EP0820529A1 - Procede de fabrication de produits allonges finis a chaud, notamment du type barre ou tube, en acier fortement allie ou hypereutectoide - Google Patents
Procede de fabrication de produits allonges finis a chaud, notamment du type barre ou tube, en acier fortement allie ou hypereutectoideInfo
- Publication number
- EP0820529A1 EP0820529A1 EP96907260A EP96907260A EP0820529A1 EP 0820529 A1 EP0820529 A1 EP 0820529A1 EP 96907260 A EP96907260 A EP 96907260A EP 96907260 A EP96907260 A EP 96907260A EP 0820529 A1 EP0820529 A1 EP 0820529A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- temperature
- rolling
- forming
- cooling
- mill
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910000831 Steel Inorganic materials 0.000 title claims description 18
- 239000010959 steel Substances 0.000 title claims description 18
- 238000004519 manufacturing process Methods 0.000 title claims description 10
- 229910045601 alloy Inorganic materials 0.000 title claims description 5
- 239000000956 alloy Substances 0.000 title claims description 5
- 238000000034 method Methods 0.000 claims abstract description 39
- 238000001816 cooling Methods 0.000 claims abstract description 21
- 238000010438 heat treatment Methods 0.000 claims abstract description 14
- 238000003303 reheating Methods 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 8
- 238000009826 distribution Methods 0.000 claims abstract description 5
- 238000005096 rolling process Methods 0.000 claims description 44
- 238000000137 annealing Methods 0.000 claims description 22
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 229910052717 sulfur Inorganic materials 0.000 claims description 7
- 229910052698 phosphorus Inorganic materials 0.000 claims description 6
- 238000009749 continuous casting Methods 0.000 claims description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
- 238000010586 diagram Methods 0.000 claims description 4
- 239000011593 sulfur Substances 0.000 claims description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- 229910001563 bainite Inorganic materials 0.000 claims description 3
- 229910000734 martensite Inorganic materials 0.000 claims description 3
- 239000011574 phosphorus Substances 0.000 claims description 3
- 239000002826 coolant Substances 0.000 claims description 2
- 238000009792 diffusion process Methods 0.000 claims description 2
- 239000007858 starting material Substances 0.000 claims description 2
- 238000005496 tempering Methods 0.000 claims description 2
- 239000000047 product Substances 0.000 claims 2
- 239000013067 intermediate product Substances 0.000 claims 1
- FXNGWBDIVIGISM-UHFFFAOYSA-N methylidynechromium Chemical compound [Cr]#[C] FXNGWBDIVIGISM-UHFFFAOYSA-N 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 101100321457 Arabidopsis thaliana ZHD8 gene Proteins 0.000 description 4
- 229910052804 chromium Inorganic materials 0.000 description 4
- 239000011651 chromium Substances 0.000 description 4
- 238000010622 cold drawing Methods 0.000 description 4
- 238000005520 cutting process Methods 0.000 description 4
- 230000001965 increasing effect Effects 0.000 description 4
- 238000003754 machining Methods 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- 229910001567 cementite Inorganic materials 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- KSOKAHYVTMZFBJ-UHFFFAOYSA-N iron;methane Chemical compound C.[Fe].[Fe].[Fe] KSOKAHYVTMZFBJ-UHFFFAOYSA-N 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 150000001247 metal acetylides Chemical class 0.000 description 3
- 229910001562 pearlite Inorganic materials 0.000 description 3
- 238000005097 cold rolling Methods 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 230000008030 elimination Effects 0.000 description 2
- 238000003379 elimination reaction Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- 241000237858 Gastropoda Species 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 206010037660 Pyrexia Diseases 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005261 decarburization Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
- 230000004304 visual acuity Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/06—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/26—Methods of annealing
- C21D1/32—Soft annealing, e.g. spheroidising
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/06—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
- C21D8/065—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires of ferrous alloys
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/10—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of tubular bodies
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/003—Cementite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/002—Heat treatment of ferrous alloys containing Cr
Definitions
- the coordinated process steps make it possible to produce the desired structure, with a Brinell hardness of less than or equal to 280 HB30, preferably less than 250 HB30, being achieved in the case of rolling bearing steel.
- This structure also makes it possible, for example, to supply hot-worked pipes directly to processing without soft annealing.
- the optimized manufacturing process is particularly cost-effective because the soft annealing and the associated transport and work steps are eliminated.
- the processing of the invention hot-formed elongated products can be cold drawing or cold pilgering or cold rolling or cross-rolling.
- the actual reheating takes place to a temperature either below Ac-i but above 650 ° C or above Ac-
- however below Ac ma (a beginning of the area of carbide dissolution).
- the Ac -) or Ac ma temperature is primarily dependent on the carbon content of the material quality used and on the history of forming.
- the former temperature range corresponds to the two-phase region + F ⁇ ßC in the continuous time-temperature conversion diagram (ZTU), the latter region corresponds to the two-phase region + F ⁇ 3C.
- Another measure for the proposed combination of coordinated process steps relates to the final continuous rolling process, preferably in the stretch-reducing mill. In contrast to other rolling processes, the intervention possibilities in this fast-running continuous rolling process are low.
- the temperature of the rolled stock must not exceed A cma .
- This narrow temperature range can be maintained by means of a controlled coolant control in special cases, heat supply by means of an external heating device, and by varying the roller geometry, the roller speed and the stitch take-off. With the roller geometry, the pressed length is of particular importance.
- the method according to the invention can generally be used for all known tube production methods which in the end have a reducing roller mill with or without a train or sizing roller.
- this can be a process on a tube mill line, stopper line or an Assel mill.
- It is particularly suitable for the push bench process for the production of seamless tubes from roller bearing steel.
- Block casting (forged or rolled) or continuous casting (square or round) can be used as the starting material for the process according to the invention, the continuous casting material being deformed and annealed in a known manner before the rolling insert.
- the method can be used particularly advantageously if the chemical analysis of the roller bearing steel known per se is modified.
- the chromium to carbon ratio should be in the range between 1.35 and 1.52, preferably at 1.45.
- the carbon content is then, for example, 0.94 percent by mass and the chromium content is approximately 1.36 percent by mass.
- the undesired carbide rate can be positively influenced by this ratio.
- Another improvement is the cooling process after the last forming process.
- the rolling stock After leaving the rolling mill, the rolling stock is cooled in still air or by means of an air shower to a temperature that corresponds to a structure in the ZTU diagram that lies above the martensite point and below the nose of the bainite.
- the formed material is kept isothermal for several hours in this area. This procedure has proven to be beneficial in terms of reducing the residual stresses. In plant terms, this can be done in such a way that the cooling bed is heat-insulating at a suitable point, for example covered or the rolling stock is fed to a temperature compensation or tempering furnace.
- the rolling stock running out of the rolling mill has a higher rigidity due to the reduced forming temperature and becomes sufficiently straight on the cooling bed. Straightening can therefore generally be omitted.
- the hole piece has the following dimensions
- the temperature of the slug drops further until the pull-out duo and reaches a level in the range of 650 to 700 ° C in the aforementioned case.
- the slug bottom is scooped.
- controlled cooling prior to the entry of the slug into the reheating device, it is subjected to controlled cooling in order to achieve a uniform temperature distribution in the range between 650 ° C. and 700 ° C. In this case, a temperature level of approx. 670 ° C is aimed for.
- the slugs are held for a certain time by means of a heat-insulated buffer, so that heat can flow from the areas of the slug with a higher temperature level to the areas with a low temperature level.
- the thermal insulation ensures that the overall level of the bobbin temperature does not drop below the specified target value.
- the temperature of the reheating furnace is set so that the temperature of the material to be formed is approximately 740 ° C.
- the billet enters a stretch-reducing mill. This consists of a large number of three-roll stands, which are each offset by 120 ° in a rolling line. 19 frames are used for the selected example with the final dimensions of 40.9 x 4.8 mm.
- the partial forming in the basic scaffolding is estimated to be between 7.1 and 8.1% decrease in cross-section. The total deformation is 72.7% corresponding to an elongation of 3.66. The forming conditions are chosen such. B.
- the tube produced according to the procedure according to the invention can be further processed without cutting or without additional heat treatment. For example, this can be cold drawing. Due to the selected procedure, targeted temperature control before entering the reheating oven - lowered temperature of the reheating oven compared to the usual mode of operation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Heat Treatment Of Steel (AREA)
- Metal Rolling (AREA)
- Metal Extraction Processes (AREA)
Abstract
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19513314 | 1995-04-03 | ||
| DE19513314A DE19513314C2 (de) | 1995-04-03 | 1995-04-03 | Verfahren zur Herstellung eines warmgefertigten langgestreckten Erzeugnisses, insbesondere Stab oder Rohr, aus übereutektoidem Stahl |
| PCT/DE1996/000501 WO1996031628A1 (fr) | 1995-04-03 | 1996-03-12 | Procede de fabrication de produits allonges finis a chaud, notamment du type barre ou tube, en acier fortement allie ou hypereutectoide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0820529A1 true EP0820529A1 (fr) | 1998-01-28 |
| EP0820529B1 EP0820529B1 (fr) | 2000-08-02 |
Family
ID=7759207
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP96907260A Expired - Lifetime EP0820529B1 (fr) | 1995-04-03 | 1996-03-12 | Procede de fabrication de produits allonges finis a chaud, notamment du type barre ou tube, en acier fortement allie ou hypereutectoide |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US5958158A (fr) |
| EP (1) | EP0820529B1 (fr) |
| JP (1) | JPH11503491A (fr) |
| KR (1) | KR19980703575A (fr) |
| AR (1) | AR001416A1 (fr) |
| BR (1) | BR9604830A (fr) |
| CA (1) | CA2217309C (fr) |
| CZ (1) | CZ304797A3 (fr) |
| DE (2) | DE19513314C2 (fr) |
| ES (1) | ES2149455T3 (fr) |
| HU (1) | HUP9800702A3 (fr) |
| PL (1) | PL322598A1 (fr) |
| SK (1) | SK134297A3 (fr) |
| WO (1) | WO1996031628A1 (fr) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE510447C2 (sv) * | 1998-03-16 | 1999-05-25 | Ovako Steel Ab | Sätt för mjukglödgning av högkolhaltigt stål |
| NL1007739C2 (nl) * | 1997-12-08 | 1999-06-09 | Hoogovens Staal Bv | Werkwijze en inrichting voor het vervaardigen van een stalen band met hoge sterkte. |
| US6233500B1 (en) * | 1997-06-19 | 2001-05-15 | The United States Of America As Represented By The Secretary Of The Air Force | Optimization and control of microstructure development during hot metal working |
| DE19734563C1 (de) * | 1997-08-04 | 1998-12-03 | Mannesmann Ag | Verfahren zur Herstellung von Wälzlagerringen aus Stahl |
| US6936119B2 (en) * | 2000-07-12 | 2005-08-30 | Mannesmannrohren-Werke Ag | Method for producing metallic, non-rotationally symmetrical rings with a constant wall thickness over their circumference |
| DE10134776C2 (de) * | 2000-07-12 | 2003-04-24 | Mannesmann Roehren Werke Ag | Verfahren zur Herstellung metallischer nicht-rotationssymmetrischer Ringe mit über den Umfang konstanter Wanddicke, sowie Vorrichtung zur Durchführung des Verfahrens |
| DE102004011021A1 (de) * | 2004-03-04 | 2005-09-29 | Mannesmannröhren-Werke Ag | Verfahren zur Herstellung eines Formteils aus übereutekoidem Stahl |
| JP4894855B2 (ja) | 2006-03-28 | 2012-03-14 | 住友金属工業株式会社 | 継目無管の製造方法 |
| US8968495B2 (en) * | 2007-03-23 | 2015-03-03 | Dayton Progress Corporation | Methods of thermo-mechanically processing tool steel and tools made from thermo-mechanically processed tool steels |
| US9132567B2 (en) * | 2007-03-23 | 2015-09-15 | Dayton Progress Corporation | Tools with a thermo-mechanically modified working region and methods of forming such tools |
| CN101722190B (zh) * | 2009-11-12 | 2012-08-22 | 无锡西姆莱斯石油专用管制造有限公司 | 一种热轧毛管的处理工艺 |
| DE102011051682B4 (de) * | 2011-07-08 | 2013-02-21 | Max Aicher | Verfahren und Vorrichtung zum Behandeln eines Stahlprodukts sowie Stahlprodukt |
| PL232555B1 (pl) * | 2017-05-25 | 2019-06-28 | Arcelormittal Poland Spolka Akcyjna | Sposób produkcji walcówki gładkiej i żebrowanej |
| CN115612802A (zh) * | 2022-10-25 | 2023-01-17 | 本钢板材股份有限公司 | 一种小规格轴承钢生产等温球化退火工艺 |
| CN117305564A (zh) * | 2023-09-06 | 2023-12-29 | 南京钢铁股份有限公司 | 一种导轨用钢降低硬度的生产控制方法 |
| CN120493572B (zh) * | 2025-07-10 | 2025-11-28 | 承德建龙特殊钢有限公司 | 钢管连轧削尖参数优化方法、装置、电子设备及存储介质 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6417820A (en) * | 1987-07-13 | 1989-01-20 | Kobe Steel Ltd | Production of electric resistance welded steel tube for heat treatment |
| JP3215891B2 (ja) * | 1991-06-14 | 2001-10-09 | 新日本製鐵株式会社 | 冷間加工用棒鋼線材の製造方法 |
| JP2544867B2 (ja) * | 1992-04-21 | 1996-10-16 | 新日本製鐵株式会社 | 過共析鋼線材の製造方法 |
| DE59310023D1 (de) * | 1992-09-02 | 2000-06-08 | Sulzer Orthopaedie Ag Baar | Zweiteilige Hüftgelenkpfanne |
-
1995
- 1995-04-03 DE DE19513314A patent/DE19513314C2/de not_active Expired - Fee Related
-
1996
- 1996-03-12 SK SK1342-97A patent/SK134297A3/sk unknown
- 1996-03-12 DE DE59605681T patent/DE59605681D1/de not_active Expired - Lifetime
- 1996-03-12 PL PL96322598A patent/PL322598A1/xx unknown
- 1996-03-12 KR KR1019970706979A patent/KR19980703575A/ko not_active Withdrawn
- 1996-03-12 CA CA002217309A patent/CA2217309C/fr not_active Expired - Fee Related
- 1996-03-12 HU HU9800702A patent/HUP9800702A3/hu unknown
- 1996-03-12 WO PCT/DE1996/000501 patent/WO1996031628A1/fr not_active Ceased
- 1996-03-12 CZ CZ973047A patent/CZ304797A3/cs unknown
- 1996-03-12 US US08/930,139 patent/US5958158A/en not_active Expired - Fee Related
- 1996-03-12 BR BR9604830A patent/BR9604830A/pt not_active IP Right Cessation
- 1996-03-12 ES ES96907260T patent/ES2149455T3/es not_active Expired - Lifetime
- 1996-03-12 EP EP96907260A patent/EP0820529B1/fr not_active Expired - Lifetime
- 1996-03-12 JP JP8529845A patent/JPH11503491A/ja active Pending
- 1996-03-25 AR AR33589296A patent/AR001416A1/es unknown
Non-Patent Citations (1)
| Title |
|---|
| See references of WO9631628A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0820529B1 (fr) | 2000-08-02 |
| DE59605681D1 (de) | 2000-09-07 |
| HUP9800702A3 (en) | 1999-08-30 |
| DE19513314A1 (de) | 1996-10-10 |
| WO1996031628A1 (fr) | 1996-10-10 |
| JPH11503491A (ja) | 1999-03-26 |
| SK134297A3 (en) | 1998-04-08 |
| BR9604830A (pt) | 1999-01-05 |
| PL322598A1 (en) | 1998-02-02 |
| AR001416A1 (es) | 1997-10-22 |
| ES2149455T3 (es) | 2000-11-01 |
| CZ304797A3 (cs) | 1998-04-15 |
| US5958158A (en) | 1999-09-28 |
| CA2217309C (fr) | 2000-11-21 |
| DE19513314C2 (de) | 1997-07-03 |
| HUP9800702A2 (hu) | 1998-07-28 |
| KR19980703575A (ko) | 1998-11-05 |
| CA2217309A1 (fr) | 1996-10-10 |
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