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EP0708296B1 - Safety device for gas radiation burners - Google Patents

Safety device for gas radiation burners Download PDF

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Publication number
EP0708296B1
EP0708296B1 EP95112896A EP95112896A EP0708296B1 EP 0708296 B1 EP0708296 B1 EP 0708296B1 EP 95112896 A EP95112896 A EP 95112896A EP 95112896 A EP95112896 A EP 95112896A EP 0708296 B1 EP0708296 B1 EP 0708296B1
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EP
European Patent Office
Prior art keywords
burner
plate
radiant gas
gas burner
burner plate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP95112896A
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German (de)
French (fr)
Other versions
EP0708296A1 (en
Inventor
Kurt Dr. Schaupert
Michael Kahlke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ceramat S Coop
Original Assignee
Carl Zeiss AG
Schott Glaswerke AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Carl Zeiss AG, Schott Glaswerke AG filed Critical Carl Zeiss AG
Publication of EP0708296A1 publication Critical patent/EP0708296A1/en
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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24CDOMESTIC STOVES OR RANGES ; DETAILS OF DOMESTIC STOVES OR RANGES, OF GENERAL APPLICATION
    • F24C3/00Stoves or ranges for gaseous fuels
    • F24C3/12Arrangement or mounting of control or safety devices
    • F24C3/126Arrangement or mounting of control or safety devices on ranges
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23DBURNERS
    • F23D14/00Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
    • F23D14/46Details
    • F23D14/72Safety devices, e.g. operative in case of failure of gas supply
    • F23D14/725Protection against flame failure by using flame detection devices
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23DBURNERS
    • F23D14/00Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
    • F23D14/12Radiant burners
    • F23D14/16Radiant burners using permeable blocks
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23NREGULATING OR CONTROLLING COMBUSTION
    • F23N5/00Systems for controlling combustion
    • F23N5/02Systems for controlling combustion using devices responsive to thermal changes or to thermal expansion of a medium
    • F23N5/14Systems for controlling combustion using devices responsive to thermal changes or to thermal expansion of a medium using thermo-sensitive resistors
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23NREGULATING OR CONTROLLING COMBUSTION
    • F23N5/00Systems for controlling combustion
    • F23N5/24Preventing development of abnormal or undesired conditions, i.e. safety arrangements
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24CDOMESTIC STOVES OR RANGES ; DETAILS OF DOMESTIC STOVES OR RANGES, OF GENERAL APPLICATION
    • F24C3/00Stoves or ranges for gaseous fuels
    • F24C3/12Arrangement or mounting of control or safety devices
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23DBURNERS
    • F23D2203/00Gaseous fuel burners
    • F23D2203/10Flame diffusing means
    • F23D2203/105Porous plates
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23DBURNERS
    • F23D2212/00Burner material specifications
    • F23D2212/10Burner material specifications ceramic
    • F23D2212/103Fibres
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23NREGULATING OR CONTROLLING COMBUSTION
    • F23N2225/00Measuring
    • F23N2225/08Measuring temperature
    • F23N2225/16Measuring temperature burner temperature
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23NREGULATING OR CONTROLLING COMBUSTION
    • F23N2231/00Fail safe
    • F23N2231/06Fail safe for flame failures

Definitions

  • the invention relates to a safety device for gas radiation burners with an electrical fuse to prevent unused outflow Gas and related devices for igniting the gas or interrupt the gas supply when the flame goes out.
  • Gas radiation burners are known and for example in DE 24 40 701 C3 described. They are mainly characterized by porous, perforated Burner plates z. B made of ceramic, which is the mixing chamber of the gas burner lock upwards. In operation burn at the top of the Channels of the perforated or perforated burner plates small flames, through which the burner plates are made to glow and as radiant heaters Act.
  • the temperature of the radiating burner plates depends on the temperature resistance of the burner plate material between about 900 ° C and 950 ° C.
  • Radiant gas burners are used, among other things. in space heating, in Hot water conditioners, in drying systems and especially in gas cooking devices.
  • thermoelectric monitoring for example, the ignition device or the main burner only an indirect control of the proper Represents operation of the burner.
  • the object of the invention is to create a cost-effective, reliable Safety device for gas radiant burners that monitor allowed directly at the location of the flame.
  • the burner plate itself is used for ignition protection.
  • the invention takes advantage of the fact that the Usually used burner plate materials, such as. B. ceramics or metals, have a strongly temperature-dependent electrical resistance. The operating state of the burner can thus be simple on the measurement of the electrical resistance of the burner plate material be recorded.
  • All burner plate materials are suitable for the present invention, whose electrical resistance is in the for the present application relevant temperature range of 100 - 900 ° C sufficiently strong and changes sufficiently quickly. For a simple regulation, it is sufficient in the Rule off when the resistance is within the temperature range described changes by at least 10%, but a change by 20% is preferred. The The rate of change in temperature and thus the resistance must be be so large that the ones prescribed in the relevant standards (for Europe EN 30) Safety time between extinguishing the flame and blocking the Gas supply or re-ignition is maintained.
  • the invention is preferably used in burner plates made of fiber material, for example made of metal or ceramic fibers because their thermal Mass is very low, resulting in a rapid change in temperature and resistance leads.
  • Burner plates from Global are particularly preferred Environmental solutions made of SiC fibers, such as z. B. in Advanced Gas-Powered Smoothtop, Proceedings of the International Appliance Technical Conference, Madison, Wisconsin, May 10-11, 1994. This Burner plate material not only has a suitable resistance / temperature curve on, it also speaks because of its low thermal Mass very quickly to changes in burner performance. details this is explained in the exemplary embodiment.
  • Suitable evaluation circuits are known in the prior art and in numerous embodiments.
  • an evaluation circuit has the following elements: current source, signal amplifier, switching amplifier and solenoid valve.
  • the structure of such a circuit is known to the person skilled in the art.
  • the evaluation takes place via the absolute values of the resistance signal.
  • So z. B. a predetermined resistance value that corresponds to a certain current can be used as a threshold value for triggering the re-ignition or switching off the gas supply.
  • a burner plate made of SiC fibers with the usual dimensions of z. B. 180 mm diameter, for example after 5 sec, a temperature of about 700 ° C.
  • the specific electrical resistance of a suitable SiC fiber material drops, for example, from 2 ⁇ 10 4 to below 10 3 ⁇ ⁇ cm.
  • the resistance value for a particular burner in both cold and is also known in the hot state these two values, if necessary under Add a security surcharge to take into account a possible Resistance aging, to monitor the burner using a suitable evaluation circuit.
  • the resistance is of the order of magnitude of the upper value, it shows that no flame burns what a new ignition or after several unsuccessful ignition attempts or After a predetermined period of time, the gas supply is switched off. If the resistance is in the range of the lower value, the burner burns perfectly. If the resistance is very small, there is a short circuit and if the resistance is extremely high, there is an interruption, both of which should lead to the gas supply being switched off for safety reasons.
  • the change in the resistance signal can also be used used over time.
  • the Evaluation circuit additionally a differentiator.
  • the change of the signal becomes very large when it is switched on or off (see also Figure 6) and their evaluation represents a procedure that also includes the safety times adheres to, but at the same time from slow material changes (such as aging) or a drift of the evaluation electronics is free. Do not kick when switching on, or when switching off, a change in resistance which is a sign that there is a short or an open circuit, what leads to the safety circuit responding.
  • DC voltage, AC voltage or a pulse-shaped signal can be used for electronic evaluation. Since the resistance of the plate in Operation must be in a very specific area, this can be used for detection of short circuits or interruptions in the supply line between the burner plate and electronics are used.
  • the evaluation can also be pulse-shaped Signals used to improve the security of the overall system as there is not only a need to have a voltage here (which may can also occur as a disturbance), but the signal is also correct Frequency must have.
  • the temperature measuring resistor according to the invention made of burner plate material can also be used to monitor the temperature of the burner plate become.
  • burner plates made of fiber material e.g. B. SiC fibers
  • the advantage here is that one has an easier contacting of the (wire-shaped) conductor. Farther is a very well-defined geometry due to the fiber / the fiber bundle given the temperature sensor, so that only small tolerances in the manufacture given are.
  • the Burner plates do not consist entirely of SiC; the only important thing is that the heated top layer consists of SiC.
  • the burner plate can For example, for large formats, a sandwich structure from a mechanical Have support structure and the active fiberboard.
  • the present invention has the particular advantage that security monitoring is made exactly at the point where actually Flames arise or go out. A detour via indirect measurements, such as common in the prior art is not required. This results in greater security. Furthermore, the invention is distinguished Safety device through a simple and inexpensive construction out.
  • Fig. 1 For three different SiC modifications that of manufactured by Nippon Carbon and are commercially available, the course of the specific electrical resistance with the temperature. This representation was taken from a manufacturer's data sheet. Man recognizes that SiC materials with very different resistance profiles are producible. It is the commercially available SiC materials around materials whose resistance increases sharply with increasing temperature sinks. Because these materials are often used for electrical heating for SiC materials, the course of the resistance with temperature usually specified by the manufacturer. Details about on which way the resistance behavior of these materials is targeted manufacturers can not be influenced, however, announce. See the expert therefore set himself the task for the invention Safety device to find suitable SiC materials, so he will i. a. use the manufacturer's information mentioned above, or the Determine resistance behavior yourself experimentally. He will then choose such materials as burner plate material, their resistance changes as much as possible in the temperature range of interest.
  • Figures 2 to 4 are different ways to attach the electrical contacts (1) to the burner plate (2) of a gas radiation burner (3).
  • the burner plate (2) is on the hot top during operation contacted.
  • the plate (2) must be of the metallic Mixing chamber (4) must be mounted electrically insulated.
  • the total resistance is made up of the parallel connection the resistors on the bottom and top of the plate (2) together. Is a Flame present, the resistance at the top drops so that the total resistance the arrangement drops.
  • the Contact made in the interior of the plate (2) on the underside, the plate (2) must not be installed insulated from the mixing chamber (4) become.
  • the electrical resistance between the two contact points in the hotter interior of the burner plate is much lower than that Resistance in the outside area, so that the current flow towards the edge is negligible is.
  • the electrical resistance in the Operation a parallel connection of resistance at the bottom of the plate (2) and resistance at the top as in Fig. 3.
  • the temperature of the contact point is also so low in burner operation ( ⁇ 100 ° C) that many Contacting procedures can be applied, e.g. B. gluing with conductive Epoxy resin.
  • the temperature can reach over 700 ° C, so that practically only welding processes can be used here.
  • the igniter such as customary in the prior art, mounted above the burner plate in the exhaust duct.
  • the plate was placed on a plate used for gas cookers with a glass ceramic cover Mixing chamber mounted; the leads were through the chamber floor guided.
  • the plate was connected to 6 V via a series resistor of 470 ⁇ AC voltage applied.
  • the voltage across the series resistor was measured with a Single channel recorder recorded.
  • the voltage drop became the electrical resistance of the burner plate during operation and its temporal Derivation calculated and shown in Figures 5 and 6.
  • the curves represent the course of the calculated values when the ignition and extinction of the Brenners.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Control Of Combustion (AREA)
  • Gas Burners (AREA)
  • Regulation And Control Of Combustion (AREA)
  • Feeding And Controlling Fuel (AREA)

Description

Die Erfindung betrifft eine Sicherheitseinrichtung für Gasstrahlungsbrenner mit einer elektrischen Zündsicherung gegen unverbraucht abströmendes Gas und damit in Wirkverbindung stehenden Einrichtungen zum Zünden des Gases bzw. Unterbrechen der Gaszufuhr bei Erlöschen der Flamme.The invention relates to a safety device for gas radiation burners with an electrical fuse to prevent unused outflow Gas and related devices for igniting the gas or interrupt the gas supply when the flame goes out.

Gasstrahlungsbrenner sind bekannt und beispielsweise in der DE 24 40 701 C3 beschrieben. Sie zeichnen sich im wesentlichen durch poröse, perforierte Brennerplatten z. B aus Keramik aus, welche die Mischkammern der Gasbrenner nach oben hin abschließen. Im Betrieb brennen am oberen Ende der Kanäle der perforierten bzw. durchlöcherten Brennerplatten kleine Flammen, durch welche die Brennerplatten zum Glühen gebracht werden und als Heizstrahler wirken.Gas radiation burners are known and for example in DE 24 40 701 C3 described. They are mainly characterized by porous, perforated Burner plates z. B made of ceramic, which is the mixing chamber of the gas burner lock upwards. In operation burn at the top of the Channels of the perforated or perforated burner plates small flames, through which the burner plates are made to glow and as radiant heaters Act.

Die Temperatur der strahlenden Brennerplatten liegt je nach der Temperaturbeständigkeit des Brennerplattenmaterials zwischen etwa 900 °C und 950°C.The temperature of the radiating burner plates depends on the temperature resistance of the burner plate material between about 900 ° C and 950 ° C.

Gasstrahlungsbrenner finden ihren Einsatz u.a. bei der Raumbeheizung, in Heißwasseraufbereitern, bei Trocknungsystemen und insbesondere bei Gaskocheinrichtungen.Radiant gas burners are used, among other things. in space heating, in Hot water conditioners, in drying systems and especially in gas cooking devices.

Gaskocheinrichtungen mit Gasstrahlungsbrennern und Glaskeramikkochplatte sind in zahlreichen Ausführungsformen beschrieben worden, so z. B. in der DE-OS 26 21 801, DE 33 15 745 A1, US-PS 4,083,355 oder in der US-PS 4,201,184. Gas cooking devices with gas radiant burners and glass ceramic hot plates have been described in numerous embodiments, e.g. B. in the DE-OS 26 21 801, DE 33 15 745 A1, US-PS 4,083,355 or in the US-PS 4,201,184.

Bei einer Gaskocheinrichtung sind ein oder mehrere solche Gasstrahlungsbrenner mit Abstand unter einer gemeinsamen, an sich bekannten Glaskeramikplatte angeordnet, wobei durch jeden Brenner an der Oberseite der Glaskeramikplatte eine Kochstelle definiert wird. Jeder einzelne Gasstrahlungsbrenner ist dabei mit einer Zündeinrichtung und mit einer Zündsicherung versehen. Die Zündsicherung dient der Überwachung des Vorhandenseins der Flamme. Verlöscht diese durch eine Betriebsstörung, müssen Maßnahmen gegen das Abströmen unverbrauchten Brenngasgemischs ergriffen werden. Derzeit sind folgende Lösungen üblich:

  • 1. Pilotflamme, die für eine Rückzündung des Brenners sorgt, die wiederum thermoelektrisch überwacht wird (z. B. DE 34 09 334 C2, EP 0 433 209 A1);
  • 2. Ionisationsüberwachung der heißen Abgase über der Brennerplatte (z. B. DE 26 21 801 C2);
  • 3. Thermoelektrische Überwachung des Hauptbrenners (z. B. DE G 86 25 847, U1; DE 37 32 271 C2);
  • 4. Periodische Funkenzündung des Hauptbrenners (z. B. DE 26 33 849 C3).
  • 5. Glühzünder im Dauerbetrieb mit thermoelektrischer Überwachung (z. B. DE 26 41 274 C3).
  • In the case of a gas cooking device, one or more such gas radiation burners are arranged at a distance below a common glass ceramic plate known per se, a cooking zone being defined by each burner on the upper side of the glass ceramic plate. Each individual gas radiation burner is provided with an ignition device and with an ignition fuse. The ignition fuse is used to monitor the presence of the flame. If this goes out due to a malfunction, measures must be taken to prevent the unused fuel gas mixture from flowing out. The following solutions are currently common:
  • 1. pilot flame, which ensures that the burner reignites, which in turn is monitored thermoelectrically (for example DE 34 09 334 C2, EP 0 433 209 A1);
  • 2. Ionization monitoring of the hot exhaust gases above the burner plate (e.g. DE 26 21 801 C2);
  • 3. Thermoelectric monitoring of the main burner (e.g. DE G 86 25 847, U1; DE 37 32 271 C2);
  • 4. Periodic spark ignition of the main burner (e.g. DE 26 33 849 C3).
  • 5. Glow igniter in continuous operation with thermoelectric monitoring (e.g. DE 26 41 274 C3).
  • Diese Maßnahmen haben den Nachteil, daß sie zum Teil technisch aufwendig sind und daß die thermoelektrische Überwachung beispielsweise der Zündeinrichtung oder des Hauptbrenners nur eine indirekte Kontrolle des ordnungsgemäßen Betriebs des Brenners darstellt.These measures have the disadvantage that they are sometimes technically complex are and that the thermoelectric monitoring, for example, the ignition device or the main burner only an indirect control of the proper Represents operation of the burner.

    Aufgabe der Erfindung ist die Schaffung einer kostengünstigen betriebssicheren Sicherheitseinrichtung für Gasstrahlungsbrenner, die eine Überwachung direkt am Ort der Flamme erlaubt. The object of the invention is to create a cost-effective, reliable Safety device for gas radiant burners that monitor allowed directly at the location of the flame.

    Diese Aufgabe wird gelöst mit einem Gasstrahlungsbrenner mit allen Merkmalen des Patentanspruchs 1.This object is achieved with a gas radiation burner with all the features of claim 1.

    Gemäß der Erfindung wird zur Zündsicherung die Brennerplatte selbst herangezogen. Die Erfindung macht sich hierbei die Tatsache zunutze, daß die üblicherweise eingesetzten Brennerplattenmaterialien, wie z. B. Keramiken oder Metalle, einen stark temperaturabhängigen elektrischen Widerstand besitzen. Der Betriebszustand des Brenners kann somit in einfacher Weise über die Messung des elektrischen Widerstandes des Brennerplattenmaterials erfaßt werden.According to the invention, the burner plate itself is used for ignition protection. The invention takes advantage of the fact that the Usually used burner plate materials, such as. B. ceramics or metals, have a strongly temperature-dependent electrical resistance. The operating state of the burner can thus be simple on the measurement of the electrical resistance of the burner plate material be recorded.

    Es genügt hierzu, die Brennerplatte an den dafür vorgesehenen Stellen mit elektrischen Anschlüssen zu versehen, die mit einer geeigneten Auswerteschaltung verbunden sind (ggf. muß noch für eine elektrische Isolierung der Brennerplatte von der metallischen Mischkammer des Brenners gesorgt werden). In Abhängigkeit von den an der Brennerplatte erhaltenen Signalen können dann über die Auswerteschaltung die an der Brennerplatte vorhandenen Zündeinrichtungen, wie beispielsweise Glühzünder, Funkenzünder u.a., oder aber auch Ventile zur Unterbrechung der Gaszufuhr zu der jeweiligen Brennerplatte betätigt werden.It is sufficient to have the burner plate in the designated places to provide electrical connections with a suitable evaluation circuit are connected (may still need electrical insulation the burner plate is taken care of by the burner's metallic mixing chamber will). Depending on the signals received on the burner plate can then the existing on the burner plate via the evaluation circuit Ignition devices, such as glow igniters, spark igniters, etc. or else valves to interrupt the gas supply to the respective Burner plate can be operated.

    Für die vorliegende Erfindung sind alle Brennerplattenmaterialien geeignet, deren elektrischer Widerstand sich in dem für die vorliegende Anwendung relevanten Temperaturbereich von 100 - 900 °C ausreichend stark und ausreichend schnell ändert. Für eine einfache Regelung reicht es in der Regel aus, wenn sich der Widerstand im beschriebenen Temperaturbereich mindestens um 10 % ändert, bevorzugt ist jedoch eine Änderung um 20 %. Die Geschwindigkeit der Änderung der Temperatur und damit des Widerstandes muß so groß sein, daß die in den relevanten Normen (für Europa EN 30) vorgeschriebene Sicherheitszeit zwischen Verlöschen der Flamme und Sperrung der Gaszufuhr bzw. erneuter Zündung eingehalten wird. Besonders geeignet sind hoch temperaturbeständige Materialien mit stark positivem oder negativem Temperaturkoeffizienten. All burner plate materials are suitable for the present invention, whose electrical resistance is in the for the present application relevant temperature range of 100 - 900 ° C sufficiently strong and changes sufficiently quickly. For a simple regulation, it is sufficient in the Rule off when the resistance is within the temperature range described changes by at least 10%, but a change by 20% is preferred. The The rate of change in temperature and thus the resistance must be be so large that the ones prescribed in the relevant standards (for Europe EN 30) Safety time between extinguishing the flame and blocking the Gas supply or re-ignition is maintained. Are particularly suitable high temperature resistant materials with strong positive or negative Temperature coefficient.

    Vorzugsweise wird die Erfindung bei Brennerplatten aus Fasermaterial, beispielsweise aus Metall- oder Keramikfasern eingesetzt, da deren thermische Masse sehr gering ist, was zu einer schnellen Temperatur- und Widerstandsänderung führt. Besonders bevorzugt sind Brennerplatten der Firma Global Environmental Solutions aus SiC-Fasern, wie sie z. B. in Advanced Gas-Powered Smoothtop, Proceedings of the International Appliance Technical Conference, Madison, Wisconsin, May 10 - 11, 1994, beschrieben sind. Dieses Brennerplattenmaterial weist nicht nur einen geeigneten Widerstands/Temperaturverlauf auf, es spricht auch aufgrund seiner geringen thermische Masse sehr schnell auf Änderungen in der Brennerleistung an. Einzelheiten hierzu sind im Ausführungsbeispiel erläutert.The invention is preferably used in burner plates made of fiber material, for example made of metal or ceramic fibers because their thermal Mass is very low, resulting in a rapid change in temperature and resistance leads. Burner plates from Global are particularly preferred Environmental solutions made of SiC fibers, such as z. B. in Advanced Gas-Powered Smoothtop, Proceedings of the International Appliance Technical Conference, Madison, Wisconsin, May 10-11, 1994. This Burner plate material not only has a suitable resistance / temperature curve on, it also speaks because of its low thermal Mass very quickly to changes in burner performance. details this is explained in the exemplary embodiment.

    Geeignete Auswerteschaltungen sind Stand der Technik und in zahlreichen Ausführungsformen bekannt. Eine Auswerteschaltung weist im einfachsten Fall folgende Elemente auf: Stromquelle, Signalverstärker, Schaltverstärker und Magnetventil. Dem Fachmann ist der Aufbau einer solchen Schaltung bekannt. Die Auswertung erfolgt im obigen Fall über die Absolutwerte des Widerstandssignals. So kann z. B. ein vorgegebener Widerstandswert, der einem bestimmten Strom entspricht als Schwellenwert für die Auslösung der erneuten Zündung bzw. das Abschalten der Gaszufuhr verwendet werden. Nach erfolgreicher Zündung hat eine Brennerplatte aus SiC-Fasern mit den üblichen Abmessungen von z. B. 180 mm Durchmesser beispielsweise nach 5 sec eine Temperatur von ca. 700 °C. Während des Aufheizens fällt der spezifische elektrische Widerstand eines geeigneten SiC-Fasermaterials beispielsweise von 2 x 104 auf unter 103 Ω x cm.Suitable evaluation circuits are known in the prior art and in numerous embodiments. In the simplest case, an evaluation circuit has the following elements: current source, signal amplifier, switching amplifier and solenoid valve. The structure of such a circuit is known to the person skilled in the art. In the above case, the evaluation takes place via the absolute values of the resistance signal. So z. B. a predetermined resistance value that corresponds to a certain current can be used as a threshold value for triggering the re-ignition or switching off the gas supply. After successful ignition, a burner plate made of SiC fibers with the usual dimensions of z. B. 180 mm diameter, for example after 5 sec, a temperature of about 700 ° C. During heating, the specific electrical resistance of a suitable SiC fiber material drops, for example, from 2 × 10 4 to below 10 3 Ω × cm.

    Da für einen bestimmten Brenner der Widerstandswert sowohl im kalten als auch im heißen Zustand bekannt ist, können diese beiden Werte, ggf. unter Hinzufügen eines Sicherheitszuschlags zur Berücksichtigung einer eventuellen Alterung des Widerstands, zur Überwachung des Brenners mittels einer geeigneten Auswerteschaltung dienen. Liegt der Widerstand in der Größenordnung des oberen Wertes, so zeigt das, daß keine Flamme brennt, was zu einer erneuten Zündung oder nach mehreren vergeblichen Zündversuchen oder Ablauf einer vorgegebenen Zeitspanne zum Abschalten der Gaszufuhr führt. Liegt der Widerstand im Bereich des unteren Wertes, brennt der Brenner einwandfrei. Ist der Widerstand sehr klein, so liegt ein Kurzschluß vor und ist der Widerstand extrem groß, liegt eine Unterbrechung vor, was beides aus Sicherheitsgründen zur Abschaltung der Gaszufuhr führen sollte.As the resistance value for a particular burner in both cold and is also known in the hot state, these two values, if necessary under Add a security surcharge to take into account a possible Resistance aging, to monitor the burner using a suitable evaluation circuit. The resistance is of the order of magnitude of the upper value, it shows that no flame burns what a new ignition or after several unsuccessful ignition attempts or After a predetermined period of time, the gas supply is switched off. If the resistance is in the range of the lower value, the burner burns perfectly. If the resistance is very small, there is a short circuit and if the resistance is extremely high, there is an interruption, both of which should lead to the gas supply being switched off for safety reasons.

    Alternativ zur Auswertung der Absolutwerte kann auch die Änderung des Widerstandssignals mit der Zeit verwendet werden. Im diesem Fall weist die Auswerteschaltung noch zusätzlich einen Differentiator auf. Die Änderung des Signals wird im Ein- bzw. Ausschaltmoment sehr groß (s. auch Figur 6) und ihre Auswertung stellt ein Verfahren dar, das ebenfalls die Sicherheitszeiten einhält, gleichzeitig aber von langsamen Materialveränderungen (wie Alterung) oder einer Drift der Auswerteelektronik frei ist. Tritt weder beim Ein-, noch beim Ausschalten eine Widerstandsänderung auf, so ist das ein Zeichen, daß ein Kurzschluß oder eine Unterbrechung vorliegt, was zum Ansprechen der Sicherheitsschaltung führt.As an alternative to evaluating the absolute values, the change in the resistance signal can also be used used over time. In this case, the Evaluation circuit additionally a differentiator. The change of the signal becomes very large when it is switched on or off (see also Figure 6) and their evaluation represents a procedure that also includes the safety times adheres to, but at the same time from slow material changes (such as aging) or a drift of the evaluation electronics is free. Do not kick when switching on, or when switching off, a change in resistance which is a sign that there is a short or an open circuit, what leads to the safety circuit responding.

    Für die elektronische Auswertung kann Gleichspannung, Wechselspannung oder ein pulsförmiges Signal verwendet werden. Da der Widerstand der Platte im Betrieb in einem ganz bestimmten Bereich sein muß, kann dies zur Erkennung von Kurzschlüssen oder Unterbrechungen in der Zuleitung zwischen Brennerplatte und Elektronik benutzt werden. Ebenso kann die Auswertung pulsförmiger Signale zur Verbesserung der Sicherheit des Gesamtsystmes benutzt werden, da hier nicht nur eine Spannung vorhanden sein muß (die eventuell auch als Störung auftreten kann), sondern das Signal auch noch die korrekte Frequenz besitzen muß.For electronic evaluation, DC voltage, AC voltage or a pulse-shaped signal can be used. Since the resistance of the plate in Operation must be in a very specific area, this can be used for detection of short circuits or interruptions in the supply line between the burner plate and electronics are used. The evaluation can also be pulse-shaped Signals used to improve the security of the overall system as there is not only a need to have a voltage here (which may can also occur as a disturbance), but the signal is also correct Frequency must have.

    Der erfindungsgemäße Temperaturmeßwiderstand aus Brennerplattenmaterial kann zusätzlich noch zur Temperaturüberwachung der Brennerplatte genutzt werden.The temperature measuring resistor according to the invention made of burner plate material can also be used to monitor the temperature of the burner plate become.

    Bei Verwendung von Brennerplatten aus Fasermaterial, z. B. SiC-Fasern, kann es zweckmäßig sein, als Temperaturmeßwiderstand in die Brennerplatte eine einzelne Faser oder ein Faserbündel einzuweben und die Enden durch die Platte nach oben oder unten durchzuführen. Vorteilhaft ist hier, daß man eine einfachere Kontaktierung des (drahtförmigen) Leiters hat. Weiterhin ist durch die Faser/das Faserbündel eine sehr gut definierte Geometrie des Temperatursensors gegeben, so daß nur geringe Toleranzen in der Herstellung gegeben sind.When using burner plates made of fiber material, e.g. B. SiC fibers, it may be useful as a temperature measuring resistor in the burner plate weave a single fiber or bundle of fibers and thread the ends through to perform the plate up or down. The advantage here is that one has an easier contacting of the (wire-shaped) conductor. Farther is a very well-defined geometry due to the fiber / the fiber bundle given the temperature sensor, so that only small tolerances in the manufacture given are.

    Nach diesem Vorbild lassen sich auch mehrere Fasern auf einer Platte verlegen, so daß Mittenbereich und Randbereich getrennt ausgewertet werden können. Auf diese Art und Weise ließe sich analog zu dem in DE-PS 40 22 844 oder US-PS 52 27 610 für Glaskeramikkochflächen mit integriertem Temperatursensor beschriebenen Verfahren aus der unterschiedlichen Erwärmung von Mitten- und Randbereich auf die Ursache der Überhitzung schließen. Beispielsweise könnte man zwischen der Verwendung schlechten Geschirrs und Leerlauf ohne Geschirr unterscheiden. Bei einer typischen Anordnung ist im Leerlauf die Temperatur in der Mitte 950 °C und am Rand 930 °C, während bei Verwendung eines schlechten Topfes in der Mitte 980 °C und am Rand 900°C gemessen werden.Following this model, several fibers can also be laid on a board, so that the central area and the peripheral area are evaluated separately can. In this way it could be analogous to that in DE-PS 40 22nd 844 or US-PS 52 27 610 for glass ceramic cooktops with integrated temperature sensor described method from the different heating deduce the cause of the overheating from the middle and edge area. For example, you could choose between using bad dishes and Distinguish idling without dishes. In a typical arrangement Idle the temperature in the middle 950 ° C and at the edge 930 ° C while when using a bad pot in the middle 980 ° C and at the edge 900 ° C can be measured.

    Bei Anwendung der erfindungsgemäßen Sicherheitseinrichtung müssen die Brennerplatten nicht vollständig aus SiC bestehen; wichtig ist lediglich, daß die beheizte oberste Schicht aus SiC besteht. Die Brennerplatte kann beispielsweise für große Formate einen Sandwichaufbau aus einer mechanischen Stützkonstruktion und der aktiven Faserplatte aufweisen.When using the safety device according to the invention, the Burner plates do not consist entirely of SiC; the only important thing is that the heated top layer consists of SiC. The burner plate can For example, for large formats, a sandwich structure from a mechanical Have support structure and the active fiberboard.

    Die vorliegende Erfindung hat insbesondere den Vorteil, daß die Sicherheitsüberwachung genau an der Stelle vorgenommen wird, an der tatsächlich Flammen entstehen oder erlöschen. Ein Umweg über indirekte Messungen, wie im Stand der Technik üblich, ist nicht erforderlich. Hieraus resultiert eine größere Sicherheit. Des weiteren zeichnet sich die erfindungsgemäße Sicherheitseinrichtung durch einen einfachen und kostengünstigen Aufbau aus.The present invention has the particular advantage that security monitoring is made exactly at the point where actually Flames arise or go out. A detour via indirect measurements, such as common in the prior art is not required. This results in greater security. Furthermore, the invention is distinguished Safety device through a simple and inexpensive construction out.

    Nachfolgend wird die Erfindung anhand der Figuren und eines Ausführungsbeispiels näher erläutert: The invention is described below with reference to the figures and an exemplary embodiment explained in more detail:

    Es zeigen:

    Figur 1:
    in einer graphischen Darstellung den Verlauf des spezifischen elektrischen Widerstandes als Funktion der Temperatur für verschiedene SiC-Modifikationen;
    Figuren 2 bis 4:
    in einer schematischen Querschnittsdarstellung Gasstrahlungsbrenner mit unterschiedlicher elektrischer Kontaktierung;
    Figur 5:
    in einer graphischen Darstellung den Verlauf des elektrischen Widerstandes als Funktion der Temperatur in der Aufheiz- und Abkühlphase gemessen an einer SiC-Brennerplatte gem. Ausführungsbeispiel;
    Figur 6:
    in einer graphischen Darstellung die erste Ableitung der Kurven aus Figur 5.
    Show it:
    Figure 1:
    in a graphic representation the course of the specific electrical resistance as a function of temperature for various SiC modifications;
    Figures 2 to 4:
    in a schematic cross-sectional view gas radiation burner with different electrical contacts;
    Figure 5:
    in a graphic representation the course of the electrical resistance as a function of the temperature in the heating and cooling phase measured on a SiC burner plate acc. Embodiment;
    Figure 6:
    the first derivative of the curves from FIG. 5 in a graphical representation.

    Man erkennt in Fig. 1 für drei verschiedene SiC-Modifikationen, die von der Firma Nippon Carbon hergestellt werden und im Handel erhältlich sind, den Verlauf des spezifischen elektrischen Widerstandes mit der Temperatur. Diese Darstellung wurde einem Datenblatt des Herstellers entnommen. Man erkennt, daß SiC-Materialien mit sehr unterschiedlichem Widerstandsverlauf herstellbar sind. Es handelt sich bei den im Handel erhältlichen SiC-Materialien um Werkstoffe, deren Widerstand stark mit ansteigender Temperatur absinkt. Da diese Werkstoffe häufig zur elektrischen Beheizung verwendet werden, wird für SiC-Materialien der Verlauf des Widerstandes mit der Temperatur in der Regel vom Hersteller angegeben. Einzelheiten darüber, auf welche Art und Weise das Widerstandsverhalten dieser Materialien gezielt beeinflußt werden kann, geben die Hersteller jedoch nicht bekannt. Sieht sich der Fachmann daher vor die Aufgabe gestellt, für die erfindungsgemäße Sicherheitseinrichtung geeignete SiC-Materialien aufzufinden, so wird er i. a. hierzu die oben erwähnten Herstellerangaben heranziehen, bzw. das Widerstandsverhalten selbst experimentell bestimmen. Er wird sich dann solche Materialien als Brennerplattenmaterial aussuchen, deren Widerstand sich im interessierenden Temperaturbereich möglichst stark ändert. One can see in Fig. 1 for three different SiC modifications that of manufactured by Nippon Carbon and are commercially available, the course of the specific electrical resistance with the temperature. This representation was taken from a manufacturer's data sheet. Man recognizes that SiC materials with very different resistance profiles are producible. It is the commercially available SiC materials around materials whose resistance increases sharply with increasing temperature sinks. Because these materials are often used for electrical heating for SiC materials, the course of the resistance with temperature usually specified by the manufacturer. Details about on which way the resistance behavior of these materials is targeted manufacturers can not be influenced, however, announce. See the expert therefore set himself the task for the invention Safety device to find suitable SiC materials, so he will i. a. use the manufacturer's information mentioned above, or the Determine resistance behavior yourself experimentally. He will then choose such materials as burner plate material, their resistance changes as much as possible in the temperature range of interest.

    In den Figuren 2 bis 4 sind verschiedene Möglichkeiten zur Anbringung der elektrischen Kontakte (1) an die Brennerplatte (2) eines Gasstrahlungsbrenners (3) dargestellt.In Figures 2 to 4 are different ways to attach the electrical contacts (1) to the burner plate (2) of a gas radiation burner (3).

    In Fig. 2 ist die Brennerplatte (2) an der im Betrieb heißen Oberseite kontaktiert. Bei dieser Anordnung muß die Platte (2) von der metallischen Mischkammer (4) elektrisch isoliert montiert sein. Alternativ kann die Kontaktierung gemäß Fig. 3 an der im Betrieb kalten Unterseite erfolgen. Der Gesamtwiderstand setzt sich in diesem Falle aus der Parallelschaltung der Widerstände an Unter- und Oberseite der Platte (2) zusammen. Ist eine Flamme vorhanden, sinkt der Widerstand an der Oberseite, so daß der Gesamtwiderstand der Anordnung absinkt. Wird, wie in Fig. 4 dargestellt, die Kontaktierung im Innenbereich der Platte (2) auf der Unterseite vorgenommen, muß die Platte (2) nicht isoliert von der Mischkammer (4) eingebaut werden. Der elektrische Widerstand zwischen den beiden Kontaktstellen im heißeren Innenbereich der Brennerplatte ist wesentlich niedriger als der Widerstand im Außenbereich, so daß der Stromfluß zum Rand hin vernachlässigbar ist. Auch bei dieser Anordnung ist der elektrische Widerstand im Betrieb eine Parallelschaltung von Widerstand an der Unterseite der Platte (2) und Widerstand an der Oberseite wie in Fig. 3.In Fig. 2 the burner plate (2) is on the hot top during operation contacted. In this arrangement, the plate (2) must be of the metallic Mixing chamber (4) must be mounted electrically insulated. Alternatively, the 3 on the cold bottom during operation. In this case, the total resistance is made up of the parallel connection the resistors on the bottom and top of the plate (2) together. Is a Flame present, the resistance at the top drops so that the total resistance the arrangement drops. As shown in Fig. 4, the Contact made in the interior of the plate (2) on the underside, the plate (2) must not be installed insulated from the mixing chamber (4) become. The electrical resistance between the two contact points in the hotter interior of the burner plate is much lower than that Resistance in the outside area, so that the current flow towards the edge is negligible is. With this arrangement, the electrical resistance in the Operation a parallel connection of resistance at the bottom of the plate (2) and resistance at the top as in Fig. 3.

    Zu bevorzugen ist die Kontaktierung von unten, da die Temperatur der Kontaktstelle auch im Brennerbetrieb so niedrig ist (< 100 °C), daß viele Kontaktierungsverfahren angewandt werden können, z. B. Kleben mit leitfähigem Epoxydharz. Auf der Oberseite kann die Temperatur über 700 °C erreichen, sodaß hier praktisch nur Schweißverfahren zum Einsatz kommen können.Contacting from below is preferred, since the temperature of the contact point is also so low in burner operation (<100 ° C) that many Contacting procedures can be applied, e.g. B. gluing with conductive Epoxy resin. On the top, the temperature can reach over 700 ° C, so that practically only welding processes can be used here.

    Bei allen oben beschriebenen Anordnungen wird die Zündeinrichtung, so wie im Stand der Technik üblich, oberhalb der Brennerplatte im Abgaskanal montiert. In all of the arrangements described above, the igniter, such as customary in the prior art, mounted above the burner plate in the exhaust duct.

    AusführungsbeispielEmbodiment

    Auf die Unterseite (den Flammen abgewandt) einer Brennerplatte aus SiC (α Modifikation) mit einem Durchmesser von 14.5 cm und einer Dicke von 4 mm wurden - jeweils 1 cm vom Außenrand entfernt - zwei Drähte aus Kupferlitze mit leitfähigem Epoxidharzkleber (Typ Elecolit 323 a+b) angeklebt.On the underside (facing away from the flames) of a burner plate made of SiC (α Modification) with a diameter of 14.5 cm and a thickness of 4 mm - 1 cm from the outer edge - two wires made of copper braid glued with conductive epoxy resin adhesive (type Elecolit 323 a + b).

    Die Platte wurde auf eine für Gasherde mit Glaskeramikabdeckung gebräuchliche Mischkammer montiert; die Anschlußdrähte wurden durch den Kammerboden geführt. Über einen Vorwiderstand von 470 Ω wurde die Platte mit 6 V Wechselspannung beaufschlagt. Die Spannung am Vorwiderstand wurde mit einem Einkanal-Schreiber aufgezeichnet. Aus dem Spannungsabfall wurde der elektrische Widerstand der Brennerplatte im Betrieb sowie dessen zeitliche Ableitung berechnet und in den Figuren 5 und 6 dargestellt. Die Kurven stellen den Verlauf der errechneten Werte bei Zündung und Verlöschen des Brenners dar.The plate was placed on a plate used for gas cookers with a glass ceramic cover Mixing chamber mounted; the leads were through the chamber floor guided. The plate was connected to 6 V via a series resistor of 470 Ω AC voltage applied. The voltage across the series resistor was measured with a Single channel recorder recorded. The voltage drop became the electrical resistance of the burner plate during operation and its temporal Derivation calculated and shown in Figures 5 and 6. The curves represent the course of the calculated values when the ignition and extinction of the Brenners.

    Man erkennt anhand der Fign. 5 und 6, daß der Widerstand beim Einschalten ("B ein") so stark sinkt, daß problemlos in diesem Versuchsaufbau innerhalb der in EN 30 vorgeschriebenen Sicherheitszeit von 10 s die Flamme erkannt wird. Ebenso wird ein Verlöschen der Flamme ("B aus") innerhalb der Sicherheitszeit von 60 s erkannt.You can see from the fig. 5 and 6 that the resistance when turning on ("B on") drops so much that it is no problem in this experimental setup the flame is recognized within the safety time of 10 s prescribed in EN 30 becomes. Likewise, the flame will go out ("B off") within the Safety time of 60 s recognized.

    In Fig. 5 ist der Absolutwert der Steigung dargestellt; der Wert ist beim Einschalten ("B an") negativ, beim Ausschalten ("B aus") positiv. Der Anstieg ist innerhalb kurzer Zeit von kleinen Werten aus so hoch, daß er leicht auswertbar ist. Nach etwa 10 s sind die Änderungen im Signal nur noch sehr gering, so daß dann bereits der nächste Schaltvorgang detektiert werden könnte.5 shows the absolute value of the slope; the value is at Switch on ("B on") negative, switch off ("B off") positive. The rise is within a short time from small values so high that it is easy to evaluate. After about 10 s the changes in the signal are only still very low, so that the next switching operation is then already detected could be.

    In Fig. 6 wird anstelle werden der Absolutmeßgrößen Änderungsgeschwindigkeiten der weiteren Auswertung zugrunde gelegt. Die Steigungen der Kurven aus Fig. 5 sind im Ein-/Ausschalt-Moment sehr groß, so daß Steuerungen realisiert werden können, mit denen die obengenannten Sicherheitszeiten nicht nur eingehalten, sondern sogar noch ganz erheblich unterschritten werden können.In Fig. 6, instead of the absolute measurands, rates of change are shown based on the further evaluation. The slopes of the curves 5 are very large in the on / off moment, so that controls are implemented with which the above security times not only adhered to, but even fell considerably short of it can be.

    Claims (9)

    1. Radiant gas burner having a safety device which has an ignition safeguard, integrated in the burner plate of the radiant gas burner, against gas escaping unconsumed, and a device, operationally connected thereto, for igniting the gas or interrupting the gas feed when the flame goes out, characterized in that the ignition safeguard comprises the temperature measuring resistor of the burner plate (2) in a limited subregion of the burner plate (2) which makes contact by means of terminal leads (1).
    2. Radiant gas burner according to Claim 1, characterized in that the burner plate (2) consists of ceramic material.
    3. Radiant gas burner according to Claim 1 or 2, characterized in that the burner plate (2) consists of fibrous material.
    4. Radiant gas burner according to Claim 3, characterized in that the burner plate (2) consists of SiC fibres.
    5. Radiant gas burner according to Claim 4, characterized in that continuous SiC fibres or SiC fibre bundles are woven into the burner plate (2) as temperature measuring resistor.
    6. Radiant gas burner according to Claims 1 to 5, characterized in that electrical contact is made with the temperature measuring resistor on the underside of the plate.
    7. Radiant gas burner according to Claim 6, characterized in that the electrical contact is provided in the inner region of the burner plate.
    8. Radiant gas burner according to at least one of Claims 1 to 7, characterized in that mutually independent temperature measuring resistors make contact in each case in the inner region and edge region of the burner plate (2).
    9. Radiant gas burner according to one of Claims 1 to 8, characterized in that the temperature measuring resistor is connected to an evaluation unit which detects both interruption and a short circuit from the fact that the ACTUAL value of the resistor or the rate of change of the resistance lies outside a prescribed range.
    EP95112896A 1994-10-20 1995-08-17 Safety device for gas radiation burners Expired - Lifetime EP0708296B1 (en)

    Applications Claiming Priority (2)

    Application Number Priority Date Filing Date Title
    DE4437510A DE4437510C1 (en) 1994-10-20 1994-10-20 Safety device for gas radiation burners
    DE4437510 1994-10-20

    Publications (2)

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    EP0708296A1 EP0708296A1 (en) 1996-04-24
    EP0708296B1 true EP0708296B1 (en) 1999-04-21

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    EP (1) EP0708296B1 (en)
    JP (1) JP2852010B2 (en)
    KR (1) KR100341090B1 (en)
    BR (1) BR9504459A (en)
    DE (2) DE4437510C1 (en)
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    Publication number Priority date Publication date Assignee Title
    IT1310192B1 (en) * 1999-03-19 2002-02-11 Worgas Bruciatori Srl METHOD AND MEANS FOR THE SAFETY CONTROL OF BURNERS.
    DE10003819C1 (en) * 2000-01-28 2001-05-17 Honeywell Bv Gas burner operating process, involving use of ionization signal and comparing differences in its readings
    ITTO20050685A1 (en) * 2005-09-30 2007-04-01 Indesit Co Spa COOKTOP WITH GAS BURNER INCLUDING A SEMIPERMEABLE ELEMENT
    EP1811230B1 (en) * 2006-01-19 2016-01-06 Vaillant GmbH Method for controlling the air-fuel ratio of a fuel operated burner

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    NL176301C (en) * 1974-08-24 Schwank Gmbh APPLIANCE WITH AT LEAST ONE GAS BURNER FOR A HOB.
    YU109677A (en) 1976-05-15 1982-05-31 Spezialglas Gmbh Glass ceramic surface for cooking by means of the radiating gas-heated surface
    DE2621801C2 (en) * 1976-05-15 1982-09-09 Schott Glaswerke, 6500 Mainz Glass ceramic hob with gas-heated jet burner
    DE2641274C3 (en) 1976-09-14 1979-08-23 Jenaer Glaswerk Schott & Gen., 6500 Mainz Safety device for gas-heated, transparent glass ceramic cooking surfaces
    DE3409334A1 (en) 1984-03-14 1985-09-26 Schott Glaswerke, 6500 Mainz Cooking area with gas-heated burners and a continuous cooking surface made of glass ceramic or comparable material
    DE3315745C2 (en) * 1983-04-30 1986-11-27 Schott Glaswerke, 6500 Mainz Hob with gas-heated burners and a continuous cooking surface made of glass ceramic or comparable material
    JPS6252214A (en) * 1985-08-30 1987-03-06 Toyota Motor Corp How to manufacture stovetops
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    AT396028B (en) * 1990-04-17 1993-05-25 Vaillant Gmbh METHOD FOR CONTROLLING A FULLY PRE-MIXING AREA BURNER
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    JP2648890B2 (en) * 1990-12-28 1997-09-03 一郎 兼坂 Gas heater
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    ES2132479T3 (en) 1999-08-16
    DE4437510C1 (en) 1996-04-04
    KR960014771A (en) 1996-05-22
    EP0708296A1 (en) 1996-04-24
    JP2852010B2 (en) 1999-01-27
    BR9504459A (en) 1997-05-20
    KR100341090B1 (en) 2002-12-28
    DE59505699D1 (en) 1999-05-27
    JPH08210630A (en) 1996-08-20

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