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EP0639434A1 - Procédé de fabrication de panneaux de moyenne densité en fibres de bois (MDF) - Google Patents

Procédé de fabrication de panneaux de moyenne densité en fibres de bois (MDF) Download PDF

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Publication number
EP0639434A1
EP0639434A1 EP94111375A EP94111375A EP0639434A1 EP 0639434 A1 EP0639434 A1 EP 0639434A1 EP 94111375 A EP94111375 A EP 94111375A EP 94111375 A EP94111375 A EP 94111375A EP 0639434 A1 EP0639434 A1 EP 0639434A1
Authority
EP
European Patent Office
Prior art keywords
wood
resin
fibers
mdf
production
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP94111375A
Other languages
German (de)
English (en)
Other versions
EP0639434B1 (fr
EP0639434B2 (fr
Inventor
Brigitte Dr. Ing. Dix
Roland Dr.Rer.Nat. Bayer
Edmone Prof. Dr. Roffael
Gert Dipl.-Ing. Bär
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fraunhofer Gesellschaft zur Foerderung der Angewandten Forschung eV
Original Assignee
Fraunhofer Gesellschaft zur Foerderung der Angewandten Forschung eV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6495480&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0639434(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Fraunhofer Gesellschaft zur Foerderung der Angewandten Forschung eV filed Critical Fraunhofer Gesellschaft zur Foerderung der Angewandten Forschung eV
Publication of EP0639434A1 publication Critical patent/EP0639434A1/fr
Publication of EP0639434B1 publication Critical patent/EP0639434B1/fr
Application granted granted Critical
Publication of EP0639434B2 publication Critical patent/EP0639434B2/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/002Manufacture of substantially flat articles, e.g. boards, from particles or fibres characterised by the type of binder
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N1/00Pretreatment of moulding material
    • B27N1/003Pretreatment of moulding material for reducing formaldehyde gas emission

Definitions

  • the invention relates to a method for producing medium density fibreboard according to the preamble of the main claim.
  • the wood is first crushed into chips with a size of approximately 20 mm x 5 mm and the resulting chips are washed in order to remove the adhering foreign bodies (in particular sand).
  • the chips are then treated for a few minutes under steam pressure and a temperature of around 160 ° C and then fed to a defibrator, where they are shredded into single fibers or small tufts of fibers between grinding disks.
  • a binder such as urea-formaldehyde resin (UF resin), mixed resin made of urea and melamine (MUF resin), phenol formaldehyde resin (PF resin), tannin formaldehyde resin (TF resin) or diisocyanate adhesive HPMDI is added to the fibrous material.
  • the binder is usually added to the still moist fibers before entering the dryer tunnel.
  • the glued fibers are briefly exposed to temperatures of 70 ° C to 80 ° C in the dryer. As a result of drying, the effectiveness of the binders used is reduced.
  • the binder can also be added to the fibers after drying.
  • the fibers run through a special glue application drum.
  • the dried and glued pulp is fed to a molding machine where it is sprinkled on a sieve that moves at high speed.
  • the mats formed in this way are then pressed into sheets.
  • the medium-density wood fiber boards produced with aminoplast resins as binders by the process described above generally have a high formaldehyde release capacity.
  • Various methods have been proposed to reduce formaldehyde release. For example, according to DE-OS 28 04 514, attempts have been made to reduce the formaldehyde release from MDF by subsequently treating the fiberboard with ammonia or ammonia-releasing compounds (DE-OS 28 04 514). This aftertreatment must, however, take place in a separate working stage in a special chamber.
  • the object of the present invention is to provide a simple process which makes it possible to reduce the formaldehyde release of the MDF produced with aminoplast resins such as UF resin without the plates having to be treated subsequently.
  • the fibers are glued in a manner known per se with urea-formaldehyde resins, sprinkled into mats and pressed into plates. It has surprisingly been found that such MDFs have a relatively low release of formaldehyde and that, moreover, the boards produced by this process have better mechanical-technological properties than the boards which are made from fibers which have been subjected to thermomechanical refiner digestion (TMP). Procedure) are open-minded.
  • TMP thermomechanical refiner digestion
  • CTMP chemo-thermo-mechanical pulps
  • the wood chips are impregnated with chemicals such as Na2SO3 under and without the addition of NaOH at high temperatures (140 ° C ... 170 ° C) and then defibrated at high temperatures.
  • the fibers obtained are used alone or in combination with other fibers (e.g. waste paper) for the production of newsprint and other types of paper (e.g. tissue paper). So far, this method has not been used for the production of MDF in the form described above.
  • the CTMP substance For the production of paper from the CTMP substance, it is washed out after the digestion in order to remove the chemicals that are still present. This leads to a wastewater problem that does not make the production of paper from CTMP material unproblematic and has prevented many companies from introducing this new technology.
  • the CTMP substance should not be washed out, especially since the omission of this process step has proven to be particularly advantageous for the MDF.
  • the binders used in the process according to the invention are the binders known in the production of MDF (medium-density fiberboard), such as urea-formaldehyde resin (UF resin), urea-melamine resin (MUF), phenol formaldehyde resin (PF resin), Tannin formaldehyde resin (TF resin) or an adhesive based on polymeric diisocyanates (PMDI) is used.
  • MDF medium-density fiberboard
  • UF resin urea-formaldehyde resin
  • UMF urea-melamine resin
  • PF resin phenol formaldehyde resin
  • TF resin Tannin formaldehyde resin
  • PMDI polymeric diisocyanates
  • the method according to the invention is also suitable for the use of hardwoods.
  • the digestion of the wood or the wood chips takes place according to the invention with chemicals such as Na2SO3 or with NaOH.
  • the wood is digested with a mixture of Na2SO3 and NaOH.
  • the chemicals mentioned When used in an optimized form, the chemicals mentioned have an advantageous effect on the properties of the finished panels.
  • Table 1 below shows the mechanical-technological properties of the MDF produced and its formaldehyde release. This table clearly shows the influence of the washout stage on the mechanical-technological properties of the MDF produced and its formaldehyde release.
  • the MDF produced according to the invention from the CTMP substance has comparatively high strength values, but a lower formaldehyde release than the corresponding plates made from the TMP substance (thermo-mechanical method).

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)
EP19940111375 1993-08-18 1994-07-21 Procédé de fabrication de panneaux de moyenne densité en fibres de bois (MDF) Expired - Lifetime EP0639434B2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4327774 1993-08-18
DE19934327774 DE4327774A1 (de) 1993-08-18 1993-08-18 Verfahren zur Herstellung von mitteldichten Holzfaserplatten (MDF)

Publications (3)

Publication Number Publication Date
EP0639434A1 true EP0639434A1 (fr) 1995-02-22
EP0639434B1 EP0639434B1 (fr) 1996-09-18
EP0639434B2 EP0639434B2 (fr) 2004-01-07

Family

ID=6495480

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19940111375 Expired - Lifetime EP0639434B2 (fr) 1993-08-18 1994-07-21 Procédé de fabrication de panneaux de moyenne densité en fibres de bois (MDF)

Country Status (4)

Country Link
EP (1) EP0639434B2 (fr)
DE (2) DE4327774A1 (fr)
DK (1) DK0639434T4 (fr)
ES (1) ES2094601T5 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6344108B1 (en) 1997-02-04 2002-02-05 Stockhausen Gmbh & Co. Kg Using a dicarboxylic acid dialkyl ester brightening
WO2006039914A1 (fr) * 2004-10-15 2006-04-20 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Procede pour reduire le degagement de composes organiques volatils (cov) par le bois et les produits de fragmentation du bois ainsi que les materiaux a base de bois, fabriques a partir de ces derniers, en particulier les panneaux de bois agglomeres
WO2006114089A1 (fr) * 2005-04-26 2006-11-02 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Procede pour fabriquer des panneaux de fibres a moyenne densite et elements de moulage fibreux a emissions polluantes reduites et faible gonflement
CN102677501A (zh) * 2012-05-29 2012-09-19 宜宾长毅浆粕有限责任公司 一种本色未漂针叶木和阔叶木复合纸浆改性制备溶解浆的备料工艺
WO2017023218A1 (fr) 2015-04-21 2017-02-09 Kastamonu Entegre Agac Sanayi Anonim Sirketi Procédé de production de résines contenant un polyflavonoïde et des dérivés et leur application dans des produits de panneaux composites à base de bois

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE513336C2 (sv) * 1998-10-14 2000-08-28 Tetra Laval Holdings & Finance Fiberskiva av MDF-typ, sätt att framställa densamma, samt användning av återvunna cellulosafibrer för tillverkning av sådana fiberskivor
DE102007054123B4 (de) 2006-11-15 2012-03-15 Edmone Roffael Verfahren zur Herstellung von Holzfaserplatten mit verringerter Formaldehydemission, hoher Feuchtebeständigkeit und Hydrolyseresistenz der Verleimung
DE102008023007A1 (de) 2007-11-11 2010-06-02 Roffael, Edmone, Prof. Dr.-Ing. Verfahren zur Herstellung von Holzfaserplatten mit verringerter Formaldehydemission, hoher Feuchtebeständigkeit und Hydrolyseresistenz der Verleimung
DE102010053467A1 (de) 2010-12-03 2012-06-06 Edmone Roffael Verfahren zur Verminderung der Dickenquellung und Wasseraufnahme von Faserplatten
CN102268832B (zh) * 2011-07-15 2013-09-25 芬欧汇川(中国)有限公司 使用落叶松化机浆生产中高档文化用纸的制浆造纸工艺
EP3178622B1 (fr) 2015-12-07 2018-07-04 SWISS KRONO Tec AG Procédé de fabrication d'une plaque en matériau dérivé du bois présentant une émission réduit de composés organiques volatiles (cov)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2804514A1 (de) * 1977-02-03 1978-08-10 Ry Ab Formaldehydfreie spanplatte
WO1992012836A1 (fr) * 1991-01-23 1992-08-06 Aci Australia Limited Substrat de construction et son procede de fabrication
WO1993025358A1 (fr) * 1992-06-11 1993-12-23 Sunds Defibrator Industries Aktiebolag Fabrication de panneau de fibres

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE436368B (sv) * 1979-01-12 1984-12-03 Sunds Defibrator Sett att framstella blekta, mekaniska, kemimekaniska och halvkemiska massor av lignocellulosahaltiga fibermaterial
JP2001501547A (ja) * 1992-06-12 2001-02-06 アルミナム カンパニー オブ アメリカ 非平面を有する多層構造の製造方法
SE502663C2 (sv) * 1993-05-19 1995-12-04 Sunds Defibrator Ind Ab Förfarande för framställning av skivor av lignocellulosahaltigt material

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2804514A1 (de) * 1977-02-03 1978-08-10 Ry Ab Formaldehydfreie spanplatte
WO1992012836A1 (fr) * 1991-01-23 1992-08-06 Aci Australia Limited Substrat de construction et son procede de fabrication
WO1993025358A1 (fr) * 1992-06-11 1993-12-23 Sunds Defibrator Industries Aktiebolag Fabrication de panneau de fibres

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6344108B1 (en) 1997-02-04 2002-02-05 Stockhausen Gmbh & Co. Kg Using a dicarboxylic acid dialkyl ester brightening
WO2006039914A1 (fr) * 2004-10-15 2006-04-20 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Procede pour reduire le degagement de composes organiques volatils (cov) par le bois et les produits de fragmentation du bois ainsi que les materiaux a base de bois, fabriques a partir de ces derniers, en particulier les panneaux de bois agglomeres
WO2006114089A1 (fr) * 2005-04-26 2006-11-02 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Procede pour fabriquer des panneaux de fibres a moyenne densite et elements de moulage fibreux a emissions polluantes reduites et faible gonflement
CN102677501A (zh) * 2012-05-29 2012-09-19 宜宾长毅浆粕有限责任公司 一种本色未漂针叶木和阔叶木复合纸浆改性制备溶解浆的备料工艺
CN102677501B (zh) * 2012-05-29 2015-04-22 宜宾丝丽雅集团有限公司 一种本色未漂针叶木和阔叶木复合纸浆改性制备溶解浆的备料工艺
WO2017023218A1 (fr) 2015-04-21 2017-02-09 Kastamonu Entegre Agac Sanayi Anonim Sirketi Procédé de production de résines contenant un polyflavonoïde et des dérivés et leur application dans des produits de panneaux composites à base de bois

Also Published As

Publication number Publication date
ES2094601T5 (es) 2004-09-01
DE4327774A1 (de) 1995-02-23
DK0639434T4 (da) 2004-02-09
EP0639434B1 (fr) 1996-09-18
DE59400679D1 (de) 1996-10-24
EP0639434B2 (fr) 2004-01-07
DK0639434T3 (da) 1996-10-21
ES2094601T3 (es) 1997-01-16

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