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EP0944700B1 - Detergents destines a des operations universelles et specifiques de nettoyage - Google Patents

Detergents destines a des operations universelles et specifiques de nettoyage Download PDF

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Publication number
EP0944700B1
EP0944700B1 EP97951784A EP97951784A EP0944700B1 EP 0944700 B1 EP0944700 B1 EP 0944700B1 EP 97951784 A EP97951784 A EP 97951784A EP 97951784 A EP97951784 A EP 97951784A EP 0944700 B1 EP0944700 B1 EP 0944700B1
Authority
EP
European Patent Office
Prior art keywords
weight
percent
module
water
solubilizer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP97951784A
Other languages
German (de)
English (en)
Other versions
EP0944700A2 (fr
Inventor
Dieter Krattenmacher
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
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Filing date
Publication date
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Publication of EP0944700A2 publication Critical patent/EP0944700A2/fr
Application granted granted Critical
Publication of EP0944700B1 publication Critical patent/EP0944700B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43—Solvents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Definitions

  • the invention reports a group of chemical products which are for the Cleaning objects made of metal, wood, plastic etc. as well as masonry, doors, Wall and floor tiles etc. and therefore due to their modular structure both for universal can also be used for special cleaning tasks.
  • Such a cleaner for dishes, glasses, Tiles and objects made of plastic in the patent specification RO 109753 consisting of: 10 - 30% sodium or potassium salt of the monoester of sulfosuccinic acid with alkyl polyglycol ether or alkylphenol polyglycol ether, 2-8% sodium, potassium, diethanolamine or triethanolamine salt the monoester of maleic acid with alkyl polyglycol ether or alkylphenol polyglycol ethers, 2-6% polyethylene fumarate or polydiethylene fumarate, 2-6% non-ionic surfactant Nonylphenol polyethoxylate or alcohol polyethoxylate type, 3 - 6% Urea, 3 - 15% triphosphate, 1 - 4% citric acid or tartronic acid, 2 - 6% ethyl alcohol or isopropyl alcohol, 0.1 - 0.8 formaldehyde, 1 - 3% sodium tetraborate, 0.5 - 2% perfume and demineral
  • a similar solution for cleaning and degreasing metals contains 1-10% by weight.
  • Another liquid product for cleaning dishes and hard surfaces contains fatty alcohol (C10-C14) ethoxylate with 2-4 moles of ethylene oxide and the corresponding sulfates, sodium or potassium alkylbenzenesulfonate, nonylphenol ethoxylate with 8-12 moles of ethylene oxide, sodium citrate, sodium chloride, coconut fatty acid diethanolamide, sodium triphosphate, Ethylene diaminotetraacetic acid, perfume, dye and water (patent specification RO 106582).
  • the known products have a specific determination with regard to the use or the materials for cleaning, they are not intended for universal use. The majority contain substances that have an undesirable effect on the environment.
  • the problem solved by the invention is through a new composition of Detergents and fixed proportions between the components, their number and thus at the same time to reduce the pollution of the environment with harmful substances.
  • the products according to the invention generally consist of at least 96% from an anion module, a nonionic module and a solubilizer module, where the anion module 5-15% by weight of alkyl, preferably C12, benzenesulfonate dissolved in water contains, the non-ionic module 10-20% by weight of fatty alcohol ethoxylate, 5-10% by weight of fatty alcohol alkoxylate, Contains 0-0.2% by weight of complexing agent dissolved in demineralized water Solubilizer module 45-100% by weight dipropylene glycol and 0-55% diethanolamine or Triethanolamine contains, the remaining composition to 100 wt Application specific substances, such as anti-corrosive and / or fragrance supplements.
  • the anion module 5-15% by weight of alkyl, preferably C12, benzenesulfonate dissolved in water contains, the non-ionic module 10-20% by weight of fatty alcohol ethoxylate, 5-10% by weight of fatty alcohol alkoxylate, Contains
  • the universal cleaners consist of 26 - 27.5% by weight of anion module and 60% by weight non-ionic module, 10% by weight from solubilizer module, 2.5 - 4% by weight from fragrance and the rest to 100% by weight of water, preferably demineralized.
  • the metal surface cleaners consist of 27 - 35% by weight of anion module, 55 - 63 % By weight from nonionic module, to -9.8 - 9.95% by weight from solubilizer module, to 0.05 - 0.2% by weight of anti-corrosive and the rest to 100% by weight of water, preferably demineralized.
  • the cleaners for plastic surfaces each consist of 10% by weight of anion module, nonionic module and solubilizer module as well as 0.4 - 1% by weight of fragrance and the rest to 100% by weight of water, preferably demineralized.
  • the cleaners for jewelry and jewels each consist of 10% by weight of anion module, non-ionic module and solubilizer module and 0.02% by weight of anti-corrosive and to 0.4-1% by weight of perfume and the rest to 100% by weight of water, preferably demineralized.
  • Example 1 Alkyl (C12) benzenesulfonate is 5-15% by weight in demineralized water dissolved at 30 - 40 ° C until the solution appears clear. This solution results in the anion module.
  • 0-0.2% by weight of complexing agents are preferred in demineralized water Ethylenediaminetetraacetic acid (EDTA), nitrilotriacetic acid (NTA), o- (carboxymethyl) malic acid or poly (tetramethylene-1,2-dicarboxylic acid), 10-20% by weight of fatty alcohol ethoxylate preferably C10 with 5 mol ethylene oxide or 3-7 mol ethylene oxide, 5-10% by weight fatty alcohol alkoxylate with 10 -18 C and preferably 2 mol of ethylene oxide, 2 mol of propylene oxide and 1 mol Butylene oxide dissolved.
  • EDTA Ethylenediaminetetraacetic acid
  • NTA nitrilotriacetic acid
  • the remaining 100% by weight is demineralized water.
  • the solution is stirred until it appears clear.
  • the non-ionic module provides this solution 1-55% by weight of diethanolamine or triethanolamine are in 99-45% by weight of dipropylene glycol stirred in until a clear solution is obtained.
  • the solubilizer module provides this solution represents, but can also consist of 100% by weight exclusively of dipropylene glycol.
  • Example 2 Anion module, nonionic module and solubilizer module are produced as described in Example 1. 27-35% by weight of anion module, 55-63% by weight of nonionic module, 9.8-9.95% by weight of solubilizer module and 0.05-0.2% by weight of an anti-corrosive are mixed and made up to 100% with demineralized water .% added.
  • This concentrate is used to clean metallic surfaces (including aluminum). Thanks to the built-in corrosion inhibitor, the concentrate can also be used in warm (pH-neutral) metal baths. The preparation of the cleaning solution depends on the respective application.
  • the cleaning solution is filled in and applied according to the instructions of the manufacturer of the high-pressure cleaner.
  • the cleaning solution (cold cleaner) is applied to the surface to be cleaned. After the exposure time (depending on the degree of contamination) with the high-pressure cleaner solution (usually a concentration of 1:49 is sufficient), proceed according to the instructions of the manufacturer of the high-pressure cleaner (corresponding to the single-phase cleaning).
  • Example 3 Anion module, nonionic module and solubilizer module are produced as described in Example 1. 10% by weight of anion module, nonionic module and solubilizer module are mixed with 0.4-1% by weight of fragrance oil and made up to 100% by weight with demineralized water.
  • This special cleaning solution is used to remove dirt, oil and grease residues on polymer-coated housings of computers, monitors, printers and other peripheral devices in the IT industry.
  • the cleaning solution is either sprayed onto the surface to be cleaned using a commercially available pump sprayer or applied to the surface to be cleaned using a cotton cloth moistened with the solution. Both methods should cover the area as completely as possible. After a short exposure time (usually and with normal soiling approx. 6 to 10 seconds), the surface is wiped dry with a dry cotton cloth in the second cleaning step. No further cleaning steps are required.
  • Example 4 Anion module, nonionic module and solubilizer module are produced as described in Example 1. 10% by weight of anion module, nonionic module and solubilizer module are mixed with 0.02% by weight of anti-corrosive and 0.4-1% by weight of fragrance oil and made up to 100% by weight with demineralized water. This special cleaning solution is used to remove dirt and grease residues from jewelry, jewels and fashion jewelry. Also suitable for cleaning metal watch straps (for waterproof watches) and for use in ultrasonic baths (for jewelers). The jewelry to be cleaned is placed in the cleaning solution.
  • Lutensol ON 50 BASF alternatively: min. 3 - 7 EO, min. C10 - C18 B) Fatty alcohol alkoxylate 5 - 10% preferably 221 (e.g. Plurafac LF 221, BASF) alternatively from the group of Plurafac LF products, BASF C) complexing agent 0.0 - 0.2% preferably ethylenediaminetetraacetic acid (EDTA), nitrilotriacetic acid (NTA), o- (carboxymethyl-) malic acid (CMOS) or poly- (tetramethylene-1,2-dicarboxylic acid) (EMA) D) water demineralized ad 100% LV (solubilizer module) substance proportion of Remarks A) Dipropylene glycol 45 - 100% B) Diethanolamine 0 - 55% alternatively.
  • EDTA ethylenediaminetetraacetic acid
  • NTA nitrilotriacetic acid
  • CMOS o- (carboxymethyl
  • Triethanolamine Composition of the cleaners Components Cleaner according to the invention universal Metals Plastics Jewellery Anion module 26-27.5% 27-35% 10% 10%
  • Nonionic module 60% 55 -63% 10%
  • Solubilizer module 10% 9.8 - 9.95%

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Claims (5)

  1. Produits pour nettoyer universels et spéciaux avec les substances connu comme l'alkyl( de préférence C12)benzène sulfonate, l'alcool gras ethoxylate, l'alcool gras alcoxylate, les agents complexants dans l'assemblage,
    caractérisé en ce,
    qu' ils sont constitué au minimum de 96 % par un module anionique, un module non ionique et un module pour simplifier la solubilité, où le module anionique contient de 5- 15 % de poids l'alkyl-, de préférence C12, benzène sulfonate dissoudré dans de l'eau, le module non ionique contient de 10 - 20 % de poids l'alcool gras éthoxylate, de 5 - 10 % de poids l'alcool gras alcoxylate, de 0 - 0,2 % de poids les agents complexants dissoudré dans de l'eau, le module pour simplifier la solubilité contient de 45 - 100 % de poids le propylène-diglycol et de 0 - 55 % de poids la diéthanolamine ou la triéthanolamine, l'assemblage restant à 100 % de poids est complété avec les substances spéciales pour l'application respectif comme une substance anticorrosive et / ou un parfum.
  2. Produits pour nettoyer universels correspondant à la revendication 1
    caractérisé en ce,
    qu' ils sont composé de 26 - 27,5 % de poids du module anionique, de 60 % de poids du module non ionique, de 10 % de poids du module pour simplifier solubilité, de 2,5 - 4 % de poids du parfum et le reste à 100 % de poids de l'eau de préférence déminéralisée.
  3. Produits pour nettoyer le métal correspondant à la revendication 1
    caractérisé en ce,
    qu' ils sont composé de 27 - 35 % de poids du module anionique, de 55 - 63 % de poids du module non ionique, de 9,8 - 9,95 % de poids du module pour simplifier la solubilité, de 0,05 - 0,2 % de poids de la substance anticorrosive et le reste à 100 % de poids de l'eau de préférence déminéralisée.
  4. Produits pour nettoyer les surfaces de matière plastique
    caractérisé en ce,
    qu' ils sont composé de 10 % de poids du module anionique, de 10 % de poids du module non ionique, de 10 % de poids du module pour simplifier la solubilité, de 0,4 - 1 % de poids du parfum et le reste à 100 % de poids de l'eau de préférence déminéralisée, où le module anionique contient de 5- 15 % de poids l'alkyl-, de préférence C12, benzène sulfonate dissoudré dans de l'eau, le module non ionique contient de 10 - 20 % de poids l'alcool gras éthoxylate, de 5 - 10 % de poids l'alcool gras alcoxylate, de 0 - 0,2 % de poids les agents complexants dissoudré dans de l'eau déminéralisée, le module pour simplifier la solubilité contient de 45 - 100 % de poids le propylène-diglycol et de 0 - 55 % de poids la diéthanolamine ou la triéthanolamine, l'assemblage restant à 100 % de poids est complété avec les substances spéciales pour l'application respectif comme une substance anticorrosive et / ou un parfum.
  5. Produits pour nettoyer les pierres précieuses et les bijoux
    caractérisé en ce,
    qu' ils sont composé de 10 % de poids du module anionique, de 10 % de poids du module non ionique, de 10 % de poids du module pour simplifier la solubilité, de 0,02 % de poids de la substance anticorrosive, de 0,4 - 1 % de poids du parfum et le reste à 100 % de poids de l'eau de préférence déminéralisée, où le module anionique contient de 5- 15 % de poids l'alkyl-, de préférence C12, benzène sulfonate dissoudré dans de l'eau, le module non ionique contient de 10 - 20 % de poids l'alcool gras éthoxylate, de 5 - 10 % de poids l'alcool gras alcoxylate, de 0 - 0,2 % les agents complexants dissoudré dans de l'eau déminéralisée, le module pour simplifier la solubilité contient de 45 - 100 % de poids le propylène-diglycol et de 0 - 55 % de poids la diéthanolamine ou la triéthanolamine, l'assemblage restant à 100 % de poids est complété avec les substances spéciales pour l'application respectif comme une substance anticorrosive et / ou un parfum.
EP97951784A 1996-11-20 1997-11-20 Detergents destines a des operations universelles et specifiques de nettoyage Expired - Lifetime EP0944700B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
RO96-02184A RO112759B1 (ro) 1996-11-20 1996-11-20 Produse de curatare pentru utilizare universala si speciala
RO9602184 1996-11-20
PCT/DE1997/002714 WO1998022563A2 (fr) 1996-11-20 1997-11-20 Detergents destines a des operations universelles et specifiques de nettoyage

Publications (2)

Publication Number Publication Date
EP0944700A2 EP0944700A2 (fr) 1999-09-29
EP0944700B1 true EP0944700B1 (fr) 2001-01-17

Family

ID=20104165

Family Applications (1)

Application Number Title Priority Date Filing Date
EP97951784A Expired - Lifetime EP0944700B1 (fr) 1996-11-20 1997-11-20 Detergents destines a des operations universelles et specifiques de nettoyage

Country Status (5)

Country Link
EP (1) EP0944700B1 (fr)
AT (1) ATE198761T1 (fr)
DE (1) DE59702938D1 (fr)
RO (1) RO112759B1 (fr)
WO (1) WO1998022563A2 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10357389B4 (de) * 2003-12-07 2005-12-15 Benda, Jürgen Michael Verfahren zur Reinigung von Speckstein
EP2177599A1 (fr) * 2008-10-16 2010-04-21 KH LLoreda, S.A. Nettoyant pour bijoux, procédé et kit de nettoyage
DE102016225904A1 (de) * 2016-12-21 2018-06-21 Henkel Ag & Co. Kgaa Klarspülformulierung

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH525949A (it) * 1970-07-15 1972-07-31 Clari Ferdinando Composizione liquida al alto potere detergente, atta a pulire gioielli ed altri oggetti, in oro o metalli preziosi, o pietre preziose
JPS5586894A (en) * 1978-12-25 1980-07-01 Kao Corp Liquid detergent composition
SU1147740A1 (ru) * 1983-05-27 1985-03-30 Уральский филиал Всесоюзного научно-исследовательского и проектного института химической промышленности Средство дл очистки твердой поверхности
JPS6051794A (ja) * 1983-08-31 1985-03-23 ライオン株式会社 液体洗浄剤組成物
AU627734B2 (en) * 1988-06-13 1992-09-03 Colgate-Palmolive Company, The Stable and homogeneous concentrated all purpose cleaner
JP2899784B2 (ja) * 1994-05-13 1999-06-02 第一工業製薬株式会社 洗浄剤組成物

Also Published As

Publication number Publication date
ATE198761T1 (de) 2001-02-15
EP0944700A2 (fr) 1999-09-29
DE59702938D1 (de) 2001-02-22
WO1998022563A3 (fr) 1998-07-23
RO112759B1 (ro) 1997-12-30
WO1998022563A2 (fr) 1998-05-28

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