristallisationsstop-Temperatur zu unterschreiten. Dies ist insbesondere dann zweckmäßig, wenn das Warmband mit einer hohen Temperatur in die Fertigstaffel einläuft. Durch das dem entscheidenden Schritt der Abkühlung unter die Rekristallisationsstop-Temperatur vorgeschaltete Kühlen "tastet" man sich an die Temperatur heran, von der aus dann mit einem Schlag das Walzgut bis mindestens 20 °C unterhalb der Rekristallisationsstop-Temperatur abgekühlt wird. Wesentlich bleibt dabei, daß diese entscheidende Abkühlung unterhalb der Rekristallisationsstop-Temperatur definiert zwischen zwei Walzgerüsten erreicht wird.In this context, it can be beneficial if that Hot strip before it is on between the two rolling stands those below the recrystallization stop temperature lying temperature is cooled, at least once is cooled between previously passed mill stands, without increasing the recrystallization stop temperature fall below. This is particularly useful if the hot strip with a high temperature in the Finished relay arrives. By the decisive Cooling step below the recrystallization stop temperature upstream cooling you "feel" the Temperature, from which the Rolled material up to at least 20 ° C below the Recrystallization stop temperature is cooled. It remains essential that this is decisive Cooling below the recrystallization stop temperature defined between two rolling stands.
Erfindungsgemäß sollte das Fertigwalzen des Warmbandes im Austenitbereich stattfinden. Daher sollte die Endwalztemperatur des Warmbandes beim Verlassen der Fertigstaffel größer als Ar3 + 30 °C sein.According to the invention, the hot rolling of the hot strip should take place in the austenite area. The final rolling temperature of the hot strip should therefore be greater than Ar 3 + 30 ° C when leaving the finishing train.
Das erfindungsgemäße Verfahren ermöglicht es, anders als das aus der DE 197 25 434 A1 bekannte Verfahren, in einem kontinuierlich durchgeführten Prozeß ein Warmband von besonderes guten Materialeigenschaften herzustellen. Diese hervorragenden Materialqualitäten lassen sich bei erfindungsgemäßer Vorgehensweise auch bei Warmbändern erreichen, die aus Stählen mit verminderten oder gar nicht vorhandenen Gehalten an teueren Legierungs- und Mikrolegierungselementen, wie Ti, Nb, V, erzeugt worden sind. Damit können durch Anwendung der Erfindung bei vorhandenen Legierungskonzepten neue Stahlqualitäten mit höheren Festigkeiten und hervorragender Zähigkeit erzeugt werden. Bei bekannten Stahlgüten können Legierungsgehalte eingespart werden, ohne daß es zu einer negativen Beeinflussung des Eigenschaftsspektrums kommt.The method according to the invention makes it possible to the method known from DE 197 25 434 A1, in one process carried out continuously to produce particularly good material properties. These excellent material qualities can be seen in Procedure according to the invention also for hot strips achieve that from steels with diminished or even not present levels of expensive alloy and Microalloying elements such as Ti, Nb, V have been created are. Thus, by using the invention existing steel concepts with new steel qualities higher strength and excellent toughness become. In the case of known steel grades, alloy contents be saved without becoming a negative Influencing the property spectrum comes.
Kostenträchtige Kühlstrecken mit hohem Platzbedarf oder für das Abkühlen erforderliche zusätzliche Prozeßzeiten werden bei der Erfindung nicht benötigt. Ebenso kann die Walzleistung aller in der Fertigstaffel zur Verfügung stehenden Walzgerüste voll genutzt werden, so daß mit der Erfindung eine uneingeschränkt große Produktpalette hergestellt werden kann.Costly cooling sections with high space requirements or additional process times required for cooling are not required in the invention. Likewise, the Rolling capacity of all available in the finishing line standing mill stands are fully used, so that with the Invention an unlimited range of products can be manufactured.
Das erfindungsgemäße Verfahren ist selbstverständlich nicht auf die Verwendung von Dünnbrammen oder vorgewalztem Material als Ausgangsmaterial beschränkt, welches direkt aus der Gießhitze verarbeitet wird. Ebenso kann die Erfindung im Rahmen des konventionellen Warmbandwalzens eingesetzt werden, bei dem Stranggußbrammen wiedererwärmt werden, bevor sie in die Walzstraße eingeführt werden.The method according to the invention is self-evident not on the use of thin slabs or pre-rolled material is limited as the starting material, which is processed directly from the pouring heat. As well can the invention within the conventional Hot strip rolling are used in the Continuous cast slabs are reheated before entering the Rolling mill to be introduced.
Mit dem erfindungsgemäßen Verfahren lassen sich Warmbänder herstellen, welche ein über den Querschnitt sehr feinkörniges und homogenes Gefüge aufweisen. Die beim konventionellen thermo-mechanischen Warmwalzen üblicherweise sich einstellende feinkörnige Gefügestruktur wird bei erfindungsgemäßer Vorgehensweise weiter verfeinert. So ist festgestellt worden, daß ein konventionell therme-mechanisch gewalztes, 12,7 mm dickes Warmband mit einer nach API X65 eingestellten Gefügestruktur ein Perlit-Ferrit-Gefüge mit einem mittleren Ferrit-Korndurchmesser von 5 - 7,5 µm aufweist. Ein vergleichbares Warmband weist, nachdem es das erfindungsgemäße Verfahren durchlaufen hat, einen mittleren Ferrit-Korndurchmesser von 3,5 bis 4,5 µm auf. Ferritkorn-Inhomogenitäten im Bandkern werden dabei vermieden. Das gleiche gilt für den Ausscheidungszustand, welcher eine feinere Dispersion besitzt und zu einem Betrag der Ausscheidungshärtung führt, welcher über den bei konventionell gewalzten Warmbändern zu erwartenden hinausgeht.With the method according to the invention Produce hot strips, which have a cross-section have a very fine-grained and homogeneous structure. The with conventional thermo-mechanical hot rolling usually fine-grained Structural structure is the procedure according to the invention refined further. It has been found that a conventionally thermo-mechanically rolled, 12.7 mm thick Hot strip with a set according to API X65 Microstructure with a pearlite-ferrite structure has an average ferrite grain diameter of 5 - 7.5 µm. A comparable hot strip shows after it has undergone a method according to the invention average ferrite grain diameter of 3.5 to 4.5 microns. Ferrite grain inhomogeneities in the strip core become avoided. The same applies to the excretion state, which has a finer dispersion and one Amount of precipitation hardening leads, which over the to be expected for conventionally rolled hot strips goes out.
Weiter wurde festgestellt, daß die Zähigkeit der erfindungsgemäß hergestellten Warmbänder trotz gestiegener Streckgrenze und höherer Banddicke verbessert ist. Die Übergangstemperatur für 80 % Mattbruch beim BDWT-Test wurde um bis zu 25 °C zu tieferen Temperaturen verschoben.It was also found that the toughness of the hot strips produced according to the invention despite improved yield strength and higher strip thickness improved is. The transition temperature for 80% matt break at BDWT test was up to 25 ° C lower temperatures postponed.
Nach dem erfindungsgemäßen Verfahren können die Walztemperaturen unter Berücksichtigung der Rekristallisationsstop-Temperatur zielsicher und sehr genau eingestellt werden. Dies ermöglicht es, das Walzen im Rekristallisationsgebiet dicht oberhalb der Rekristallisationsstop-Temperatur durchzuführen. So kann die Austenitkornverfeinung optimal ausgenutzt werden. Die anschließende Umformung unterhalb der Rekristallisationsstop-Temperatur wird dann zur Verfestigung der feinkörnigen Austenitkornstruktur genutzt. Diese feinkörnige und verfestigte Austenitstruktur führt zu einer optimalen, sehr feinen Gefügestruktur nach der γ/α-Umwandlung.According to the inventive method, the Rolling temperatures taking into account the Recrystallization stop temperature unerringly and very can be set precisely. This enables the rolling in the recrystallization area just above the Carry out recrystallization stop temperature. So can the austenite grain refinement can be optimally used. The subsequent forming below the The recrystallization stop temperature then becomes Solidification of the fine-grained austenite grain structure used. This fine-grained and solidified Austenite structure leads to an optimal, very fine Structural structure after the γ / α conversion.
Des weiteren werden bei der Erfindung verformungsinduzierte Ausscheidungsvorgänge auf die nur eine kurze Zeit in Anspruch nehmende Verformung in den letzten Gerüsten der Fertigwalzstaffel beschränkt. Der Anteil der ausgeschiedenen Mikrolegierungsgehalte wird aufgrund dieser kurzen Zeitspanne deutlich verringert. Gleichzeitig wird das Ausscheidungspotential für die Ausscheidungshärtung des Gefüges nach der γ/α-Umwandlung besser genutzt.Furthermore, in the invention deformation-induced excretion processes on the only a short time consuming deformation in the last stands of the finishing mill. The Proportion of the excreted micro-alloy contents significantly reduced due to this short period of time. At the same time, the elimination potential for the Precipitation hardening of the structure after the γ / α conversion better used.
Ein weiterer Vorteil der erfindungsgemäßen Vorgehensweise besteht darin, daß der Oberflächenzustand des Warmbandes positiv beeinflußt wird. Durch die gezielte Kühlung zwischen den Walzgerüsten wird die Zunderbildung nahezu vollständig unterdrückt, so daß geringe Materialverluste entstehen und das Warmband im Lieferzustand mit einer geringen Zunderschicht von weniger als 10 µm belegt ist. Dadurch sind einerseits Vorteile beim Direkteinsatz mit gut haftendem, weil dünnen Zunder, zu erwarten, wie beispielsweise bei der Fertigung von Gasflaschen, welche ohne vorheriges Entzundern nach der Umformung lackiert werden. Andererseits kann in solchen Fällen, in denen das Warmband vor seiner Weiterverarbeitung entzundert wird, die beispielsweise für das Beizen benötigte Zeit verkürzt und die Kapazität der Beize erhöht werden.Another advantage of the procedure according to the invention is that the surface condition of the hot strip is positively influenced. Through targeted cooling between the mill stands the scale formation is almost completely suppressed so that little material loss arise and the hot strip in the delivery condition with a small scale layer of less than 10 µm is occupied. On the one hand, this has advantages in direct use well adhering because thin scale, as expected for example in the manufacture of gas bottles, which painted without descaling after forming become. On the other hand, in cases where the Hot strip is descaled before it is processed, the time required for pickling, for example, is reduced and the capacity of the stain can be increased.
Hinsichtlich der Warmbandlinie zur Durchführung des Verfahrens wird die oben angegebene Aufgabe dadurch gelöst, daß mindestens in einem der zwischen zwei Walzgerüsten der Fertigstaffel verbleibenden Freiräume eine Kühleinrichtung angeordnet ist. Diese zusätzlich zu den üblichen Kühlungen der Walzgerüste vorgesehene Kühleinrichtung ist in der Lage, das Warmband während des Übergangs vom einen zum nächsten Walzgerüst so stark abzukühlen, daß der Rekristallisationsbereich des Austenits nach der Kühlung vollständig verlassen ist und das anschließende Walzen bei Temperaturen unterhalb der Rekristallisationsstop-Temperatur durchgeführt wird. With regard to the hot strip line for carrying out the This accomplishes the above-mentioned task solved that at least in one of the two Rolling frames of the finishing line free spaces a cooling device is arranged. This in addition to the usual cooling of the roll stands Cooling device is able to remove the hot strip during the Transition from one to the next mill stand so strong cool that the recrystallization area of the Austenite is completely left after cooling and the subsequent rolling at temperatures below the Recrystallization stop temperature is carried out.
Vorteilhafter Weise bringt die Kühleinrichung mindestens einen Hochdruck-Wasserstrahl aus, dessen Volumenstrom regelbar ist. Bei einer derart ausgestalteten Kühleinrichtung kann die Kühlleistung auf einfache Weise an die jeweiligen Erfordernisse angepaßt werden. Letzteres gilt insbesondere dann, wenn die Kühleinrichtung mehrere Düsen umfaßt, welche einzeln oder in Gruppen mit Kühlflüssigkeit beaufschlagbar sind. Günstig ist es auch, wenn nicht nur zwischen einem der jeweiligen Walzgerüstpaare eine Kühleinrichtung vorgesehen ist, sondern wenn in mehreren der zwischen jeweils zwei Walzgerüsten vorhandenen Räumen eine derartige Einrichtung angeordnet ist. Dies gibt die Möglichkeit, den Übergang des Warmbandes zu einer Temperatur unterhalb der Rekristallisationsstop-Temperatur gezielt an der für den jeweiligen Walzprozeß im Hinblick auf das gewünschte Ergebnis optimalen Stelle durchzuführen.The cooling device advantageously brings at least a high-pressure water jet whose volume flow is adjustable. With such a design Cooling device can easily reduce the cooling capacity be adapted to the respective requirements. The latter applies in particular if the Cooling device comprises several nozzles, which individually or coolant can be applied in groups. It is also favorable, if not only between one of the a respective cooling device is provided, but if in several of the between two existing stands one each such device is arranged. This gives the Possibility to change the hot strip to a Temperature below the recrystallization stop temperature targeted at that for the respective rolling process optimal position with regard to the desired result perform.
Weitere vorteilhafte Ausgestaltungen der Erfindung sind in den abhängigen Ansprüchen angegeben.Further advantageous embodiments of the invention are specified in the dependent claims.
Nachfolgend wird die Erfindung anhand eines Ausführungsbeispiels näher erläutert. Es zeigen in schematischer Darstellung:
- Fig. 1
- die Fertigstaffel und den Auslaufrollgang einer Walzstraße in seitlicher Ansicht;
- Fig. 2
- den über die Zeit aufgetragenen Temperaturverlauf während des Walzens in der Fertigstaffel der Walzstraße.
- Fig. 1
- the finishing scale and the run-out roller table of a rolling mill in a side view;
- Fig. 2
- the temperature profile plotted over time during rolling in the finishing line of the rolling mill.
Beim hier erläuterten Ausführungsbeispiel ist die Fertigstaffel FS aus sieben Walzgerüsten F1,F2,F3,F4,F5,F6,F7 gebildet, welche von einem Warmband W in Förderrichtung E nacheinander durchlaufen werden. Es versteht sich von selbst, daß die Fertigstaffel FS je nach deren Auslegung und Leistungsvermögen mit einer geringeren oder eine größeren Zahl von Walzgerüsten ausgestattet sein kann.In the exemplary embodiment explained here, the Finished relay FS from seven roll stands F1, F2, F3, F4, F5, F6, F7 formed by a hot strip W in the direction of conveyance E one after the other. It it goes without saying that the finished relay FS ever according to their design and performance with a fewer or a larger number of roll stands can be equipped.
Dem ersten Walzgerüst F1 in Förderrichtung F vorgeordnet ist eine erste Kühleinrichtung K1. Diese Kühleinrichtung K1 weist hier nicht gezeigte Düsen auf, über die Wasser unter hohem Druck auf das Warmband W gestrahlt wird, bevor es in das erste Walzgerüst F1 eintritt.Upstream of the first roll stand F1 in the conveying direction F. is a first cooling device K1. This cooling device K1 has nozzles, not shown, over which water is blasted under high pressure on the hot strip W, before it enters the first mill stand F1.
In jedem der zwischen den Walzgerüsten F1,F2; F2,F3; F3,F4; F5,F6; F6,F7 jeweils verbliebenen Räumen R ist jeweils eine Kühleinrichtung K2,K3,K4,K5,K6,K7 angeordnet. Die Kühleinrichtungen K2 - K7 weisen ebenfalls Düsen auf, welche über Versorgungsleitungen L an eine Steuereinrichtung S angeschlossen sind. Über die Steuereinrichtung S werden die Düsen der Kühleinrichtungen K2 - K7 wahlweise mit unter hohem Druck stehendem Kühlwasser beaufschlagt. Dabei arbeiten die Kühleinrichtungen K2 - K7 zusätzlich und unabhängig von den Kühlungen, mit denen die jeweiligen Walzgerüste F1 - F7 standardmäßig ausgestattet sind.In each of the mill stands F1, F2; F2, F3; F3, F4; F5, F6; F6, F7 each of the remaining rooms R. one cooling device each K2, K3, K4, K5, K6, K7 arranged. The cooling devices K2 - K7 have also nozzles, which via supply lines L are connected to a control device S. About the Control device S are the nozzles of Cooling devices K2 - K7 optionally with high pressure standing cooling water. The work here Cooling devices K2 - K7 additionally and independently of the cooling systems with which the respective rolling stands F1 - F7 are equipped as standard.
Im Bereich des Auslaufrollgangs A ist im geringen Abstand zum letzten Walzgerüst F7 der Fertigstaffel FS eine herkömmlich ausgebildete Kühleinrichtung K8 angeordnet, in der nach Art einer Laminarkühlstrecke oder einer eine beschleunigte Abkühlung ermöglichenden Kompaktkühlstrecke Kühlwasser auf das Warmband W aufgebracht werden kann. Am Ende des Auslaufrollgangs A befindet sich schließlich eine Haspeleinrichtung H, in welcher das Warmband W zu Coils C gewickelt werden kann.In the area of the run-out roller table A is at a short distance to the last rolling stand F7 of the FS 1 finishing line conventionally designed cooling device K8, in the manner of a laminar cooling section or a accelerated cooling enabling compact cooling section Cooling water can be applied to the hot strip W. At the The end of the run-out roller table A is finally a reel device H, in which the hot strip W to Coils C can be wound.
Beispielsweise aus konventionellem Strangguß hergestelltes, anschließend abgekühltes, wiedererwärmtes und vorgewalztes Warmband W wird in der ersten Kühleinrichtung K1 mittels unter hohem Druck ausgebrachtem Wasser auf eine Temperatur abgekühlt, welche im Bereich von wenig mehr als 30 °C oberhalb der Rekristallisationsstop-Temperatur TREK STOP des Stahls liegt, aus dem das Warmband W erzeugt worden ist. Alternativ kann auch eine direkt aus der Gießhitze eingesetzte und vorgewalzte Dünnbramme oder ein durch endabmessungsnahes Gießen erzeugtes Band in die Fertigstaffel eingeleitet werden. Dabei wird, wenn erforderlich, die Bramme oder das Band durch die Kühleinrichtung K1 auf die erforderliche Temperatur T1 oberhalb der Rekristallisationsstop-Temperatur gekühlt.For example, made from conventional continuous casting, then cooled, reheated and pre-rolled hot strip W is cooled in the first cooling device K1 by means of water applied under high pressure to a temperature which is in the range of a little more than 30 ° C above the recrystallization stop temperature T REK STOP des Steel lies from which the hot strip W has been produced. Alternatively, a thin slab inserted and pre-rolled directly from the casting heat or a strip produced by casting close to the final dimensions can be introduced into the finished batch. If necessary, the slab or the strip is cooled by the cooling device K1 to the required temperature T 1 above the recrystallization stop temperature.
Das derart abgekühlte Warmband W wird im ersten Walzgerüst F1 einer ersten Umformung unterzogen. Da die Temperatur des Warmbandes W während dieser ersten Umformung oberhalb der Rekristallisationsstop-Temperatur TREK STOP liegt, erfolgt diese Umformung innerhalb des Rekristallisationsbereichs des Austenits.The hot strip W cooled in this way is subjected to a first forming in the first roll stand F1. Since the temperature of the hot strip W is above the recrystallization stop temperature T REK STOP during this first forming, this forming takes place within the recrystallization area of the austenite.
Ein formelmäßiger Zusammenhang für die Bestimmung der Rekristallisationsstop-Temperatur in Abhängigkeit bestimmter Legierungselemente ist beispielsweise aus dem Artikel "Determination of Recrystallization Stop Temperature from Rolling Mill Logs and Comparison with Laboratory Simulation Results", T.M. Maccagno et al., ISIJ International, Vol. 34 (1994) No. 11, pp. 917-922, bekannt.A formal connection for determining the Recrystallization stop temperature depending certain alloying elements is, for example, from the Article "Determination of Recrystallization Stop Temperature from Rolling Mill Logs and Comparison with Laboratory Simulation Results ", T.M. Maccagno et al., ISIJ International, Vol. 34 (1994) No. 11, pp. 917-922, known.
Nach dem ersten Umformvorgang wird das Warmband W beispielsweise durch das von der Kühleinrichtung K2 zwischen dem ersten und dem zweiten Walzgerüst F1,F2 unter hohem Druck ausgebrachte Kühlwasser mit einer Abkühlgeschwindigkeit von mehr als 10 °C/s auf eine Temperatur gekühlt, die um mindestens 20 °C geringer ist als die Rekristallisationsstop-Temperatur TREK-STOP. Das derart gekühlte Warmband W wird in den Walzgerüsten F2 bis F7 im nichtrekristallisierten Bereich des Austenits fertiggewalzt, wobei ein Gesamtumformgrad εh beim Walzen in diesen Walzgerüsten F1-F7 erreicht wird, der mehr als 30 % beträgt. Die weiteren zwischen den nachfolgend durchlaufenen Walzgerüsten F2 - F7 angeordnete Kühleinrichtung K3 - K7 bleiben in diesem Fall außer Funktion.After the first forming process, the hot strip W is cooled, for example, by the cooling water, which is applied by the cooling device K2 between the first and the second roll stands F1, F2 under high pressure, at a cooling rate of more than 10 ° C./s to a temperature which is at least 20 ° C is lower than the recrystallization stop temperature T REK-STOP . The hot strip W cooled in this way is finish-rolled in the roll stands F2 to F7 in the non-recrystallized area of the austenite, an overall degree of deformation ε h being achieved in these roll stands F1-F7, which is more than 30%. The further cooling devices K3-K7 arranged between the subsequent rolling stands F2-F7 remain inoperative in this case.
Ist dagegen ein größerer Umformgrad beim Walzen im rekristallisierten Austenit erforderlich, so kann die Temperatur T1, mit welcher das Warmband W in die Fertigstaffel FS eintritt, durch eine entsprechende Kühlleistung der Kühleinrichtung K1 so eingestellt werden, daß das Warmband W, mit einer Temperatur oberhalb der Rekristallisationsstop-Temperatur TREK STOP auch in das zweite Walzgerüst F2 einläuft, um dort ebenfalls im Rekristallisationsbereich des Austenits gewalzt zu werden. In diesem Fall kann das Warmband W anschließend durch die dritte Kühleinrichtung K3 mit Abkühlgeschwindigkeiten von mehr als 10 °C/s auf eine um mindestens 20 °C unterhalb der Rekristallisationsstop-Temperatur TREK STOP liegende Temperatur T2 gekühlt und in den folgenden Walzgerüsten F3 bis F7 im nichtrekristallisierten Austenitbereich bei einem Gesamtumformgrad von wiederum mindestens 30 % fertiggewalzt werden. Dabei kann die Kühleinrichtung K2 zwischen den Walzgerüsten F1,F2 dazu benutzt werden, die Temperatur des Warmbandes W vor seinem Eintritt in das zweite Walzgerüst F2 abzusenken, ohne dabei jedoch die Rekristallisationsstop-Temperatur TREK STOP zu unterschreiten (Fig. 2).If, on the other hand, a greater degree of deformation is required when rolling in recrystallized austenite, the temperature T 1 with which the hot strip W enters the finishing season FS can be set by a corresponding cooling capacity of the cooling device K1 so that the hot strip W, with a temperature above the recrystallization stop temperature T REK STOP also enters the second roll stand F2 in order to be rolled there in the recrystallization area of the austenite as well. In this case, the hot strip W can then be cooled by the third cooling device K3 at cooling speeds of more than 10 ° C / s to a temperature T 2 which is at least 20 ° C below the recrystallization stop temperature T REK STOP and in the following roll stands F3 to F7 in the non-recrystallized austenite area with a total degree of deformation of at least 30%. The cooling device K2 between the roll stands F1, F2 can be used to lower the temperature of the hot strip W before it enters the second roll stand F2, but without falling below the recrystallization stop temperature T REK STOP (FIG. 2).
Indem im Raum R zwischen jedem der Walzgerüst-Paare F2,F3; F3,F4; F4,F5; F5,F6; F6,F7 eine Kühleinrichtung K2 - K7 angeordnet ist, kann somit der entscheidende Schritt der Abkühlung unterhalb der Rekristallisationsstop-Temperatur TREK STOP an der für die Eigenschaften des verarbeiteten Warmbands W jeweils günstigsten Stelle der Fertigstaffel FS durchgeführt werden. Dabei können die jeweils vor dieser entscheidenden Abkühlung durchlaufenen Kühleinrichtungen dazu genutzt werden, das Warmband W abzukühlen, ohne die Rekristallisationsstop-Temperatur TREK STOP zu unterschreiten. Auf diese Weise kann unter anderem der Bedarf an Kühlleistung bei der entscheidenden Kühlung von einer Temperatur oberhalb der Rekristallisationsstop-Temperatur TREK STOP auf eine Temperatur unterhalb der Rekristallisationsstop-Temperatur TREK STOP vermindert werden. By in the space R between each of the pairs of stands F2, F3; F3, F4; F4, F5; F5, F6; F6, F7 a cooling device K2 - K7 is arranged, the decisive step of cooling below the recrystallization stop temperature T REK STOP can thus be carried out at the point of the finished scale FS that is most favorable for the properties of the processed hot strip W. In this case, the cooling devices which have passed through this crucial cooling can be used to cool the hot strip W without falling below the recrystallization stop temperature T REK STOP . In this way, among other things, the need for cooling power in the decisive cooling can be reduced from a temperature above the recrystallization stop temperature T REK STOP to a temperature below the recrystallization stop temperature T REK STOP .
Das im hier erläuterten Beispiel mit einer oberhalb der Ar3-Temperatur liegenden Temperatur T3 aus der Fertigstaffel FS austretende Warmband W tritt spätestens nach 10, vorzugsweise aber schon nach 2 Sekunden in die vierte Kühleinrichtung K4 ein. In dieser wird es mit einer Abkühlgeschwindigkeit von mehr als 20 °C/s auf eine Haspeltemperatur von nicht mehr als 650 °C, vorzugsweise nicht mehr als 550 °C, gekühlt. Das so gekühlte Warmband W wird schließlich auf der Haspeleinrichtung H zu einem Coil C gehaspelt.The hot strip W exiting the finishing season FS with a temperature T 3 above the A r3 temperature enters the fourth cooling device K4 at the latest after 10, but preferably after only 2 seconds. In it, it is cooled at a cooling rate of more than 20 ° C./s to a coiling temperature of not more than 650 ° C., preferably not more than 550 ° C. The hot strip W cooled in this way is finally coiled on the reel device H to form a coil C.
Das derart hergestellte Warmband W wird vorteilhafter Weise zu einem Kaltband mit einer Dicke von weniger als 5 mm kaltgewalzt, wobei der während des Kaltwalzens erreichte Gesamtumformgrad mindestens 55 % betragen sollte. Vorteilhaft ist es in diesem Zusammenhang auch, wenn das Kaltband rekristallisierend geglüht wird. Dabei kann das Glühen je nach gewünschter Eigenschaft des Endprodukts in einem Hauben- oder einem Durchlaufofen durchgeführt werden. Weiter ist es möglich, das derart geglühte Kaltband mit einem Korrosionsschutz zu versehen, der in Form einer Feuerverzinkung oder einer elektrolytisch aufgebrachten Beschichtung gebildet wird.The hot strip W produced in this way becomes more advantageous Way to a cold strip with a thickness of less than 5 mm cold rolled, the during the cold rolling achieved total degree of deformation at least 55% should. In this context, it is also advantageous when the cold strip is annealed to recrystallize. Here Depending on the desired property of the End product in a hood or a continuous furnace be performed. It is also possible to do this to provide annealed cold rolled strip with corrosion protection, that in the form of hot dip galvanizing or electrolytically applied coating is formed.
In Tabelle 1 sind für drei aus einem Stahl mit in Masse-%
0,06 % C, 0,28 % Si, 1,07 % Mn, 0,019 % P, 0,001 % S,
0,03 % Al, 0,11 % Cu, 0,05 % Ni, 0,007 % N, 0,057 % Nb,
0,056 % V, Rest Eisen und unvermeidbare Verunreinigungen
in konventioneller Vorgehensweise hergestellte
Warmbandproben PK1,PK2,PK3 die jeweilige Dicke D in mm, die
Endwalztemperatur ET in °C, die Haspeltemperatur HT in
°C, die Streckgrenze Re in N/mm2, die Zugfestigkeit Rm in
N/mm2, die Bruchdehnung A in %, die Ergebnisse des BDWT-Tests
BDWT 0°C in % bzw. BDWT 85 % in °C, sowie der
jeweilige mittlere Ferrit-Korndurchmesser FKm in µm
angegeben.
In Tabelle 2 sind, soweit ermittelt, die gleichen Angaben für sechs in erfindungsgemäßer Weise aus demselben Stahl hergestellte Warmbandproben PE1, PE2, PE3, PE4, PE5, PE6 zusammengestellt.As far as determined, Table 2 summarizes the same information for six hot strip samples P E1 , P E2 , P E3 , P E4 , P E5 , P E6 produced from the same steel in accordance with the invention.
Der Vergleich der Materialeigenschaften der nach dem
konventionellen Verfahren hergestellten Warmbandproben
PK1,PK2,PK3 mit den Eigenschaften der nach dem
erfindungsgemäßen Verfahren erzeugten Warmbandproben PE1,
PE2, PE3, PE4, PE5, PE6 zeigt deutlich, daß die
erfindungsgemäß erzeugten Warmbänder bei einer größeren
Dicke erheblich verbesserte Festigkeitseigenschaften,
einen deutlich verbesserten Mattbruchanteil und eine sehr
viel feinere Körnung aufweisen.
- AA
- AuslaufrollgangOutlet roller table
- CC.
- CoilCoil
- εH ε H
- Gesamtumformgrad nach der Abkühlung unterhalb der Rekristallisationsstop-TemperaturTotal degree of deformation after the Cooling below the Stop recrystallization temperature
- ETET
- Endtemperatur des Warmbandes beim Verlassen der Fertigstaffel FSFinal temperature of the hot strip at Leaving the finished relay FS
- FF
- FörderrichtungDirection of conveyance
- FSFS
- FertigstaffelFinished relay
- F1,F2,F3,F4,F5,F6,F7F1, F2, F3, F4, F5, F6, F7
- WalzgerüsteMill stands
- HH
- HaspeleinrichtungDecoiler
- HTHT
- HaspeltemperaturReel temperature
- K1 - K8K1 - K8
- KühleinrichtungenCooling devices
- LL
- VersorgungsleitungenSupply lines
- RR
- Raum zwischen jeweils zwei WalzgerüstenSpace between two Roll stands
- SS
- SteuereinrichtungControl device
- T1 T 1
- Temperatur des in die Fertigstaffel eintretenden Warmbandes WTemperature of the in Finishing season entering Hot strip W
- TREK STOP T REK STOP
- Rekristallisationsstop-TemperaturStop recrystallization temperature
- T2 T 2
- Unterhalb TREK STOP liegende TemperaturTemperature below T REK STOP
- WW
- WarmbandHot strip
Claims (16)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19913498A DE19913498C1 (en) | 1999-03-25 | 1999-03-25 | Process for producing a hot strip and hot strip line for carrying out the method |
| DE19913498 | 1999-03-25 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1038978A1 true EP1038978A1 (en) | 2000-09-27 |
| EP1038978B1 EP1038978B1 (en) | 2004-05-12 |
Family
ID=7902339
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP00103097A Revoked EP1038978B1 (en) | 1999-03-25 | 2000-02-16 | Process for manufacturing hot strip |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP1038978B1 (en) |
| AT (1) | ATE266741T1 (en) |
| DE (2) | DE19913498C1 (en) |
| ES (1) | ES2220272T3 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103447295A (en) * | 2013-08-14 | 2013-12-18 | 武钢集团昆明钢铁股份有限公司 | Manufacturing method of hot rolled steel plate with low alloy structural steel |
| WO2015000895A1 (en) * | 2013-07-03 | 2015-01-08 | Thyssenkrupp Steel Europe Ag | Plant and method for hot rolling steel strip |
| CN110665964A (en) * | 2019-10-14 | 2020-01-10 | 攀钢集团攀枝花钢铁研究院有限公司 | Method for rolling thin X70 pipeline steel strip |
| CN114472515A (en) * | 2021-12-21 | 2022-05-13 | 江西铜业集团铜板带有限公司 | Preparation method of multi-element alloy thin strip for lead frame |
| EP4101552A1 (en) * | 2021-06-09 | 2022-12-14 | Primetals Technologies Austria GmbH | Method for producing of a microalloyed steel, a microalloyed steel produced by means of the method, and an integrated casting-rolling system |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE112006003169B4 (en) * | 2005-12-01 | 2013-03-21 | Posco | Steel sheets for hot press forming with excellent heat treatment and impact properties, hot pressed parts produced therefrom and process for their production |
| KR100660229B1 (en) * | 2005-12-26 | 2006-12-21 | 주식회사 포스코 | Ultra-thick steel plate for welded structure with excellent strength and toughness at the center of thickness and low material deviation and its manufacturing method |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3437637A1 (en) * | 1984-10-13 | 1986-04-24 | Thyssen Stahl AG, 4100 Duisburg | Process for producing heavy plate |
| US4662950A (en) * | 1985-11-05 | 1987-05-05 | Bethlehem Steel Corporation | Method of making a steel plate for construction applications |
| WO1990006821A1 (en) * | 1988-12-15 | 1990-06-28 | Davy Mckee (Sheffield) Limited | The operation of a multi-stand hot rolling mill |
| WO1996041024A1 (en) * | 1995-06-07 | 1996-12-19 | Ipsco Inc. | Steckel mill/on-line accelerated cooling combination |
| DE19725434A1 (en) * | 1997-06-16 | 1998-12-24 | Schloemann Siemag Ag | Process and plant for rolling hot wide strip in a CSP plant |
-
1999
- 1999-03-25 DE DE19913498A patent/DE19913498C1/en not_active Expired - Fee Related
-
2000
- 2000-02-16 ES ES00103097T patent/ES2220272T3/en not_active Expired - Lifetime
- 2000-02-16 AT AT00103097T patent/ATE266741T1/en not_active IP Right Cessation
- 2000-02-16 EP EP00103097A patent/EP1038978B1/en not_active Revoked
- 2000-02-16 DE DE50006370T patent/DE50006370D1/en not_active Revoked
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3437637A1 (en) * | 1984-10-13 | 1986-04-24 | Thyssen Stahl AG, 4100 Duisburg | Process for producing heavy plate |
| US4662950A (en) * | 1985-11-05 | 1987-05-05 | Bethlehem Steel Corporation | Method of making a steel plate for construction applications |
| WO1990006821A1 (en) * | 1988-12-15 | 1990-06-28 | Davy Mckee (Sheffield) Limited | The operation of a multi-stand hot rolling mill |
| WO1996041024A1 (en) * | 1995-06-07 | 1996-12-19 | Ipsco Inc. | Steckel mill/on-line accelerated cooling combination |
| DE19725434A1 (en) * | 1997-06-16 | 1998-12-24 | Schloemann Siemag Ag | Process and plant for rolling hot wide strip in a CSP plant |
Non-Patent Citations (2)
| Title |
|---|
| DILG C ET AL: "TMCP PROCESS INCLUDING TWO ACCELERATED COOLING STAGES", CAHIERS D'INFORMATIONS TECHNIQUES DE LA REVUE DE METALLURGIE,FR,REVUE DE METALLURGIE. PARIS, vol. 92, no. 7/08, 1 July 1995 (1995-07-01), pages 883 - 892, XP000550405, ISSN: 0035-1563 * |
| KAUP K ET AL: "OPTIMIERUNG DER WARMWALZBEDINGUNGEN ZUR VERBESSERUNG UND VERGLEICHMAESSIGUNG DER WERKSTOFFEIGENSCHAFTEN", STAHL UND EISEN,DE,VERLAG STAHLEISEN GMBH. DUSSELDORF, vol. 104, no. 20, 1984, pages 1017 - 1024, XP000907087, ISSN: 0340-4803 * |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015000895A1 (en) * | 2013-07-03 | 2015-01-08 | Thyssenkrupp Steel Europe Ag | Plant and method for hot rolling steel strip |
| CN105392574A (en) * | 2013-07-03 | 2016-03-09 | 蒂森克虏伯钢铁欧洲股份公司 | Apparatus and method for hot strip rolling |
| US10335840B2 (en) | 2013-07-03 | 2019-07-02 | Thyssenkrupp Steel Europe Ag | Production lines and methods for hot rolling steel strip |
| EP3016754B1 (en) | 2013-07-03 | 2019-09-04 | ThyssenKrupp Steel Europe AG | Plant and method for hot rolling steel strip |
| CN103447295A (en) * | 2013-08-14 | 2013-12-18 | 武钢集团昆明钢铁股份有限公司 | Manufacturing method of hot rolled steel plate with low alloy structural steel |
| CN103447295B (en) * | 2013-08-14 | 2015-02-04 | 武钢集团昆明钢铁股份有限公司 | Manufacturing method of hot rolled steel plate with low alloy structural steel |
| CN110665964A (en) * | 2019-10-14 | 2020-01-10 | 攀钢集团攀枝花钢铁研究院有限公司 | Method for rolling thin X70 pipeline steel strip |
| CN110665964B (en) * | 2019-10-14 | 2021-06-04 | 攀钢集团攀枝花钢铁研究院有限公司 | A kind of thin gauge X70 pipeline steel strip rolling method |
| EP4101552A1 (en) * | 2021-06-09 | 2022-12-14 | Primetals Technologies Austria GmbH | Method for producing of a microalloyed steel, a microalloyed steel produced by means of the method, and an integrated casting-rolling system |
| WO2022258376A1 (en) * | 2021-06-09 | 2022-12-15 | Primetals Technologies Austria GmbH | Method for producing a microalloyed steel, a microalloyed steel produced using the method, and a combined casting/rolling installation |
| CN114472515A (en) * | 2021-12-21 | 2022-05-13 | 江西铜业集团铜板带有限公司 | Preparation method of multi-element alloy thin strip for lead frame |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2220272T3 (en) | 2004-12-16 |
| DE50006370D1 (en) | 2004-06-17 |
| ATE266741T1 (en) | 2004-05-15 |
| EP1038978B1 (en) | 2004-05-12 |
| DE19913498C1 (en) | 2000-10-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP1752549B1 (en) | Process for manufacturing grain-oriented magnetic steel spring | |
| EP1752548B1 (en) | Method for producing a magnetic grain oriented steel strip | |
| EP1469954B2 (en) | Method for producing a hot rolled strip from austenitic rust-resistant steels | |
| EP2690183B1 (en) | Hot-rolled steel flat product and method for its production | |
| EP0804300B1 (en) | Process and device for producing a steel strip with the properties of a cold-rolled product | |
| WO2007048497A1 (en) | Method for producing hot strip with a multiphase structure | |
| AT504782A4 (en) | METHOD FOR PRODUCING A HOT-ROLLED STEEL STRIP AND COMBINED CASTING AND ROLLING MACHINE TO PERFORM THE METHOD | |
| EP2507399B1 (en) | Hot rolling mill and method for hot rolling a metal strip or sheet | |
| DE69508725T2 (en) | Process for direct rolling of continuously cast slabs | |
| EP1918406B1 (en) | Process for manufacturing steel flat products from boron microalloyed multi phase steel | |
| EP1633894B1 (en) | Method and installation for the production of hot-rolled strip having a dual-phase structure | |
| EP1918402B1 (en) | Process for manufacturing steel flat products from a steel forming a complex phase structure | |
| EP1319725B1 (en) | Hot strip manufacturing process | |
| EP1038978B1 (en) | Process for manufacturing hot strip | |
| EP3206808B1 (en) | Installation and method for producing heavy plate | |
| EP3974072B1 (en) | Casting roller composite system and method for operating the casting roller composite system | |
| EP1453984B1 (en) | Method for the production of hot strip or sheet from a micro-alloyed steel | |
| DE69327091T2 (en) | Process for producing profiles from steel with low carbon equivalent by controlled rolling | |
| EP3719147B1 (en) | Hot-rolled flat steel product and method for its production | |
| EP4101552A1 (en) | Method for producing of a microalloyed steel, a microalloyed steel produced by means of the method, and an integrated casting-rolling system | |
| EP2460596B1 (en) | Method for producing high-strength, low alloy steel with copper | |
| WO2001029273A1 (en) | Method for production of a hot rolled strip | |
| EP0970256B1 (en) | Hot-rolling steel strip | |
| EP1411140B1 (en) | Process for manufacturing of cold-rolled steel strips or sheets having excellent formability | |
| EP1918404B1 (en) | Process for manufacturing steel flat products from aluminium alloyed multi phase steel |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE |
|
| AX | Request for extension of the european patent |
Free format text: AL;LT;LV;MK;RO;SI |
|
| 17P | Request for examination filed |
Effective date: 20000908 |
|
| AKX | Designation fees paid |
Free format text: AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE |
|
| RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: THYSSENKRUPP STAHL AG |
|
| 17Q | First examination report despatched |
Effective date: 20030416 |
|
| GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
| RTI1 | Title (correction) |
Free format text: PROCESS FOR MANUFACTURING HOT STRIP |
|
| GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
| GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
| AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20040512 |
|
| REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
| RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: ENGL, BERNHARD, DR.-ING. Inventor name: FRIEDRICH, KARL ERNST, DIPL.-ING. Inventor name: PIRCHER, HANS, DR.-ING. Inventor name: KAWALLA, RUDOLF, PROF. DR.-ING. Inventor name: HELLER,THOMAS, DR.-ING. Inventor name: SCHMITZ, HANS-PETER, DIPL.-ING. |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
| REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: GERMAN |
|
| REF | Corresponds to: |
Ref document number: 50006370 Country of ref document: DE Date of ref document: 20040617 Kind code of ref document: P |
|
| GBT | Gb: translation of ep patent filed (gb section 77(6)(a)/1977) |
Effective date: 20040714 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20040812 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20040812 |
|
| REG | Reference to a national code |
Ref country code: SE Ref legal event code: TRGR |
|
| REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2220272 Country of ref document: ES Kind code of ref document: T3 |
|
| REG | Reference to a national code |
Ref country code: IE Ref legal event code: FD4D |
|
| ET | Fr: translation filed | ||
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20050216 Ref country code: FI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20050216 Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20050216 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20050217 |
|
| PLAQ | Examination of admissibility of opposition: information related to despatch of communication + time limit deleted |
Free format text: ORIGINAL CODE: EPIDOSDOPE2 |
|
| PLAR | Examination of admissibility of opposition: information related to receipt of reply deleted |
Free format text: ORIGINAL CODE: EPIDOSDOPE4 |
|
| PLBQ | Unpublished change to opponent data |
Free format text: ORIGINAL CODE: EPIDOS OPPO |
|
| PLAQ | Examination of admissibility of opposition: information related to despatch of communication + time limit deleted |
Free format text: ORIGINAL CODE: EPIDOSDOPE2 |
|
| PLAR | Examination of admissibility of opposition: information related to receipt of reply deleted |
Free format text: ORIGINAL CODE: EPIDOSDOPE4 |
|
| PLBQ | Unpublished change to opponent data |
Free format text: ORIGINAL CODE: EPIDOS OPPO |
|
| PLBI | Opposition filed |
Free format text: ORIGINAL CODE: 0009260 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20050228 Ref country code: MC Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20050228 Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20050228 |
|
| PLAX | Notice of opposition and request to file observation + time limit sent |
Free format text: ORIGINAL CODE: EPIDOSNOBS2 |
|
| 26 | Opposition filed |
Opponent name: CORUS STAAL BV Effective date: 20050214 |
|
| NLR1 | Nl: opposition has been filed with the epo |
Opponent name: CORUS STAAL BV |
|
| PLAF | Information modified related to communication of a notice of opposition and request to file observations + time limit |
Free format text: ORIGINAL CODE: EPIDOSCOBS2 |
|
| EUG | Se: european patent has lapsed | ||
| PLAF | Information modified related to communication of a notice of opposition and request to file observations + time limit |
Free format text: ORIGINAL CODE: EPIDOSCOBS2 |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
| PLBB | Reply of patent proprietor to notice(s) of opposition received |
Free format text: ORIGINAL CODE: EPIDOSNOBS3 |
|
| PLAY | Examination report in opposition despatched + time limit |
Free format text: ORIGINAL CODE: EPIDOSNORE2 |
|
| PLBC | Reply to examination report in opposition received |
Free format text: ORIGINAL CODE: EPIDOSNORE3 |
|
| RDAF | Communication despatched that patent is revoked |
Free format text: ORIGINAL CODE: EPIDOSNREV1 |
|
| RDAE | Information deleted related to despatch of communication that patent is revoked |
Free format text: ORIGINAL CODE: EPIDOSDREV1 |
|
| RDAF | Communication despatched that patent is revoked |
Free format text: ORIGINAL CODE: EPIDOSNREV1 |
|
| APBP | Date of receipt of notice of appeal recorded |
Free format text: ORIGINAL CODE: EPIDOSNNOA2O |
|
| APAH | Appeal reference modified |
Free format text: ORIGINAL CODE: EPIDOSCREFNO |
|
| RAP2 | Party data changed (patent owner data changed or rights of a patent transferred) |
Owner name: THYSSENKRUPP STEEL AG |
|
| APBQ | Date of receipt of statement of grounds of appeal recorded |
Free format text: ORIGINAL CODE: EPIDOSNNOA3O |
|
| NLT2 | Nl: modifications (of names), taken from the european patent patent bulletin |
Owner name: THYSSENKRUPP STEEL AG Effective date: 20070711 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20041012 |
|
| APAH | Appeal reference modified |
Free format text: ORIGINAL CODE: EPIDOSCREFNO |
|
| PLAB | Opposition data, opponent's data or that of the opponent's representative modified |
Free format text: ORIGINAL CODE: 0009299OPPO |
|
| R26 | Opposition filed (corrected) |
Opponent name: CORUS STAAL BV Effective date: 20050214 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: AT Payment date: 20090224 Year of fee payment: 10 Ref country code: ES Payment date: 20090225 Year of fee payment: 10 |
|
| APBU | Appeal procedure closed |
Free format text: ORIGINAL CODE: EPIDOSNNOA9O |
|
| NLR1 | Nl: opposition has been filed with the epo |
Opponent name: CORUS STAAL BV |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 20090225 Year of fee payment: 10 Ref country code: DE Payment date: 20090224 Year of fee payment: 10 |
|
| RDAG | Patent revoked |
Free format text: ORIGINAL CODE: 0009271 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: PATENT REVOKED |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20090224 Year of fee payment: 10 |
|
| 27W | Patent revoked |
Effective date: 20090423 |
|
| GBPR | Gb: patent revoked under art. 102 of the ep convention designating the uk as contracting state |
Effective date: 20090423 |
|
| NLR2 | Nl: decision of opposition |
Effective date: 20090423 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: BE Payment date: 20090408 Year of fee payment: 10 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20090224 Year of fee payment: 10 |