EP0661367A1 - Procédé de traitement de déchets - Google Patents
Procédé de traitement de déchets Download PDFInfo
- Publication number
- EP0661367A1 EP0661367A1 EP94890218A EP94890218A EP0661367A1 EP 0661367 A1 EP0661367 A1 EP 0661367A1 EP 94890218 A EP94890218 A EP 94890218A EP 94890218 A EP94890218 A EP 94890218A EP 0661367 A1 EP0661367 A1 EP 0661367A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fermentation process
- biological
- rotting
- annealing treatment
- subjected
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 27
- 239000002699 waste material Substances 0.000 title claims abstract description 17
- 239000000463 material Substances 0.000 claims abstract description 26
- 238000000855 fermentation Methods 0.000 claims abstract description 16
- 230000004151 fermentation Effects 0.000 claims abstract description 16
- 238000000137 annealing Methods 0.000 claims description 16
- 239000007789 gas Substances 0.000 claims description 16
- 239000000126 substance Substances 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 8
- 238000004140 cleaning Methods 0.000 claims description 4
- 239000002351 wastewater Substances 0.000 claims description 3
- 239000002912 waste gas Substances 0.000 claims 1
- 230000029087 digestion Effects 0.000 abstract 2
- 239000000047 product Substances 0.000 description 8
- 238000010586 diagram Methods 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- 238000004064 recycling Methods 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 239000003344 environmental pollutant Substances 0.000 description 3
- 231100000719 pollutant Toxicity 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 230000031018 biological processes and functions Effects 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 239000013505 freshwater Substances 0.000 description 2
- 239000002920 hazardous waste Substances 0.000 description 2
- 239000002440 industrial waste Substances 0.000 description 2
- 238000000197 pyrolysis Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000010801 sewage sludge Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 206010053615 Thermal burn Diseases 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000010791 domestic waste Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 238000010169 landfilling Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 239000013502 plastic waste Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03B—SEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
- B03B9/00—General arrangement of separating plant, e.g. flow sheets
- B03B9/06—General arrangement of separating plant, e.g. flow sheets specially adapted for refuse
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
Definitions
- the invention relates to a method for treating residual waste, in which the light fraction is implemented by thermal methods and the heavy fraction is subjected to a biological rotting or fermentation process.
- Residual waste usually comes from municipal, commercial or industrial waste and arises after the previous collection and recycling of all material and biological components in the waste. These substances are collected using the well-known, different methods and used for material or biological recycling. The remaining remainder as well as the remnants from the treatment plants for material and biological recycling form the residual waste.
- the composition of the residual waste to be treated is similar to that of mixed household waste, but has a lower content of organic substances, but an increased content of plastic waste.
- a method of the type mentioned at the outset is now known, in which there is the possibility of combining the two methods, namely the so-called “residual waste splitting method”.
- a fuel with a high proportion of ignition loss is mechanically separated and subjected to a targeted thermal utilization by means of light fraction incineration plants or light fraction pyrolysis plants.
- the remaining heavy fraction is subjected to a biological rotting or fermentation process, optionally with the addition of sewage sludge.
- the end product obtained there does not meet the requirements of the "Technical instructions for municipal waste" with regard to the maximum loss on ignition of the dry matter.
- the invention is therefore based on the object of providing a method of the type mentioned at the outset with which the prescribed parameters for the remaining constituents to be deposited are achieved.
- this object is achieved in that the material coming from the biological rotting or fermentation process of the heavy fraction is subjected to an annealing treatment, preferably at a temperature of approximately 1600 ° C.
- an annealing treatment preferably at a temperature of approximately 1600 ° C.
- the product is converted into a melt state and has a glass-like character at the outlet of the corresponding furnace. Landfilling is easily possible according to all current regulations.
- the material coming from the biological rotting or fermentation process can be freed of the remaining light materials by air separation prior to the annealing treatment.
- This has the advantage that those substances which are not necessarily to be subjected to the annealing treatment, since they can be used elsewhere, do not burden the annealing process and thus the energy balance.
- the light substances separated by wind sifting can be added to the light fraction prior to their thermal utilization, whereby the energy content contained in the light substances can be used particularly well.
- the exhaust gases resulting from the annealing treatment can, if necessary, Cleaning, be introduced into the biological rotting or fermentation process, whereby the resulting exhaust gases are processed accordingly in the biological treatment plant, so that pollution of the environment by these exhaust gases is eliminated.
- the gases introduced to cool the annealing material at the end of the annealing treatment can be used at the beginning of the annealing treatment to heat the material to be annealed.
- the gases emerging from this after heating the material to be glowed can be dewatered, the resulting wastewater being fed to the biological rotting or fermentation process.
- FIG. 2 shows a quantity flow diagram with regard to the recycling of residual waste.
- FIG. 3 shows a basic diagram of the annealing treatment step.
- the residual waste is separated into a light fraction and a heavy fraction in a mechanical processing plant, in which hazardous waste and valuable materials are separated.
- the light fraction which can be used thermally, is fed to a special incinerator.
- the high loss on ignition is used as an energy source and the carbon is burned to carbon dioxide.
- the light fraction has a high calorific value and has an essentially constant composition, which enables the operation of ecologically sensible and economically favorable combustion plants, for example according to the principle of the circulating fluidized bed.
- the heavy fraction coming from the mechanical treatment plant is sent to a biological treatment, where appropriate sewage sludge can be added.
- the biological treatment is a rotting or fermentation process.
- this biological treatment plant now follows that the material coming from this biological rotting is further processed after it has been separated into a light and heavy fraction by sieving and air separation.
- the light fraction obtained is mixed with the light fraction, which comes directly from the mechanical processing plant of the residual waste, and burned there.
- the fraction falling through the sieve or the heavy fraction coming from the air classifier is subjected to an afterglow step.
- the product is screened through a sieve with a preferred mesh size of 15 mm.
- the afterglow is carried out in a special tunnel furnace, but it is a prerequisite that the water content of the material emerging in the biological treatment stage is reduced to approximately 20% by weight and that the maximum possible removal of all light materials is achieved by the air classifier.
- the tunnel kiln is preferably heated by means of electrical resistance heating elements in order to avoid an open flame in the kiln and thereby reduce the risk of fire.
- the material to be treated is heated to a temperature of around 1600 ° C in this tunnel oven.
- a glass-like product is then created, which after appropriate cooling can be deposited in any case.
- the tunnel furnace is designated by 1 in Fig. 3 and has a resistance heating element 2 for annealing the material.
- the tunnel kiln 1 is loaded via a conveyor belt 3, which places the material via a hopper 4 on the conveyor belt 5 leading through the kiln.
- the product is then thrown off this conveyor belt 5 at 6 and fed to a landfill.
- the kiln 1 has a heating zone 7 and a cooling zone 8, which is achieved by a targeted air flow.
- the product is annealed between these zones.
- a pump 9 the cooling air is introduced at the end of the cooling zone 8 at the bottom of the furnace, passes through the materials to be cooled and is led out of the furnace at 10 at the upper end.
- the line 10 then leads into the central region of the heating zone 7, as a result of which the material introduced into the kiln 1 is heated.
- the warming-up gas led out of the kiln via line 11 is passed through a heat exchanger 12 which is cooled via a fresh water line 13.
- the cooled gas emerging from the heat exchanger 12, which is mixed with condensate, is fed via a line 14 to a separator 15, the cooled air being introduced via line 16 into the cooling zone of the kiln 1, etc. in the direction of the product flow in front of the line coming from the pump 9.
- the cooling air is heated by the annealed material and exits the cooling zone of the kiln via line 17 and, after the line 10 flows into the kiln 1, etc.
- the cleaning station 25 consists of two washing stages 26, 27, in which the pollutants entrained in the exhaust gas are washed out or neutralized. The first washing stage works in the acidic area and the second washing stage in the basic area.
- the pollutants in the exhaust gas are thereby neutralized and excreted in the wash water treatment system 25 as solids (REA products). These solids should be sent to a hazardous waste landfill.
- the exhaust gases coming from the washing system 25 are cleaned again via an activated carbon filter 28 in order to separate any special organic pollutants that may also be present.
- By means of a pump 29, these exhaust gases are discharged through a Line 30 fed to a rotting plant 31, etc. the biological treatment plant of the heavy fraction of the residual waste fraction coming from the mechanical treatment plant.
- Exhaust gases emerging from this decomposition system 31 are fed to a bio-washing system 33 via a pump 32 and then discharged into the atmosphere via line 34.
- the condensate coming from the separators 15 and 23, as well as the fresh water emerging from the heat exchanger 12, is fed via lines 35 and 36 into the rotting plant 31 in order to control the moisture balance there and also to break down any pollutant particles that have been carried along.
- the quantity flow diagram shown in FIG. 2 shows in another form the flow diagram according to FIG. 1, but with the addition of the substrate quantities carried in the individual branches.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Processing Of Solid Wastes (AREA)
- Removal Of Specific Substances (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT2644/93 | 1993-12-29 | ||
| AT0264493A AT399864B (de) | 1993-12-29 | 1993-12-29 | Verfahren zur behandlung von restmüll |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0661367A1 true EP0661367A1 (fr) | 1995-07-05 |
| EP0661367B1 EP0661367B1 (fr) | 1998-09-02 |
Family
ID=3537967
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP94890218A Expired - Lifetime EP0661367B1 (fr) | 1993-12-29 | 1994-12-22 | Procédé de traitement de déchets |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP0661367B1 (fr) |
| AT (2) | AT399864B (fr) |
| DE (1) | DE59406828D1 (fr) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0899509B1 (fr) | 1997-07-18 | 2000-11-02 | Amand Entwicklungs GmbH | Procédé et installation de traitement thermique de déchets et/ou de fragments de déchets |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3736111A (en) * | 1971-05-17 | 1973-05-29 | Hercules Inc | Process and apparatus for the complete reclamation of valuable products from solid waste |
| DE3402215A1 (de) * | 1984-01-24 | 1985-07-25 | Peter 7869 Holzinshaus Voelskow | Verfahren, anlage und einrichtungen zur gleichzeitigen verwertung von muell und klaerschlamm |
| DE3440484A1 (de) * | 1984-11-06 | 1986-05-07 | Peter 7869 Aitern Voelskow | Verfahren zur verschwelung teilweise feuchter biomasse - abfaelle |
| DE3807249C1 (en) * | 1988-01-26 | 1990-02-15 | Peter 7869 Aitern De Voelskow | A process for the thermal utilisation of organic wastes |
-
1993
- 1993-12-29 AT AT0264493A patent/AT399864B/de not_active IP Right Cessation
-
1994
- 1994-12-22 DE DE59406828T patent/DE59406828D1/de not_active Expired - Lifetime
- 1994-12-22 EP EP94890218A patent/EP0661367B1/fr not_active Expired - Lifetime
- 1994-12-22 AT AT94890218T patent/ATE170543T1/de not_active IP Right Cessation
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3736111A (en) * | 1971-05-17 | 1973-05-29 | Hercules Inc | Process and apparatus for the complete reclamation of valuable products from solid waste |
| DE3402215A1 (de) * | 1984-01-24 | 1985-07-25 | Peter 7869 Holzinshaus Voelskow | Verfahren, anlage und einrichtungen zur gleichzeitigen verwertung von muell und klaerschlamm |
| DE3440484A1 (de) * | 1984-11-06 | 1986-05-07 | Peter 7869 Aitern Voelskow | Verfahren zur verschwelung teilweise feuchter biomasse - abfaelle |
| DE3807249C1 (en) * | 1988-01-26 | 1990-02-15 | Peter 7869 Aitern De Voelskow | A process for the thermal utilisation of organic wastes |
Also Published As
| Publication number | Publication date |
|---|---|
| AT399864B (de) | 1995-08-25 |
| ATE170543T1 (de) | 1998-09-15 |
| ATA264493A (de) | 1994-12-15 |
| EP0661367B1 (fr) | 1998-09-02 |
| DE59406828D1 (de) | 1998-10-08 |
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