EP0619365A1 - Composition nettoyante et procédé de sa fabrication - Google Patents
Composition nettoyante et procédé de sa fabrication Download PDFInfo
- Publication number
- EP0619365A1 EP0619365A1 EP94105386A EP94105386A EP0619365A1 EP 0619365 A1 EP0619365 A1 EP 0619365A1 EP 94105386 A EP94105386 A EP 94105386A EP 94105386 A EP94105386 A EP 94105386A EP 0619365 A1 EP0619365 A1 EP 0619365A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cleaning agent
- agent according
- cleaning
- mixture
- substances
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 21
- 239000000203 mixture Substances 0.000 title claims abstract description 19
- 238000000034 method Methods 0.000 title claims description 9
- 239000000126 substance Substances 0.000 claims abstract description 19
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 8
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 claims abstract description 6
- 241000207199 Citrus Species 0.000 claims abstract description 4
- 235000020971 citrus fruits Nutrition 0.000 claims abstract description 4
- 239000000839 emulsion Substances 0.000 claims abstract description 3
- 235000007586 terpenes Nutrition 0.000 claims abstract description 3
- 239000012459 cleaning agent Substances 0.000 claims description 31
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 15
- 239000003921 oil Substances 0.000 claims description 14
- UAHWPYUMFXYFJY-UHFFFAOYSA-N beta-myrcene Chemical compound CC(C)=CCCC(=C)C=C UAHWPYUMFXYFJY-UHFFFAOYSA-N 0.000 claims description 8
- 238000010790 dilution Methods 0.000 claims description 7
- 239000012895 dilution Substances 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- GRWFGVWFFZKLTI-IUCAKERBSA-N (-)-α-pinene Chemical compound CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 claims description 4
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 claims description 4
- VYBREYKSZAROCT-UHFFFAOYSA-N alpha-myrcene Natural products CC(=C)CCCC(=C)C=C VYBREYKSZAROCT-UHFFFAOYSA-N 0.000 claims description 4
- CRPUJAZIXJMDBK-UHFFFAOYSA-N camphene Chemical compound C1CC2C(=C)C(C)(C)C1C2 CRPUJAZIXJMDBK-UHFFFAOYSA-N 0.000 claims description 4
- 239000003599 detergent Substances 0.000 claims description 4
- 238000004821 distillation Methods 0.000 claims description 4
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- -1 monocyclic terpenes Chemical class 0.000 claims description 4
- 239000000341 volatile oil Substances 0.000 claims description 3
- WTARULDDTDQWMU-RKDXNWHRSA-N (+)-β-pinene Chemical compound C1[C@H]2C(C)(C)[C@@H]1CCC2=C WTARULDDTDQWMU-RKDXNWHRSA-N 0.000 claims description 2
- WTARULDDTDQWMU-IUCAKERBSA-N (-)-Nopinene Natural products C1[C@@H]2C(C)(C)[C@H]1CCC2=C WTARULDDTDQWMU-IUCAKERBSA-N 0.000 claims description 2
- 239000001169 1-methyl-4-propan-2-ylcyclohexa-1,4-diene Substances 0.000 claims description 2
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 2
- PXRCIOIWVGAZEP-UHFFFAOYSA-N Primaeres Camphenhydrat Natural products C1CC2C(O)(C)C(C)(C)C1C2 PXRCIOIWVGAZEP-UHFFFAOYSA-N 0.000 claims description 2
- WTARULDDTDQWMU-UHFFFAOYSA-N Pseudopinene Natural products C1C2C(C)(C)C1CCC2=C WTARULDDTDQWMU-UHFFFAOYSA-N 0.000 claims description 2
- MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 claims description 2
- 229930006722 beta-pinene Natural products 0.000 claims description 2
- 229930006739 camphene Natural products 0.000 claims description 2
- ZYPYEBYNXWUCEA-UHFFFAOYSA-N camphenilone Natural products C1CC2C(=O)C(C)(C)C1C2 ZYPYEBYNXWUCEA-UHFFFAOYSA-N 0.000 claims description 2
- LCWMKIHBLJLORW-UHFFFAOYSA-N gamma-carene Natural products C1CC(=C)CC2C(C)(C)C21 LCWMKIHBLJLORW-UHFFFAOYSA-N 0.000 claims description 2
- 239000004571 lime Substances 0.000 claims description 2
- 235000001510 limonene Nutrition 0.000 claims description 2
- 229940087305 limonene Drugs 0.000 claims description 2
- 150000007875 phellandrene derivatives Chemical class 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- GRWFGVWFFZKLTI-UHFFFAOYSA-N rac-alpha-Pinene Natural products CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 238000000265 homogenisation Methods 0.000 claims 1
- 150000003505 terpenes Chemical class 0.000 abstract 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 4
- 229920000388 Polyphosphate Polymers 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 239000001205 polyphosphate Substances 0.000 description 3
- 235000011176 polyphosphates Nutrition 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- 206010039509 Scab Diseases 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 241000779819 Syncarpia glomulifera Species 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 229940112822 chewing gum Drugs 0.000 description 1
- 235000015218 chewing gum Nutrition 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 238000011086 high cleaning Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 244000005706 microflora Species 0.000 description 1
- 239000008239 natural water Substances 0.000 description 1
- 239000001739 pinus spp. Substances 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 239000008262 pumice Substances 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 229940036248 turpentine Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
Definitions
- the invention relates to a cleaning agent and a manufacturing method.
- cleaning agent is a collective name for mixtures of suitable substances that are used in particular for the surface cleaning of objects of all kinds. Cleaning agents are used on a large scale in industry, in commercial companies and in the household.
- Alkaline cleaning agents are known which mostly consist of strongly alkaline substances, such as sodium hydroxide solution and soda, and also often contain polyphosphates as softeners and silicates to improve the dirt-carrying capacity.
- washing-active substances such as, for example, fatty alcohol sulfates and disinfectants, for example chlorine bleach, can also be present.
- acidic cleaning agents are also common, e.g. Contain amidosulfonic acid and suitable detergent substances.
- Turpentine, benzene and benzine are also used as cleaning agents and solvents in the commercial sector.
- the main constituents of powdered or liquid household cleaning agents are mostly washing-active substances and polyphosphates, to which stabilizers, skin protection agents as well as colors and fragrances are added.
- mechanical abrasives consisting of finely ground quartz sand, chalk, diatomaceous earth or pumice stone in grain sizes smaller than 0.1 mm are common, which contain additives of alkalis, polyphosphates, washing-active and disinfectant substances.
- orange peel oil is a very good fat solvent.
- Orange peel oil is a purely biological substance with a high cleaning ability, which is also deodorising and mildly disinfecting and which does not create any ecological problems when it comes to disposal. There is only a germicidal effect up to a concentration of 1: 10,000, at a lower concentration, such as occurs in the disposal, essential orange peel oil is broken down very quickly and decomposed into unproblematic components.
- the object of the invention is to improve a cleaning agent based on orange peel oil with regard to the cleaning action and handling.
- an all-purpose cleaner is created which is suitable for a large number of applications both in the industrial and commercial sectors and in the household.
- the cleaner can be used as a concentrate, for example for removing stains, as well as in dilution with water, for example for house cleaning, in car washes, in canteen kitchens, etc.
- the degree of dilution depends on the type and extent of contamination.
- the cleaning agent is either added directly to the cleaning water or the cleaning agent is applied and washed off with water after the cleaning process.
- the use of the cleaning agent according to the invention is simple, easy and convenient, with no streaks, cleaning strips, etc., as residues.
- the cleaning effect is high even with economical dosing, which in connection with the high environmental compatibility and the quick degradation does not lead to disposal problems.
- the cold-pressed orange peel oil is an essential oil of 96.7% limonene; 1.9% myrcene; 0.6% ⁇ -pinene; 0.2% ⁇ -pinene and 0.1% phellandrene.
- the substance citrus phenene D-limone is obtained by distillation from orange peel as a mixture of predominantly monocyclic terpenes of the empirical formula C10H16, the 96% to 98% D-limonene; Contains 1% to 2% myrcene and 0.5% camphene.
- the cleaning effect and handling is optimized in particular by the mixture of cold-pressed orange peel oil and orange peel oil obtained by distillation.
- a known emulsifier of the composition mono- / diglycerides - polyoxyethylene (20) sorbitan monostearate is used, as is also used in the food sector. This eliminates a toxic effect and ensures good degradability.
- dilution with water in a ratio of 1:10 to 1: 500 can be used with good cleaning results.
- substances a) and b) and possibly d) are mixed in a first process step.
- the emulsifier is heated to 35 ° C. to 50 ° C. in accordance with c) and incorporated into the mixture by stirring.
- the citric acid may be added in a further process step.
- Claim 9 proposes to produce the required dilution by slowly and uniformly adding water and then to homogenize the mixture in order to counteract segregation.
- a preferred application in the household sector is that the cleaning agent is filled into a commercially available pump-spray bottle in the required dilution.
- the objects to be cleaned such as window panes, mirrors, sinks, tiles, etc., are sprayed with a thin film. Then wipe over with a damp cloth.
- the diluted detergent can also be applied directly to the cloth.
- almost all stains in the household such as crusts, oil stains, tar, shoe polish, wax stains, chewing gum, are loosened and removed.
- the cleaning agent according to the invention is well suited for cleaning carpets and carpets and for cleaning upholstery.
- the fabrics are also sprayed and then rubbed off with terry towels to remove dirt.
- the towels can be easily cleaned in the washing machine. Good cleaning results are also achieved with chrome cleaning, e.g. in car and engine care.
- the invention provides an inexpensive, ecologically well tolerated, effective cleaning agent which is suitable for a large number of applications.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4311409 | 1993-04-07 | ||
| DE19934311409 DE4311409A1 (de) | 1993-04-07 | 1993-04-07 | Reinigungsmittel und Herstellungsverfahren |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP0619365A1 true EP0619365A1 (fr) | 1994-10-12 |
Family
ID=6484947
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP94105386A Withdrawn EP0619365A1 (fr) | 1993-04-07 | 1994-04-07 | Composition nettoyante et procédé de sa fabrication |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP0619365A1 (fr) |
| DE (1) | DE4311409A1 (fr) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999011744A3 (fr) * | 1997-09-04 | 1999-08-19 | Serefina Lamarca | Produit de nettoyage |
| EP0943239A1 (fr) * | 1997-05-16 | 1999-09-22 | pro-pack Handels- und Vertriebsgesellschaft mbH & Co. KG | Compositios comprenant des terpènes des agrumes. |
| WO2011072861A1 (fr) | 2009-12-15 | 2011-06-23 | Bene-Arzneimittel Gmbh | Suppositoire comprenant du pantoprazole |
| WO2012171540A1 (fr) | 2011-06-15 | 2012-12-20 | Bene-Arzneimittel Gmbh | Suppositoire comportant du pantoprazole contenu dans des pastilles avec un noyau de cellulose |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0716143B1 (fr) * | 1994-12-09 | 1999-06-02 | Horst K. Veith | Procédé de nettoyage et de désinfection d'articles textiles agent de nettoyage et de désinfection biologique |
| DE10119825A1 (de) * | 2001-04-23 | 2002-11-07 | Nanogate Technologies Gmbh | Reinigungsanordnung und -verfahren |
| DE10315304B4 (de) * | 2002-09-11 | 2014-03-13 | Karsten Püschner | Verfahren zur Dekontaminierung eines mit chlororganischen Bioziden belasteten Objektes |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4533487A (en) * | 1983-08-15 | 1985-08-06 | Pitre-Jones | Process for producing blended d-Limonene and uses of the blended product |
| JPH01272700A (ja) * | 1988-04-25 | 1989-10-31 | Dai Ichi Kogyo Seiyaku Co Ltd | 精密部品の洗浄方法 |
| EP0384292A2 (fr) * | 1989-02-22 | 1990-08-29 | Joachim Koss | Agent de nettoyage et son procédé de préparation |
| JPH03243700A (ja) * | 1990-02-20 | 1991-10-30 | Nippon Oil & Fats Co Ltd | 洗浄剤組成物 |
| EP0512328A1 (fr) * | 1991-05-06 | 1992-11-11 | Miles Inc. | Composition nettoyante inoffensive vis à vis des produits alimentaires |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USRE33210E (en) * | 1986-05-01 | 1990-05-08 | Cleaning composition of terpene hydrocarbon and a coconut oil fatty acid alkanolamide having water dispersed therein |
-
1993
- 1993-04-07 DE DE19934311409 patent/DE4311409A1/de not_active Withdrawn
-
1994
- 1994-04-07 EP EP94105386A patent/EP0619365A1/fr not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4533487A (en) * | 1983-08-15 | 1985-08-06 | Pitre-Jones | Process for producing blended d-Limonene and uses of the blended product |
| JPH01272700A (ja) * | 1988-04-25 | 1989-10-31 | Dai Ichi Kogyo Seiyaku Co Ltd | 精密部品の洗浄方法 |
| EP0384292A2 (fr) * | 1989-02-22 | 1990-08-29 | Joachim Koss | Agent de nettoyage et son procédé de préparation |
| JPH03243700A (ja) * | 1990-02-20 | 1991-10-30 | Nippon Oil & Fats Co Ltd | 洗浄剤組成物 |
| EP0512328A1 (fr) * | 1991-05-06 | 1992-11-11 | Miles Inc. | Composition nettoyante inoffensive vis à vis des produits alimentaires |
Non-Patent Citations (2)
| Title |
|---|
| PATENT ABSTRACTS OF JAPAN vol. 014, no. 037 (C - 680) 24 January 1990 (1990-01-24) * |
| PATENT ABSTRACTS OF JAPAN vol. 016, no. 033 (C - 0905) 28 January 1992 (1992-01-28) * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0943239A1 (fr) * | 1997-05-16 | 1999-09-22 | pro-pack Handels- und Vertriebsgesellschaft mbH & Co. KG | Compositios comprenant des terpènes des agrumes. |
| WO1999011744A3 (fr) * | 1997-09-04 | 1999-08-19 | Serefina Lamarca | Produit de nettoyage |
| WO2011072861A1 (fr) | 2009-12-15 | 2011-06-23 | Bene-Arzneimittel Gmbh | Suppositoire comprenant du pantoprazole |
| EP2338477A1 (fr) | 2009-12-15 | 2011-06-29 | bene-Arzneimittel GmbH | Suppositoire comportant du pantoprazole |
| WO2012171540A1 (fr) | 2011-06-15 | 2012-12-20 | Bene-Arzneimittel Gmbh | Suppositoire comportant du pantoprazole contenu dans des pastilles avec un noyau de cellulose |
Also Published As
| Publication number | Publication date |
|---|---|
| DE4311409A1 (de) | 1994-10-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH DE DK ES FR GB GR IT LI LU NL PT SE |
|
| 17P | Request for examination filed |
Effective date: 19950330 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
| 18D | Application deemed to be withdrawn |
Effective date: 19961101 |