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EP0956321A1 - Composition de rev tement pour des recipients alimentaires - Google Patents

Composition de rev tement pour des recipients alimentaires

Info

Publication number
EP0956321A1
EP0956321A1 EP97953778A EP97953778A EP0956321A1 EP 0956321 A1 EP0956321 A1 EP 0956321A1 EP 97953778 A EP97953778 A EP 97953778A EP 97953778 A EP97953778 A EP 97953778A EP 0956321 A1 EP0956321 A1 EP 0956321A1
Authority
EP
European Patent Office
Prior art keywords
weight
coating composition
water
composition according
coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP97953778A
Other languages
German (de)
English (en)
Inventor
Gerrit Jungheim
Jürgen Erwin LEMKE
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PPG Industries Ohio Inc
Original Assignee
PPG Industries Ohio Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by PPG Industries Ohio Inc filed Critical PPG Industries Ohio Inc
Publication of EP0956321A1 publication Critical patent/EP0956321A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/06—Polyurethanes from polyesters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
    • C08G18/625—Polymers of alpha-beta ethylenically unsaturated carboxylic acids; hydrolyzed polymers of esters of these acids
    • C08G18/6254—Polymers of alpha-beta ethylenically unsaturated carboxylic acids and of esters of these acids containing hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062—Copolymers with monomers not covered by C09D133/06
    • C09D133/066—Copolymers with monomers not covered by C09D133/06 containing -OH groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes

Definitions

  • the invention relates to a coating composition for food containers, comprising a binder polymer from the group 'Water-soluble or water-dispersible polyester resin; water-soluble or water-dispersible acrylic polymer" or mixtures thereof, a crosslin ing resin, a solvent and, if desired, customary auxiliaries. Adjustment to a viscosity optimal for the processing of the coating composition can be made with the water and/or with the organic solvent. It is understood that the resulting binder polymer from the group 'Water-soluble or water-dispersible polyester resin; water-soluble or water-dispersible acrylic polymer" or mixtures thereof, a crosslin ing resin, a solvent and, if desired, customary auxiliaries. Adjustment to a viscosity optimal for the processing of the coating composition can be made with the water and/or with the organic solvent. It is understood that the resulting
  • the binder polymer generally has a considerable number of OH groups capable of bond formation, by means of which, in conjunction with the crosslinking resin, it is possible to achieve crosslinking and, accordingly, curing.
  • coatings produced from a coating composition are required to have particular properties.
  • suitability for foods per se When used as an (external, for example) coating on food containers, such as cans, for example, suitability for foods per se must be accompanied by suitability for germ elimination stages in food processing, in particular for both interior and exterior can coatings.
  • a germ elimination stage of this kind usually operates by pasteurization. In pasteurization, the contents (together with the container) are brought to temperatures in the range from 60°C to 80°C, but at any rate below 100°C, and are held at these temperatures for a certain time. By this means, microbes in the foods are damaged or killed. Pasteurization does not, however, lead to a microbe-free product but leads merely
  • a can In a sterilization stage, for the purpose of virtually complete killing of microbes, a can is heated at temperatures of more than 120°C, in many cases even more than 130°C, for at least several minutes, for example 30 minutes. If a coating is to be exposed not to pasteurization but to a sterilization stage, then the coating must be so designed that
  • the coatings must meet the particular requirements of the manufacturing processes of sheet-metal packaging, for example on Rutherford machines.
  • the coatings are required to withstand shaping procedures such as folding, crimping, drawing, etc.
  • they should be of high gloss, resistant to abrasion and readily printable, and should show good adhesion, a smooth surface texture (i.e. no craters) and a good humidity effect. What has been said applies especially in the case of use as a non-varnish exterior coating, i.e. without a final colourless protective coat.
  • Food container coating compositions of the basic composition specified at the outset, albeit based on organic solvents, are known from the art.
  • the resin used for curing the hydroxyl-containing binder polymer is a melamine or benzoguanamine resin.
  • These known coating compositions have become well established in food technology, and indeed for containers including those subjected to a sterilization stage. On environmental protection grounds, and grounds of workplace safety, however, it is desirable to replace coating compositions comprising organic solvents by those comprising water as solvent.
  • the document EP 0006336 Bl discloses a food container coating composition based on a hydroxyl-containing binder polymer which is likewise cured with an amino resin or phenolic resin, but which is aqueous. This known coating composition is suitable at best for pasteurization stages, but does not meet all requirements, especially with regard to hardness before and after sterilization stages.
  • the document PCT EP90/00283 discloses a food container coating composition in which the curing of the hydroxyl-containing binder polymer takes place with the aid of blocked di- or polyisocyanates.
  • Polyisocyanate resins are not employed for this purpose.
  • the solvent is purely organic. Consequently, this known coating composition is subject to the environmental concerns already addressed above.
  • the document DE-A 2507884 discloses aqueous coating composition based, inter alia, on hydroxyl-containing polymers which can be cured by means of blocked polyisocyanates. Polyisocyanate resins are not employed. These known coating compositions do not meet the requirements of the food industry from a technical standpoint, especially after exposure under sterilization conditions of the coatings produced therefrom.
  • the documents DE 4421823 Al and EP 0358979B1 disclose aqueous coating compositions for the automotive industry which are based on hydroxyl-containing polymers that can be cured with polyisocyanates containing free NCO groups.
  • the polyisocyanates are not resins.
  • These coating compositions known from a different sector of technology, can in any case not be used for food containers in terms of their processing properties, the properties of the coatings produced therefrom, and, in particular, their food suitability.
  • the coating technology is a different one.
  • the invention is based on the technical problem of providing a coating composition with which it is possible to produce coatings which, even subsequent to sterilization stages, meet all requirements in terms of hardness, elasticity and water absorption behaviour but which nevertheless meet heightened environmental requirements through the use of water as solvent.
  • a coating composition for food containers comprising a) 20-70% by weight of a binder polymer from the group 'Water-soluble or water-dispersible polyester resin; water-soluble or water- dispersible acrylic polymer" or mixtures thereof, b) 5-20% by weight of a crosslinking urethane resin which is virtually free from free NCO groups, c) 20-
  • the coating composition can be completed by further additives, for example fillers.
  • the invention is based on the surprising finding that, with the use of crosslinking urethane resins which per se are uncommon for the above-mentioned water-based binder polymers, and which are virtually free from free NCO groups, it is possible to provide a water-based coating composition which meets all requirements when the urethane resin is combined with the binder polymer in the manner indicated. This specific combination also, in particular, ensures sufficient crosslinking and thus sufficient hardness of the finished coating if the OH number and the content of NCO groups are within the stated ranges.
  • Crosslinking urethane resins which are virtually free from free NCO groups are also referred to as blocked polyisocyanate resins.
  • composition can, moreover, be applied particularly well with the Rutherford
  • a novel coating composition produces a coating which meets all of the requirements despite the very short baking times in this case, for example 30 s (at a maximum article temperature of about 190°C).
  • a particularly important advantage is that in conjunction with the above positive properties a coating produced from a novel coating composition, even after exposure to the severe conditions of sterilization stages, meets all requirements in terms of hardness, solvent resistance and adhesion (both to the
  • the literature reference DE-A-4209248 does indeed disclose mixing a binder polymer with a crosslinking urethane resin which is virtually free from free NCO groups, the coating composition being obtained in aqueous solution or dispersion.
  • the binder polymer is a very specific graft copolymer on
  • invention is the complex and expensive preparation of the binder polymer.
  • a novel coating composition preferably contains 25-35% by weight of the binder polymer, based on the solids content of the binder, 8-15% of urethane resin, 61- 34% of water, 1-15% by weight, preferably 5-15% by weight, of an organic solvent and 0.3-1% by weight of other auxiliaries.
  • the novel coating composition can be designed in various ways in terms of the binder polymer.
  • the polyester resin used can be an acrylic-modified, saturated polyester resin whose preparation is conducted with the proviso that the polyester resin has an OH number of 30 - 120 mg of KOH/g, preferably of 35 - 45 mg of KOH/g, and an acid number of 40 - 80 mg of KOH/g, preferably of 45 - 55 mg of KOH/g. It is advantageous if the polyester resin has a viscosity of 500 - 900 mPa.s, measured at 23°C and 50% by weight in butyl glycol as solvent.
  • polyester resins examples include those from the group 'hydroxyl-containing polyesters, hydroxyl-containing acrylic-modified polyesters, hydroxyl-containing epoxy-modified polyesters" or mixtures thereof. They can also be employed, if desired, in combination with epoxy resins and/or hydroxyl- containing acrylate polymers or copolymers.
  • the polyester resins are prepared, for example, by customary techniques of polyesterification reactions, by esterifying 9
  • aromatic and/or aliphatic dicarboxylic acids dicarboxylic anhydrides, tricarboxylic anhydrides and/or tetracarboxylic mono- and dianhydrides with aliphatic, cyclo- aliphatic and/or aromatic mono-, di- and/or polyols.
  • carboxylic acids suitable for the synthesis of the polyesters are phthalic, isophthalic, terephthalic, tetrahydrophthalic and hexahydrophthalic acids, dimethyl terephalate, trimellitic acid, trimellitic anhydride, adipic, azelaic, sebacic, maleic and glutaric acids and also dimeric and/or trimeric fatty acids.
  • alcohol components which can be employed are aliphatic monools having 4 to 20 C atoms, 2,2-dimethyl-l,3- propanediol, ethylene glycol, diethylene glycol, 1,2- and 1,3-propylene glycol, butanediols, pentanediols, neopentyl glycol, hexane-diols, 2-methyl-l,5-pentane- diol, 2-ethyl-l,4-butane-diol, dimethylolcyclohexane, glycerol, trimethylol-ethane, trimethylolpropane, trimethylolbutane, pentaerythritol, dipentaerythritol, polycaprolactone-diols and -triols, and bisphenol A.
  • the acrylic polymer employed can be one obtainable by using methacrylic acid and ethyl acrylate as starting materials, and styrene for copolymeriza-tion, and carrying out polymerization in the presence of butyl glycol and butanol.
  • the acrylic polymer has an OH number of 10 - 100 mg of KOH/g, preferably of 25 - 35 mg of KOH/g, and a neutralization number of 40 - 100 mg of KOH/g, preferably of 65 - 75 mg of KOH/g.
  • Acrylic polymers are essentially copolymers of acrylic esters with carboxyl-containing monomers. Examples of acrylic esters which can be used are esters of acrylic or methacrylic acid with methanol, ethanol, the butanols or ethylhexanol, or mixtures thereof, and esters with higher alcohols (having for example up to 20 C atoms).
  • carboxyl-containing monomers which can be used are acrylic, methacrylic, crotonic, maleic or fumaric acid or mixtures thereof. Polymerization can also be carried out with further hydroxyl-containing compounds, such as esters of acrylic or methacrylic acid with ethanediol, propanediol or butanediol or reaction products of these acids with monoepoxide compounds or mixtures thereof.
  • further suitable comonomers are styrene, methylstyrene, vinyltoluene, acrylamide, methacrylamide and the non-etherified or etherified N- methylol compounds thereof, or mixtures of these.
  • Polymerization can be carried out using customary peroxy compounds as initiators, an example being tertiary-butyl peroxybenzoate.
  • Organic solvents employed are, for example,. aliphatic, cycloaliphatic and aromatic hydrocarbons, esters, ethers and ketones, examples being butanol, xylene, various
  • Shellsol® grades butyl glycol, ethylene glycol dibutyl ether, ethylene glycol diethyl
  • ether ethylene glycol dimethyl ether, methyl ethyl ketone, methyl n-amyl ketone, diethyl ketone, ethyl butyl ketone, diisopropyl ketone, diisobutyl ketone, ⁇ acetylacetone, methyl acetate, ethyl acetate, propyl acetate, butyl acetate, amyl
  • crosslinking urethane resin it is possible to employ blocked polyisocyanates based, for example, on polymerization products of monomeric diisocyanates having uretdione and/or biuret and/or isocyanurate and/or allophanate groups.
  • blocked polyisocyanates it is possible to use any desired polyisocyanates in which the isocyanate groups have been reacted with a compound so that the blocked polyisocyanate formed is resistant at room temperature to hydroxyl and amino groups but reacts at elevated temperatures, generally in the range from about 80°C to about 300°C.
  • In preparing the blocked polyisocyanates it is possible to use any organic polyisocyanates which are suitable for crosslinking.
  • isocyanates which contain about 3 to 38, in particular about 8 to 15, carbon atoms.
  • suitable diisocyanates are hexamethylene diisocyanate, 2,4- tolylene diisocyanate, 2,6-tolylene diisocyanate and l-isocyanatomethyl-5- isocyanato-l,3,3-trimethylcyclohexane.
  • Polyisocyanates of higher isocyanate functionality can also be used. Examples of these are trimerized hexamethylene diisocyanate and trimerized isophorone diisocyanate. Mixtures of polyisocyanates can also be utilized.
  • the organic polyisocyanates suitable as crosslinking agents in the context of the invention can also be prepolymers derived, for example, from a polyol, including a polyetherpolyol or a polyesterpolyol.
  • alcohols such as methyl, ethyl, chloroethyl, propyl, butyl, amyl, hexyl, octyl, nonyl, 3,3,5-trimethylhexyl, decyl and lauryl alcohols; cycloaliphatic alcohols such as cyclopentanol and cyclohexanol; and aromatic alkyl alcohols, such as phenyl carbinol and methylphenyl carbinol.
  • blocking agents are hydroxy amines, such as ethanolamine, oximes, such as methyl ethyl ketone oxime and acetone oxime, and aliphatic diamines,such as dibutylamine and diisopropylamine. In suitable proportions, these polyisocyanates and blocking agents can also be used to prepare the partially blocked polyisocyanates mentioned above.
  • urethane resin preferably 30-70% of the amount of urethane resin employed, is replaced by amino resins, in particular a highly methylated melamine resin.
  • Typical suitable amino resins are melamine, benzoguanamine and urea- formaldehyde resins. They are preferably used in a form etherified with lower alcohols, mostly methanol and/or butanol. Suitable amino resins are available commercially under the tradenames Cymel, Luwipal, Maprenal and Beetle, for example. Hexamethoxymethylmelamine, for example, is a suitable amino resin. / 2_
  • novel coating composition can be formulated as a colourless, i.e. as
  • a clearcoat or as a coloured coating material.
  • a customary pigment is added to the coating composition, for example TiO 2 for a white coating material.
  • a customary lubricant may be advisable as a further additive. Pigments and additives of this kind are referred to as auxiliaries.
  • pigments examples being iron oxides, colorants on an inorganic or organic basis, bentonite, carbon black,
  • auxiliaries can be added to the coating composition, examples being antifoams, stabilizers, plasticizers, light protection additives, etc.
  • the invention also relates to the use of a novel coating composition according to Claim 8, to a process for preparing a novel coating composition according to Claim 9, and to a sterilizable can according to Claim 10.
  • the can can be designed, in particular, as a two-piece can and/or may consist of sheet aluminium. Use for steel cans is likewise possible.
  • the invention is illustrated on the basis of coating compositions which represent merely exemplary embodiments.
  • Example 1 A novel coating composition was prepared from the following components: 27.96% by weight of an acrylic-modified saturated polyester resin, 9.32% by weight of butyl diglycol, 12.79% by weight of a crosslinking urethane resin which is virtually free from free NCO groups, 1.60% by weight of DMEA (dimethylethanolamine), 48.03%> by weight of demineralized water and 0.30% by weight of an auxiliary with the designation Additol XW 329 (silicone-containing coatings auxiliary, 50% strength in butyl glycol).
  • the polyester resin employed has an OH number of about 40 mg of KOH/g and a neutralization number of about 50 mg of KOH/g and also a viscosity of about 700 mPa.s (the viscosity measured at 23°C and 50% by weight in butyl glycol as solvent) and is obtainable under the
  • polyester resin relates to an 80% strength solution of the resin in ethoxypropanol/butyl glycol. This polyester resin is readily soluble in water.
  • the urethane resin employed is a urethane baking resin based on hexamethylene
  • This urethane resin is per se readily soluble only in organic solvents. It has an equivalent weight of about 378 and an NCO content of about 11.1% (blocked).
  • the viscosity at 23°C and in accordance with DIN 53019/1 (75% strength in solvent naphtha 100) is about 3250 mPa.s. It is self-evident that the data given above and in the subsequent examples for the materials employed can be varied, it being possible for the variations in the numerical parameters to be up to 50% or more, provided the fundamental structural properties indicated are unchanged. Comparative experiments revealed that a coating of the above coating composition
  • polyester/amino based coating (acrylate-modified, water-dilutable, saturated polyester resin/benzoguanamine resin): the hardness of the coating at 25°C after a sterilization stage at 129°C for 30 minutes was more than 4 H (film hardness in units of the hardness of customary commercial pencils) and was reduced virtually not at all relative to the initial hardness (customary coating: slight reduction by about 1 hardness unit).
  • the hardness of the coating in hot water at 80°C after a sterilization stage at 129°C for 30 minutes was more than 2 H and was reduced relative to the initial hardness by only about 2 hardness units (customary coating: reduction by more than 6 hardness units).
  • the solvent resistance (indicated as double strokes of a cotton wool pad soaked with MEK) after a sterilization stage at 129°C for 30 minutes was up to 60 DS (customary coating: about 6 DS).
  • the polyester resin and also the urethane resin from Example 1 were employed.
  • the proportion of the polyester resin was 32.40% by weight and that of the urethane resin 14.83% by weight. Additionally employed were: 0.40% by weight of Additol XW 329 (50% strength in butyl glycol), 7.62% by weight of butyl /S glycol, 8.51% by weight of butanol, 1.87% by weight of DMEA and 0.49% by
  • BYK®-020 10% (antifoam for water-soluble systems, based on a
  • Example 1 The product had a binder content of 37.04% by weight and a solids content of 37.29% by weight (0.25% by weight of solids from the additive). The proportion of water was 33.88% by weight, while the proportion of other solvents was likewise 33.88% by weight.
  • Example 1 hardness relative to Example 1 while at the same time having greatly improved solvent resistance (MEK more than 80 after sterilization stage in accordance with Example 1).
  • the third mixture is then added to the first mixture. 10% of the resulting first mixture are then added to the second mixture in a reactor. The temperature rises as a result of exothermic reaction and should be maintained within the range from 120°C to 129°C. The remainder of the first mixture is then metered into the contents of the reactor over 3 h at from 129°C to 131°C. 80 g of butyl glycol are added as the rinsing medium. Then the temperature is maintained at from 129°C to
  • the substance A is a lubricant based on polyethylene glycol dioleate and is
  • Variations of the acrylic polymer in terms of the OH number of 30 mg of KOH/g, in accordance with the above acrylic polymer, to more than 50 and from 75 to 100 mg of KOH/g showed that an increasing OH number leads to a rise in the viscosity of the coating composition, to a reduction in the hardness of the coating and to a reduction in the solvent resistance of the coating. From this it is evident that the OH number established should also not be too high.
  • a coating produced with the above coating composition was subjected to the following test.
  • An autoclave was preheated to 95°C.
  • a metal panel bearing the coating was introduced into the autoclave and subjected to 1 1 of water (23°C).
  • the autoclave was then run up to 125°C, where it was held for 30 minutes.
  • the metal panel was then removed and the coating was assessed. Only very slight changes were evident in limited regions, and, moreover, these changes had completely disappeared again after 1 h.
  • the coating meets all requirements with respect to hardness and solvent resistance as well.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)

Abstract

L'invention concerne une composition de revêtement pour des récipients alimentaires. Cette composition comprend: a) 20-40 % en poids d'un polymère de liaison dans le groupe 'résine de polyester soluble à l'eau ou dispersible dans l'eau; polymère acrylique soluble à l'eau ou dispersible dans l'eau'; b) 5-20 % en poids d'une résine d'uréthane réticulable qui est virtuellement dépourvue de groupes NCO libres; c) 20-70 % en poids d'eau; d) 0-18 % en poids d'un solvant organique et e) 0-5 % en poids d'auxiliaires. Le polymère de liaison comporte un nombre d'OH d'au moins 10 mg de KOH/g et la résine d'uréthane présente une teneur de NCO gropupes (bloqués) d'au moins 5 %.
EP97953778A 1997-01-29 1997-12-10 Composition de rev tement pour des recipients alimentaires Withdrawn EP0956321A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19703091 1997-01-29
DE19703091A DE19703091A1 (de) 1997-01-29 1997-01-29 Überzugsmittel für Nahrungsmittelbehälter
PCT/EP1997/006906 WO1998032807A1 (fr) 1997-01-29 1997-12-10 Composition de revêtement pour des recipients alimentaires

Publications (1)

Publication Number Publication Date
EP0956321A1 true EP0956321A1 (fr) 1999-11-17

Family

ID=7818607

Family Applications (1)

Application Number Title Priority Date Filing Date
EP97953778A Withdrawn EP0956321A1 (fr) 1997-01-29 1997-12-10 Composition de rev tement pour des recipients alimentaires

Country Status (7)

Country Link
EP (1) EP0956321A1 (fr)
KR (1) KR20000070606A (fr)
AU (1) AU5756098A (fr)
BR (1) BR9714327A (fr)
CA (1) CA2278351A1 (fr)
DE (1) DE19703091A1 (fr)
WO (1) WO1998032807A1 (fr)

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DE10349811A1 (de) * 2003-10-24 2005-05-25 Bayer Materialscience Ag Beschichtungen für Nahrungsmittelbehälter
DE102004060798A1 (de) * 2004-12-17 2006-06-29 Bayer Materialscience Ag Wässrige Beschichtungen für Nahrungsmittelbehälter
RU2011146073A (ru) 2009-04-13 2013-05-20 У.Р. Грейс Энд Ко.-Конн. Покрытие для металлических пищевых контейнеров, стойкое к процессам при высоких рн
CN109423129B (zh) * 2017-06-21 2020-08-28 广东华润涂料有限公司 适用于在三片罐上形成侧缝条或侧缝涂层的水性涂料组合物

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KR20000070606A (ko) 2000-11-25
WO1998032807A1 (fr) 1998-07-30
CA2278351A1 (fr) 1998-07-30
AU5756098A (en) 1998-08-18
BR9714327A (pt) 2000-02-08
DE19703091A1 (de) 1998-07-30

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