[go: up one dir, main page]

EP0941299B1 - Formulation de produit de lavage pour textiles a base de glycine-nitriles quaternises, d'agents blanchissants, de tensioactifs non ioniques et/ou anioniques et de composes sequestrant les ions calcium et/ou magnesium - Google Patents

Formulation de produit de lavage pour textiles a base de glycine-nitriles quaternises, d'agents blanchissants, de tensioactifs non ioniques et/ou anioniques et de composes sequestrant les ions calcium et/ou magnesium Download PDF

Info

Publication number
EP0941299B1
EP0941299B1 EP97952779A EP97952779A EP0941299B1 EP 0941299 B1 EP0941299 B1 EP 0941299B1 EP 97952779 A EP97952779 A EP 97952779A EP 97952779 A EP97952779 A EP 97952779A EP 0941299 B1 EP0941299 B1 EP 0941299B1
Authority
EP
European Patent Office
Prior art keywords
weight
detergent formulation
textile detergent
acid
bis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP97952779A
Other languages
German (de)
English (en)
Other versions
EP0941299A2 (fr
Inventor
Dieter BÖCKH
Gregor Schürmann
Klaus Mundinger
Michael SCHÖNHERR
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of EP0941299A2 publication Critical patent/EP0941299A2/fr
Application granted granted Critical
Publication of EP0941299B1 publication Critical patent/EP0941299B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3907—Organic compounds
    • C11D3/3917—Nitrogen-containing compounds
    • C11D3/3925—Nitriles; Isocyanates or quarternary ammonium nitriles
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds

Definitions

  • Suitable amorphous or crystalline silicates are mainly amorphous and crystalline disilicates Disilicates such as the layered silicate SKS-6 (manufacturer Fa. Maximum).
  • the silicates can be in the form of their alkali metal, alkaline earth metal or ammonium salts can be used. Preferably Na, Li and Mg silicates are used.
  • Suitable modifying Monomers are the above group monomers (ii) and (iii).
  • nonionic surfactants are alkoxylated C 8 to C 22 alcohols, such as fatty alcohol alkoxylates or oxo alcohol alkoxylates.
  • the alkoxylation can be carried out using ethylene oxide, propylene oxide and / or butylene oxide. All alkoxylated alcohols which contain at least two molecules of an alkylene oxide mentioned above can be used as the surfactant.
  • block polymers of ethylene oxide, propylene oxide and / or butylene oxide come into consideration or addition products which contain the alkylene oxides mentioned in a statistical distribution.
  • 2 to 50, preferably 3 to 20 mol of at least one alkylene oxide are used per mol of alcohol.
  • Ethylene oxide is preferably used as the alkylene oxide.
  • the alcohols preferably have 10 to 18 carbon atoms.
  • the invention Textile detergent formulation usual color transfer inhibitors in the usual amounts for this (about 0.1 to 2 wt .-%).
  • Phosphate-free compact detergents have the following composition, for example: 15 to 70% Zeolites, layered silicates, polycarboxylate or aminopolycarboxylates or mixtures thereof 5 to 35% Surfactants 0.5 to 6% quaternized glycine nitriles 10 to 25% inorganic peroxo compounds as bleach ad 100 other ingredients. Detergents of this type are usually dosed with 2.5 to 7 g / l.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Claims (7)

  1. Formulation de détergent pour textiles, comprenant
    (A) de 0,1 à 10 % en poids d'au moins un glycine-nitrile quaternisé du groupe comprenant l'acétonitrileméthylsulfate, l'acétonitrilesulfate et l'acétonitrilehydrogénosulfate de N-méthylmorpholinium, éventuellement en combinaison avec d'autres activateurs de blanchiment, les glycine-nitriles quaternisés représentant au moins 5 % en poids du total de l'ensemble des activateurs de blanchiment,
    (B) de 0,5 à 40 % en poids d'agents de blanchiment sous forme de composés peroxo et/ou de peracides,
    (C) de 0,5 à 50 % en poids de tensioactifs non-ioniques et/ou anioniques, et
    (D) de 5 à 85 % en poids d'au moins un composé séquestrant les ions calcium et/ou magnésium ayant une fonction d'adjuvant ou de co-adjuvant.
  2. Formulation de détergent textile selon la revendication 1, contenant
    (A) de 0,5 à 7 % en poids d'au moins un glycine-nitrile quaternisé (A),
    (B) de 5 à 30 % en poids d'agents de blanchiment sous forme de composés peroxo et/ou de peracides,
    (C) de 5 à 30 % en poids de tensioactifs non-ioniques et/ou anioniques, et
    (D) de 10 à 70 % en poids d'au moins un composé séquestrant les ions calcium et/ou magnésium, ayant une fonction d'adjuvant ou de co-adjuvant.
  3. Formulation de détergent textile selon la revendication 1 ou 2, contenant le composant (A) sous forme d'un mélange ou de granulés des glycine-nitriles (A) avec des matériaux supports poreux inertes appropriés.
  4. Formulation de détergent textile selon les revendications 1 à 3, contenant en tant que composant (D) des zéolites, des silicates, des phosphates de métaux alcalins, des polycarboxylates et/ou des aminopolycarboxylates.
  5. Formulation de détergent textile selon les revendications 1 à 4 sous forme d'une poudre ou d'un granulé, ayant une masse volumique apparente de 200 à 1100 g/l.
  6. Utilisation de la formulation de détergent textile selon les revendications 1 à 5 à une dose supérieure à 2 g par litre de lessive, de préférence à une dose de 2,5 à 15 g par litre de lessive, pour laver des textiles en utilisation domestique et industrielle.
  7. Utilisation de la formulation de détergent textile selon la revendication 6 pour un rapport de bain article textile:lessive de 1:10 à 1:2, de préférence de 1:5 à 1:3.
EP97952779A 1996-11-29 1997-11-18 Formulation de produit de lavage pour textiles a base de glycine-nitriles quaternises, d'agents blanchissants, de tensioactifs non ioniques et/ou anioniques et de composes sequestrant les ions calcium et/ou magnesium Expired - Lifetime EP0941299B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19649384 1996-11-29
DE19649384A DE19649384A1 (de) 1996-11-29 1996-11-29 Textilwaschmittel-Formulierung auf Basis von quaternierten Glycinnitrilen, Bleichmitteln, nichtionischen und/oder anionischen Tensiden und Calcium- und/oder Magnesiumionen sequestierenden Verbindungen
PCT/EP1997/006429 WO1998023718A2 (fr) 1996-11-29 1997-11-18 Formulation de produit de lavage pour textiles a base de glycine-nitriles quaternises, d'agents blanchissants, de tensioactifs non ioniques et/ou anioniques et de composes sequestrant les ions calcium et/ou magnesium

Publications (2)

Publication Number Publication Date
EP0941299A2 EP0941299A2 (fr) 1999-09-15
EP0941299B1 true EP0941299B1 (fr) 2001-08-29

Family

ID=7813064

Family Applications (1)

Application Number Title Priority Date Filing Date
EP97952779A Expired - Lifetime EP0941299B1 (fr) 1996-11-29 1997-11-18 Formulation de produit de lavage pour textiles a base de glycine-nitriles quaternises, d'agents blanchissants, de tensioactifs non ioniques et/ou anioniques et de composes sequestrant les ions calcium et/ou magnesium

Country Status (11)

Country Link
US (1) US6174853B1 (fr)
EP (1) EP0941299B1 (fr)
JP (1) JP2001504882A (fr)
AT (1) ATE204901T1 (fr)
AU (1) AU5653998A (fr)
BR (1) BR9713457A (fr)
CA (1) CA2272271A1 (fr)
DE (2) DE19649384A1 (fr)
DK (1) DK0941299T3 (fr)
ES (1) ES2162687T3 (fr)
WO (1) WO1998023718A2 (fr)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6010994A (en) * 1995-06-07 2000-01-04 The Clorox Company Liquid compositions containing N-alkyl ammonium acetonitrile salts
US6211130B1 (en) * 1997-08-21 2001-04-03 Henkel Kommanditgesellschaft Auf Aktien Use of quaternary acetonitrile compounds as activators for detergents
DE19914811A1 (de) * 1999-03-31 2000-10-05 Henkel Kgaa Enzym- und bleichaktivatorhaltige Wasch- und Reinigungsmittel
US20010046951A1 (en) * 2000-02-02 2001-11-29 Kao Corporation Bleaching detergent composition
DE10057045A1 (de) * 2000-11-17 2002-05-23 Clariant Gmbh Teilchenförmige Bleichaktivatoren auf der Basis von Acetonitrilen
US20020137659A1 (en) * 2000-12-18 2002-09-26 Gross Stephen F. Reaction products of polycarboxylic acids derivatives thereof
DE10211389A1 (de) * 2002-03-15 2003-09-25 Clariant Gmbh Ammoniumnitrile und deren Verwendung als hydrophobe Bleichaktivatoren
BR0309861A (pt) * 2002-05-02 2005-03-29 Procter & Gamble Partìcula, composição detergente compreendendo a mesma e método para limpeza de tecidos
EP1433839B2 (fr) * 2002-12-24 2015-04-01 Dalli-Werke GmbH & Co. KG Compositions de lavage et nettoyage optimisées pour un effet amélioré de blanchiment à basse température
ES2249175B1 (es) * 2004-09-08 2008-06-01 M. Jose Roldan Herrero Composicion de jabon para lavar con poder suavizante.
EP2029690B1 (fr) * 2006-05-24 2013-09-25 Harald Weirich Méthode de préparation de liants modifiés à l'aide d'huiles végétales et de dérivés d'huiles végétales et adjuvants et utilisation des liants modifiés et adjuvants préparés.
US11713435B2 (en) 2018-01-30 2023-08-01 Eastman Chemical Company Aminocarboxylate chelating agents and detergent compositions containing them

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9011618D0 (en) * 1990-05-24 1990-07-11 Unilever Plc Bleaching composition
DE4431212A1 (de) * 1994-09-02 1996-03-07 Basf Ag Verfahren zur Herstellung von quaternierten Glycinnitrilen
US5739327A (en) * 1995-06-07 1998-04-14 The Clorox Company N-alkyl ammonium acetonitrile bleach activators
DE19605526A1 (de) * 1996-02-15 1997-08-21 Hoechst Ag Ammoniumnitrile und deren Verwendung als Bleichaktivatoren

Also Published As

Publication number Publication date
JP2001504882A (ja) 2001-04-10
ES2162687T3 (es) 2002-01-01
DK0941299T3 (da) 2001-10-08
WO1998023718A2 (fr) 1998-06-04
DE19649384A1 (de) 1998-06-04
ATE204901T1 (de) 2001-09-15
US6174853B1 (en) 2001-01-16
BR9713457A (pt) 2000-03-28
EP0941299A2 (fr) 1999-09-15
DE59704478D1 (de) 2001-10-04
AU5653998A (en) 1998-06-22
CA2272271A1 (fr) 1998-06-04
WO1998023718A3 (fr) 1998-08-06

Similar Documents

Publication Publication Date Title
EP1002046B1 (fr) Formulation detergente solide pour textiles a base de derives d'acide n,n-diacetique de glycine
EP0826025B1 (fr) Utilisation de composes heterocycliques comme activateurs pour des composes peroxy inorganiques
EP0859825A1 (fr) Utilisation d'acides aminodicarboxyliques polymeres dans des detergents
EP0941299B1 (fr) Formulation de produit de lavage pour textiles a base de glycine-nitriles quaternises, d'agents blanchissants, de tensioactifs non ioniques et/ou anioniques et de composes sequestrant les ions calcium et/ou magnesium
EP0863976B1 (fr) Derives glycine-n,n-acide diacetique utilises comme co-adjuvants organiques dans des formulations d'agents de lavage de textiles
EP1520910A1 (fr) Utilisation de complexes de métaux de transition comprenant des ligands lactames comme catalysateurs de blanchiment
EP0891411B1 (fr) Renfor ateur du pouvoir lavant de detergents
EP0892846B1 (fr) Renfor ateur de pouvoir de blanchiment pour compositions d'agents de blanchiment et de detergents textiles
EP0964912B1 (fr) Formulations detergentes et nettoyantes comprenant un systeme de blanchiment et un melange d'amines et d'agents complexants
EP1003826B1 (fr) Formulation detergente solide pour textiles a base de derives d'acide n,n-diacetique de glycine a teneur fortement reduite en autres tensioactifs anioniques
EP0384912A2 (fr) "Hydroxamate" comme stabilisateur de blanchiment
EP1433839B2 (fr) Compositions de lavage et nettoyage optimisées pour un effet amélioré de blanchiment à basse température
DE2132898A1 (de) Schwachschaeumendes wasch-, reinigungsund enthaertungsmittel
EP0958345A2 (fr) Activateurs pour composes per
DE19732689A1 (de) Feste Textilwaschmittel-Formulierung auf Basis von Glycin-N,N-diessigsäure-Derivaten mit stark reduziertem Anteil an weiteren anionischen Tensiden
DE2154318A1 (de) Schwachschaeumendes wasch-, reinigungsund enthaertungsmittel
DE19829746A1 (de) Glycin-N,N-carbonsäure-Derivate mit carbonylgruppenhaltiger Seitenkette, ihre Herstellung sowie ihre Verwendung in Wasch- und Reinigungsmitteln
DE19807105A1 (de) Feste Textilwaschmittel-Formulierung auf Basis von Glycin-N,N-diessigsäure-Derivaten mit stark reduziertem Anteil an weiteren anionischen Tensiden
EP0806473A2 (fr) Composés de cyanopyridinium comme activateurs de blanchiment
DE19611992A1 (de) Bleichkraftverstärker für Bleichmittel- und Textilwaschmittelzusammensetzungen
WO1998022431A1 (fr) Hydroxyamides d'acides gras et leur utilisation comme substances a activite de surface, comme agents tensioactifs non ioniques ou comme emulsifiants
DE19625908A1 (de) Bleichkraftverstärker für Bleichmittel- und Textilwaschmittelzusammensetzungen
MXPA99004981A (en) Textile detergent formulation on the basis of quaternized glycine nitriles, bleaching agents, nonionic and/or anionic tensides and calcium ion and/or magnesium ion sequestering compounds
DE19732688A1 (de) Feste Textilwaschmittel-Formulierung auf Basis von Glycin-N,N-diessigsäure-Derivaten als Buildern mit stark reduziertem Anteil an Silicat-Buildern
DE102004041760A1 (de) Diethylmethyl-Ammoniumnitrile und Wasch- und Reinigungsmittel, enthaltend diese Ammoniumnitrile

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 19990428

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AT BE CH DE DK ES FI FR GB IT LI NL SE

17Q First examination report despatched

Effective date: 20000216

GRAG Despatch of communication of intention to grant

Free format text: ORIGINAL CODE: EPIDOS AGRA

GRAG Despatch of communication of intention to grant

Free format text: ORIGINAL CODE: EPIDOS AGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH DE DK ES FI FR GB IT LI NL SE

REF Corresponds to:

Ref document number: 204901

Country of ref document: AT

Date of ref document: 20010915

Kind code of ref document: T

REG Reference to a national code

Ref country code: CH

Ref legal event code: NV

Representative=s name: SCHMAUDER & PARTNER AG PATENTANWALTSBUERO

Ref country code: CH

Ref legal event code: EP

REF Corresponds to:

Ref document number: 59704478

Country of ref document: DE

Date of ref document: 20011004

REG Reference to a national code

Ref country code: DK

Ref legal event code: T3

GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

Effective date: 20011018

REG Reference to a national code

Ref country code: GB

Ref legal event code: IF02

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2162687

Country of ref document: ES

Kind code of ref document: T3

EN Fr: translation not filed
PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed
PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 20031105

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: AT

Payment date: 20031112

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FI

Payment date: 20031113

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DK

Payment date: 20031114

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CH

Payment date: 20031118

Year of fee payment: 7

ET Fr: translation filed
REG Reference to a national code

Ref country code: FR

Ref legal event code: ERR

Free format text: BOPI DE PUBLICATION N: 02/04 PAGES: 245 PARTIE DU BULLETIN CONCERNEE: BREVETS EUROPEENS DONT LA TRADUCTION N'A PAS ETE REMISE A I'INPI IL Y A LIEU DE SUPPRIMER: LA MENTION DE LA NON REMISE. LA REMISE DE LA TRADUCTION EST PUBLIEE DANS LE PRESENT BOPI.

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20041118

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20041118

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20041119

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20041130

Ref country code: DK

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20041130

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20041130

REG Reference to a national code

Ref country code: DK

Ref legal event code: EBP

EUG Se: european patent has lapsed
REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20061105

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20061108

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20061115

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20061116

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20061130

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20061222

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20070118

Year of fee payment: 10

BERE Be: lapsed

Owner name: *BASF A.G.

Effective date: 20071130

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20071118

NLV4 Nl: lapsed or anulled due to non-payment of the annual fee

Effective date: 20080601

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20071130

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080601

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080603

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20080930

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20071118

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20071119

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20071130

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20071119

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20071118