EP0520023B1 - Spinning of high molecular weight polyethylene fiber and the resulting spun fiber - Google Patents
Spinning of high molecular weight polyethylene fiber and the resulting spun fiber Download PDFInfo
- Publication number
- EP0520023B1 EP0520023B1 EP91906840A EP91906840A EP0520023B1 EP 0520023 B1 EP0520023 B1 EP 0520023B1 EP 91906840 A EP91906840 A EP 91906840A EP 91906840 A EP91906840 A EP 91906840A EP 0520023 B1 EP0520023 B1 EP 0520023B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fiber
- molecular weight
- spun
- yarn
- spinning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 198
- 238000009987 spinning Methods 0.000 title claims abstract description 28
- 239000004705 High-molecular-weight polyethylene Substances 0.000 title claims abstract description 17
- -1 polyethylene Polymers 0.000 claims abstract description 44
- 239000004698 Polyethylene Substances 0.000 claims abstract description 32
- 229920000573 polyethylene Polymers 0.000 claims abstract description 32
- 239000000203 mixture Substances 0.000 claims abstract description 28
- 229920000742 Cotton Polymers 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 11
- 229920000728 polyester Polymers 0.000 claims abstract description 11
- 239000004743 Polypropylene Substances 0.000 claims abstract description 7
- 229920001155 polypropylene Polymers 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 229920006231 aramid fiber Polymers 0.000 claims description 9
- 210000002268 wool Anatomy 0.000 claims description 5
- 239000004952 Polyamide Substances 0.000 claims description 4
- 229920000297 Rayon Polymers 0.000 claims description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 4
- 229920002647 polyamide Polymers 0.000 claims description 4
- 239000002964 rayon Substances 0.000 claims description 4
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 3
- 239000004917 carbon fiber Substances 0.000 claims description 3
- 230000006835 compression Effects 0.000 claims description 3
- 238000007906 compression Methods 0.000 claims description 3
- 229920003366 poly(p-phenylene terephthalamide) Polymers 0.000 claims description 2
- 229920003235 aromatic polyamide Polymers 0.000 abstract description 6
- 229920002480 polybenzimidazole Polymers 0.000 abstract description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052799 carbon Inorganic materials 0.000 abstract description 3
- 239000002131 composite material Substances 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 2
- 238000002835 absorbance Methods 0.000 abstract 1
- 239000004744 fabric Substances 0.000 description 19
- 241000219146 Gossypium Species 0.000 description 12
- 238000001228 spectrum Methods 0.000 description 11
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 description 10
- 238000012986 modification Methods 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 229920000098 polyolefin Polymers 0.000 description 5
- 229920000271 Kevlar® Polymers 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 239000004760 aramid Substances 0.000 description 4
- 230000002238 attenuated effect Effects 0.000 description 4
- 238000009960 carding Methods 0.000 description 4
- 239000004761 kevlar Substances 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 229920002544 Olefin fiber Polymers 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000002390 adhesive tape Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000002788 crimping Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000004767 olefin fiber Substances 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 238000007378 ring spinning Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000009864 tensile test Methods 0.000 description 2
- 229920013683 Celanese Polymers 0.000 description 1
- 229920000784 Nomex Polymers 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229910001651 emery Inorganic materials 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000005673 monoalkenes Chemical class 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000004763 nomex Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000019612 pigmentation Effects 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000001755 vocal effect Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
- D02G3/047—Blended or other yarns or threads containing components made from different materials including aramid fibres
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/02—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
- D10B2321/021—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polyethylene
- D10B2321/0211—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polyethylene high-strength or high-molecular-weight polyethylene, e.g. ultra-high molecular weight polyethylene [UHMWPE]
Definitions
- the present invention relates to the spinning of staple fibers into yarn and to the resulting spun yarn. More particularly, it relates to the spinning of high molecular weight polyethylene staple fiber and to modifications to conventional spinning technology necessary to spin the high molecular weight polyethylene fiber.
- EP-A-0 310 202 describes combining polyolefin filament or yarns with filaments or yarns having high wetting and adhesive power. The filaments or yarns are combined by core spinning or twisting and there is no mention that a spun yarn could be formed from staple fibers of this combination.
- GB-A-2 152 543 discloses a high bulk olefin blended yarn which includes olefin fiber and a naturally occurring fiber such as cotton or wool. There is no mention of solution or gel spun high molecular weight polyethylene fiber.
- This invention is a spun yarn, comprising discontinuous lengths of a high molecular weight polyethylene fiber and a sufficient amount of discontinuous lengths of any other fiber to permit spinning a blend of the fiber lengths.
- the molecular weight of the polyethylene is greater than 300,000, and more preferred is the molecular weight of greater than 500,000.
- the preferred other fiber has memory.
- memory is meant ability to return to original shape after distortion. For example a straightened, formerly crimped fiber that will return to its original crimped state.
- the preferred other fiber has a denier per filament of no greater than 20 (180 tex), more preferably the other fiber has a denier per filament of no greater than 3 (27 tex).
- the preferred discontinuous lengths of the polyethylene fiber and the other fiber are no longer than 14 inches (35.6 cm), more preferably the discontinuous lengths of the polyethylene fiber and the other fiber have a length ranging from 0.75 to 14 inches (1.9 to 35.6 cm).
- the polyethylene fiber forms 5 to 95% by weight of the spun fiber, more preferably, the polyethylene fiber forms 5 to 60% by weight of the spun fiber.
- the polyethylene fiber has an ultimate elongation of less than 8% at room temperature, more preferably 2 to 4.5%.
- the polyethylene fiber has a denier per filament of no greater than 20 (180 tex), more preferably 1 to 15 (9 to 135 tex), and most preferably, 1 to 10 (9 to 90 tex). Even more preferably the polyethylene fiber has a denier per filament of 1 to 3 (9 to 27 tex).
- the preferred other fiber is selected from the group consisting of polyester fiber, polyamide fiber, cotton fiber, wool fiber, rayon fiber, polypropylene fiber, aramid fiber, lower molecular weight polyethylene fibers, carbon fiber, and mixtures thereof.
- the other fiber forming 5 to 95% by weight of the spun fiber, is characterized by having memory, a denier per filament of no more than 20 (180 tex), and discontinuous lengths of no more than 14 inches (35.6 cm).
- polyethylene fiber forming 5 to 95% by weight of the spun fiber is characterized by an elongation of no more than 8% at room temperature, a denier per filament of no more than 20 (180 tex), and discontinuous lengths of no more than 14 inches (35.6 cm).
- the other fiber is an aramid fiber which forms no more than 50% by weight of the spun fiber.
- the preferred aramid other fiber is poly(p-phenylene terephthalamide).
- This invention is also an article made from the spun yarn of the spun fiber described above, preferably the article made from the spun fiber of 50% aramid.
- This invention is also a method of spinning discontinuous lengths of a high molecular weight polyethylene fiber, comprising blending a sufficient amount of discontinuous lengths of any other fiber to permit spinning of a blend of the fiber lengths.
- the preferred and more preferred molecular weights of the polyethylene are given above, along with the preferred, more preferred percent by weight blends, fiber weights, other fiber types, elongations, etc.
- This invention is also an apparatus for moving a fiber batt of at least 50 weight percent high molecular weight polyethylene fiber, comprising rotating means, said rotating means having a surface which rotates into contact with said fiber batt, and a cord aligned with a trumpet to form the fiber batt into a sliver, said surface being modified across at least a portion thereof to increase the friction between the surface and the fiber batt so that the batt moves when contacted by the rotating surface.
- the trumpet has an exit for the sliver sufficiently enlarged to limit compression of the sliver to the extent that it can be piddled.
- the surface be modified by having an adhesive across said portion, a double-backed tape across said portion, or fabric capable of increasing friction or engaging the fiber (such as a Velcro tape or Emory cloth) attached to said portion.
- the surface also can be modified by roughening to a surface of roughness of similar to 800 grit sandpaper or more coarse.
- discontinuous fiber lengths are placed by an operator into the backs of a plurality of hoppers 11.
- the individual mass of fibers is broken into smaller tufts by spiked conveying aprons (not shown) which then feed the tufts onto conveyor belt 12 to mix with tufts of fibers from other hoppers 11.
- Conveyor belt 12 then feeds the mixture of fibers into a blending unit 13 where they are further broken into smaller elements and further mixed. From unit 13 the fibers are transported through pipe 15 via Whitin Axi-Flo Unit 14 which is a pneumatic system, to pneumatic distributor 16.
- Distributor 16 further opens and fluffs the fibrous mass and then meters the fiber into the CMC Evenfeed Unit 17 which begins to form the fiber batt 35 from fiber 24 (referred to as a fiber lap in the art).
- fiber batt 35 is fed via feed plate 37 in association with feed roll 23 to lickerin 22 which has a plurality of wires 50 (card cloth) which rotate against batt 35 to pull and align discrete fibers from batt 35 and transfer them to the card cloth 50 covering the card cylinder 33 where they are further oriented and worked (brushed/combed) by the carding plates or flats 25.
- Doffer 30 is also covered with a card cloth, removes the accumulating sheet of oriented fibers from card 18 and carries the sheet of fibers to a removal point where it can be removed by a comb 28.
- the sheet of fibers is then fed through a trumpet 21 which forces the sheet to neck down for passage through a circular aperture 54. From aperture 54, the sliver 20 (necked down fiber sheet) is piddled into a take-up can 19 where it is loosely coiled.
- the modification to feed roll 23 is shown in Fig. 4; double-sided adhesive tape 52 was spiralled around roll 23, as shown. Without use of an adhesive such as the tape, or another surface modification the feed roll does not function properly when high strength, high molecular weight polyethylene staple fiber is being processed, especially when blends over about 50% high molecular weight polyethylene are being processed. Without modification, the batt of fibers just slips and backs up, forms clumps and therefore the machine must be stopped because the fiber can not be carded.
- Figs. 2,3,4 and 5 provide more detail regarding the prior art process showing feed roll 23 and surrounding members in greater detail.
- Fig. 2 shows feed plate 37, card cylinder 33 screen 38, having wire 50 protruding, lickerin screen 40, backplate 34, spiral brush 31 for flats 25, front plate 29.
- Calender rolls 27 convey the sliver 20 from trumpet 21 to sliver can 19 on holder 26.
- Clearer 43 clears feed roll 23.
- Lap guide 45 guides the lap to feed roll 23.
- Mote knives 48 cut away motes which may accumulate from the lap.
- Fig. 5 shows trumpet 21 in various aspects.
- Figure 5A is an isometric view and Fig. 5B is a cross section showing outlet opening 54 while 5D shows end view of trumpet 21 having outer perimeter 55 and outlet 54.
- Fig. 5C show the enlarged outlet opening 57, necessary for production of the spun fiber of this invention.
- feed roll 23 could not move batt 35 forward to the lickerin. Two modifications were made. The fiber was blended with other fiber, to be discussed in more detail below, and the feed roll 23 was modified as shown in FIGURE 4 with a spiral of double-backed masking tape on its surface that rotates into contact with batt 35 to permit it to move batt 35 forward. Anything that can be put on the feed roll 23 to enchance the frictional characteristics between its surface and batt 35 is acceptable, and it may be coextensive with the roll surface or distributed over a portion thereof as long as the batt 18 can be moved by it. For example, Velcro - type tape, Emery cloth, a roughened surface, adhesive, double-backed tape or the like can be used.
- trumpet 21 Another problem was encountered at trumpet 21. Due to the inability of the fiber to hold crimp, it does not spring back after deformation. After the neck down of trumpet 21 aperture 28, the sliver 20 is like a rod and difficult to piddle. Therefore, trumpet 21 was bored out sufficiently to increase the size of the sliver 20 and to reduce or limit the compression of the sliver to the extent that it could be piddled (see FIGURE 5C).
- Cans of the attenuated sliver are collected and transferred to a draw frame, in the accompanying examples a Saco Lowell four over five draw frame, where several individual slivers are blended and further attenuated/drawn.
- the cans of attenuated, blended sliver are then transferred to a roving frame for further attenuation and a very low level of twist is inserted.
- the sliver is now ready for spinning and is taken-up on a bobbin which is the feeder package for the spinning frame.
- the bobbins are hung on a spinning frame, preferably a ring spinning frame, where the slivers are again individually attenuated and spun into yarn by twisting.
- the spun yarn is then taken up for packaging or further processing.
- US-A-4,457,985 generally discusses high molecular weight polyethylene.
- suitable fibers are those of molecular weight of at least 300,000, more preferably at least 500,000, most preferably in excess of one million.
- ECPE extended chain polyethylene
- Such extended chain polyethylene (ECPE) fibers may be grown in solution as described in US-A-4,137,394 or US-A-4,356,138, or may be a filament spun from a solution to form a gel structure, as described in DE-A-3,004,699 and GB-A-2,051,667, and especially described in US-A-4,551,296.
- polyethylene shall mean a predominantly linear polyethylene material that may contain minor amounts of chain branching or comonomers not exceeding 5 modifying units per 100 main chain carbon atoms, and that may also contain admixed therewith not more than 50 weight percent of one or more polymeric additives such as alkene-1-polymers, in particular low density polyethylene, polypropylene or polybutylene, copolymers containing mono-olefins as primary monomers, oxidized polyolefins, graft polyolefin copolymers and polyoxymethylenes, or low molecular weight additives such as lubricants, colorants, fillers and the like which are commonly incorporated by reference.
- polymeric additives such as alkene-1-polymers, in particular low density polyethylene, polypropylene or polybutylene, copolymers containing mono-olefins as primary monomers, oxidized polyolefins, graft polyolefin copolymers and polyoxymethylenes,
- the tenacity of the filaments should be at least 8 g/d (7.1 dN/tex), preferably in the range of from 8 to 45 g/d (7.1 to 39.7 dN/tex), most preferably in the range of 25 to 35 g/d/ (22.1 to 30.9 dN/tex).
- the tensile modulus of the filaments is at least 160 g/d (141.3 dN/tex), preferably in the range of 150 to 3300 g/d (132.5 to 2913.9 dN/tex), most preferably in the range of 1,200 to 2,500 g/d (1059.6 to 2207.5 dN/tex).
- These highest values for tensile modulus and tenacity are generally obtainable only by employing solution grown or solution spun, gel filament processes.
- the polyethylene fiber should preferably have an ultimate elongation by Instron tensile test of no greater than 8%, preferably in range of 2 to 4.5%, at room temperature, i.e., about 25° C.
- the denier per filament is preferably no greater than 20 (180 tex), more preferably 1 to 15 (9 to 135 tex), most preferably 1 to 10 (9 to 90 tex), even more preferably 1 to 3 (9 to 27 tex).
- the smaller denier per filament fibers are desirable to use in spinning blends for apparel applications.
- the larger denier per filament fibers are better to use in spinning blends for cordage, ropes, or heavy fabric applications.
- the amount of polyethylene fiber in the blend ranges from about 5 to 95% by weight, preferably 20 to 80 % by weight as the primary fiber and 5 to 40% by weight as the support fiber.
- the carrier fiber may be any other fiber. i.e., anything except the high molecular weight polyethylene fiber just described. Exemplary fibers may be found listed in allowed U.S. Patent Application S.N. 62,998 filed July 13, 1987, now US-A-4 916 000. A partial listing would include the aramids, cottons, carbon, polyester, polyamides, wool, rayon, polypropylene, lower molecular weight polyethylenes, etc.
- the carrier fiber preferably should have the following characteristics: it should preferably be a fiber which has memory or is permanently crimped; it should preferably have a denier per filament of no greater than 20 (180 tex), more preferably 0.5 to 3 (4.5 to 27 tex) for apparel applications and preferably 3 to 20 (27 to 180 tex) for ropes, cordage, and heavy fabric applications.
- the minimum amount of carrier fiber needed is 5% by weight of the spun fiber, and up to 95% by weight is acceptable.
- the preferred amount will range from about 20 to 50% by weight.
- the amount will be a function of the denier of the polyethylene fiber, e.g. one would need about 30% by weight carrier fiber to spin a 20 denier (180 tex) per filament polyethylene fiber, and would need less to spin a lower denier per filament polyethylene fiber.
- Both the carrier fiber and the polyethylene fiber are formed from discontinuous lengths of no greater than about 14 inches (35.6 cm), preferably no longer than 2.25 inches (5.7 cm) in the cotton system, more preferably 0.75 to 2 inches (1.9 to 5.1 cm).
- carrier fibers will depend on desired properties of the spun fiber. It is contemplated that a blend of polyester and/or cotton with the polyethylene will enhance hand; polypropylene can be blended for pigmentation; aramids, specifically Kevlar and Nomex can be includes for flame resistance; polybenzimidazoles (PBI), avilable commercially from Hoechst-Celanese, can be included for flame resistance and enchanced comfort due to higher moisture regain; carbon for use in fiber for composites requiring strength and toughness. Activated carbon fiber could be used for chemical absorption protection.
- PBI polybenzimidazoles
- Activated carbon fiber could be used for chemical absorption protection.
- SPECTRA 900 fiber available from Allied-Signal Inc. is run on the apparatus, unsuccessfully. The fiber slips on the feed rolls, clumps up in the feed mechanism and the machine must be stopped.
- a second trial was attempted with a fiber blend of 70% of the SPECTRA 10 dpf (90 tex) fiber above and 30% 1.2 denier (10.8 tex) per filament (dpf) Kodel polyester 1.5 inch (3.8 cm) staple.
- the mixture of 70% Spectra 10 dpf (90 tex) two inch (5.1 cm) staple and 30% 1.2 dpf (10.8 tex) Kodel 1.5 inch (3.8 cm) polyester staple was prepared and loaded into the card feeder.
- the second trial was conducted using a blend by weight of 60% Spectra 900 10 dpf (90 tex) 2.0 inch (5.1 cm) staple fiber and 40% Kevlar 1.5 dpf (13.5 tex) 1.5 inch (3.8 cm) staple fiber.
- a length of double-backed adhesive tape was spirally wrapped around feed roll 23 as in Fig. 4. The difference in the two fibers dpf caused some problems with how well the mixture blended and carded. The problems were not serious. However, to optimize the process it may be desirable to have fibers which have similar dpf.
- the main problem encountered during carding was the loading of the card main cylinder by the Spectra fiber. This problem may be solved by using a fiber with a smaller dpf or development of a special fiber finish. There was also a large amount of Spectra fiber removed by the card flats. The card flats rotate against the main cylinder to help clean it. This problem may disappear if the cylinder loading problem can be solved.
- the carded sliver was divided into six ends which were fed into a Saco Lowell 4 over 5 draw frame.
- the draw frame was running black coated rubber rolls. The black rolls seemed to minimize the tendency of the sliver to wrap.
- the draw frame further blended the carded sliver and reduced the sliver weight by about 50%.
- the roving was produced on a Saco Lowell roving frame. No problems were encountered during the roving formation.
- the roving was converted to spun yarn on a ring spinning frame. The speeds and conditions were varied to produce a yarn which had a specific cotton count. The first yarn count attempted was a 20's.
- the two spun yarns produced were a 10's and a 5's cotton count. Both of these yarns spun easily. Some optimization will be necessary to achieve the best balance of physical properties in the finished yarn.
- Example 1 was repeated loading the following fibers: 70% of 3 dpf (27 tex) SPECTRA * 2" (5.1 cm) staple 30% of 1.2 dpf (10.8 tex) Kodel polyester 1.5" (3.8 cm) staple
- the SPECTRA fiber had a lower intrinsic viscosity of between 6 and 8, estimated molecular weight about 700,000.
- the article made from the blond of Spectra and Kevlar fiber from Example #1 exhibited good flame resistance and insulating properties.
- the fabric in this cane a knitted glove
- the exposed polyethylene fibers on the fabric surface melted back into the fabric even with the aramid fiber surface.
- the fabric did not ignite or burn which in surprising because Spectra fiber is a polyolefin which will burn if it becomes hot enough.
- the inside of the glove remained cool.
- the Spectra fibers did not seem to melt on the side of the fabric opposite the flame.
- the fabric exhibited a self extinguishing behavior and did not readily support combustion. (Surprising because olefin fibers are known to burn).
- the Spectra fiber should improve the abrasion resistance of the aramid fiber (in the case of the glove) and allow the item to have a longer service life.
- the fabric made from the blend of fibers had a good hand and the frictional characteristics of the fabric surface were improved over an all Spectra fabric because the aramid fiber reduced the slickness of the surface. This improved frictional property would be desirable in a glove because of the necessity of keeping a good grip on objects being handled.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Preliminary Treatment Of Fibers (AREA)
Abstract
Description
- The present invention relates to the spinning of staple fibers into yarn and to the resulting spun yarn. More particularly, it relates to the spinning of high molecular weight polyethylene staple fiber and to modifications to conventional spinning technology necessary to spin the high molecular weight polyethylene fiber.
- The spinning of staple (discontinuous lengths) fibers has been practiced for centuries. Natural fibers are of discontinuous lengths and require spinning to form a continuous yarn. Synthetic continuous filament fibers are converted into staple fiber and spun for a variety of reasons. One such reason is to improve the hand or appearance of the yarn. Another reason is to make a good yarn less expensively since the spinning process permits the use of some fiber which would have been wasted.
- With the advent of the high molecular weight polyethylene continuous filament fibers which are produced by solution spinning, such as SPECTRA high strength polyethylene fiber, it was only a matter of time before an attempt was made to cut the continuous filament fiber into staple and spin the staple fiber a fiber into yarn. When the attempt was made, it was not possible to card the fiber since the fiber batt was so slippery that it could not be moved by the conventional feed roll to the card. Furthermore, when an attempt was made to overcome the slipperiness problem by crimping the fiber, it was found that the fiber would not hold crimp. Another reason to attempt crimping was that the high strength polyethylene fibers would not spring back from being compressed during normal spinning processing, which is contrary to experience with other fibers. Until this invention that problem was not solved. The present invention was developed to overcome these problems.
- There have been disclosures of polyolefin fibers blended with other fibers, but none of these disclosures focuses on high molecular weight polyethylene staple fiber. For example, EP-A-0 310 202 describes combining polyolefin filament or yarns with filaments or yarns having high wetting and adhesive power. The filaments or yarns are combined by core spinning or twisting and there is no mention that a spun yarn could be formed from staple fibers of this combination. GB-A-2 152 543 discloses a high bulk olefin blended yarn which includes olefin fiber and a naturally occurring fiber such as cotton or wool. There is no mention of solution or gel spun high molecular weight polyethylene fiber.
- This invention is a spun yarn, comprising discontinuous lengths of a high molecular weight polyethylene fiber and a sufficient amount of discontinuous lengths of any other fiber to permit spinning a blend of the fiber lengths.
- The molecular weight of the polyethylene is greater than 300,000, and more preferred is the molecular weight of greater than 500,000.
- The preferred other fiber has memory. By memory is meant ability to return to original shape after distortion. For example a straightened, formerly crimped fiber that will return to its original crimped state.
- The preferred other fiber has a denier per filament of no greater than 20 (180 tex), more preferably the other fiber has a denier per filament of no greater than 3 (27 tex).
- The preferred discontinuous lengths of the polyethylene fiber and the other fiber are no longer than 14 inches (35.6 cm), more preferably the discontinuous lengths of the polyethylene fiber and the other fiber have a length ranging from 0.75 to 14 inches (1.9 to 35.6 cm).
- The polyethylene fiber forms 5 to 95% by weight of the spun fiber, more preferably, the polyethylene fiber forms 5 to 60% by weight of the spun fiber.
- Preferably, the polyethylene fiber has an ultimate elongation of less than 8% at room temperature, more preferably 2 to 4.5%. Preferably the polyethylene fiber has a denier per filament of no greater than 20 (180 tex), more preferably 1 to 15 (9 to 135 tex), and most preferably, 1 to 10 (9 to 90 tex). Even more preferably the polyethylene fiber has a denier per filament of 1 to 3 (9 to 27 tex).
- The preferred other fiber is selected from the group consisting of polyester fiber, polyamide fiber, cotton fiber, wool fiber, rayon fiber, polypropylene fiber, aramid fiber, lower molecular weight polyethylene fibers, carbon fiber, and mixtures thereof.
- It is preferred that the other fiber, forming 5 to 95% by weight of the spun fiber, is characterized by having memory, a denier per filament of no more than 20 (180 tex), and discontinuous lengths of no more than 14 inches (35.6 cm).
- It is preferred that polyethylene fiber forming 5 to 95% by weight of the spun fiber, is characterized by an elongation of no more than 8% at room temperature, a denier per filament of no more than 20 (180 tex), and discontinuous lengths of no more than 14 inches (35.6 cm).
- It is more preferred that the other fiber is an aramid fiber which forms no more than 50% by weight of the spun fiber.
- The preferred aramid other fiber is poly(p-phenylene terephthalamide).
- Use of lower price other fiber can create lower cost yarn blends.
- This invention is also an article made from the spun yarn of the spun fiber described above, preferably the article made from the spun fiber of 50% aramid.
- This invention is also a method of spinning discontinuous lengths of a high molecular weight polyethylene fiber, comprising blending a sufficient amount of discontinuous lengths of any other fiber to permit spinning of a blend of the fiber lengths.
- The preferred and more preferred molecular weights of the polyethylene are given above, along with the preferred, more preferred percent by weight blends, fiber weights, other fiber types, elongations, etc.
- This invention is also an apparatus for moving a fiber batt of at least 50 weight percent high molecular weight polyethylene fiber, comprising rotating means, said rotating means having a surface which rotates into contact with said fiber batt, and a cord aligned with a trumpet to form the fiber batt into a sliver, said surface being modified across at least a portion thereof to increase the friction between the surface and the fiber batt so that the batt moves when contacted by the rotating surface. The trumpet has an exit for the sliver sufficiently enlarged to limit compression of the sliver to the extent that it can be piddled.
- It is preferred that the surface be modified by having an adhesive across said portion, a double-backed tape across said portion, or fabric capable of increasing friction or engaging the fiber (such as a Velcro tape or Emory cloth) attached to said portion.
- The surface also can be modified by roughening to a surface of roughness of similar to 800 grit sandpaper or more coarse.
- In the accompanying drawings,
- FIGURE 1 is a schematic overview of the prior art cotton carding process for sliver production;
- FIGURE 2 is a detail of the card from FIGURE 1;
- FIGURE 3 is a detail of the feed to the card, with emphasis on feed to the lickerin;
- FIGURE 4 is a detail of the modified
feed roll 23; - FIGURE 5 has various views of
trumpet 21. - FIGURE 5A is an isometric view of a prior art trumpet shown in section in FIGURE 5B; and FIGURE 5C is a section of a modified trumpet, showing the enlarged exit opening. FIGURE 5D is an end view.
- In the accompanying drawings, like numbers refer to like apparatus. The process which is depicted and which was used in the examples which follow was the cotton system of spinning yarn. For more detail on this system, reference may be had to Textile Processing Vol. I by John H. Marvin, (1973) - South Carolina State Dept. of Education Office of Vocational Education; and Textiles: Fiber to Fabric by M.D. Potter and B.P. Corbman (1975) - McGraw-Hill Inc., see Chpt. 3
pp 35 to 71. - With reference to FIGURE 1, discontinuous fiber lengths, here staple, are placed by an operator into the backs of a plurality of
hoppers 11. Inside eachhopper 11, the individual mass of fibers is broken into smaller tufts by spiked conveying aprons (not shown) which then feed the tufts ontoconveyor belt 12 to mix with tufts of fibers fromother hoppers 11.Conveyor belt 12 then feeds the mixture of fibers into ablending unit 13 where they are further broken into smaller elements and further mixed. Fromunit 13 the fibers are transported throughpipe 15 via Whitin Axi-Flo Unit 14 which is a pneumatic system, topneumatic distributor 16.Distributor 16 further opens and fluffs the fibrous mass and then meters the fiber into theCMC Evenfeed Unit 17 which begins to form thefiber batt 35 from fiber 24 (referred to as a fiber lap in the art). With reference to Fig. 1, Fig. 2, Fig. 3 and FIGURE 5,fiber batt 35 is fed viafeed plate 37 in association withfeed roll 23 to lickerin 22 which has a plurality of wires 50 (card cloth) which rotate againstbatt 35 to pull and align discrete fibers frombatt 35 and transfer them to thecard cloth 50 covering thecard cylinder 33 where they are further oriented and worked (brushed/combed) by the carding plates orflats 25.Doffer 30 is also covered with a card cloth, removes the accumulating sheet of oriented fibers fromcard 18 and carries the sheet of fibers to a removal point where it can be removed by acomb 28. The sheet of fibers is then fed through atrumpet 21 which forces the sheet to neck down for passage through acircular aperture 54. Fromaperture 54, the sliver 20 (necked down fiber sheet) is piddled into a take-up can 19 where it is loosely coiled. - The modification to feed
roll 23 is shown in Fig. 4; double-sidedadhesive tape 52 was spiralled aroundroll 23, as shown. Without use of an adhesive such as the tape, or another surface modification the feed roll does not function properly when high strength, high molecular weight polyethylene staple fiber is being processed, especially when blends over about 50% high molecular weight polyethylene are being processed. Without modification, the batt of fibers just slips and backs up, forms clumps and therefore the machine must be stopped because the fiber can not be carded. - Figs. 2,3,4 and 5 provide more detail regarding the prior art process showing
feed roll 23 and surrounding members in greater detail. - Fig. 2 shows feed
plate 37,card cylinder 33 screen 38, havingwire 50 protruding,lickerin screen 40,backplate 34,spiral brush 31 forflats 25,front plate 29. Calender rolls 27 convey thesliver 20 fromtrumpet 21 to sliver can 19 onholder 26.Clearer 43, clearsfeed roll 23. Lap guide 45 guides the lap to feedroll 23.Mote knives 48 cut away motes which may accumulate from the lap. - Fig. 5 shows
trumpet 21 in various aspects. Figure 5A is an isometric view and Fig. 5B is a cross section showing outlet opening 54 while 5D shows end view oftrumpet 21 havingouter perimeter 55 andoutlet 54. Fig. 5C show theenlarged outlet opening 57, necessary for production of the spun fiber of this invention. For further reference to the general discussion which follows, refer to Textile Processing Vol.I, supra. - As previously indicated, when an attempt was made to spin staple high molecular weight polyethylene fiber alone with the system depicted in the drawing figures, feed
roll 23 could not movebatt 35 forward to the lickerin. Two modifications were made. The fiber was blended with other fiber, to be discussed in more detail below, and thefeed roll 23 was modified as shown in FIGURE 4 with a spiral of double-backed masking tape on its surface that rotates into contact withbatt 35 to permit it to movebatt 35 forward. Anything that can be put on thefeed roll 23 to enchance the frictional characteristics between its surface andbatt 35 is acceptable, and it may be coextensive with the roll surface or distributed over a portion thereof as long as thebatt 18 can be moved by it. For example, Velcro - type tape, Emery cloth, a roughened surface, adhesive, double-backed tape or the like can be used. - Another problem was encountered at
trumpet 21. Due to the inability of the fiber to hold crimp, it does not spring back after deformation. After the neck down oftrumpet 21aperture 28, thesliver 20 is like a rod and difficult to piddle. Therefore,trumpet 21 was bored out sufficiently to increase the size of thesliver 20 and to reduce or limit the compression of the sliver to the extent that it could be piddled (see FIGURE 5C). - Cans of the attenuated sliver are collected and transferred to a draw frame, in the accompanying examples a Saco Lowell four over five draw frame, where several individual slivers are blended and further attenuated/drawn.
- The cans of attenuated, blended sliver are then transferred to a roving frame for further attenuation and a very low level of twist is inserted. The sliver is now ready for spinning and is taken-up on a bobbin which is the feeder package for the spinning frame.
- The bobbins are hung on a spinning frame, preferably a ring spinning frame, where the slivers are again individually attenuated and spun into yarn by twisting. The spun yarn is then taken up for packaging or further processing.
- US-A-4,457,985, generally discusses high molecular weight polyethylene. In the case of polyethylene, suitable fibers are those of molecular weight of at least 300,000, more preferably at least 500,000, most preferably in excess of one million. Such extended chain polyethylene (ECPE) fibers may be grown in solution as described in US-A-4,137,394 or US-A-4,356,138, or may be a filament spun from a solution to form a gel structure, as described in DE-A-3,004,699 and GB-A-2,051,667, and especially described in US-A-4,551,296. As used herein, the term polyethylene shall mean a predominantly linear polyethylene material that may contain minor amounts of chain branching or comonomers not exceeding 5 modifying units per 100 main chain carbon atoms, and that may also contain admixed therewith not more than 50 weight percent of one or more polymeric additives such as alkene-1-polymers, in particular low density polyethylene, polypropylene or polybutylene, copolymers containing mono-olefins as primary monomers, oxidized polyolefins, graft polyolefin copolymers and polyoxymethylenes, or low molecular weight additives such as lubricants, colorants, fillers and the like which are commonly incorporated by reference. Depending upon the formation technique, the draw ratio and temperatures, and other conditions, a variety of properties can be imparted to these filaments. The tenacity of the filaments should be at least 8 g/d (7.1 dN/tex), preferably in the range of from 8 to 45 g/d (7.1 to 39.7 dN/tex), most preferably in the range of 25 to 35 g/d/ (22.1 to 30.9 dN/tex). Similarly, the tensile modulus of the filaments, as measured by an Instron tensile testing machine, is at least 160 g/d (141.3 dN/tex), preferably in the range of 150 to 3300 g/d (132.5 to 2913.9 dN/tex), most preferably in the range of 1,200 to 2,500 g/d (1059.6 to 2207.5 dN/tex). These highest values for tensile modulus and tenacity are generally obtainable only by employing solution grown or solution spun, gel filament processes.
- The polyethylene fiber should preferably have an ultimate elongation by Instron tensile test of no greater than 8%, preferably in range of 2 to 4.5%, at room temperature, i.e., about 25° C. The denier per filament is preferably no greater than 20 (180 tex), more preferably 1 to 15 (9 to 135 tex), most preferably 1 to 10 (9 to 90 tex), even more preferably 1 to 3 (9 to 27 tex). The smaller denier per filament fibers are desirable to use in spinning blends for apparel applications. The larger denier per filament fibers are better to use in spinning blends for cordage, ropes, or heavy fabric applications.
- The amount of polyethylene fiber in the blend ranges from about 5 to 95% by weight, preferably 20 to 80 % by weight as the primary fiber and 5 to 40% by weight as the support fiber.
- The carrier fiber may be any other fiber. i.e., anything except the high molecular weight polyethylene fiber just described. Exemplary fibers may be found listed in allowed U.S. Patent Application S.N. 62,998 filed July 13, 1987, now US-A-4 916 000. A partial listing would include the aramids, cottons, carbon, polyester, polyamides, wool, rayon, polypropylene, lower molecular weight polyethylenes, etc.
- The carrier fiber preferably should have the following characteristics: it should preferably be a fiber which has memory or is permanently crimped; it should preferably have a denier per filament of no greater than 20 (180 tex), more preferably 0.5 to 3 (4.5 to 27 tex) for apparel applications and preferably 3 to 20 (27 to 180 tex) for ropes, cordage, and heavy fabric applications.
- The minimum amount of carrier fiber needed is 5% by weight of the spun fiber, and up to 95% by weight is acceptable. The preferred amount will range from about 20 to 50% by weight. The amount will be a function of the denier of the polyethylene fiber, e.g. one would need about 30% by weight carrier fiber to spin a 20 denier (180 tex) per filament polyethylene fiber, and would need less to spin a lower denier per filament polyethylene fiber.
- Both the carrier fiber and the polyethylene fiber are formed from discontinuous lengths of no greater than about 14 inches (35.6 cm), preferably no longer than 2.25 inches (5.7 cm) in the cotton system, more preferably 0.75 to 2 inches (1.9 to 5.1 cm).
- The particular blends of carrier fibers will depend on desired properties of the spun fiber. It is contemplated that a blend of polyester and/or cotton with the polyethylene will enhance hand; polypropylene can be blended for pigmentation; aramids, specifically Kevlar and Nomex can be includes for flame resistance; polybenzimidazoles (PBI), avilable commercially from Hoechst-Celanese, can be included for flame resistance and enchanced comfort due to higher moisture regain; carbon for use in fiber for composites requiring strength and toughness. Activated carbon fiber could be used for chemical absorption protection.
- Using the apparatus of Fig. 1, a two-inch (5.1 cm) SPECTRA 900 fiber available from Allied-Signal Inc. is run on the apparatus, unsuccessfully. The fiber slips on the feed rolls, clumps up in the feed mechanism and the machine must be stopped. A second trial was attempted with a fiber blend of 70% of the SPECTRA 10 dpf (90 tex) fiber above and 30% 1.2 denier (10.8 tex) per filament (dpf) Kodel polyester 1.5 inch (3.8 cm) staple. The mixture of 70% Spectra 10 dpf (90 tex) two inch (5.1 cm) staple and 30% 1.2 dpf (10.8 tex) Kodel 1.5 inch (3.8 cm) polyester staple was prepared and loaded into the card feeder. Difficulty in carding the fiber mixture was encountered after about 30 minutes because the polyester fiber rolled on itself and formed small balls of fiber. The screen inside the Even Feed unit could not move the bat of Spectra fiber and the balls of polyester fiber to the card main cylinder. The fiber bat was probably too slippery to be moved by the feeder mechanism. The trial was terminated and the card feeder was cleaned.
- The second trial was conducted using a blend by weight of 60% Spectra 900 10 dpf (90 tex) 2.0 inch (5.1 cm) staple fiber and 40% Kevlar 1.5 dpf (13.5 tex) 1.5 inch (3.8 cm) staple fiber. A length of double-backed adhesive tape was spirally wrapped around
feed roll 23 as in Fig. 4. The difference in the two fibers dpf caused some problems with how well the mixture blended and carded. The problems were not serious. However, to optimize the process it may be desirable to have fibers which have similar dpf. - A total of 50 pounds (22.7 kg) of Spectra/Kevlar fiber blend was made. To control static electricity Stay Guard antistatic spray was purchased from a local grocery store. The anti static spray was added to the fiber in the opener as the fiber was being opened and blended. There were no static electricity problems.
- The main problem encountered during carding was the loading of the card main cylinder by the Spectra fiber. This problem may be solved by using a fiber with a smaller dpf or development of a special fiber finish. There was also a large amount of Spectra fiber removed by the card flats. The card flats rotate against the main cylinder to help clean it. This problem may disappear if the cylinder loading problem can be solved.
- The carded sliver was divided into six ends which were fed into a Saco Lowell 4 over 5 draw frame. The draw frame was running black coated rubber rolls. The black rolls seemed to minimize the tendency of the sliver to wrap. The draw frame further blended the carded sliver and reduced the sliver weight by about 50%.
- The roving was produced on a Saco Lowell roving frame. No problems were encountered during the roving formation.
- The roving was converted to spun yarn on a ring spinning frame. The speeds and conditions were varied to produce a yarn which had a specific cotton count. The first yarn count attempted was a 20's.
- The spinning of the 20's yarn was very difficult because the yarn kept breaking. A calculation showed that because of the fiber diameters, the formation of a 20's count yarn was on the edge of being a physical impossibility. (Theoretically, at least 88 fibers are required in the cross section of a spun yarn. Because of the dpf of the Spectra fiber, it is impossible to have enough fiber in the spun yarn cross section and the yarn still be small enough to be a 20's.)
- The two spun yarns produced were a 10's and a 5's cotton count. Both of these yarns spun easily. Some optimization will be necessary to achieve the best balance of physical properties in the finished yarn.
- Example 1 was repeated loading the following fibers:
70% of 3 dpf (27 tex) SPECTRA * 2" (5.1 cm) staple
30% of 1.2 dpf (10.8 tex) Kodel polyester 1.5" (3.8 cm) staple Four spun yarns were successfuly produced:
10 cotton count single, 10 cotton count two-ply,
20 cotton count single, 20 cotton count two-ply.
*The SPECTRA fiber had a lower intrinsic viscosity of between 6 and 8, estimated molecular weight about 700,000. - An attempt to spin 100% SPECTRA fiber on the unmodified apparatus of Example 1 was unsuccessful, as was another attempt on a worsted spinning system.
- The article made from the blond of Spectra and Kevlar fiber from Example #1 exhibited good flame resistance and insulating properties. When the fabric (in this cane a knitted glove) was exposed to a flame from a cigarette lighter the exposed polyethylene fibers on the fabric surface melted back into the fabric even with the aramid fiber surface. The fabric did not ignite or burn which in surprising because Spectra fiber is a polyolefin which will burn if it becomes hot enough. The inside of the glove remained cool. The Spectra fibers did not seem to melt on the side of the fabric opposite the flame. When an attempt to intentionally ignite the fabric made from the blend of Spectra and aramid fibers was made the fabric exhibited a self extinguishing behavior and did not readily support combustion. (Surprising because olefin fibers are known to burn).
- The Spectra fiber should improve the abrasion resistance of the aramid fiber (in the case of the glove) and allow the item to have a longer service life. The fabric made from the blend of fibers had a good hand and the frictional characteristics of the fabric surface were improved over an all Spectra fabric because the aramid fiber reduced the slickness of the surface. This improved frictional property would be desirable in a glove because of the necessity of keeping a good grip on objects being handled.
Claims (10)
- A spun yarn comprising discontinuous lengths of at least two different types of fibers, characterized in that one fiber type is a solution or gel spun polyethylene fiber having a molecular weight of greater than 300,000 and the second fiber type or types is any other fiber which is present in an amount from 5 to 95% by weight, based on spun fiber, and sufficient to permit spinning a blend of the different fiber types.
- The yarn of claim 1 wherein the other fiber has memory.
- The yarn of claim 1 wherein the other fiber has a denier per filament of no greater than 20 (180 tex).
- The yarn of claim 1 wherein the other fiber is selected from the group consisting of polyester fiber, polyamide fiber, cotton fiber, wool fiber, rayon fiber, polypropylene fiber, aramid fiber, lower molecular weight polyethylene fibers, carbon fiber, and mixtures thereof.
- The yarn of claim 2 wherein the other fiber is an aramid fiber which forms no more than 50% by weight of the spun fiber.
- The yarn of claim 2 wherein the other fiber is poly (p-phenylene terephthalamide).
- An article made from a spun yarn comprising discontinuous lengths of at least two different types of fibers, characterized in that one fiber type is a solution or gel spun polyethylene fiber having a molecular weight of greater than 300,000 and the second fiber type or types is any other fiber which is present in an amount from 5 to 95% by weight, based on spun fiber, and sufficient to permit spinning a blend of the different fiber types.
- A method of spinning discontinuous lengths of at least two different types of fibers, characterized by (a) blending 5 to 95% by weight of discontinuous lengths of a solution or gel spun polyethylene fiber having a molecular weight of greater than 300,000 with a sufficient amount of discontinuous lengths of any other fiber to permit spinning of the blend, and (b) spinning the resultant blend to form a yarn.
- The method of claim 8 wherein the other fiber is selected from the group consisting of polyester fiber, polyamide fiber, cotton fiber, wool fiber, rayon fiber, polypropylene fiber, aramid fiber, lower molecular weight polyethylene fibers, carbon fiber, and mixtures thereof.
- An apparatus for transporting a fiber batt (35) of at least 50 weight percent high molecular weight polyethylene fiber which includes a rotating means (23) having a surface which rotates into contact with the fiber batt (35) and a card (18) aligned with a trumpet (21) to form the fiber batt (35) into a sliver (20), wherein at least a portion of the surface is characterized by being modified to increase the friction between the surface and the fiber batt (35) and the trumpet (21) is characterized by having an exit (57) for the sliver (20) sufficiently enlarged to limit compression of the sliver to the extent that it can be piddled.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US493178 | 1983-05-10 | ||
| US49317890A | 1990-03-14 | 1990-03-14 | |
| PCT/US1991/001561 WO1991014029A1 (en) | 1990-03-14 | 1991-03-06 | Spinning of high molecular weight polyethylene fiber and the resulting spun fiber |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0520023A1 EP0520023A1 (en) | 1992-12-30 |
| EP0520023B1 true EP0520023B1 (en) | 1995-05-24 |
Family
ID=23959212
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP91906840A Revoked EP0520023B1 (en) | 1990-03-14 | 1991-03-06 | Spinning of high molecular weight polyethylene fiber and the resulting spun fiber |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0520023B1 (en) |
| JP (1) | JPH05505656A (en) |
| CA (1) | CA2075825A1 (en) |
| WO (1) | WO1991014029A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007051675A1 (en) * | 2007-10-26 | 2009-04-30 | Hoffmann Air Cargo Equipment Gmbh | Method of making seams on webbings for technical purposes |
| CN102995200A (en) * | 2012-11-27 | 2013-03-27 | 河南工程学院 | Silkworm pupa protein fiber blended yarns, moisture-absorbing suspension ultraviolet-resistant fabric, spinning method and production process |
| US11598027B2 (en) | 2019-12-18 | 2023-03-07 | Patrick Yarn Mills, Inc. | Methods and systems for forming a composite yarn |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03277836A (en) * | 1990-03-26 | 1991-12-09 | Aisin Chem Co Ltd | Manufacture of base material for friction material |
| NL1006606C2 (en) † | 1997-07-17 | 1999-01-19 | Desseaux H Tapijtfab | Yarn for artificial grass, method of manufacturing the yarn and artificial grass field in which said yarn is incorporated. |
| WO2004033773A1 (en) * | 2002-10-10 | 2004-04-22 | Dsm Ip Assets B.V. | Spun yarn from staple fibres |
| JP5701767B2 (en) * | 2008-11-26 | 2015-04-15 | ディーエスエム アイピー アセッツ ビー.ブイ. | Yarns and fabrics with temperature control and cutting resistance |
| IT1401061B1 (en) * | 2010-07-13 | 2013-07-12 | Filtes Internat S R L | TEXTILE YARN, FABRIC MADE WITH THIS YARN AND A CLOTHING. |
| EP2707527B1 (en) * | 2011-05-10 | 2018-07-18 | DSM IP Assets B.V. | Yarn, a process for making the yarn, and products containing the yarn |
| CN103541079B (en) * | 2013-10-06 | 2015-10-28 | 太原理工大学 | A kind of high-strength, fire-retardant, antistatic blended yarn and production method thereof |
| DE112016002330T5 (en) * | 2015-05-22 | 2018-03-08 | Primaloft, Inc. | Self-heating insulation |
| CN110552097A (en) * | 2019-08-29 | 2019-12-10 | 张家港市华益纺织有限公司 | Formula and production method of mulberry fiber and terylene blended yarn |
| CN115418765B (en) * | 2022-08-30 | 2023-09-05 | 普宁市杰隆织造有限公司 | Anti-cutting blended yarn and preparation method and application thereof |
| CN117418341A (en) * | 2023-12-04 | 2024-01-19 | 山东环升新材料科技有限公司 | Ultra-long high-performance fiber flame-retardant yarn |
| WO2025200181A1 (en) * | 2024-03-28 | 2025-10-02 | 华巧国际有限公司 | Bioenergy hybrid-twisted filament and use thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4457985A (en) * | 1982-03-19 | 1984-07-03 | Allied Corporation | Ballistic-resistant article |
| GB2152543B (en) * | 1984-01-11 | 1987-01-28 | Bertrand Goldenstein | Blended yarn |
| JPH01156538A (en) * | 1987-10-02 | 1989-06-20 | Stamicarbon Bv | Combination of low wetting and low adhesion polyolefin filaments or yarns with high wetting and high adhesion filaments or yarns |
-
1991
- 1991-03-06 EP EP91906840A patent/EP0520023B1/en not_active Revoked
- 1991-03-06 CA CA 2075825 patent/CA2075825A1/en not_active Abandoned
- 1991-03-06 WO PCT/US1991/001561 patent/WO1991014029A1/en not_active Ceased
- 1991-03-06 JP JP91507184A patent/JPH05505656A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007051675A1 (en) * | 2007-10-26 | 2009-04-30 | Hoffmann Air Cargo Equipment Gmbh | Method of making seams on webbings for technical purposes |
| DE102007051675B4 (en) * | 2007-10-26 | 2011-11-24 | Hoffmann Air Cargo Equipment Gmbh | Method of making seams on webbings for technical purposes |
| CN102995200A (en) * | 2012-11-27 | 2013-03-27 | 河南工程学院 | Silkworm pupa protein fiber blended yarns, moisture-absorbing suspension ultraviolet-resistant fabric, spinning method and production process |
| CN102995200B (en) * | 2012-11-27 | 2016-02-03 | 河南工程学院 | Silkworm protein fiber blended yarn, moisture absorption pendency uvioresistant fabric and spinning method and production technology |
| US11598027B2 (en) | 2019-12-18 | 2023-03-07 | Patrick Yarn Mills, Inc. | Methods and systems for forming a composite yarn |
Also Published As
| Publication number | Publication date |
|---|---|
| WO1991014029A1 (en) | 1991-09-19 |
| JPH05505656A (en) | 1993-08-19 |
| CA2075825A1 (en) | 1991-09-15 |
| EP0520023A1 (en) | 1992-12-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0520023B1 (en) | Spinning of high molecular weight polyethylene fiber and the resulting spun fiber | |
| US6701703B2 (en) | High performance yarns and method of manufacture | |
| EP0038143B1 (en) | Twisted yarn and method of producing the same | |
| US5568719A (en) | Composite yarn including a staple fiber covering a filament yarn component and confining the filament yarn component to a second thickness that is less than a first thickness of the filament in a relaxed state and a process for producing the same | |
| US3367095A (en) | Process and apparatus for making wrapped yarns | |
| CA1036437A (en) | Product and process for making a wrapped yarn | |
| WO2004033773A1 (en) | Spun yarn from staple fibres | |
| US20030205041A1 (en) | Composite yarn | |
| AU1746995A (en) | Core/wrap yarn | |
| US6532724B2 (en) | Cut-resistant yarn and method of manufacture | |
| US4196574A (en) | Composite yarn and method of manufacture | |
| KR100215262B1 (en) | Tight, stiff, elastic yarn | |
| JPH06257027A (en) | Compound yarn and its production | |
| JP3449433B2 (en) | Method for producing composite yarn woven or knitted fabric | |
| WO1994000627A1 (en) | Spinning of high molecular weight polyethylene fiber and the resulting spun fiber | |
| US4922701A (en) | System for producing yarn | |
| JP3098757B2 (en) | Confounding elastic yarn and elastic knitted fabric | |
| US7594381B1 (en) | Sewing thread | |
| JP3102515B2 (en) | Multi-layer composite yarn | |
| CN111394844A (en) | Flame-retardant antistatic core-spun yarn and processing method thereof | |
| JPH03206139A (en) | Blended yarn of antibacterial polyester/wool or antibacterial polyester/wool/polyester produced by pneumatic false-twisting method and production thereof | |
| WO2001071073A1 (en) | Composite yarn | |
| JPH0814045B2 (en) | Method for manufacturing fire resistant / heat resistant composite spun yarn | |
| JPH0742619B2 (en) | Method for manufacturing composite spun yarn | |
| JPH01213425A (en) | Rayon/polyester blended yarn by air false twist method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| 17P | Request for examination filed |
Effective date: 19920807 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): FR GB IT NL |
|
| 17Q | First examination report despatched |
Effective date: 19930629 |
|
| RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: ALLIEDSIGNAL INC. |
|
| ITF | It: translation for a ep patent filed | ||
| GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
| AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): FR GB IT NL |
|
| ET | Fr: translation filed | ||
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 19951231 Year of fee payment: 6 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 19960208 Year of fee payment: 6 |
|
| PLBQ | Unpublished change to opponent data |
Free format text: ORIGINAL CODE: EPIDOS OPPO |
|
| PLBI | Opposition filed |
Free format text: ORIGINAL CODE: 0009260 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 19960307 Year of fee payment: 6 |
|
| PLBF | Reply of patent proprietor to notice(s) of opposition |
Free format text: ORIGINAL CODE: EPIDOS OBSO |
|
| 26 | Opposition filed |
Opponent name: DSM N.V Effective date: 19960223 |
|
| NLR1 | Nl: opposition has been filed with the epo |
Opponent name: DSM N.V |
|
| PLBF | Reply of patent proprietor to notice(s) of opposition |
Free format text: ORIGINAL CODE: EPIDOS OBSO |
|
| PLBF | Reply of patent proprietor to notice(s) of opposition |
Free format text: ORIGINAL CODE: EPIDOS OBSO |
|
| RDAH | Patent revoked |
Free format text: ORIGINAL CODE: EPIDOS REVO |
|
| RDAG | Patent revoked |
Free format text: ORIGINAL CODE: 0009271 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: PATENT REVOKED |
|
| GBPR | Gb: patent revoked under art. 102 of the ep convention designating the uk as contracting state |
Free format text: 961107 |
|
| 27W | Patent revoked |
Effective date: 19961107 |
|
| NLR2 | Nl: decision of opposition |