[go: up one dir, main page]

EP0979067A2 - Compositions cosmetiques veloutees a base d'hydrocarbures - Google Patents

Compositions cosmetiques veloutees a base d'hydrocarbures

Info

Publication number
EP0979067A2
EP0979067A2 EP99907009A EP99907009A EP0979067A2 EP 0979067 A2 EP0979067 A2 EP 0979067A2 EP 99907009 A EP99907009 A EP 99907009A EP 99907009 A EP99907009 A EP 99907009A EP 0979067 A2 EP0979067 A2 EP 0979067A2
Authority
EP
European Patent Office
Prior art keywords
composition
earner
vehicle
oil
silicone gel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP99907009A
Other languages
German (de)
English (en)
Other versions
EP0979067B1 (fr
Inventor
Amit R. Shah
Linda Najdek
Jeffrey Ehrenberg
Nicole B. Huggins
Aya Shidara
Carl C. Orr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EL Management LLC
Original Assignee
EL Management LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EL Management LLC filed Critical EL Management LLC
Publication of EP0979067A2 publication Critical patent/EP0979067A2/fr
Application granted granted Critical
Publication of EP0979067B1 publication Critical patent/EP0979067B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31—Hydrocarbons
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
    • A61K8/585—Organosilicon compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
    • A61Q1/06—Lipsticks
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin

Definitions

  • the invention relates to cosmetic compositions. More specifically, the invention relates to cosmetic compositions comprising an organopolysiloxane elastomer and a hydrocarbon vehicle which results in a makeup cosmetic product that feels soft and powdery on the skm and is transfer resistant.
  • silicone fluids in makeup products. Silicones provide an elegant feel in that the makeup containing them goes onto the skm smoothly, with an excellent slip, and yet does not produce the greasy, heavy feel that non-silicone oils frequently have. Despite the excellent characteristics of silicone oil, especially that of low viscosity silicone oils which give a less sticky fresh feeling, it does not provide a fresh feeling on the skm.
  • Silicone oils remain attractive because of their tendency to produce a very shiny appearance on the skm.
  • a significant amount of shininess is not desired. Therefore, attempts have been made using higher levels of pigment. The problem that frequently occurs is that the makeup is heavy and cakey, and does not feel good on the skm of a majority of consumers
  • matte makeup has been achieved by the addition of solid powders, such as mica, silica, talc, and the like, to the formulation.
  • solid powders such as mica, silica, talc, and the like.
  • counteracting the shine produced tends to be more difficult than with more conventional cosmetic oils, thus requinng the addition of even greater amounts of solid fillers.
  • the larger proportion of solids in a formulation results in the heavy, draggy feel on the skin. Therefore, the benefit of the silicone oil is to some extent canceled.
  • the present invention provides such a method, as well as non-silicone oil based formulations which are transfer resistant on the skm.
  • the invention relates to cosmetic compositions for topical application to the skm.
  • the composition comp ⁇ ses an organopolysiloxane elastomer dispersed in a hydrocarbon vehicle which produces a powdery feeling on the skm.
  • the present invention also includes a method of producing a cosmetic which comp ⁇ ses adding to a compatible cosmetically acceptable earner a silicone gel comp ⁇ smg an organopolysiloxane elastomer dispersed in a hydrocarbon vehicle.
  • a cosmetic composition having long-lasting and unique tactile properties is provided in the present invention.
  • the composition compnses an organopolysiloxane elastomer dispersed in a hydrocarbon vehicle.
  • the elastomer dispersed m the hydrocarbon vehicle together form a silicone gel that is in turn, combined with a compatible cosmetically acceptable earner to produce a cosmetic composition that possesses a characteristic soft and powdery feel on the skm and is also transfer resistant. Therefore, the present invention also includes a cosmetic composition compnsmg the silicone gel in combination with the compatible cosmetically acceptable earner.
  • hydrocarbon vehicle as used m the present specification and claims is any cosmetically acceptable hydrocarbon oil.
  • the hydrocarbon vehicle can be a volatile or a non-volatile hydrocarbon oil.
  • Suitable volatile oils include straight (i.e., linear) or branched chain volatile hydrocarbon oils having from 1 to 14 carbon atoms, such as decane, dodecane, tndecane, tetradecane, and C8-20 isoparaffins; non-volatile hydrocarbons include but are not limited to isoparaffins, squalane, or petrolatum, or mixtures thereof.
  • the hydrocarbon vehicle is present in an amount of about 5 to about 60 percent by weight of the silicone gel. In a preferred embodiment, the hydrocarbon vehicle is isododecane.
  • the silicone gel of the present invention is prepared by dispersing in the hydrocarbon vehicle, the organopolysiloxane elastomer.
  • Gels of this type have been previously disclosed for use in water- m-oil emulsion products, for example in US Patent No. 5,599,533. Silicone gels have also been reported in anhydrous non-silicone oil-based products in US Patent No. 5,266,321. However, they have not previously been dispersed in a hydrocarbon vehicle and combined m makeup products with any compatible earner, and the ability of such products to provide a soft powdery feel on the skm has not previously been disclosed.
  • the gels i.e., the elastomer and the hydrocarbon vehicle
  • any compatible earner yields a cosmetic product that feels soft and powdery on the skm and is transfer resistant.
  • the gels combined with the compatible earner permit the production of "soft-focus" and matte-finish products without feeling heavy, greasy or oily, or cakmg or dragging on the skin caused by the addition of solids and fillers.
  • the silicone gel is present in an amount of about 5 to about 60 percent by weight of the composition.
  • the elastomer of the present invention is a reaction product of an organopolysiloxane having an unsaturated group bound to a terminal silicon atom and an organohydrogensiloxane which reaction product is at least partially cross-linked.
  • Cross-links are junctions of polymer strands m a three-dimensional structured network. They are like long-chain branches which are so numerous that a continuous insoluble gel is formed.
  • An elastomer is generally, a chain polymer having a degree of cross-linking sufficient to provide a gel-like substance. Such an elastomer may have a viscosity of about 100,000 to 1,000,000 cps.
  • the elastomer can be cured by mechanisms known in the art such as addition-type or condensation-type.
  • the organopolysiloxane elastomers of the present invention are hetero-cham polymers.
  • Preferred organopolysiloxane are ones which are at least partially cross-linked addition reaction products, i.e., hydrosilation products, or addition polyme ⁇ zation products, of an organopolysiloxane having unsaturated groups, such as vinyl or allyl, preferably bonded to at least one terminal silicon atom, and another silicone compound capable of participation in the addition reaction, such as an organohydrogenpolysiloxane
  • organopolysiloxane elastomers having a partial three- dimensional cross-lmked structure are desc ⁇ bed, for example, m US Patent No. 5,266,321, the contents of which are incorporated herein by reference.
  • other suitable elastomer matenals are disclosed in, for example, US Patent Nos. 4,980,167, 4,742,142, EP 790055, and EP 295886.
  • the chosen elastomer is dispersed m the hydrocarbon vehicle by known homogenization techniques.
  • the elastomer dispersed in the vehicle provides a soft, stable viscous gel, or gel-like matenal.
  • the gel can be purchased premade, with the elastomer already dispersed m the vehicle.
  • the silicone gel is a premade product that is offered commercially under the name Gransil (e.g., Gransil IDS) from Grant Industnes, Inc., Elmwood Park, New Jersey, or it may be obtained from other commercial sources. A mixture of these commercial products may also be used.
  • Gransil e.g., Gransil IDS
  • the amounts of elastomer and vehicle may vary, depending on the desired viscosity, but generally they should be in the range of about 35 to about 65 percent for the elastomer and the vehicle, respectively. In a preferred embodiment, they are in about a 50:50 ratio.
  • the gel in the preferred embodiment, is polys ⁇ hcone-11, which is also a commercially available product.
  • compatible earner in the present specification and claims is meant any cosmetically acceptable oil which is compatible with the silicone gel. The earner compnses, in the composition as a whole, preferably at least about 0.5 to about 60 percent by weight.
  • the compatible earner is one that does not interfere with the soft powdery feel of the silicone gel comp ⁇ smg the organopolysiloxane elastomer in combination with the hydrocarbon vehicle.
  • the compatible earner can be the same as or different than the hydrocarbon vehicle.
  • a preferred compatible earner can be any cosmetically acceptable hydrocarbon oil in which the elastomer is dispersible.
  • the hydrocarbon oil can be volatile or non-volatile
  • the volatile hydrocarbon oil can be a linear or branched chain hydrocarbon having at least about 1 to about 14 carbon atoms.
  • the hydrocarbon oil is volatile and more preferably, it is isododecane.
  • the earner can also be any cosmetically acceptable silicone oil.
  • the silicone oil can be any volatile or non-volatile silicone, or any combination thereof.
  • Suitable volatile oils include cyclic and linear silicones, such as hexamethylcyclot ⁇ siloxane, octamethylcyclotetrasiloxane, and decamethylcyclopentasiloxane or volatile linear dimethylpolysiloxanes; suitable non-volatile silicones include but are not limited to dimethicone, dimethiconol, phenyl t ⁇ methicone, simethicone, organomodified versions of any of these, or mixtures thereof.
  • the silicone oil may be present m an amount of at least about 0.5 to about 10 percent when combined with hydrocarbon oil.
  • oils or oil-like emollients may be employed, m which case they may be present m an amount of about 1 to about 10 percent by weight of the composition.
  • suitable oils or oil-like emollients, as well as other optional ingredients can be found in the International Cosmetic Ingredient Handbook, CTFA, 1996, the contents of which are incorporated herein by reference.
  • Useful materials include, but are not limited to, castor oil, coconut oil, corn oil, jojoba oil, cottonseed oil, soybean oil, walnut oil, wheat germ oil, sunflower seed oil, palm kernel oil, calendula oil, CIO- 18 tnglycendes, lanolin and lanolm de ⁇ vatives, ll pe butter, shea butter; esters having the formula RCO-OR' wherein RCO represents a carboxylic acid radical and OR' represents an alcohol residue, such as isodecyl neopentanoate, tndecyl octanoate, cetyl palmitate, cetyl octanoate, cetyl stearate, cetyl my ⁇ state, isopropyl palmitate, isopropyl mynstate, polyglyceryl-2- ⁇ sostearate, neopentyl glycol distearate, isodecyl oleate, decyl isostearate, dns
  • the benefit of combining the gel in a hydrocarbon oil earner is obtained in any type of anhydrous composition.
  • the compositions of the present mvention can be used in any type of makeup or, skm or sun care product. Typical examples include foundations, eyeshadows, eyeliners, mascaras, blushes, powders, lipsticks, pglosses, lip paints, oil control skm mattifiers, and sunscreen lotions. Alternately, however, the gel may form part of the oil phase of a water-m-oil or oil-m- water emulsion. In formulating the product, the silicone gel is simply added to a compatible cosmetically acceptable earner.
  • the elastomer component of the gel can be added directly to the cosmetically acceptable earner, if the earner contains a hydrocarbon oil.
  • the makeup compositions prepared in this way possess a significant level of transfer resistance, this property can be further improved by the addition of a film forming agent.
  • another optional component of the formulation is one or more film forming agents. The use of a film former improves the wear of the composition, and can confer transfer-resistance to the makeup product.
  • useful film forming agents include natural waxes, polymers such as polyethylene polymers and copolymers of polyvmylpyrrohdone ("PVP"), dimethicone gum, and resms, such as shellac, polyterpenes, and various silicone res s.
  • PVP polyvmylpyrrohdone
  • resms such as shellac, polyterpenes, and various silicone res s.
  • a particularly preferred film former is tnmethylsiloxysilicate and may be present in an amount of from about 0.1 to about 20 percent by weight of the composition.
  • waxes may also be desirable to incorporate one or more waxes the composition, particularly if the product is a lipstick or other makeup products in the form of a stick.
  • the term "wax” will be understood to encompass not only waxes in the traditional sense, i.e., those plant, animal or mineral waxes containing p ⁇ ma ⁇ ly esters of higher fatty acids and alcohols, free higher acids and alcohols, and saturated hydrocarbons, but also synthetic resinous products having a wax-like, i.e , hard, bnttle, relatively non-greasy texture at room temperature, such as silicone waxes.
  • suitable waxes include, but are not limited to, carnauba wax, candehlla wax, beeswax, microcrystalline wax, polyethylene, japan wax, synthetic wax, shellac wax, spermaceti, lanolm wax, ozokerite, bran wax, ceresm wax, bayberry wax, paraffin, rice wax, mink wax, montan wax, ouncoury wax, jojoba wax, and the like.
  • Additional preferred components of the cosmetic compositions of the invention include one or more pigments.
  • Any cosmetically acceptable pigment either organic, inorganic, or combinations thereof, can be used in the 'makeup compositions of the invention.
  • useful inorganic pigments include iron oxides (yellow, red, brown or black), ultrama ⁇ nes, chromium hydroxide green, chromium oxide, titanium dioxide (white), feme ferrocyanide, feme ammonium ferrocya de, and mixtures thereof.
  • the organic pigments include natural colorants and synthetic monome ⁇ c and polymenc colorants.
  • Exemplary are aromatic compounds such as azo, tnphenylmethane, mdigo, anthraqumone, and xanthine dyes, which are referred to as D&C or FD&C pigments.
  • D&C or FD&C pigments are also useful.
  • lakes which are pigments formed by the precipitation and absorption of organic dyes in an insoluble base, such as alumina, banum, or calcium hydrates.
  • Particularly preferred lakes are pnmary FD&C or D&C Lakes and blends thereof. Pigment concentrations will vary depending upon the color of the final product, but generally will be in the range of from about 0.1 to about 30 percent by weight of the total composition.
  • the composition can also contain small amounts of fillers or powders.
  • fillers or powders examples of such silica, talc, mica, starch, nylon, kaolin, bismuth oxychlonde, or coated versions of each of these, for example, with lecithin, silicones, ammo acids, fatty acids, fatty alcohols, or metallic soap coatings.
  • composition can contain other optional components including, but not limited to, oil soluble sunscreens, such as octyl methoxycinnamate; particulate sunscreens such as zinc oxide; oil- soluble antioxidants and/or preservatives, such as butylated hydroxytoluene ("BHT”); chelatmg agents such as disodium ethylene diamine tetra acetic acid (“EDTA”); fragrances (such as pinene); flavonng agents; waterproofing agents (such as PVP/eicosene copolymer); surfactants, such as silicone copolyols or fatty acid glycerol esters; and oil-soluble actives, such as tocopherol and its denvatives or ret ol and its denvatives; and the like.
  • oil soluble sunscreens such as octyl methoxycinnamate
  • particulate sunscreens such as zinc oxide
  • oil- soluble antioxidants and/or preservatives such as butylated
  • the compositions of the present invention are in the form of a foundation.
  • the foundation is a light and creamy substance similar to that of a somewhat dry chocolate mousse or a hair mousse.
  • the texture of the foundations changes. It becomes powdery to the touch and feels light, soft and powdery on the skm.
  • Particularly preferred are cosmetic compositions compnsmg tnmethylsiloxysiloxate as the film forming agent for the hydrocarbon oil cosmetically acceptable earner.
  • compositions are in the form of a lip paint.
  • the lip pamt is easily applied and has a viscosity such that it can be applied to the lip without running. Similar to the foundation, as it is applied to the lip, the texture of the lip pamt transforms and feels soft and velvety on the lips.
  • the invention is further illustrated by the following non-limiting example.
  • a makeup foundation according to the present invention containing a silicone gel combined with a compatible cosmetically acceptable earner is tested using a panel of 20 female individuals.
  • Qualifying panelists are selected from ages 18 to 55. They have normal, normal-oily, or oily facial skm, have a light to medium skm tone, and are regular users of a liquid foundation at least 5 days a week. Chosen panelists participate m an unidentified one day monadic study and complete a questionnaire at the close of the study. The questionnaire allows the panelists to rate vanous properties of the composition of the present invention. The panelists respond to questions about the properties of the composition using a five point scale (e.g. ranging from excellent/very good to poor).
  • Vanous portions of the questionnaire correspond to different characteristics of the composition.
  • a Performance Rating portion of the questionnaire examines the ability of the composition to maintain its appearance on the skm throughout the day, the texture of the composition, whether the composition feels greasy or oily on the skm, whether the composition is transfer-resistant, and whether the composition is long weanng (i.e. whether the composition lasts over a long penod of time). The scale for this portion ranges from excellent to poor.
  • a Texture Rating examines in more detail the texture of the composition. The panelists rate how smooth or soft, lightweight, powdery, or greasy or oily the composition is. The five point scale for this portion is divided into catego ⁇ es of extremely, very, somewhat, slightly and not at all.
  • an Application Rating portion of the questionnaire allows the panelists to rate the slip and drag of the composition as it is applied to the skin. This rating portion is divided into a five point scale ranging from much too much slip, somewhat too much slip, just ⁇ ght - neither slips or drags, somewhat too much drag, to much too much drag. Further still, a Finish Rating examines whether the composition has a finish that is matte or shmy. The five point scale for this rating is very matte, somewhat matte, neither matte or shiny, somewhat shmy, and very shmy.
  • the results of the questionnaire for the Performance Rating indicate that 14 out of 20 panelists rate the composition excellent/very good for product texture, feeling lightweight on the skm, not feeling greasy/oily, being transfer-resistant and being long weanng, and that 15 out of 20 rate the composition as excellent/very good for maintaining appearance throughout the day.
  • 18 out of 20 panelists find that the composition is extremely/very smooth or soft; 15 out of 20 panelists find the composition to be extremely/very lightweight; and 11 out of 20 panelists rate the composition extremely/very powdery.
  • the Application Rating portion reveals that the composition, according to 15 out of 20 panelists, is just nght - neither slips nor drags. Finally, 18 out of 20 of the panelists find the composition to be very or somewhat matte.
  • the soft powdery feel conferred by the composition of the invention is evaluated by companng the present invention with a current brand of foundation used by the panelists which is otherwise a comparable makeup formulation.
  • a portion of the questionnaire is entitled Compared to Brand Used Most Often and has a five point scale divided into sections of liked much more, somewhat more, same as, somewhat less, and much less.
  • the results show the makeup composition of the present invention is liked much more or somewhat more by 14 out of 20 panelists for not feeling greasy or oily and for its texture.
  • Silicone Gel 30 (50:50 organopolysiloxane elastomer m isododecane)

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
EP99907009A 1998-02-27 1999-02-12 Procédé pour la préparation de compositions cosmétiques à base d'hydrocarbure et leurs utilisations. Expired - Lifetime EP0979067B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/032,614 US6387405B1 (en) 1998-02-27 1998-02-27 Velvety hydrocarbon based cosmetic compositions
US32614P 1998-02-27
PCT/US1999/003151 WO1999043297A2 (fr) 1998-02-27 1999-02-12 Compositions cosmetiques veloutees a base d'hydrocarbures

Publications (2)

Publication Number Publication Date
EP0979067A2 true EP0979067A2 (fr) 2000-02-16
EP0979067B1 EP0979067B1 (fr) 2007-04-18

Family

ID=21865868

Family Applications (1)

Application Number Title Priority Date Filing Date
EP99907009A Expired - Lifetime EP0979067B1 (fr) 1998-02-27 1999-02-12 Procédé pour la préparation de compositions cosmétiques à base d'hydrocarbure et leurs utilisations.

Country Status (10)

Country Link
US (1) US6387405B1 (fr)
EP (1) EP0979067B1 (fr)
JP (1) JP3604154B2 (fr)
KR (1) KR100360060B1 (fr)
AT (1) ATE359849T1 (fr)
AU (1) AU743587B2 (fr)
CA (1) CA2284885C (fr)
DE (1) DE69935827T2 (fr)
ES (1) ES2285831T3 (fr)
WO (1) WO1999043297A2 (fr)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2781146B1 (fr) * 1998-07-17 2000-08-18 Oreal Composition cosmetique comprenant des pigments, un agent antitranspirant et un organopolysiloxane solide elastomerique partiellement reticule, utilisation d'une telle composition
ATE311847T1 (de) 2000-07-10 2005-12-15 Procter & Gamble Kosmetische zusammensetzungen
AU2001271929A1 (en) 2000-07-10 2002-01-21 The Procter And Gamble Company Transfer-resistant makeup removing compositions
US7241835B2 (en) * 2001-05-16 2007-07-10 General Electric Company Cosmetic compositions comprising silicone gels
US20030091522A1 (en) * 2001-08-24 2003-05-15 Collins Carol J. Reduced-wax mascara compositions
GB0125778D0 (en) 2001-10-26 2001-12-19 Procter & Gamble Silicone elastomer emulsion cosmetic composition comprising colorant inclusive internal phase
US6783766B2 (en) 2002-03-06 2004-08-31 Dow Global Technologies Inc. Process for preparing a cosmetic formulation
US6887934B2 (en) 2002-08-26 2005-05-03 Dow Corning Corporation Resin modified elastomers
US6770708B2 (en) 2002-08-27 2004-08-03 Dow Corning Corporation Silicone elastomers compositions
US6936686B2 (en) * 2002-12-11 2005-08-30 Nutech Corporation Cross-linked silicone gels; products containing the same; and methods of manufacture thereof
US20050031658A1 (en) * 2003-08-01 2005-02-10 L'oreal Cosmetic skin treatment process and device for implementing such a process
US20080145443A1 (en) * 2006-12-15 2008-06-19 Kimberly-Clark Worldwide, Inc. Diaper rash composition and method
CA2681802C (fr) * 2007-02-16 2015-12-08 Elevance Renewable Sciences, Inc. Compositions de cire et leurs procedes de fabrication
EP2011471A1 (fr) * 2007-07-02 2009-01-07 Johnson & Johnson Consumer France SAS Compositions d'huile mousseuses
US20100322877A1 (en) * 2007-10-22 2010-12-23 Zofchak Albert A Silicone elastomers in cosmetic esters
CN102026682A (zh) * 2007-12-05 2011-04-20 莱雅公司 使用硅氧烷树脂和成膜聚合物的美容性化妆和/或护理方法
US8865194B1 (en) 2007-12-20 2014-10-21 Theraplex Company, LLC Reducing tackiness and greasiness of petrolatum-like materials
FR2926022B1 (fr) * 2008-01-08 2013-02-15 Oreal Composition cosmetique, notamment de maquillage des matieres keratiniques, a proprietes cosmetiques ameliorees.
FR2944289B1 (fr) * 2009-04-10 2011-12-23 Biosynthis Sarl Composition huileuse volatile
CA2799512C (fr) 2010-05-17 2018-07-24 Mary Kay Inc. Compositions topiques a base de gel
ES2676426T3 (es) * 2010-09-20 2018-07-19 L'oreal Composición cosmética acuosa que comprende alquilcelulosa
JP5774706B2 (ja) 2010-09-20 2015-09-09 ロレアルＬ′Ｏｒｅａｌ アルキルセルロースを含む水性化粧料組成物
FR2985176B1 (fr) 2012-01-02 2015-05-29 Oreal Composition cosmetique liquide aqueuse comprenant de l'alkylcellulose, des huiles non volatiles et au moins un tensioactif
KR20150136077A (ko) * 2013-03-10 2015-12-04 페리테크 파마 엘티디. 국소 조성물 및 국소 질환의 치료 방법
GB2537648B (en) * 2015-04-22 2020-01-08 Cosmetic Warriors Ltd Composition
JP6829581B2 (ja) * 2015-11-27 2021-02-10 花王株式会社 油性化粧料
KR102108114B1 (ko) 2015-12-21 2020-05-11 로레알 알킬셀룰로오스, 불상용성 탄화수소 및 실리콘 오일을 포함하는 조성물 및 이의 이용 방법
US10687601B2 (en) 2016-07-29 2020-06-23 L'oreal Cosmetic care system
US10688034B2 (en) 2016-07-29 2020-06-23 L'oreal Long-wearing, transfer-resistant cosmetic composition having improved tackiness
US12318469B2 (en) 2020-06-30 2025-06-03 L'oréal Cosmetic compositions capable of forming a multilayer structure after application to a keratinous material containing a combination of silicone resins

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62243621A (ja) 1986-04-17 1987-10-24 Toray Silicone Co Ltd シリコ−ンゴム粒状物の製造方法
JPS63313710A (ja) 1987-06-16 1988-12-21 Toray Silicone Co Ltd 洗顔化粧料
US5266321A (en) 1988-03-31 1993-11-30 Kobayashi Kose Co., Ltd. Oily make-up cosmetic comprising oil base and silicone gel composition
JPH0753646B2 (ja) 1989-01-31 1995-06-07 東レ・ダウコーニング・シリコーン株式会社 化粧料
JPH07258028A (ja) 1994-03-16 1995-10-09 Shiseido Co Ltd メーキャップ化粧料
US5599533A (en) 1994-12-15 1997-02-04 Estee Lauder, Inc. Stable water-in-oil emulsion system
FR2744911B1 (fr) 1996-02-19 1998-03-20 Oreal Utilisation d'un organopolysiloxane solide elastomere associe a une phase grasse pour la preparation d'une composition ou dans une composition de soin ou de maquillage pour matifier la peau
US5849314A (en) 1996-06-28 1998-12-15 Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. Anhydrous cosmetic compositions
FR2754175B1 (fr) * 1996-10-07 1999-07-02 Oreal Utilisation d'un organopolysiloxane de nature elastomerique associe a une phase organique dans un produit de demaquillage des ongles
FR2757379B1 (fr) 1996-12-24 1999-01-15 Oreal Composition gelifiee d'organopolysiloxane elastomerique associe a une phase grasse pour le demaquillage des yeux
FR2757380B1 (fr) 1996-12-24 1999-01-29 Oreal Composition de maquillage ou de soin, sans transfert, contenant un organopolysiloxane et une phase grasse
US6027738A (en) * 1997-10-31 2000-02-22 E-L Management Corp. Anhydrous matte cosmetic

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9943297A2 *

Also Published As

Publication number Publication date
AU743587B2 (en) 2002-01-31
ATE359849T1 (de) 2007-05-15
JP2001507377A (ja) 2001-06-05
KR100360060B1 (ko) 2002-11-04
WO1999043297A3 (fr) 1999-10-28
KR20010006242A (ko) 2001-01-26
US6387405B1 (en) 2002-05-14
AU2678299A (en) 1999-09-15
DE69935827D1 (de) 2007-05-31
WO1999043297A2 (fr) 1999-09-02
CA2284885C (fr) 2007-09-18
EP0979067B1 (fr) 2007-04-18
JP3604154B2 (ja) 2004-12-22
CA2284885A1 (fr) 1999-09-02
ES2285831T3 (es) 2007-11-16
DE69935827T2 (de) 2007-12-27

Similar Documents

Publication Publication Date Title
AU743587B2 (en) Velvety hydrocarbon based cosmetic compositions
JP3034490B2 (ja) 弗素含有化合物またはシリコーンを含有し、改善された快適感を呈する転移しない局所用組成物およびその使用
KR100602037B1 (ko) 무수 매트 화장품
JP4021561B2 (ja) フルオロシリコーンを含有する化粧料または皮膚科学的組成物
JP3242874B2 (ja) オルガノポリシロキサン及び脂肪相を含む色移りしないメークアップもしくはケア用組成物
AU679863B2 (en) Anhydrous, water-resistant cosmetic composition
DE69903697T2 (de) Zusammensetzung zum Schminken oder zur Pflege ohne Transfer, die ein geradkettiges flüchtiges Silicon enthält
US6403704B1 (en) Composition comprising particles of a hydrophilic polyorganosiloxane suspended in an aqueous phase
EP0548694B2 (fr) Composition cosmétique solide à base d'huile
JP3061766B2 (ja) アルキルポリシロキサンを含む色移りしないメーキャップまたはケア用化粧料
JP2000309504A (ja) 親水性オルガノポリシロキサンを含有するメークアップまたは手入れ用組成物
US6440430B1 (en) W/O emulsion composition comprising such an mulsion and cosmetic pharmaceutical or hygiene use thereof
US20040170588A1 (en) W/O emulsion, composition comprising such an emulsion and cosmetic, pharmaceutical or hygiene use thereof
USRE39218E1 (en) Anhydrous and water-resistant cosmetic compositions
JP2001048724A (ja) 欠点を目立たなくさせ皮膚をマットにするための揮発性フルオロ油の使用と該フルオロ油を使用する美容処理方法
HK1025513B (en) Anhydrous matte cosmetic
MXPA97004985A (en) Cosmetic bar compositions resistant to transfer with semi-m finish

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE

17P Request for examination filed

Effective date: 20000428

17Q First examination report despatched

Effective date: 20021126

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

RIC1 Information provided on ipc code assigned before grant

Ipc: A61K 8/31 20060101ALI20060725BHEP

Ipc: A61K 8/89 20060101ALI20060725BHEP

Ipc: A61Q 19/00 20060101AFI20060725BHEP

RTI1 Title (correction)

Free format text: PROCESS FOR THE PREPARATION OF A HYDROCARBON BASED COMPOSITION AND THE USE THEREOF

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20070418

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20070418

Ref country code: CH

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20070418

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REF Corresponds to:

Ref document number: 69935827

Country of ref document: DE

Date of ref document: 20070531

Kind code of ref document: P

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20070718

ET Fr: translation filed
PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20070918

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

NLV1 Nl: lapsed or annulled due to failure to fulfill the requirements of art. 29p and 29m of the patents act
REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2285831

Country of ref document: ES

Kind code of ref document: T3

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20070418

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20070418

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20070418

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20080121

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20070719

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080228

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080212

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20070418

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080212

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 18

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 19

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 20

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20180301

Year of fee payment: 20

Ref country code: GB

Payment date: 20180122

Year of fee payment: 20

Ref country code: DE

Payment date: 20180122

Year of fee payment: 20

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20180123

Year of fee payment: 20

Ref country code: IT

Payment date: 20180122

Year of fee payment: 20

Ref country code: BE

Payment date: 20180124

Year of fee payment: 20

REG Reference to a national code

Ref country code: DE

Ref legal event code: R071

Ref document number: 69935827

Country of ref document: DE

REG Reference to a national code

Ref country code: GB

Ref legal event code: PE20

Expiry date: 20190211

REG Reference to a national code

Ref country code: BE

Ref legal event code: MK

Effective date: 20190212

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION

Effective date: 20190211

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20220127

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION

Effective date: 20190213