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EP0673493A1 - Glow plug. - Google Patents

Glow plug.

Info

Publication number
EP0673493A1
EP0673493A1 EP94930165A EP94930165A EP0673493A1 EP 0673493 A1 EP0673493 A1 EP 0673493A1 EP 94930165 A EP94930165 A EP 94930165A EP 94930165 A EP94930165 A EP 94930165A EP 0673493 A1 EP0673493 A1 EP 0673493A1
Authority
EP
European Patent Office
Prior art keywords
glow
glow plug
tube
glow tube
plug according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP94930165A
Other languages
German (de)
French (fr)
Other versions
EP0673493B1 (en
Inventor
Gabriele Schmidt
Karl-Heinz Schmidt
Hans Delesky
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beru Werk Albert Ruprecht GmbH and Co KG
Original Assignee
Beru Werk Albert Ruprecht GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beru Werk Albert Ruprecht GmbH and Co KG filed Critical Beru Werk Albert Ruprecht GmbH and Co KG
Publication of EP0673493A1 publication Critical patent/EP0673493A1/en
Application granted granted Critical
Publication of EP0673493B1 publication Critical patent/EP0673493B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23Q—IGNITION; EXTINGUISHING-DEVICES
    • F23Q7/00—Incandescent ignition; Igniters using electrically-produced heat, e.g. lighters for cigarettes; Electrically-heated glowing plugs
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23Q—IGNITION; EXTINGUISHING-DEVICES
    • F23Q7/00—Incandescent ignition; Igniters using electrically-produced heat, e.g. lighters for cigarettes; Electrically-heated glowing plugs
    • F23Q7/001—Glowing plugs for internal-combustion engines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
    • Y10T428/12611—Oxide-containing component
    • Y10T428/12618—Plural oxides

Definitions

  • the invention relates to a glow plug with a heating rod consisting of an inner pole and a glow tube, in which a heating element is arranged which is electrically connected to the inner pole.
  • Such a glow plug which is known for example from DE-OS 41 33 338, can be designed in the form of a rod glow plug and is used, for example, as a starting aid for an air-compressing internal combustion engine.
  • Glow plugs are also used for ignition support in heaters.
  • the object on which the invention is based is therefore to provide a glow plug of the type mentioned at the outset which has a shorter heating-up time without its service life being impaired.
  • This object is achieved according to the invention in that the glow tube is provided with a coating of a ceramic material at least in the region of its tip.
  • the ceramic coating provided according to the invention acts as surface protection for the glow tube, so that its wall thickness can be reduced considerably.
  • the resultant lower mass has the consequence that the glow plug according to the invention shows a short heating-up time, ie a rapid heating-up, which means that diesel vehicles whose engine is equipped with such glow plugs can be started more quickly. 'The extremely fast heat-up time without compromising Le ⁇ is achieved service life of the glow plug.
  • the design according to the invention also has the advantage that scaling of the material of the glow tube is avoided with the short heating times achieved, long afterglow and high temperatures, which makes it possible to use glow tubes made of a material which is associated with low costs.
  • a cost saving also results from the fact that the glow tube can have smaller tube wall thicknesses.
  • the coating provided according to the invention further fulfills the requirement existing in heating devices that the glowing heating rod tip must be electrically insulated from the glow current.
  • the single figure shows the exemplary embodiment of the glow plug according to the invention in an axial partial section.
  • the embodiment of the glow plug according to the invention shown in the drawing comprises a housing in which a heating rod 1 is arranged, which consists of an inner pole 2 for connection to the electrical power supply and a glow tube 5, in which a heating element 3 is arranged, which has the inner pole 2 is electrically connected.
  • the glow tube 5 has at least at its tip a coating 6, 7 made of a ceramic material, which in the embodiment shown in the drawing consists of a base or adhesive layer 6 made of NiCrAlY, in particular Ni 22Cr 10A1 1Y or a similar material and the actual ceramic cover layer 7, which preferably consists of yttrium-stabilized zirconium dioxide mixed with Ni Cr Al Y.
  • the mixing ratio between the zirconium dioxide and the admixtures is between 10 and 80% for Zr02, especially 50:50.
  • the adhesive layer 6, which is applied directly to the glow tube 5, has a thickness between 10 and 50 ⁇ m, in particular between 20 and 30 ⁇ m.
  • the cover layer 7 is provided on the adhesive layer 6.
  • the glow tube 5 can be made of the alloys commonly used up to now, such as Inconel 600 or 601, but with a low Rigen wall thickness over its entire length or at its tip or made of another particularly cheaper alloy.
  • a suitable heating rod or glow tube shape is provided with a geometry in which edges, corners and sharp transitions are avoided and rounded.
  • R1 denotes a point where there is no coating. If the entire heating rod tip is coated, a radius of approximately 3-5 mm is provided between R1 and R2. In contrast, the radius R3 can only be approximately 1 to 2 mm.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Resistance Heating (AREA)
  • Vessels And Coating Films For Discharge Lamps (AREA)
  • Investigating, Analyzing Materials By Fluorescence Or Luminescence (AREA)

Abstract

PCT No. PCT/EP94/03367 Sec. 371 Date Jun. 12, 1995 Sec. 102(e) Date Jun. 12, 1995 PCT Filed Oct. 12, 1994 PCT Pub. No. WO95/10736 PCT Pub. Date Apr. 20, 1995Glow plug with a heating rod formed of an inner pole (2) and a glow tube (5) in which there is heating element (3) which is electrically connected to the inner pole (2). At least in the area of its tip, the glow tube (5) is provided with a coating (7) of ceramic material, especially yttrium-stabilized zirconium dioxide which has a subsurface or adhesive layer (6) of NiCrAlY which is directly provided on the glow tube (5).

Description

Glühkerze Glow plug
Beschreibungdescription
Die Erfindung betrifft eine Glühkerze mit einem Heiz- stab aus einem Innenpol und einem Glührohr, in dem ein Hei¬ zelement angeordnet ist, das mit dem Innenpol elektrisch verbunden ist.The invention relates to a glow plug with a heating rod consisting of an inner pole and a glow tube, in which a heating element is arranged which is electrically connected to the inner pole.
Eine derartige Glühkerze, die beispielsweise aus der DE-OS 41 33 338 bekannt ist, kann in Form einer Stabglühker¬ ze ausgebildet sein und dient z.B. als Starthilfe für eine luftverdichtetende Brennkraftmaschine.Such a glow plug, which is known for example from DE-OS 41 33 338, can be designed in the form of a rod glow plug and is used, for example, as a starting aid for an air-compressing internal combustion engine.
Glühkerzen werden darüber hinaus auch zur Zündungsun¬ terstützung bei Heizgeräten eingesetzt.Glow plugs are also used for ignition support in heaters.
Das Problem bei den bisher üblichen bekannten Glühker¬ zen dieser Art besteht darin, daß sie den künftigen Anfor¬ derungen an eine kurze Aufheizzeit nicht genügen, oder aber die Verkürzung der Aufheizzeit mit einer Verringerung der Lebensdauer der Glühkerze erkauft werden muß.The problem with the previously known glow plugs of this type is that they do not meet the future requirements for a short heating-up time, or the shortening of the heating-up time must be bought with a reduction in the life of the glow plug.
Die der Erfindung zugrundeliegende Aufgabe besteht daher darin, eine Glühke ze der eingangs genannten Art zu schaffen, die eine kürzere Aufheizzeit hat, ohne daß ihre Lebensdauer beeinträchtigt ist. Diese Aufgabe wird gemäß der Erfindung dadurch gelöst, daß das Glührohr wenigstens im Bereich seiner Spitze mit einer Beschichtung aus einem keramischen Material versehen ist .The object on which the invention is based is therefore to provide a glow plug of the type mentioned at the outset which has a shorter heating-up time without its service life being impaired. This object is achieved according to the invention in that the glow tube is provided with a coating of a ceramic material at least in the region of its tip.
Die gemäß der Erfindung vorgesehene Keramikbeschichtung wirkt als Oberflächenschutz des Glührohres, so daß dessen Wandstärke erheblich verringert werden kann. Die dadurch erzielte geringere Masse hat zur Folge, daß die erfindungs- gemäße Glühkerze eine kurze Aufheizzeit, d.h. eine schnelle Aufheizung zeigt, wodurch eine schnellere Startbereitschaft bei Dieselfahrzeugen erreicht werden kann, deren Maschine mit derartigen Glühkerzen ausgerüstet ist.' Dabei wird die extrem schnelle Aufheizzeit ohne Beeinträchtigung der Le¬ bensdauer der Glühkerze erzielt.The ceramic coating provided according to the invention acts as surface protection for the glow tube, so that its wall thickness can be reduced considerably. The resultant lower mass has the consequence that the glow plug according to the invention shows a short heating-up time, ie a rapid heating-up, which means that diesel vehicles whose engine is equipped with such glow plugs can be started more quickly. 'The extremely fast heat-up time without compromising Le¬ is achieved service life of the glow plug.
Die erfindungsgemäße Ausbildung hat weiterhin den Vor¬ teil, daß ein Abzundern des Materials des Glührohres bei den erzielten kurzen Aufheizzeiten, einem langen Nachglühen und hohen Temperaturen vermieden wird, wodurch der Einsatz von Glührohren aus einem Material möglich wird, das mit geringen Kosten verbunden ist. Eine Kostenersparnis ergibt sich dar¬ über hinaus dadurch, daß das Glührohr geringere Rohrwand¬ stärken haben kann.The design according to the invention also has the advantage that scaling of the material of the glow tube is avoided with the short heating times achieved, long afterglow and high temperatures, which makes it possible to use glow tubes made of a material which is associated with low costs. A cost saving also results from the fact that the glow tube can have smaller tube wall thicknesses.
Die gemäß der Erfindung vorgesehene Beschichtung er¬ füllt weiterhin die bei Heizgeräten bestehende Forderung, daß die glühende Heizstabspitze vom Glühstrom elektrisch isoliert sein muß.The coating provided according to the invention further fulfills the requirement existing in heating devices that the glowing heating rod tip must be electrically insulated from the glow current.
Schließlich wird eine zuverlässige Massefreiheit der Heizstabspitze bzw. des Heizstabes bei zweipoligen Glühker¬ zen, z.B. beim Einbau in das Schutzrohr in Heizungen er¬ reicht.Finally, reliable freedom from mass of the heating rod tip or the heating rod in the case of two-pole glow plugs, e.g. when installed in the protective tube in heaters.
Besonders bevorzugte Weiterbildungen und Ausgestaltun¬ gen der erfindungsgemäßen Glühkerze sind Gegenstand der Ansorüche 2 bis 11. Im folgenden wird anhand der zugehörigen Zeichnung ein besonders bevorzugtes Ausführungsbeispiel der Erfindung näher beschrieben.Particularly preferred developments and refinements of the glow plug according to the invention are the subject of claims 2 to 11. A particularly preferred exemplary embodiment of the invention is described in more detail below with reference to the accompanying drawing.
Die einzige Figur zeigt das Ausführungsbeispiel der erfindungsgemäßen Glühkerze in einer axialen Teilschnitt- ansieht .The single figure shows the exemplary embodiment of the glow plug according to the invention in an axial partial section.
Das in der Zeichnung dargestellte Ausführungsbeispiel der erfindungsgemäßen Glühkerze umfaßt ein Gehäuse, in dem ein Heizstab 1 angeordnet ist, der aus einem Innenpol 2 zum Anschluß an die elektrische Energieversorgung und einem Glührohr 5 besteht, in dem ein Heizelement 3 angeordnet ist, das mit dem Innenpol 2 elektrisch verbunden ist. Das Heiz¬ element 3, das aus einer Heiz- und einer Regelwendel beste¬ hen kann, von denen die Regelwendel mit dem Innenpol 2 ver¬ bunden ist, ist in eine MgO-Füllung 4 im Glührohr 5 einge¬ bettet.The embodiment of the glow plug according to the invention shown in the drawing comprises a housing in which a heating rod 1 is arranged, which consists of an inner pole 2 for connection to the electrical power supply and a glow tube 5, in which a heating element 3 is arranged, which has the inner pole 2 is electrically connected. The heating element 3, which can consist of a heating coil and a control coil, of which the control coil is connected to the inner pole 2, is embedded in an MgO filling 4 in the glow tube 5.
Das Glührohr 5 weist wenigstens an seiner Spitze eine Beschichtung 6, 7 aus einem keramischen Material auf, die bei dem in der Zeichnung dargestellten Ausführungsbeispiel aus einer Untergrund- oder HaftSchicht 6 aus NiCrAlY, ins¬ besondere aus Ni 22Cr 10A1 1Y oder einem ähnlichen Material und der eigentlichen keramischen Deckschicht 7 besteht, die vorzugsweise aus yttriumstabilisiertem Zirkondioxid gemischt mit Ni Cr AI Y besteht . Das Mischungsverhältnis zwischen dem Zirkondioxid und den Zumischungen liegt zwischen 10 und 80 % für Zr02, insbesondere bei 50:50.The glow tube 5 has at least at its tip a coating 6, 7 made of a ceramic material, which in the embodiment shown in the drawing consists of a base or adhesive layer 6 made of NiCrAlY, in particular Ni 22Cr 10A1 1Y or a similar material and the actual ceramic cover layer 7, which preferably consists of yttrium-stabilized zirconium dioxide mixed with Ni Cr Al Y. The mixing ratio between the zirconium dioxide and the admixtures is between 10 and 80% for Zr02, especially 50:50.
Die Haftschicht 6, die direkt auf das Glührohr 5 aufge¬ bracht ist, hat eine Dicke zwischen 10 und 50 μm, insbeson¬ dere zwischen 20 und 30 μm. Die Deckschicht 7 ist auf der Haftschicht 6 vorgesehen.The adhesive layer 6, which is applied directly to the glow tube 5, has a thickness between 10 and 50 μm, in particular between 20 and 30 μm. The cover layer 7 is provided on the adhesive layer 6.
Bei einer derartigen Ausbildung kann das Glührohr 5 aus den bisher üblicherweise verwendeten Legierungen, wie bei¬ spielsweise Inconel 600 oder 601, allerdings mit einer nied- rigen Wandstärke über seine gesamte Länge oder an seiner Spitze oder aus einer anderen insbesondere kostengünstigeren Legierung bestehen.With such a configuration, the glow tube 5 can be made of the alloys commonly used up to now, such as Inconel 600 or 601, but with a low Rigen wall thickness over its entire length or at its tip or made of another particularly cheaper alloy.
Bei einer dünneren Wandung des Glührohres 5 wird eine schnellere Wärmeübertragung vom Heizelement 3 zur Glührohr¬ oberfläche erreicht, wobei darüber hinaus das Glührohr 5 vor einer Verzunderung geschützt ist.With a thinner wall of the glow tube 5, faster heat transfer from the heating element 3 to the glow tube surface is achieved, the glow tube 5 also being protected against scaling.
Um eine ausreichende Haftung der Beschichtung über die gesamte Lebensdauer der Glühkerze sicherzustellen, ist eine geeignete Heizstab- oder Glührohrform mit einer Geometrie vorgesehen, bei der Kanten, Ecken und scharfe Übergänge vermieden und abgerundet sind. In der Zeichnung bezeichnet Rl eine Stelle, an der keine Beschichtung vorhanden ist. Bei einer Beschichtung der ganzen Heizstabspitze ist zwischen Rl und R2 ein Radius von etwa 3 - 5 mm vorgesehen. Der Radius R3 kann demgegenüber nur etwa 1 bis 2 mm betragen.In order to ensure sufficient adhesion of the coating over the entire life of the glow plug, a suitable heating rod or glow tube shape is provided with a geometry in which edges, corners and sharp transitions are avoided and rounded. In the drawing, R1 denotes a point where there is no coating. If the entire heating rod tip is coated, a radius of approximately 3-5 mm is provided between R1 and R2. In contrast, the radius R3 can only be approximately 1 to 2 mm.
Aufgrund der möglichen geringeren Rohrwandstärke des Glührohres 5 und dem erzielten gleichbleibenden Aufheizver¬ halten kann der Energiebedarf der Glühkerze erheblich ge¬ senkt werden, was das Heizelement 3 schont. Dabei sind nied¬ rigere Heizstabendtemperaturen aufgrund der erzielten größe¬ ren Oberfläche möglich und ergibt sich eine Annäherung an Keramikkerzen. Due to the possible lower tube wall thickness of the glow tube 5 and the constant heating behavior achieved, the energy requirement of the glow plug can be considerably reduced, which protects the heating element 3. Lower heating rod temperatures are possible due to the larger surface area achieved and there is an approximation to ceramic candles.

Claims

Patentansprüche claims
1. Glühkerze mit einem Heizstab aus einem Innenpol und einem Glührohr, in dem ein Heizelement angeordnet ist, das mit dem Innenpol elektrisch verbunden ist, wobei das Glührohr wenigstens im Bereich seiner Spitze mit einer Beschichtung aus einem keramischen Material versehen ist, dadurch gekennzeichnet, daß eine HaftSchicht (6) aus Ni Cr AI Y auf dem Glührohr (5) ausgebildet ist und die Beschichtung (7) aus dem keramischen Material in Form einer Deckschicht aus yttriumstabilisiertem Zirkondioxid auf der Haftschicht (6) vorgesehen ist.1. Glow plug with a heating rod made of an inner pole and a glow tube, in which a heating element is arranged which is electrically connected to the inner pole, wherein the glow tube is provided at least in the region of its tip with a coating of a ceramic material, characterized in that an adhesive layer (6) of Ni Cr Al Y is formed on the glow tube (5) and the coating (7) made of the ceramic material is provided on the adhesive layer (6) in the form of a cover layer made of yttrium-stabilized zirconium dioxide.
2. Glühkerze nach Anspruch 1 dadurch gekennzeichnet, daß dem Zirkondioxid Ni Cr AI Y zugemischt ist.2. Glow plug according to claim 1, characterized in that the zirconium dioxide Ni Cr AI Y is mixed.
3. Glühkerze nach Anspruch 2 dadurch gekennzeichnet, daß der Anteil an Zr02 zwischen 10 und 80 % liegt.3. Glow plug according to claim 2, characterized in that the proportion of Zr02 is between 10 and 80%.
4. Glühkerze nach Anspruch 3 dadurch gekennzeichnet, daß das Mischungsverhältnis 50:50 beträgt.4. Glow plug according to claim 3, characterized in that the mixing ratio is 50:50.
5. Glühkerze nach Anspruch 1 dadurch gekennzeichnet, daß die Haftschicht (6) eine Stärke zwischen 10 und 50 μm hat.5. Glow plug according to claim 1, characterized in that the adhesive layer (6) has a thickness between 10 and 50 microns.
6. Glühkerze nach Anspruch 5 dadurch gekennzeichnet, daß die Stärke der Haftschicht (6) zwischen 20 und 30 μm liegt.6. Glow plug according to claim 5, characterized in that the thickness of the adhesive layer (6) is between 20 and 30 microns.
7. Glühkerze nach einem der vorhergehenden Ansprüche dadurch gekennzeichnet, daß das Glührohr (5) kanten- und eckenfrei und ohne scharfe Übergänge ausgebildet ist. 7. Glow plug according to one of the preceding claims, characterized in that the glow tube (5) is formed without edges and corners and without sharp transitions.
EP94930165A 1993-10-12 1994-10-12 Glow plug Expired - Lifetime EP0673493B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE4334771A DE4334771C2 (en) 1993-10-12 1993-10-12 Glow plug
DE4334771 1993-10-12
PCT/EP1994/003367 WO1995010736A1 (en) 1993-10-12 1994-10-12 Glow plug

Publications (2)

Publication Number Publication Date
EP0673493A1 true EP0673493A1 (en) 1995-09-27
EP0673493B1 EP0673493B1 (en) 1997-01-15

Family

ID=6499976

Family Applications (1)

Application Number Title Priority Date Filing Date
EP94930165A Expired - Lifetime EP0673493B1 (en) 1993-10-12 1994-10-12 Glow plug

Country Status (9)

Country Link
US (1) US5645742A (en)
EP (1) EP0673493B1 (en)
JP (1) JP3609087B2 (en)
KR (1) KR100366464B1 (en)
AT (1) ATE147845T1 (en)
BR (1) BR9405637A (en)
DE (2) DE4334771C2 (en)
ES (1) ES2098159T3 (en)
WO (1) WO1995010736A1 (en)

Cited By (1)

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Publication number Priority date Publication date Assignee Title
EP0771882A1 (en) * 1995-11-06 1997-05-07 Isuzu Ceramics Research Institute Co., Ltd. Heat resistance stainless steel wire or strip

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DE19630402C2 (en) * 1996-07-26 2000-12-28 Beru Ag Pole flame glow plug
DE19812785A1 (en) * 1998-03-24 1999-10-07 Beru Ag Protection tubes for glow and measuring elements
US6144015A (en) * 1998-09-25 2000-11-07 General Motors Corporation Glow sensor--ceramic flat plate
US6076493A (en) * 1998-10-26 2000-06-20 Caterpillar Inc. Glow plug shield with thermal barrier coating and ignition catalyst
DE19920766C1 (en) * 1999-05-05 2000-12-21 Beru Ag Glow plug and method of making the same
US6215105B1 (en) * 1999-08-18 2001-04-10 Delphi Technologies, Inc. Ion sensor glow plug assembly with coating between sheath and shell
US6285007B1 (en) * 1999-08-18 2001-09-04 Delphi Technologies, Inc. Ion sensor glow plug assembly
US6465759B1 (en) * 2000-03-14 2002-10-15 Delphi Technologies, Inc. Ion sensor glow plug assembly
US6512204B1 (en) * 2000-03-14 2003-01-28 Delphi Technologies, Inc. Ion sensor glow plug assembly
DE10117641C2 (en) * 2001-04-09 2003-02-27 Beru Ag glow plug
JP3816073B2 (en) * 2003-01-28 2006-08-30 日本特殊陶業株式会社 Glow plug and method of manufacturing glow plug
JP6667327B2 (en) * 2016-03-17 2020-03-18 日本特殊陶業株式会社 Heating device and temperature estimation device

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US4055705A (en) * 1976-05-14 1977-10-25 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Thermal barrier coating system
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JPS61107013A (en) * 1984-10-31 1986-05-24 Ngk Spark Plug Co Ltd Ceramic glow plug
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US5084606A (en) * 1990-05-17 1992-01-28 Caterpillar Inc. Encapsulated heating filament for glow plug
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0771882A1 (en) * 1995-11-06 1997-05-07 Isuzu Ceramics Research Institute Co., Ltd. Heat resistance stainless steel wire or strip
US5976708A (en) * 1995-11-06 1999-11-02 Isuzu Ceramics Research Institute Co., Ltd. Heat resistant stainless steel wire

Also Published As

Publication number Publication date
WO1995010736A1 (en) 1995-04-20
JPH08504938A (en) 1996-05-28
EP0673493B1 (en) 1997-01-15
ATE147845T1 (en) 1997-02-15
DE59401603D1 (en) 1997-02-27
JP3609087B2 (en) 2005-01-12
DE4334771A1 (en) 1995-04-13
DE4334771C2 (en) 1996-03-28
US5645742A (en) 1997-07-08
BR9405637A (en) 1999-09-08
ES2098159T3 (en) 1997-04-16
KR100366464B1 (en) 2003-02-25
KR950704655A (en) 1995-11-20

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