EP0741767A1 - Composition ameliorant le frottement, son procede de formulation et d'utilisation - Google Patents
Composition ameliorant le frottement, son procede de formulation et d'utilisationInfo
- Publication number
- EP0741767A1 EP0741767A1 EP95903634A EP95903634A EP0741767A1 EP 0741767 A1 EP0741767 A1 EP 0741767A1 EP 95903634 A EP95903634 A EP 95903634A EP 95903634 A EP95903634 A EP 95903634A EP 0741767 A1 EP0741767 A1 EP 0741767A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- friction
- abrasive substance
- enhancing composition
- substance
- matter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 105
- 238000000034 method Methods 0.000 title claims description 11
- 239000000126 substance Substances 0.000 claims abstract description 72
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 22
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 22
- 239000002480 mineral oil Substances 0.000 claims description 13
- 235000010446 mineral oil Nutrition 0.000 claims description 13
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 9
- 150000001247 metal acetylides Chemical class 0.000 claims description 9
- 239000011707 mineral Substances 0.000 claims description 9
- 235000019271 petrolatum Nutrition 0.000 claims description 9
- 239000003208 petroleum Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 6
- 230000002708 enhancing effect Effects 0.000 claims description 5
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 238000009835 boiling Methods 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 125000003367 polycyclic group Chemical group 0.000 claims description 4
- 239000004264 Petrolatum Substances 0.000 claims description 3
- 239000004200 microcrystalline wax Substances 0.000 claims description 3
- 235000019808 microcrystalline wax Nutrition 0.000 claims description 3
- 229940066842 petrolatum Drugs 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 2
- 239000011874 heated mixture Substances 0.000 claims description 2
- 239000001993 wax Substances 0.000 claims description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 10
- 239000003871 white petrolatum Substances 0.000 description 5
- 230000003116 impacting effect Effects 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 229910010271 silicon carbide Inorganic materials 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 229910021418 black silicon Inorganic materials 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 230000009965 odorless effect Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 235000009854 Cucurbita moschata Nutrition 0.000 description 1
- 240000001980 Cucurbita pepo Species 0.000 description 1
- 235000009852 Cucurbita pepo Nutrition 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- -1 for example Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000020354 squash Nutrition 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/14—Anti-slip materials; Abrasives
Definitions
- the invention relates to a composition to aid in removal and retention of bolts and screws, and in controlling the impact and resulting trajectory between impacting bodies.
- the invention relates to friction-enhancing compositions comprising a semisolid mixture of hydrocarbons, a thinning substance, and two or more abrasive substances which comprise no greater than approximately 53% by volume of the composition, and novel methods of formulating and utilizing such compositions.
- the composition aids a tool, such as a screwdriver or socket wrench, to grip the head of a headed fastener, such as a bolt or screw.
- a tool such as a screwdriver or socket wrench
- the composition may also be used in place of a lock washer, or where it is desired to provide or increase friction between two objects to hold or control the objects relative to one another.
- One aspect of the invention eliminates stripped fastener heads, and provides tighter and more secure fasteners.
- the relevant art is exemplified by Nohejl U.S. Patent 2,787,967; Morton Swiss
- Patent 404,835 Ingimarsson U.S. Patent 3,656,522; Wesner French Patent 2,278,981;
- the invention provides a friction-enhancing composition of matter, comprising a semisolid mixture of hydrocarbons, a thinning substance, and two or more abrasive substances which comprise no greater than approximately 53% by volume of the friction- enhancing composition of matter.
- thinning substance as used herein means any substance having a specific gravity which is less than that of said semisolid mixture of hydrocarbons, and with which said semisolid mixture of hydrocarbons may be mixed to form a paste.
- the term "thinning substance” includes, but is not limited to, various polycyclic high-boiling fractions of petroleum, such as, for example, mineral oil.
- the invention also provides a method of formulating a friction-enhancing composition of matter, comprising the steps of: heating a semisolid mixture of hydrocarbons so that said mixture becomes pourable; pouring said heated mixture into a mineral oil thinning substance; mixing said semisolid mixture and said mineral oil thinning substance to form a substantially homogenized paste; gradually adding aluminum oxide to the substantially homogenized paste while stirring it at a substantially high rate of speed; and then gradually adding silicon carbide to the composition while stirring it at a substantially high rate of speed.
- An object of the invention is to provide a novel composition which facilitates the removal of fasteners, such as bolts and screw. Another object is to provide a composition for aiding in the removal of fasteners with stripped heads.
- a further object is to provide a composition which can be used to provide greater friction than is normally created between objects, thus providing better holding power and/or impact control therebetween.
- the composition may also be used in place of a lock washer.
- the invention provides a friction-enhancing composition of matter, comprising: a semisolid mixture of hydrocarbons; a thinning substance; and two or more abrasive substances which comprise no greater than approximately 53% by volume of the friction- enhancing composition of matter.
- the semisolid mixture of hydrocarbons preferably, but not necessarily, contains approximately 16 to 32 carbon atoms per molecule.
- the semisolid mixture of hydrocarbons may preferably, but not necessarily, be selected from a group consisting of microcrystalline waxes, fractions of petroleum, and hydrocarbons containing approximately 16 to 32 carbon atoms per molecule.
- the thinning substance may preferably, but not necessarily, comprise a polycyclic high-boiling fraction of petroleum, such as, for example, a mineral oil.
- the composition may comprise two or more abrasive substances preferably, but not necessarily, selected from a group consisting of refractory oxides, minerals, and carbides.
- the composition includes a first abrasive substance and a second abrasive substance, wherein the second abrasive substance is harder than the first abrasive substance.
- the first abrasive substance comprises an oxide of aluminum
- the second abrasive substance may preferably, but not necessarily, comprise silicon carbide.
- the semisolid mixture of hydrocarbons should preferably, but not necessarily, be present in the total composition of matter in the range of approximately 6% to 26% by volume.
- the thinmng substance should preferably, but not necessarily, be present in the total composition of matter in the range where approximately 40% to 60% by volume.
- the first abrasive substance should preferably, but not necessarily, be present in the total composition of matter in the range of approximately 15% to 35% by volume.
- the second abrasive substance should preferably, but not necessarily, be present in the total composition of matter in the range of approximately 2% to 18% by volume.
- the petrolatum or petroleum jelly is a microcrystalline wax with a defined oil content.
- Microciyst ⁇ lline waxes consist mainly of iso and cycloparaffins with some alkylated aromatic hydrocarbons.
- the white petrolatum used in this example is odorless, soluble in hydrocarbons, has a specific gravity of approximately 0.86 at 60°F, and is a white opaque semisohd.
- the particular thinning substance used in this example may be a low temperature white mineral oil USP, such as sold under the trade name DrakeoP Supreme.
- the white mineral oil employed has a clear fluid appearance, is odorless, is insoluble in water, and has a specific gravity of 0.872 at 60°F.
- the first abrasive substance is a refractory oxide, such as fused aluminum oxide which contains 96 to 100% of alpha alumina ( ⁇ 0 3 ), and 0 to 4% of titanium dioxide (TiO ⁇ ).
- the second abrasive substance is an inorganic carbide, such as black silicon carbide which is also known as Carbolon.
- Carbolon contains 97 to 100% of silicon carbide, and 0 to 3% of carbon.
- the base of white petrolatum is heated to approximately 240°F to bring it to a good pouring condition. Then the heated petrolatum is poured into the thinning substance, viz., the white mineral oil.
- the white petrolatum and white mineral oil are mixed for approximately 12 to 15 minutes to form a substantially homogenized paste.
- the homogenized paste can be used immediately to complete the formulation of the novel composition, or alternatively may be stored for later use for completing the formulation. It has been found that the homogenized paste can be stored for indefinite periods of time including days, weeks, months and much longer.
- the refractory oxide is then gradually added to the substantially homogenized paste while stirring at a substantially high rate of speed, e.g., approximately 2200 RPMs, for approximately 5 minutes. Thereafter, the Carbolon is gradually added to the composition while stirring at a substantially high rate of speed, e.g., 3500 RPMs, for approximately 5 minutes until the composition is substantially homogenized.
- Example No. 1 has approximately 12 gallons of starting ingredients, and yields approximately IOV2 gallons of final composition product.
- Example No. 2 3 gallons (base) white petrolatum
- Example No. 2 The composition of Example No. 2 is formulated substantially according to the method described hereinabove with respect to Example No. 1.
- Example No. 1 has better shelf life and better friction-enhancing properties than the composition of Example No. 2.
- the second abrasive substance be substantially harder than the first abrasive substance.
- fused aluminum oxide has been specifically mentioned hereinabove, various different refractory oxides may be satisfactorily employed as the first abrasive substance.
- the friction-enhancing composition of the present invention remains workable, does not loose its beneficial properties, does not dry out, and does not separate within a temperature range of approximately 15°F to 125°F.
- the novel composition is very useful in controlling the impact between colliding or impacting bodies.
- the composition may be applied to a golf club head, and thereby give the golfer greater control over the trajectory of the impacted golfball.
- the composition may be useful for various impacting bodies including, but not limited to, sports appUcations, such as golf, tennis, basebaU, squash, ping-pong, etc., and other applications where it is necessary to control the impact and resulting trajectory between colliding or impacting bodies.
- composition When using the composition for fasteners and tools, a small amount of the composition is placed on either the tool or the fastener. The tool can then be used to remove stubborn and/or corroded fasteners. The composition may also be applied to a nut used in conjunction with a fastener.
- composition aids the tool in removing the fastener by providing greatly increased friction along the contact surfaces between the tool and fastener.
- the force or torque applied to the fastener head is more evenly distributed along these contact surfaces, and the head of the fastener is not stripped by excessive pressure on unlocalized contact surfaces.
- the composition acts in a similar manner when removing a fastener with a previously-stripped head.
- the composition may also be used in place of a standard lock washer. More force or torque is required to remove a fastener having the composition used in place of a lock washer then that required when the fastener is provided with a standard lock washer.
- a very important feature of the invention also resides in the fact that the composition when applied to a tool or to the fastener, no matter what the purpose or use of such tool may be, increases the Ufe of such tool by minimizing wear of such tool.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
Composition améliorant le frottement comprenant un mélange semi-solide d'hydrocarbures, une substance de dilution, une première substance abrasive et une deuxième substance abrasive plus dure que la première, les deux subtances abrasives ne représentant ensemble que 53 % en volume de la composition au maximum.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US1994/013719 WO1996017032A1 (fr) | 1994-11-30 | 1994-11-30 | Composition ameliorant le frottement, son procede de formulation et d'utilisation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0741767A1 true EP0741767A1 (fr) | 1996-11-13 |
| EP0741767A4 EP0741767A4 (fr) | 1997-09-10 |
Family
ID=22243334
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP95903634A Withdrawn EP0741767A4 (fr) | 1994-11-30 | 1994-11-30 | Composition ameliorant le frottement, son procede de formulation et d'utilisation |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP0741767A4 (fr) |
| WO (1) | WO1996017032A1 (fr) |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2787966A (en) * | 1955-05-02 | 1957-04-09 | Nat Aluminate Corp | Method of improving the coefficient of friction between contacting metal surfaces and article produced thereby |
| US3035988A (en) * | 1958-03-19 | 1962-05-22 | Dover Chemical Corp | Method of forming friction film on hand |
| DE3335522C2 (de) * | 1983-09-30 | 1985-10-03 | Jakob 7900 Ulm Schuler | Anti-Rutsch-Mittel |
| US5062895A (en) * | 1989-07-20 | 1991-11-05 | Pockrandt Frank J | Chemical composition, and methods of constructing and utilizing same |
-
1994
- 1994-11-30 EP EP95903634A patent/EP0741767A4/fr not_active Withdrawn
- 1994-11-30 WO PCT/US1994/013719 patent/WO1996017032A1/fr not_active Ceased
Non-Patent Citations (2)
| Title |
|---|
| No further relevant documents disclosed * |
| See also references of WO9617032A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0741767A4 (fr) | 1997-09-10 |
| WO1996017032A1 (fr) | 1996-06-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| 17P | Request for examination filed |
Effective date: 19960830 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): DE ES FR GB IT NL |
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| A4 | Supplementary search report drawn up and despatched |
Effective date: 19970102 |
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| AK | Designated contracting states |
Kind code of ref document: A4 Designated state(s): DE ES FR GB IT NL |
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| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN WITHDRAWN |
|
| 18W | Application withdrawn |
Withdrawal date: 19970924 |