[go: up one dir, main page]

EP1095296A2 - Procede de production d'une fibre optique plastique, et fibre optique plastique - Google Patents

Procede de production d'une fibre optique plastique, et fibre optique plastique

Info

Publication number
EP1095296A2
EP1095296A2 EP99952123A EP99952123A EP1095296A2 EP 1095296 A2 EP1095296 A2 EP 1095296A2 EP 99952123 A EP99952123 A EP 99952123A EP 99952123 A EP99952123 A EP 99952123A EP 1095296 A2 EP1095296 A2 EP 1095296A2
Authority
EP
European Patent Office
Prior art keywords
plastic
layers
fibre
optical fibre
conical extruder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP99952123A
Other languages
German (de)
English (en)
Inventor
Kari Kirjavainen
Markku Suvanto
Jouni Heinonen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mindset Holding SA
Draka NK Cables Oy
Original Assignee
Nextrom Holding SA
NK Cables Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nextrom Holding SA, NK Cables Oy filed Critical Nextrom Holding SA
Publication of EP1095296A2 publication Critical patent/EP1095296A2/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/02—Optical fibres with cladding with or without a coating
    • G02B6/02057—Optical fibres with cladding with or without a coating comprising gratings
    • G02B6/02076—Refractive index modulation gratings, e.g. Bragg gratings
    • G02B6/02123—Refractive index modulation gratings, e.g. Bragg gratings characterised by the method of manufacture of the grating
    • G02B6/02152—Refractive index modulation gratings, e.g. Bragg gratings characterised by the method of manufacture of the grating involving moving the fibre or a manufacturing element, stretching of the fibre
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/02—Optical fibres with cladding with or without a coating
    • G02B6/02033—Core or cladding made from organic material, e.g. polymeric material
    • G02B6/02038—Core or cladding made from organic material, e.g. polymeric material with core or cladding having graded refractive index
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/05—Filamentary, e.g. strands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D11/00—Producing optical elements, e.g. lenses or prisms
    • B29D11/00663—Production of light guides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor

Definitions

  • the invention relates to a method of making a plastic optical fibre, in which method plastic materials with suitable optical properties are fed into an extrusion apparatus, which forms a multilayer structure where the refractive index decreases gradually from the inside outwards.
  • the invention further relates to a plastic optical fibre.
  • Optical fibres are rather well known in several fields of technology.
  • Optical fibres are normally manufactured by forming a preform from a silica tube for example by means of a Modified Chemical Vapour Deposition (MCVD) method. Gases are blown into the preform, which is simultaneously heated, so that the gases react at a high temperature (ca 2000°C) to form silica glass (Si0 2 ) and mixed oxides (Ge0 2 , P 2 0 5 , B 2 0 3 ) at the inner surface of the tube. The process is repeated in a predetermined manner.
  • the composition of the gas is changed by means of computer control, for example, so that a desired number of layers with different refractive indices are obtained superimposed at the tube's inner surface.
  • the preform is collapsed so that the centre hole of the tube disappears.
  • An optical fibre is thereafter formed from the preform in a separate stage of operation by drawing at a high temperature, and the fibre is coated in a suitable manner, for example with acrylate that hardens in UV light.
  • Discontinuity of fibre production means that an optical fibre of only a limited length can be formed from a preform.
  • the process is such that the preform is drawn to the end, whereafter the drawing is started from another preform.
  • a new preform has naturally been produced as described above, in this manner, it is possible to achieve only limited fibre lengths of, for example, 50 to 100 km.
  • the process is characterized by the use of very high temperatures in each step.
  • a drawback is the rather high costs of the fibre manufacture, which result from the sensitivity and poor controllability of the manufacturing process.
  • plastic optical fibres are graded index (Gl) optical fibres from plastic material.
  • graded index plastic fibres come closer to the optical properties of glass fibres.
  • Plastic optical fibres generally provide the following advantages over glass fibres: better mountability and splicing (larger diameter, splices), better processibility, better bending properties, recyclability, easier manufacture (considerably lower temperatures, continuous process) among other things. Due to higher damping than in silica glass, plastic fibres are mainly used in short-distance applications, which include office and factory automation, consumer electronics, computers, multimedia, electronic systems in aeroplanes and vehicles, and lighting.
  • graded index plastic fibres has utilized so far mainly the same technique as the production of glass fibres, wherein a rod-like preform is made in the first step, and it is later drawn to a desired thickness in a separate step.
  • a mixture of methyl methacrylate and a compound (dopant) with a suitable refractive index is polymerized in a tube made of polymethyl methacrylate (PMMA) to provide a desired refractive index distribution (High bandwidth, low loss polymer fibers by Y. Koike in Proc. ECOC'92, Vol 2, 1992, pp 679-686).
  • the refractive index distribution is based on the diffusion of the dopant during the polymerization.
  • this process has several disadvantages; for example poor controllability of the diffusion and the refractive index profile, great amount of residue monomers (impurities), and the discontinuity of the process. Therefore the refractive index profile is not stable in the longitudinal direction of the fibre. Further, due to the poor controllability of the process, the use of the process is limited to a laboratory scale and it is thus not suitable for large-scale industrial production.
  • graded index plastic optical fibres can also be manufactured with an extrusion method.
  • An example of prior art arrangements is a manufacturing method disclosed in Japanese Patent Application 7-291080 (publication number 9- 133818).
  • This reference discloses an arrangement which enables the manufacture of an optical fibre structure comprising only a few, preferably at most six, layers.
  • the arrangement is based on a conventional coextrusion technique where melt flows intended for different layers are combined in a complicated multilayer crosshead die.
  • this arrangement cannot provide, in an advantageous manner, multilayer structures where the layers are very thin and/or there is a plurality of layers.
  • the purpose of the invention is to provide a method of making particularly a graded index plastic optical fibre, and a graded index plastic fibre, the method comprising none of the prior art drawbacks.
  • the method is also suitable for the production of conventional step index plastic optical fibres. This is achieved with a method and plastic fibre according to the invention.
  • the method according to the invention is characterized by continuously feeding several different plastic materials with suitable optical properties into an extrusion apparatus so as to form a multilayer structure where the refractive index decreases gradually from the inside outwards, the extrusion apparatus consisting of at least one multilayer conical extruder unit with which a fibre is extruded close to the correct diameter, whereafter the fibre is drawn to the final diameter immediately after the multilayer conical extruder unit.
  • the optical fibre according to the invention is, in turn, characterized in that it comprises superimposed layers formed without weld lines from plastic materials with different refractive indices by means of a conical extrusion apparatus, and that the fibre is characterized by a controlled layer thickness and a stable refractive index distribution.
  • the number of the layers may also be high (e.g. 10 to 50) and it can be modified easily.
  • a primary advantage of the invention is that it enables the manufacture of very different plastic optical fibres in an advantageous manner.
  • the invention provides multilayer structures with several round, symmetrical layers with no weld lines, which leads to a controlled refractive index distribution, a stable fibre structure and good centricity.
  • An important advantage of the invention is that the mass flows of the materials intended for different layers do not have to be turned 90 degrees, and no weld line resulting from the tool is formed in the layers as in case of conventional machines.
  • the fact that the product according to the invention is formed without weld lines means that each individual layer is strong and whole and has stable dimensions even when it is thin, which is the basis for the operation of a high- quality graded index plastic fibre.
  • the refractive index distribution must be of an accurate form. Variation of the refractive index as a function of the radius of the plastic optical fibre can be described with the following formula:
  • n(r) n 1 (1-2 ⁇ (r/a) B ) 1 2 (1 )
  • n, the refractive index of the core
  • n k the refractive index of the cladding
  • r the fibre radius
  • a the radius of the fibre section transmitting light
  • g the exponent defining the form of the refractive index distribution
  • the optimum bandwidth may be obtained from the used wavelength of light also with other values of g.
  • the number of layers is high and the refractive indices of adjacent layers differ only a little so that the distribution resembles the continuous, stepless form of formula 1. This is achieved most preferably with the method according to the invention, which results in an optimum bandwidth with each fibre structure.
  • Another essential feature of the invention is that the entire fibre structure is manufactured in one step, which ensures the purity of the materials and the adhesion between the layers. The compatibility of the different layers is ensured not only with the selection of the materials but also with control of the process parameters, such as temperatures and viscosities.
  • the method according to the invention is characterized by a short residence time of the melt plastic at a high temperature and by low shear forces, which are particularly advantageous in the processing of thermosensitive materials, such as PMMA. Due to the aforementioned advantages, the graded index plastic optical fibres according to the invention provide a stable and even refractive index distribution in the longitudinal direction of the fibre, which cannot be achieved with conventional techniques. Also, it is essential that the method according to the invention is continuous, wherefore the length of the fibres produced with the method is not restricted in theory. It is characteristic of the method according to the invention that it enables flexible production of very different plastic optical fibres.
  • the method does not restrict in any way the materials to be used, which is a significant advantage compared to the prior art method disclosed above and based on the polymerization of acrylate and the diffusion of dopant. It is possible to use in the method according to the invention any extrudable plastic materials with suitable optical properties, which can be combined almost without limits to adjust suitably the optical, thermal, mechanical and other properties of the plastic fibre.
  • Figure 1 is a general side view of a conical extruder unit used in the method according to the invention
  • Figure 2 is a general side view of an arrangement utilizing the method according to the invention
  • Figure 3 is a general sectional view of a plastic optical fibre made with the method according to the invention.
  • FIG. 1 shows the basic features of a conical extruder unit 1 used in the method according to the invention.
  • the conical extruder unit 1 comprises a central channel, which is surrounded by stator and rotor parts.
  • the rotor parts are rotated by a suitable power source 2.
  • Plastic material is supplied to the rotor surfaces by means of feed screws or pressurized air, for example.
  • the power source may be, for example, an electric motor, a hydraulic motor or some other suitable device.
  • the conical extruder unit shown in Figure 1 forms a longitudinal layer structure where the layers are superimposed coaxially.
  • the aforementioned facts are characteristic of a conical extruder, wherefore they will not be described in greater detail herein. Reference is made to WO 89/11961 , which describes the structure and operation of the aforementioned conical extruder.
  • the aforementioned conical extruder is used to manufacture preferably a graded index plastic optical fibre.
  • plastic materials with suitable optical properties are fed into an extrusion apparatus, which is used to form a multilayer structure where the refractive index decreases gradually from the inside outwards.
  • the extrusion apparatus consists of at least one conical extruder unit 1. The fibre is compressed in the multilayer conical extruder unit close to the correct diameter and the fibre is drawn to the final diameter immediately after the multilayer conical extruder unit at a suitable temperature. All the aforementioned steps are carried out in one stage of operation.
  • Figure 2 shows generally a preferred embodiment of the invention utilizing two conical extruder units 1 placed one after the other.
  • a product 3 to be prepared is drawn, either without cooling or after suitable cooling, from the previous conical extruder unit 1 to the next conical extruder unit 1.
  • the product is drawn through several extrusion units and hose tools are used, it is rather difficult to control the layer thicknesses.
  • hose tools are used, the product must be stretched slightly at each new layer, which also results in changes in the inner layer(s).
  • all the layers constitute a stiff mass if the product is not cooled occasionally.
  • the layer thicknesses are also very small. Therefore the successive conical extruders 1 must also be synchronized together so that the layer thicknesses are reduced in the correct proportion from the inside outwards.
  • the layers are formed in the invention such that the tool does not touch the inner layer in order not to damage it.
  • the plastic material used for forming the layers is supplied to the conical extruder in a manner known per se. These matters constitute conventional technology to a person skilled in the art, wherefore they will not be described in greater detail herein.
  • the process of Figure 2 is carried out in a clean space at a standardized pressure.
  • Standard conditions can be provided, for example, by means of a suitable protective gas.
  • the protective gas may be nitrogen, for example.
  • the different refractive indices of the different layers are achieved by means of the properties of the plastic materials. Different refractive indices can be obtained, for example, by mixing together different plastic components. The components can be mixed either in a separate step or as a part of the fibre manufacture. However, it has been found particularly advantageous that the mixing is carried out by means of the conical extruder unit 1 , i.e. the same apparatus which forms the final product.
  • the different refractive indices of the layers can naturally also be achieved by means of different plastic materials.
  • 12 layers are formed in each conical extruder unit 1 , which means that in this example the final product 3 comprises 24 layers. The layers are formed by supplying selected plastic materials to the inner and outer surfaces of the rotors.
  • Figure 3 shows generally a graded index plastic optical fibre according to the invention comprising 24 layers whose refractive index decreases gradually from the inside outwards. This product is manufactured by means of the arrangement shown in Figure 2. Figure 3 shows generally how the refractive index decreases from the inside outwards.
  • the layers can be formed from any plastic material with suitable optical properties.
  • plastic material with suitable optical properties.
  • materials include polymethyi methacrylate (PMMA), polystyrene (PS), polycarbonate (PC), cyclic olefin copolymer (COC), polymethylpentene (PMP), silicon polymers, micro- crystalline polyamide (PA) or derivatives thereof, such as copolymers with suitable, for example fluoridated or deuterated, monomers.
  • PMMA polymethyi methacrylate
  • PS polystyrene
  • PC polycarbonate
  • COC cyclic olefin copolymer
  • PMP polymethylpentene
  • PA micro- crystalline polyamide
  • Different materials can naturally be modified for different layers suitably by mixing therein other polymers, softeners (plasticizing) or other suitable additives.
  • the modification of the materials can be carried out either beforehand in a separate step, or in a mixer integrated into the conical extruder or in the extruder
  • Figure 2 shows an arrangement with two conical extruder units. However, this is not the only alternative but the invention can naturally be applied also by means of for example one, three, four or any other number of conical extruder units. The invention can also be applied in connection with conical extruder units forming for example two, three, four or some other number of layers.
  • a fibre or rod made from a homogenous plastic material with suitable optical properties in a separate step is coated by a desired number of layers extruded by a conical extruder to provide either a desired plastic optical fibre or a preform thereof.
  • the plastic layers transmitting light can be coated by a cladding extruded in the same step from a suitable plastic material to provide mechanical, thermal and chemical protection and to prevent the contamination of the optical fibre already during the manufacture.
  • the cladding is shown generally in Figure 3 by means of reference numeral 4.

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Health & Medical Sciences (AREA)
  • Ophthalmology & Optometry (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)

Abstract

L'invention concerne un procédé de production d'une fibre optique plastique, consistant à amener dans un appareil d'extrusion des matières plastiques à propriétés optiques convenables, de façon à former une structure multicouche, dans laquelle l'indice de réfraction diminue graduellement, de manière régulée, de l'intérieur vers l'extérieur. L'invention concerne également une fibre optique plastique. Pour obtenir une production souple et continue, ainsi qu'une fibre à large bande, l'appareil d'extrusion est constitué par au moins une unité extrudeuse conique multicouche (1) produisant un produit dans lequel les couches, formées sans ligne de soudure, sont symétriques et adhèrent bien les unes aux autres. Le nombre de couches peut en outre être élevé.
EP99952123A 1998-05-19 1999-05-17 Procede de production d'une fibre optique plastique, et fibre optique plastique Withdrawn EP1095296A2 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FI981114A FI981114A7 (fi) 1998-05-19 1998-05-19 Menetelmä optisen muovikuidun valmistamiseksi ja optinen muovikuitu
FI981114 1998-05-19
PCT/FI1999/000425 WO1999060426A2 (fr) 1998-05-19 1999-05-17 Procede de production d'une fibre optique plastique, et fibre optique plastique

Publications (1)

Publication Number Publication Date
EP1095296A2 true EP1095296A2 (fr) 2001-05-02

Family

ID=8551760

Family Applications (1)

Application Number Title Priority Date Filing Date
EP99952123A Withdrawn EP1095296A2 (fr) 1998-05-19 1999-05-17 Procede de production d'une fibre optique plastique, et fibre optique plastique

Country Status (7)

Country Link
EP (1) EP1095296A2 (fr)
JP (1) JP2002516402A (fr)
KR (1) KR20010043715A (fr)
AU (1) AU4267399A (fr)
BR (1) BR9911052A (fr)
FI (1) FI981114A7 (fr)
WO (1) WO1999060426A2 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7764854B2 (en) * 2005-12-27 2010-07-27 Ofs Fitel Llc Optical fiber with specialized index profile to compensate for bend-induced distortions

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0452603A (ja) * 1990-06-20 1992-02-20 Nok Corp 屈折率分布型ゴム光ファイバの製造方法
US5235660A (en) * 1992-07-10 1993-08-10 Peachtree Fiberoptics, Inc. Graded polymer optical fibers and process for the manufacture thereof
US5555525A (en) * 1994-09-07 1996-09-10 Industrial Technology Research Institute Method of making graded refractive index polymeric optical fibers and optical fibers made by the method
JPH09133818A (ja) * 1995-11-09 1997-05-20 Sumitomo Wiring Syst Ltd 屈折率分布型プラスチック光ファイバの製造方法
US5729645A (en) * 1996-08-13 1998-03-17 The Trustees Of The University Of Pennsylvania Graded index optical fibers

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9960426A2 *

Also Published As

Publication number Publication date
FI981114A0 (fi) 1998-05-19
WO1999060426A3 (fr) 2000-01-13
BR9911052A (pt) 2001-02-06
JP2002516402A (ja) 2002-06-04
WO1999060426A2 (fr) 1999-11-25
KR20010043715A (ko) 2001-05-25
FI981114A7 (fi) 1999-11-20
AU4267399A (en) 1999-12-06

Similar Documents

Publication Publication Date Title
US5235660A (en) Graded polymer optical fibers and process for the manufacture thereof
JP2003527299A (ja) 高粘性液体を収束させることにより光ファイバを製作する方法
US6254808B1 (en) Process for fabricating plastic optical fiber
AU734519B2 (en) Illumination waveguide and method for producing same
US7460756B2 (en) Plastic optical fiber and method for manufacturing the same
KR20040078874A (ko) 플라스틱 광섬유용 클래드 파이프의 제조 방법 및 제조장치 및 클래드 파이프, 플라스틱 광섬유
EP1395861A1 (fr) Procede de production d'une preforme de fibre optique
WO2004046777A1 (fr) Element polymere microstructure de guidage de signaux
WO1999060426A2 (fr) Procede de production d'une fibre optique plastique, et fibre optique plastique
US4898603A (en) Method for manufacturing halide glass optical fiber
US20040197061A1 (en) Method of and apparatus for producing plastic optical fiber
US20040251567A1 (en) Method and system for producing plastic optical fiber
EP1509380B1 (fr) Produit optique en plastique, fibre optique en plastique, appareil et procede de fabrication de partie optique en plastique et de produit optique en plastique
US20050056952A1 (en) Method of manufacturing multi-polymer optical fiber cable
US20080277810A1 (en) Method and Apparatus for Manufacturing Plastic Optical Fiber
JP2006163031A (ja) プラスチック光学部材の製造方法及び製造装置
JP2006058775A (ja) プラスチック光ファイバの被覆方法
KR20070010126A (ko) 수지로 플라스틱 광섬유를 코팅하기 위한 장치 및 방법
CN100405098C (zh) 制造塑料光纤的方法和设备
EP1536255A1 (fr) Dispositif et procédé pour la fabrication de fibres optiques en plastique
JP2006126703A (ja) プラスチック光学部材の製造方法
CN1260498A (zh) 共挤法拉制塑料光纤生产装置
JPH08157227A (ja) キャピラリの製造方法およびキャピラリ
Yaoming et al. Study on Co-extrusion Process using Die of Multi—Orifice for Plastic Optic Fiber Production
JP2006126702A (ja) プラスチック光学部材連続押出装置及び連続製造方法

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20001124

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AT CH DE ES FI FR GB IT LI NL SE

17Q First examination report despatched

Effective date: 20050223

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 20050706