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EP0758693A1 - Demi-produit pour matériau composite - Google Patents

Demi-produit pour matériau composite Download PDF

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Publication number
EP0758693A1
EP0758693A1 EP95112661A EP95112661A EP0758693A1 EP 0758693 A1 EP0758693 A1 EP 0758693A1 EP 95112661 A EP95112661 A EP 95112661A EP 95112661 A EP95112661 A EP 95112661A EP 0758693 A1 EP0758693 A1 EP 0758693A1
Authority
EP
European Patent Office
Prior art keywords
finished product
semi
threads
product according
knitted fabric
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP95112661A
Other languages
German (de)
English (en)
Other versions
EP0758693B1 (fr
Inventor
Alfred Buck
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BUCK, ALFRED
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to DE59509754T priority Critical patent/DE59509754D1/de
Priority to AT95112661T priority patent/ATE207554T1/de
Priority to EP95112661A priority patent/EP0758693B1/fr
Publication of EP0758693A1 publication Critical patent/EP0758693A1/fr
Application granted granted Critical
Publication of EP0758693B1 publication Critical patent/EP0758693B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04B—KNITTING
    • D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/04—Heat-responsive characteristics
    • D10B2401/041—Heat-responsive characteristics thermoplastic; thermosetting
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2403/00—Details of fabric structure established in the fabric forming process
    • D10B2403/01—Surface features
    • D10B2403/011—Dissimilar front and back faces
    • D10B2403/0114—Dissimilar front and back faces with one or more yarns appearing predominantly on one face, e.g. plated or paralleled yarns
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2505/00—Industrial
    • D10B2505/02—Reinforcing materials; Prepregs

Definitions

  • thermoplastics are very well suited to producing complicated molded parts. Different procedures are known for this.
  • thermoplastic synthetic peat can be in the form of pellets and is melted in appropriate injection molding machines and filled into the injection mold under pressure. Such molded parts have only a limited strength, which results solely from the properties of the thermoplastic. However, the injection molding process has so far essentially only been able to produce parts which do not have an excessively unfavorable ratio between the wall thickness and the area of the wall in question.
  • thermoplastic material In the case of less favorable conditions, i.e. parts that are relatively thin in relation to their areal expansion, another procedure is preferred, which consists in first extruding the thermoplastic material as a large film, which is then brought into its final shape in the deep-drawing process. Also these parts have low strength. All that is left to increase the strength is to embed fibers.
  • another technique is used, which consists in embedding long glass fibers in a thermoplastic resin that has not yet fully cured, and in giving this viscous mass in a mold in which the mass is shaped and cured into the appropriate shape.
  • a disadvantage of this process is the limited shelf life of the semi-finished product, which tends to harden completely over time, so that it no longer has the desired, approximately chewing-gum-like consistency. Once cured, it can usually no longer be introduced into complicated shapes.
  • hybrid yarn that consists of approximately 64% carbon fibers and 38% polyamide fibers.
  • This yarn is processed into a textile fabric, for example a knitted fabric.
  • a fiber-reinforced molded body can result from the action of heat while simultaneously pressing the knitted fabric be generated.
  • this hybrid yarn shows an extreme static charge when knitting. The strong electrostatic charge hinders the knitting process, so that knitting or knitting is not practically possible.
  • the hybrid yarn can only be processed into other textile fabrics, such as woven fabrics, scrims and bobbins, i.e. in processes in which the electrostatic charge does not occur or does not interfere.
  • the processing operation cannot vary the mixing ratio between the two materials.
  • the mixing ratio is fixed by the structure of the hybrid yarn.
  • the use of the knitted fabric which consists of threads of two different materials, ensures that comparable amounts of the first and second materials are present in each sufficiently large volume element of the textile fabric.
  • the semi-finished product thus produced can be inserted into any shape that only needs to be heated to melt the thermoplastic second material, that is to bring it to a temperature above the glass transition point, so that it is cohesive, that is to say permanently and firmly with the threads from the first Can connect material. Because of the uniform or uniform distribution of the threads of the second material in the semifinished product, the thermoplastic serving as a binder is already in place inherently at the point where he should glue the threads of the first material together.
  • the semifinished product has the advantage that the mixing ratio between the two materials can be freely selected practically as desired in the processing operation.
  • Any electrostatic charge that might otherwise occur can be prevented by pretreating the electrostatically charging material accordingly before the processing operation. Due to the fact that both materials can be pre-processed separately, knitting problems can be largely avoided.
  • thermoplastic material is evenly distributed over the entire surface of the semi-finished product, the size of the finished product to be manufactured is practically unlimited. By stacking several layers of the semifinished product according to the invention, workpieces of any thickness and of any size can be easily produced.
  • thermoplastic is used.
  • the semi-finished product is not subject to any processing special aging, which would make subsequent processing more difficult. It is also not sticky, and special handling precautions are not necessary, as is the case with some, not fully cured thermoplastics.
  • the semi-finished product consists of individual threads which are essentially not connected to one another, it can also be easily brought into almost any shape. It does not counter any special forces when it is inserted into the shaping tool in question.
  • the second material expediently has a shape memory such that, when heated above a predetermined temperature and then cooled, it maintains the course which it had during the heating. It can thereby be achieved that the structure is predetermined in a certain way during the manufacture of the semi-finished product, whereby, for example, the structure formed by the threads of the first material is held under a predetermined prestress.
  • the first material is preferably not an organic material and can be selected from substances such as metal, ceramic or other inorganic compounds.
  • the mechanical structure of the threads of the first material and the threads of the second material can correspond to the mechanical requirements during manufacture, processing or the requirements for the finished product to be chosen.
  • the threads made of the second material are continuous yarns or monofilaments, since the thermoplastic material can be easily brought into this form.
  • continuous fibers can only be produced to a limited extent under certain circumstances, which is why yarns made from staple fibers can be useful there.
  • the long mesh legs in turn result in good strength of the finished product produced from the semifinished product according to the invention.
  • the threads of the first and the second material can either be distributed randomly on the front and the back, as a result of which the thermoplastic material is easily penetrated evenly through the knitted fabric formed from the first threads.
  • a so-called plated product can also be used, in which the thermoplastic thread is only on one side and the non-thermoplastic thread on the other side. If such a semi-finished product is processed into the finished product, a complete penetration of the knitted fabric from the threads of the first material through the thermoplastic material can be prevented by a corresponding brief exposure to heat, whereby the knitted fabric character is retained on one side.
  • the processing of the semi-finished product can be simplified if it is pre-fixed as a flat fabric with a certain internal tension. This pre-fixation can be achieved either by heating the semi-finished product to a temperature at which the second material does not yet bond to other parts of the semi-finished product, but shape memory is already reprogrammed to the state that it takes on during the heating process. Subsequent cooling to ambient temperature then essentially maintains the threads of the second material in which they were brought to the fixing temperature during the heating. Such a semi-finished product is still very elastic.
  • the proportion of threads of the same material depends on the strength of the finished product or the proportion of binder contained in the finished product.
  • Fig. 1 shows a semi-finished product 20 in the form of a textile fabric which is formed by a right / left knitted fabric.
  • the right / left knitted fabric consists of two threads 4 and 5 made of a first and a second material. These two threads 4 and 5 are knitted together, and that they are inserted into the needles of the respective knitting machine when knitting, that the thread 4 or the thread 5 appears randomly and randomly on the front or right side of the knitted fabric 20.
  • the thread 4 in the left stitch leg 22 is at the front, while it runs in the right stitch leg 23 on the rear side facing away from the viewer.
  • the first material from which the thread 4 is made is preferably not an organic material, but rather a material selected from the substances metal, ceramic or other inorganic compounds such as mineral fibers.
  • the thread 5, however, consists of a thermoplastic material. Any plastic is suitable as a thermoplastic material which is suitable for integrally bonding to itself or the material for the first thread 4 by heating. If the adhesion is insufficient, there is also the possibility of coating the first thread 4 with a third material, which serves as an adhesion promoter or bonding bridge between the second material and the first material.
  • the threads 4 can be yarns, spun fiber yarns, continuous yarns, Monifile, plied yarns or threads, just as the threads 5 can be yarns, spun fiber yarns, continuous yarns, monofilaments, plied yarns or threads, the type of thread 4 being of the type of thread 5 can deviate.
  • the threads 5 are expediently made of the second material, the thermoplastic, continuous yarns or monofilaments or threads made therefrom, since it is readily possible to produce corresponding continuous filaments.
  • the knitted fabric 20 can be produced as a flat knitted fabric on a flat knitting machine or as a tube on a circular knitting machine. It is expediently fixed by heating immediately after the knitting, a distinction being made between two cases. In one case, the temperature of the knitted fabric 20 is only increased to such an extent that the thread 5 made of the thermoplastic material does not yet melt, but just takes on the force-free pattern that the knitted fabric 20 assumes during the fixing due to external forces. Then the knitted fabric 20 is allowed to cool back to room temperature without changing the external forces, whereby the threads 5 made of the thermoplastic are permanently formed into the desired mesh structure. Even when the external prestressing forces are removed, the knitted fabric 20 no longer springs back into its original shape. Such a pre-fixed knitted fabric 20 has practically the original suppleness and can be brought into almost any shape without effort, and practically without wrinkles.
  • pre-fixing is to raise the temperature of the knitted fabric 20 until the thread 5 made of the thermoplastic material locally becomes sticky and at the intersection points is integrally bonded to the other threads 4, 5 running above or below it . After cooling to ambient temperature, a tissue which has already been solidified at certain points is obtained, which is considerably stiffer than that which is obtained if the heating temperature is just driven until the shape memory of the thermoplastic is reprogrammed to the other course of the thread 4.
  • the knitted fabric 20 thus obtained can be inserted into a heatable form by the user, which brings the semifinished product 1 to a temperature at which the threads 5 of the second material melt, so that their material is distributed uniformly over the entire surface and thereby the in the embedded material 4 threads 4 of the first material integrally connected to each other by gluing. After cooling, a stiff and solidified molded part, which can also be flat, is obtained.
  • the knitted fabric 20 shown in FIG. 1 can either be the finished product, if it is to form a wallpaper, for example, or it is a semi-finished product from which, as previously described, molded parts can be pressed.
  • the threads consisting of the thermoplastic plastic represent the more evenly distributed binder supply, with the aid of which the reinforcement embedded in the finished molded part is encased from the knitted threads 4.
  • the knitting is carried out in such a way that the stitch legs 22, 23 have a length of greater than 2 mm.
  • the length of the mesh legs 22, 23 is preferably between 2 mm and 12 mm, more preferably between 4 mm and 8 mm. Under certain circumstances, particularly good conditions with 6 mm leg length can be achieved.
  • the ratio between the amount of binder to the amount of reinforcing insert can be controlled by the volume ratio between the threads 4 and the threads 5.
  • the thread 4 made of the thermoplastic material is randomly distributed on the front and on the back of the knitted fabric 20, it is produced when the semi-finished product is pressed in the corresponding molded body, a molded body in which the insert runs largely in the middle, ie thermoplastic binder is present on both sides of the insert.
  • the knitted fabric can be produced as a plated product, as shown in FIG. 3.
  • the thread 5 is, for example, always only on the right side of the knitted fabric remote from the viewer, while the thread 4 runs on the left side facing the viewer.
  • a simple right / left knitted fabric is shown in each of the two FIGS. 1 and 2.
  • This knitted fabric is relatively easy to manufacture even with a large length of the stitch legs.
  • the right / left knitted fabric shown is by no means the only suitable type of binding. Rather, knitted fabrics on the right / right / or left / left and interlockware may also be considered.
  • semi-finished products with comparable properties can also be produced as knitted goods or warp knitted goods.
  • the main advantage of a knitted fabric is that the semi-finished product has a very high tensile strength in the direction parallel to two axes running at an acute angle to one another.
  • the further processing is as described above, with a significant advantage being that the thread 5 or possibly several threads 5 made of thermoplastic material that have been processed have practically no aging, which means that the semi-finished product 20 or 30 can be processed for as long as required Molding is storable.
  • the thread 5 made of thermoplastic material is not sticky at ambient temperature, which is also a considerable advantage in further processing.
  • the mixture ratio is the same everywhere between the thread portion made of the first material and the thread portion made of the second material, namely the thermoplastic, there is the same supply of binder in each volume element of the semi-finished product 20 or 30, formed by the thread 5 made of thermoplastic.
  • the binder only has to cover distances corresponding to the size of the mesh size.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Knitting Of Fabric (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
EP95112661A 1995-08-11 1995-08-11 Demi-produit pour matériau composite Expired - Lifetime EP0758693B1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
DE59509754T DE59509754D1 (de) 1995-08-11 1995-08-11 Halbzeug für Verbundwerkstoff
AT95112661T ATE207554T1 (de) 1995-08-11 1995-08-11 Halbzeug für verbundwerkstoff
EP95112661A EP0758693B1 (fr) 1995-08-11 1995-08-11 Demi-produit pour matériau composite

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP95112661A EP0758693B1 (fr) 1995-08-11 1995-08-11 Demi-produit pour matériau composite

Publications (2)

Publication Number Publication Date
EP0758693A1 true EP0758693A1 (fr) 1997-02-19
EP0758693B1 EP0758693B1 (fr) 2001-10-24

Family

ID=8219515

Family Applications (1)

Application Number Title Priority Date Filing Date
EP95112661A Expired - Lifetime EP0758693B1 (fr) 1995-08-11 1995-08-11 Demi-produit pour matériau composite

Country Status (3)

Country Link
EP (1) EP0758693B1 (fr)
AT (1) ATE207554T1 (fr)
DE (1) DE59509754D1 (fr)

Cited By (70)

* Cited by examiner, † Cited by third party
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GB2322638A (en) * 1997-02-13 1998-09-02 T & N Technology Ltd Knife-resistant sheet
WO2001044548A1 (fr) * 1999-12-15 2001-06-21 N.V. Bekaert S.A. Tissu renforce
WO2002063083A1 (fr) * 2001-02-07 2002-08-15 Rhodia Industrial Yarns Ag Tissu maille en fils de polyamide pour la production de corps composites a couches, ainsi que son utilisation
EP1233091A1 (fr) * 2001-02-20 2002-08-21 Sara Lee Corporation Etoffe tricotée
WO2002061189A3 (fr) * 2001-02-01 2002-12-12 Detlef Militz Matiere textile
US6777081B2 (en) 1999-12-15 2004-08-17 N.V. Bekaert S.A. Reinforcing structure for stiff composite articles
GB2441589A (en) * 2006-09-05 2008-03-12 Anthony Walter Anson Heat treatment method for composite textiles
EP2050848A2 (fr) 2007-09-17 2009-04-22 Orfit Industries Tissu hybride
US8650916B2 (en) 2006-11-10 2014-02-18 Nike, Inc. Article of footwear having a flat knit upper construction or other upper construction
US8745896B2 (en) 2008-12-18 2014-06-10 Nike, Inc. Article of footwear having an upper incorporating a knitted component
US8800172B2 (en) 2011-04-04 2014-08-12 Nike, Inc. Article of footwear having a knit upper with a polymer layer
US8899079B2 (en) 2013-02-28 2014-12-02 Nike, Inc. Independently controlled rollers for take-down assembly of knitting machine
US9060570B2 (en) 2011-03-15 2015-06-23 Nike, Inc. Method of manufacturing a knitted component
US9150986B2 (en) 2011-05-04 2015-10-06 Nike, Inc. Knit component bonding
US9149086B2 (en) 2009-10-07 2015-10-06 Nike, Inc. Article of footwear having an upper with knitted elements
US9220318B2 (en) 2013-09-27 2015-12-29 Nike, Inc. Article of footwear with adjustable fitting system
US9226540B2 (en) 2013-02-28 2016-01-05 Nike, Inc. Method of knitting a knitted component with a vertically inlaid tensile element
US9371603B2 (en) 2013-02-28 2016-06-21 Nike, Inc. Feeder for knitting machine with friction reducing features
US9404206B2 (en) 2013-02-28 2016-08-02 Nike, Inc. Feeder for knitting machine having pushing member
US9420844B2 (en) 2012-02-20 2016-08-23 Nike, Inc. Method of knitting a knitted component with an integral knit tongue
US9441316B2 (en) 2011-03-15 2016-09-13 Nike, Inc. Combination feeder for a knitting machine
US9526293B2 (en) 2013-05-31 2016-12-27 Nike, Inc. Method of knitting a knitted component for an article of footwear
US9545128B2 (en) 2013-03-04 2017-01-17 Nike, Inc. Article of footwear incorporating a knitted component with tensile strand
US9622536B2 (en) 2012-11-15 2017-04-18 Nike, Inc. Article of footwear incorporating a knitted component
US9681704B2 (en) 2012-11-30 2017-06-20 Nike, Inc. Article of footwear incorporating a knitted component
US9723890B2 (en) 2013-11-22 2017-08-08 Nike, Inc. Article of footwear incorporating a knitted component with body and heel portions
US9743705B2 (en) 2004-03-03 2017-08-29 Nike, Inc. Method of manufacturing an article of footwear having a textile upper
US9745678B2 (en) 2014-02-03 2017-08-29 Nike, Inc. Article of footwear including a monofilament knit element with peripheral knit portions
US9777412B2 (en) 2014-02-03 2017-10-03 Nike, Inc. Article of footwear including a monofilament knit element with a fusible strand
US9775406B2 (en) 2014-11-12 2017-10-03 Nike, Inc. Article of footwear with a sole assembly having a bladder element and a guide component and method of manufacturing the article of footwear
US9803299B2 (en) 2014-02-03 2017-10-31 Nike, Inc. Knitted component for an article of footwear including a full monofilament upper
US9848672B2 (en) 2013-03-04 2017-12-26 Nike, Inc. Article of footwear incorporating a knitted component with integrally knit contoured portion
US9877536B2 (en) 2014-05-30 2018-01-30 Nike, Inc. Method of making an article of footwear including knitting a knitted component of warp knit construction forming a seamless bootie with wrap-around portion
US9888742B2 (en) 2015-09-11 2018-02-13 Nike, Inc. Article of footwear with knitted component having plurality of graduated projections
US9890485B2 (en) 2014-02-03 2018-02-13 Nike, Inc. Method of knitting a gusseted tongue for a knitted component
US9903054B2 (en) 2014-08-27 2018-02-27 Nike, Inc. Knitted component having tensile strand for adjusting auxetic portion
US9907349B2 (en) 2014-05-30 2018-03-06 Nike, Inc. Article of footwear including knitting a knitted component of warp knit construction forming a seamless bootie
US9924757B2 (en) 2013-09-05 2018-03-27 Nike, Inc. Article of footwear incorporating a trimmed knitted upper
US9924761B2 (en) 2011-03-15 2018-03-27 Nike, Inc. Article of footwear incorporating a knitted component
US9936757B2 (en) 2013-03-04 2018-04-10 Nike, Inc. Article of footwear incorporating a knitted component with integrally knit contoured portion
US9968156B2 (en) 2014-05-30 2018-05-15 Nike, Inc. Method of making an article of footwear including knitting a knitted component of warp knit construction forming a seamless bootie with tucked-in portion
US10045579B2 (en) 2013-09-24 2018-08-14 Nike, Inc. Knitted component with adjustable knitted portion
US10070679B2 (en) 2014-09-30 2018-09-11 Nike, Inc. Article of footwear incorporating a lenticular knit structure
US10092058B2 (en) 2013-09-05 2018-10-09 Nike, Inc. Method of forming an article of footwear incorporating a knitted upper with tensile strand
US10172422B2 (en) 2011-03-15 2019-01-08 Nike, Inc. Knitted footwear component with an inlaid ankle strand
US10182617B2 (en) 2012-11-20 2019-01-22 Nike, Inc. Footwear upper incorporating a knitted component with collar and throat portions
US10194711B2 (en) 2014-05-06 2019-02-05 Nike, Inc. Packaged dyed knitted component
DE102017214564A1 (de) * 2017-08-21 2019-02-21 Robert Bosch Gmbh Textilvorrichtung
US10273604B2 (en) 2014-09-30 2019-04-30 Nike, Inc. Article of footwear incorporating a knitted component
US10299531B2 (en) 2013-05-14 2019-05-28 Nike, Inc. Article of footwear incorporating a knitted component for a heel portion of an upper
US10306946B2 (en) 2013-05-14 2019-06-04 Nike, Inc. Article of footwear having heel portion with knitted component
US10368606B2 (en) 2014-04-15 2019-08-06 Nike, Inc. Resilient knitted component with wave features
US10378130B2 (en) 2012-02-20 2019-08-13 Nike, Inc. Article of footwear incorporating a knitted component with an integral knit tongue
US10385485B2 (en) 2014-06-16 2019-08-20 Nike, Inc. Article with at least two securable inlaid strands
US10398196B2 (en) 2011-03-15 2019-09-03 Nike, Inc. Knitted component with adjustable inlaid strand for an article of footwear
US10455885B2 (en) 2014-10-02 2019-10-29 Adidas Ag Flat weft-knitted upper for sports shoes
US10524542B2 (en) 2013-11-22 2020-01-07 Nike, Inc. Sole structure with side stiffener for article of footwear
US10721997B2 (en) 2015-09-11 2020-07-28 Nike, Inc. Method of manufacturing article of footwear with graduated projections
US10822728B2 (en) 2014-09-30 2020-11-03 Nike, Inc. Knitted components exhibiting color shifting effects
US10834992B2 (en) 2013-04-19 2020-11-17 Adidas Ag Shoe
US10918155B2 (en) 2013-08-29 2021-02-16 Nike, Inc. Article of footwear incorporating a knitted component with an integral knit ankle cuff
US10939729B2 (en) 2013-04-19 2021-03-09 Adidas Ag Knitted shoe upper
US11044963B2 (en) 2014-02-11 2021-06-29 Adidas Ag Soccer shoe
US11129443B2 (en) 2012-11-20 2021-09-28 Nike, Inc. Footwear upper incorporating a knitted component with sock and tongue portions
US11197518B2 (en) 2014-09-30 2021-12-14 Nike, Inc. Article of footwear upper incorporating a textile component with tensile elements
US11319651B2 (en) 2012-02-20 2022-05-03 Nike, Inc. Article of footwear incorporating a knitted component with an integral knit tongue
US11464289B2 (en) 2010-08-02 2022-10-11 Nike, Inc. Upper for an article of footwear with at least one strand for lasting
US11666113B2 (en) 2013-04-19 2023-06-06 Adidas Ag Shoe with knitted outer sole
US12082639B2 (en) 2012-04-13 2024-09-10 Adidas Ag Shoe upper
US12250994B2 (en) 2013-04-19 2025-03-18 Adidas Ag Shoe

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US8225530B2 (en) 2006-11-10 2012-07-24 Nike, Inc. Article of footwear having a flat knit upper construction or other upper construction
US9295298B2 (en) 2009-10-07 2016-03-29 Nike, Inc. Footwear uppers with knitted tongue elements
DE102013207163B4 (de) 2013-04-19 2022-09-22 Adidas Ag Schuhoberteil
US9301567B2 (en) 2014-08-29 2016-04-05 Nike, Inc. Article of footwear incorporating a knitted component with monofilament areas

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EP0310200A2 (fr) * 1987-10-02 1989-04-05 Stamicarbon B.V. Mélanges de filaments ayant des points de fusion ou de décomposition différents et utilisation de ces combinaisons
DE4137406A1 (de) 1991-11-14 1993-05-19 Basf Ag Hybridgarn aus polyamidfasern und verstaerkungsfasern
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Cited By (163)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2322638B (en) * 1997-02-13 2001-05-30 T & N Technology Ltd Knife-resistant sheet
GB2322638A (en) * 1997-02-13 1998-09-02 T & N Technology Ltd Knife-resistant sheet
US6787491B2 (en) 1999-12-15 2004-09-07 N.V. Bekaert S.A. Woven composite fabric
WO2001044548A1 (fr) * 1999-12-15 2001-06-21 N.V. Bekaert S.A. Tissu renforce
US7304007B2 (en) 1999-12-15 2007-12-04 Nv Bekaert Sa Woven composite fabric
US6777081B2 (en) 1999-12-15 2004-08-17 N.V. Bekaert S.A. Reinforcing structure for stiff composite articles
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DE59509754D1 (de) 2001-11-29
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