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EP0902099A1 - Surfaces résistantes à l'usure et à la corrosion - Google Patents

Surfaces résistantes à l'usure et à la corrosion Download PDF

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Publication number
EP0902099A1
EP0902099A1 EP98116523A EP98116523A EP0902099A1 EP 0902099 A1 EP0902099 A1 EP 0902099A1 EP 98116523 A EP98116523 A EP 98116523A EP 98116523 A EP98116523 A EP 98116523A EP 0902099 A1 EP0902099 A1 EP 0902099A1
Authority
EP
European Patent Office
Prior art keywords
coating
nitrogen
particular according
alloy
vanadium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP98116523A
Other languages
German (de)
English (en)
Inventor
Stephan D. Siegmann
Peter J. Uggowitzer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eidgenoessische Materialpruefungs und Forschungsanstalt
Original Assignee
Eidgenoessische Materialpruefungs und Forschungsanstalt
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eidgenoessische Materialpruefungs und Forschungsanstalt filed Critical Eidgenoessische Materialpruefungs und Forschungsanstalt
Publication of EP0902099A1 publication Critical patent/EP0902099A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/24Ferrous alloys, e.g. steel alloys containing chromium with vanadium
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/12Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/18After-treatment

Definitions

  • the present invention relates to a wear and corrosion resistant Surface or a wear and corrosion resistant Coating, a steel alloy for coating a ceramic, metallic or other object as well Process for producing a wear and corrosion resistant Coating.
  • CVD chemical vapor deposition
  • PVD physical vapor phase deposition
  • thermal spraying ion beam processes
  • laser coatings build-up welding
  • electrolytic and chemical coatings Conventional hard material layers are often brittle, such as aluminum oxide (Al 2 O 3 ), tungsten carbide-cobalt (WC-Co), diamond-like layers (DLC's), etc., whereas highly corrosion-resistant materials such as molybdenum or chromium are often not hard enough.
  • steel alloys are often used used for relatively thick and inexpensive coatings.
  • the main advantage of iron-based alloys consists in the high ductility compared to ceramics and hard metal coatings. Good corrosion resistance, high Toughness, hardness and good processability are further Advantages.
  • the abrasion resistance is rather moderate, but acceptable for a variety of applications.
  • An improvement the abrasion resistance or the wear resistance can be achieved are made by reinforcing the steel alloy, for example by adding nitrogen to that too applying steel alloy wettable powders.
  • the object of the present invention is based on a novel coating material or a new, on Iron based alloy significantly improved surfaces for simultaneous wear and corrosion protection to be able to.
  • the object is achieved by means of a wear and corrosion-resistant surface or a wear and corrosion-resistant coating, in particular according to claim 1, solved.
  • Chromium is one of the crucial elements for increasing the corrosion resistance.
  • the chromium content should be between 12% and 25% so that sufficient effect can be achieved.
  • Chromium stabilizes the ferritic crystal structure.
  • Manganese suppresses the formation of delta ferrite and increases it Nitrogen solubility. However, excessive manganese levels promote Formation of intermetallic phases and deteriorate Corrosion resistance.
  • the manganese content should be between 0% and 15% lie.
  • molybdenum is the second decisive element for Increase in corrosion resistance. Too high a molybdenum content however leads to the formation of delta ferrite and increases the Elimination tendency of sigma phases.
  • the molybdenum content should are between 2% and 6%.
  • Nickel is usually the decisive element for the setting of an austenitic crystal structure.
  • the nickel content in the nickel-containing alloy should not exceed 15%, whereas the nickel-free alloy obtains its austenitic crystal structure through the addition of nitrogen (N).
  • Vanadium is one of the most nitrogen-affecting alloy elements.
  • the vanadium content should be between 1%, preferably 2 %, and 12% are.
  • the vanadium dissolved in the alloy forms with nitrogen hard phases (vanadium nitrides, VN), which in turn not only the wear but also the one Significantly increase corrosion resistance.
  • the one in the solution homogeneously excreted hard phases (VN) have typical sizes in the range from 10 to approx. 5,000 nm.
  • Nitrogen is one of the most important alloying elements. It increases the alloy types 1 to a large extent austenitic crystal structure. Nitrogen forms with the in the desired hard phases in the alloys dissolved vanadium (Vanadium nitrides, VN).
  • the alloys mentioned is the nickel equivalent Ni ⁇ equal to or greater than the chromium equivalent Cr ⁇ minus 8, ie Ni ⁇ ⁇ Cr ⁇ - 8 , the alloy is non-magnetic because there are enough elements, such as nitrogen or nitrogen and nickel in the alloy, which stabilize the face-centered cubic, austenitic crystal lattice.
  • the surfaces or coatings according to the invention have the following chemical compositions (in percent by mass): Chrome (Cr) 12 to 25% Manganese (Mn) 0 to 15% Molybdenum (Mo) 2 to 6% Nickel (Ni) 0 to 15% Vanadium (V) 1, preferably 2 to 12% Nitrogen (N) 0 to 5%, the rest iron and technically usual impurities, optionally with up to a total of 5% of the elements copper, cobalt, niobium, titanium, zirconium, silicon, tungsten.
  • this is used to form the hard phases amount of nitrogen required before coating, for example brought into the alloy by means of thermal spraying and when applying resp. Syringes kept in the alloy.
  • This is for the application or Syringes needed
  • Steel alloy preferably in powder form with which desired chemical composition.
  • Such steel powder are usually commercially available, preferably the grain size range is typically 5 to approx. 120 ⁇ m.
  • this is used to form hard phases amount of nitrogen required during coating, such as for example thermal spraying, the steel powder in introduced the alloy. Nitrogen is released during the coating process, such as the spraying process, so to speak inflated, i.e. Nitrogen is used, for example, as a plasma or Reaction gas used.
  • the nitrogen diffuses into the wear and tear corrosion-resistant surface into the nitride hard phases to build.
  • thermal spraying All three application methods have in common that they are suitable for so-called thermal spraying.
  • the following illustration shows all thermal spraying processes by means of which the steel alloys defined according to the invention can be applied, for example, to a ceramic, metallic or other surface, to form the wear and corrosion-resistant surfaces defined according to the invention.
  • Steel powder with the chemical composition Fe17Cr10Mn4Mo6V in the grain size range from 5 to 106 ⁇ m was in a rotary nitrogen oven embroidered to a nitrogen content of 2 to 4% and then thermally sprayed.
  • the same alloy composition was without prior embroidery, however with nitrogen supply during the thermal spraying process, deposited. In the end, the same thing happened again Starting material thermally sprayed and subsequently the required Amount of nitrogen supplied.
  • the resulting structure of the surface layers achieved in this way is marked by a in all cases austenitic non-magnetic matrix with embedded hard phase of the vanadium nitride (VN) type.
  • VN vanadium nitride
  • Steel powder with the chemical composition Fe16Cr8Mn2.5Mo8Ni4V in the grain size range from 5 to 106 ⁇ m was in a rotary nitrogen oven to a nitrogen content embroidered by 3 to 4% and then thermally sprayed.
  • the same alloy composition was used without previous Nitrification, but with nitrogen supply during the thermal spraying process, deposited.
  • the same source material was finally thermally sprayed and subsequently supplied the required amount of nitrogen.
  • the resulting structure of the surface layer achieved in this way is characterized by an austenitic in all cases non-magnetic matrix with two families of embedded Vanadium nitride (VN) hard phases.
  • the first phase exists from primary nitrides in the order of a few micrometers.
  • the second phase consists of secondary nitrides in the order of magnitude of a few nanometers.
  • the same alloy composition was without prior embroidery, however with nitrogen supply during the thermal spraying process, deposited. In the end, the same thing happened again Starting material thermally sprayed and subsequently the required Amount of nitrogen supplied.
  • the resulting structure of the surface layer achieved in this way is characterized in all cases by a martensitic Matrix with two families of embedded hard phases of the vanadium nitride (VN) type.
  • the first phase consists of primary nitrides on the order of a few micrometers.
  • the second Phase consists of secondary nitrides on the order of a few nanometers.
  • VN cubic vanadium nitrides
  • chrome (Cr), molybdenum (Mo) and nitrogen (N) the layers receive a high level of corrosion protection.
  • the waiver of the alloying element allows Nickel (Ni) used in an austenitic alloy Areas where nickel allergies can otherwise be triggered. This is especially true for applications where skin contact or contact with Parts of the human body is possible.
  • the surfaces or coatings according to the invention in accordance with the proposed alloys include applications in those areas where high wear and corrosion protection with simultaneous ductility are required.
  • the alloys can thus be used in the following industries, for example:

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Coating By Spraying Or Casting (AREA)
EP98116523A 1997-09-10 1998-09-01 Surfaces résistantes à l'usure et à la corrosion Withdrawn EP0902099A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH2134/97 1997-09-10
CH213497 1997-09-10

Publications (1)

Publication Number Publication Date
EP0902099A1 true EP0902099A1 (fr) 1999-03-17

Family

ID=4226671

Family Applications (1)

Application Number Title Priority Date Filing Date
EP98116523A Withdrawn EP0902099A1 (fr) 1997-09-10 1998-09-01 Surfaces résistantes à l'usure et à la corrosion

Country Status (1)

Country Link
EP (1) EP0902099A1 (fr)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002083362A1 (fr) * 2001-04-11 2002-10-24 Steinemann Technology Ag Elements d'appui et procede pour ameliorer l'etat d'usure d'elements d'appui de rectifieuses larges
WO2006136610A3 (fr) * 2005-06-23 2007-07-12 Colorobbia Italiana Spa Materiaux permettant de revetir des corps en ceramiqe, procedes de preparation et utilisation de ces materiaux et articles en ceramique contenant lesdits materiaux
DE102014113846A1 (de) * 2014-09-24 2016-03-24 Härterei Technotherm Gmbh & Co. Kg Verfahren zur Behandlung eines Eisenwerkstoffs und behandelter Eisenwerkstoff
CN110004400A (zh) * 2017-11-29 2019-07-12 空中客车运营简化股份公司 用于改善部件的耐磨性能的方法以及部件
DE102018103321A1 (de) * 2018-02-14 2019-08-14 Iwis Motorsysteme Gmbh & Co. Kg Verfahren zur Herstellung von Hartstoffschichten
DE102018103319A1 (de) * 2018-02-14 2019-08-14 Iwis Motorsysteme Gmbh & Co. Kg Metallbauteil
CN115341168A (zh) * 2022-06-28 2022-11-15 江苏甬金金属科技有限公司 一种基于渗氮处理的不锈钢带的制备方法
DE102022205963A1 (de) 2022-06-13 2023-12-14 Volkswagen Aktiengesellschaft Oberflächenschicht für einen Grundkörper aus Grauguss oder einem ferritischen Stahl, Grundkörper mit einer solchen Oberflächenschicht sowie Verfahren zur Herstellung eines Bremskörpers für eine Reibungsbremse eines Kraftfahrzeugs
WO2024103093A1 (fr) 2022-11-16 2024-05-23 Hascic Daniel Élément de frein
CN120330584A (zh) * 2025-04-17 2025-07-18 兴化市精密铸钢有限公司 一种复合微合金化的抗腐蚀ZG40Cr25Ni20Si2母合金及其制备方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1439947A (en) * 1972-05-30 1976-06-16 Union Carbide Corp Corrosion resistant coatings and process for making the same
JPS62227072A (ja) * 1986-03-28 1987-10-06 Hitachi Ltd 高強度部材およびその製造法
EP0266149A2 (fr) * 1986-10-27 1988-05-04 Hitachi, Ltd. Membre résistant à l'usure, son procédé de fabrication et valve l'utilisant dans une machine à combustion interne
EP0383466A1 (fr) * 1989-02-16 1990-08-22 Valmet-Tampella Inc. Cylindre Yankee et procédé de revêtement d'un cylindre Yankee
JPH04158910A (ja) * 1990-10-19 1992-06-02 Hitachi Ltd 圧延用複合ロール及びその製造法
JPH07138727A (ja) * 1993-11-11 1995-05-30 Mitsubishi Heavy Ind Ltd 耐摩耗性皮膜の被覆方法
JPH07316771A (ja) * 1994-05-31 1995-12-05 Mitsubishi Heavy Ind Ltd 溶射材料

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1439947A (en) * 1972-05-30 1976-06-16 Union Carbide Corp Corrosion resistant coatings and process for making the same
JPS62227072A (ja) * 1986-03-28 1987-10-06 Hitachi Ltd 高強度部材およびその製造法
EP0266149A2 (fr) * 1986-10-27 1988-05-04 Hitachi, Ltd. Membre résistant à l'usure, son procédé de fabrication et valve l'utilisant dans une machine à combustion interne
EP0383466A1 (fr) * 1989-02-16 1990-08-22 Valmet-Tampella Inc. Cylindre Yankee et procédé de revêtement d'un cylindre Yankee
JPH04158910A (ja) * 1990-10-19 1992-06-02 Hitachi Ltd 圧延用複合ロール及びその製造法
JPH07138727A (ja) * 1993-11-11 1995-05-30 Mitsubishi Heavy Ind Ltd 耐摩耗性皮膜の被覆方法
JPH07316771A (ja) * 1994-05-31 1995-12-05 Mitsubishi Heavy Ind Ltd 溶射材料

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
D.BIRCHON: "DICTIONARY OF METALLURGY", 1965, GEORGE NEWNES LIMITED, LONDON, GB, XP002088917 *
DATABASE WPI Section Ch Week 8745, Derwent World Patents Index; Class M13, AN 87-318278, XP002088919 *
DATABASE WPI Section Ch Week 9228, Derwent World Patents Index; Class M13, AN 92-231797, XP002088918 *
DATABASE WPI Section Ch Week 9530, Derwent World Patents Index; Class M13, AN 95-229056, XP002088921 *
DATABASE WPI Section Ch Week 9606, Derwent World Patents Index; Class M13, AN 96-056467, XP002088920 *

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002083362A1 (fr) * 2001-04-11 2002-10-24 Steinemann Technology Ag Elements d'appui et procede pour ameliorer l'etat d'usure d'elements d'appui de rectifieuses larges
WO2006136610A3 (fr) * 2005-06-23 2007-07-12 Colorobbia Italiana Spa Materiaux permettant de revetir des corps en ceramiqe, procedes de preparation et utilisation de ces materiaux et articles en ceramique contenant lesdits materiaux
DE102014113846A1 (de) * 2014-09-24 2016-03-24 Härterei Technotherm Gmbh & Co. Kg Verfahren zur Behandlung eines Eisenwerkstoffs und behandelter Eisenwerkstoff
CN110004400A (zh) * 2017-11-29 2019-07-12 空中客车运营简化股份公司 用于改善部件的耐磨性能的方法以及部件
DE102018103321A1 (de) * 2018-02-14 2019-08-14 Iwis Motorsysteme Gmbh & Co. Kg Verfahren zur Herstellung von Hartstoffschichten
DE102018103319A1 (de) * 2018-02-14 2019-08-14 Iwis Motorsysteme Gmbh & Co. Kg Metallbauteil
US12065729B2 (en) 2018-02-14 2024-08-20 Iwis Motorsysteme Gmbh & Co. Kg Metal component and method for producing same
EP4292810A1 (fr) * 2022-06-13 2023-12-20 Volkswagen Aktiengesellschaft Couche de surface pour un corps de base en fonte grise ou en acier ferritique, corps de base pourvu d'une telle couche de surface et procédé de fabrication d'un corps de frein pour un frein à friction
DE102022205963A1 (de) 2022-06-13 2023-12-14 Volkswagen Aktiengesellschaft Oberflächenschicht für einen Grundkörper aus Grauguss oder einem ferritischen Stahl, Grundkörper mit einer solchen Oberflächenschicht sowie Verfahren zur Herstellung eines Bremskörpers für eine Reibungsbremse eines Kraftfahrzeugs
CN115341168B (zh) * 2022-06-28 2023-12-19 江苏甬金金属科技有限公司 一种基于渗氮处理的不锈钢带的制备方法
CN115341168A (zh) * 2022-06-28 2022-11-15 江苏甬金金属科技有限公司 一种基于渗氮处理的不锈钢带的制备方法
WO2024103093A1 (fr) 2022-11-16 2024-05-23 Hascic Daniel Élément de frein
AT526715A1 (de) * 2022-11-16 2024-06-15 Hascic Ing Daniel Bremselement
AT526715B1 (de) * 2022-11-16 2025-08-15 Hascic Ing Daniel Bremselement
CN120330584A (zh) * 2025-04-17 2025-07-18 兴化市精密铸钢有限公司 一种复合微合金化的抗腐蚀ZG40Cr25Ni20Si2母合金及其制备方法

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