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EP0563777A3 - Process and apparatus for production of synthesis gas by thermal treatment of raw materials containing metallic and organic substances - Google Patents

Process and apparatus for production of synthesis gas by thermal treatment of raw materials containing metallic and organic substances Download PDF

Info

Publication number
EP0563777A3
EP0563777A3 EP19930104882 EP93104882A EP0563777A3 EP 0563777 A3 EP0563777 A3 EP 0563777A3 EP 19930104882 EP19930104882 EP 19930104882 EP 93104882 A EP93104882 A EP 93104882A EP 0563777 A3 EP0563777 A3 EP 0563777A3
Authority
EP
European Patent Office
Prior art keywords
synthesis gas
reactor
pyrolysis
temperatures
gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP19930104882
Other languages
German (de)
Other versions
EP0563777B1 (en
EP0563777A2 (en
Inventor
Helmut Dobert
Hartmunt Dr.-Ing. Rossel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Thyssen Still Otto Anlagentechnik GmbH
Vaw Aluminium AG
Original Assignee
Still Otto GmbH
Thyssen Still Otto Anlagentechnik GmbH
Vereinigte Aluminium Werke AG
Vaw Aluminium AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6454891&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0563777(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Still Otto GmbH, Thyssen Still Otto Anlagentechnik GmbH, Vereinigte Aluminium Werke AG, Vaw Aluminium AG filed Critical Still Otto GmbH
Publication of EP0563777A2 publication Critical patent/EP0563777A2/en
Publication of EP0563777A3 publication Critical patent/EP0563777A3/en
Application granted granted Critical
Publication of EP0563777B1 publication Critical patent/EP0563777B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
    • C10J3/60—Processes
    • C10J3/62—Processes with separate withdrawal of the distillation products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
    • C10J3/60—Processes
    • C10J3/64—Processes with decomposition of the distillation products
    • C10J3/66—Processes with decomposition of the distillation products by introducing them into the gasification zone
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • C10K1/101—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids with water only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0956—Air or oxygen enriched air
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0959—Oxygen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Processing Of Solid Wastes (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)

Abstract

A process was to be developed, by means of which the residual materials arising in the separate collection and sorting of packaging materials and the like can be utilized for producing a synthesis gas and at the same time the pollution potential inherent in the residual materials is destroyed and the formation of new pollutants is prevented. This is effected in such a way that, after a pyrolysis reaction at temperatures from 300-500 DEG C, the metallic constituents are separated off and the remaining solid phase is charged to a gasification stage and gasified at temperatures between 1450 and 1850 DEG C with oxygen-enriched air or oxygen under reducing conditions. The ash fractions arising in the gasification stage are taken off in the form of a vitrified slag, and the gas phase leaving the pyrolysis is converted to synthesis gas together with the gases formed in the gasification stage at temperatures between 800 and 1250 DEG C, with simultaneous addition of steam. Apparatus for carrying out the process consists of a rotary pipe reactor which has a gas outflow line for the pyrolysis gases formed at the end opposite the charging side. On the solids take-off side, the rotary pipe is connected to a metal separator device and a gasification reactor which is connected via a gas outlet to a decomposition reactor, the pyrolysis gases taken off from the rotary pipe reactor and steam also being introduced into the decomposition reactor. The crude synthesis gas formed is discharged from the decomposition reactor via a cooling and scrubbing device.
EP93104882A 1992-03-24 1993-03-24 Process for production of synthesis gas by thermal treatment of raw materials containing metallic and organic substances Expired - Lifetime EP0563777B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4209549A DE4209549A1 (en) 1992-03-24 1992-03-24 Processes for the thermal treatment of residues, e.g. for the separation and recycling of metal compounds with organic components, using a combination of pyrolysis and gasification
DE4209549 1992-03-24

Publications (3)

Publication Number Publication Date
EP0563777A2 EP0563777A2 (en) 1993-10-06
EP0563777A3 true EP0563777A3 (en) 1993-11-18
EP0563777B1 EP0563777B1 (en) 1996-05-29

Family

ID=6454891

Family Applications (1)

Application Number Title Priority Date Filing Date
EP93104882A Expired - Lifetime EP0563777B1 (en) 1992-03-24 1993-03-24 Process for production of synthesis gas by thermal treatment of raw materials containing metallic and organic substances

Country Status (3)

Country Link
EP (1) EP0563777B1 (en)
AT (1) ATE138679T1 (en)
DE (2) DE4209549A1 (en)

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4308551A1 (en) * 1993-03-17 1994-01-05 Siemens Ag Thermal waste disposal process - involves gasification of carbonisation fines to reduce process costs
DE69412559T2 (en) * 1993-10-19 1999-03-25 Mitsubishi Jukogyo K.K., Tokio/Tokyo Process for the gasification of organic matter
DE69427878T2 (en) * 1993-10-19 2002-04-11 Mitsubishi Jukogyo K.K., Tokio/Tokyo Process for gasification of glass fiber reinforced plastics and device
DE4402565B4 (en) * 1994-01-28 2005-05-04 Siemens Ag Use at least one separation aid for the separation of sticky dusts in a device for waste processing
DE4404673C2 (en) * 1994-02-15 1995-11-23 Entec Recycling Und Industriea Process for the production of fuel gas
DE4435144A1 (en) * 1994-09-30 1996-04-04 Kloeckner Humboldt Deutz Ag Process and plant for thermal recycling of waste materials
DE4446803C2 (en) * 1994-12-24 1998-05-28 Krc Umwelttechnik Gmbh Process and device for thermal and material recycling of residual and waste materials
DE19513832B4 (en) * 1995-04-12 2005-08-11 Future Energy Gmbh Process for recycling residual and waste materials by combining a fluidized-bed thermolysis with an entrainment gasification
IT1289557B1 (en) * 1996-01-19 1998-10-15 Texas Instruments Italia Spa PROCEDURE FOR OBTAINING SYNTHESIS GAS FROM INDUSTRIAL SOLID OR LIQUID WASTE WITH HIGH CONTENT OF VOLATILE MATERIAL
DE19730385C5 (en) * 1997-07-16 2006-06-08 Future Energy Gmbh Process for the production of fuel and synthesis gas from fuels and combustible waste and an apparatus for carrying out the process
NL1007710C2 (en) * 1997-12-05 1999-06-08 Gibros Pec Bv Method for processing waste or biomass material.
DE19843613C2 (en) * 1998-09-23 2000-12-07 Harald Martin Process and device for processing waste products and waste materials
FR2786196A1 (en) * 1998-11-20 2000-05-26 Air Liquide COMBUSTION PROCESS, PARTICULARLY FOR THE CASTING OF CAST IRON OR THE MANUFACTURE OF CEMENT
DE19937521A1 (en) 1999-08-03 2001-02-15 Harald Martin Process and device for drying, separating, classifying and decomposing waste products
DE19937524A1 (en) * 1999-08-03 2001-02-15 Harald Martin Method and device for removing waste products and waste materials
DE102007034139A1 (en) 2007-07-21 2009-01-22 Helmut Hoffmann Method for thermal treatment of wet wastes, production residues and other residual substances having native organic or synthetic organic constituents, involves shredding coarse particle material mixtures mechanically
UY33038A (en) 2009-11-20 2011-06-30 Rv Lizenz Ag THERMAL AND CHEMICAL USE OF CABONACE SUBSTANCES IN PARTICULAR FOR THE GENERATION OF ENERGY WITHOUT EMISSIONS
CA2832895A1 (en) * 2011-04-13 2012-10-18 Alter Nrg Corp. Process and apparatus for treatment of incinerator ash
DE102012017107A1 (en) 2012-08-28 2014-03-06 Linde Aktiengesellschaft Heating a process exhaust
DE102013008518A1 (en) 2013-05-16 2014-11-20 Linde Aktiengesellschaft Process and plant for the at least partial gasification of solid, organic feedstock
DE102013008519A1 (en) 2013-05-16 2014-11-20 Linde Aktiengesellschaft Process and plant for the at least partial gasification of solid, organic feedstock
DE102013009950A1 (en) 2013-06-13 2014-12-18 Linde Aktiengesellschaft Process and plant for the treatment and thermal gasification of hydrous organic feedstock
DE102013012661A1 (en) 2013-07-30 2015-02-05 Linde Aktiengesellschaft Process and installation for enriching a synthesis gas generated by gasification with hydrogen
DE102013014042A1 (en) 2013-08-22 2015-02-26 Linde Aktiengesellschaft Process and plant for the at least partial gasification of solid, organic feedstock
DE102013015539A1 (en) 2013-09-18 2015-03-19 Linde Aktiengesellschaft Plant and process for the at least partial gasification of solid organic feedstock
DE102013015536A1 (en) 2013-09-18 2015-03-19 Linde Aktiengesellschaft Process and plant for the at least partial gasification of solid, organic feedstock
DE102013017546A1 (en) 2013-10-22 2015-04-23 Linde Aktiengesellschaft Process and plant for the gasification of feedstock
DE102013017945A1 (en) 2013-10-29 2015-04-30 Linde Aktiengesellschaft power plant
DE102013018332A1 (en) 2013-10-31 2015-04-30 Linde Aktiengesellschaft Device for introducing solid organic feed into a gasification plant
DE102013018992A1 (en) 2013-11-13 2015-05-13 Linde Aktiengesellschaft Apparatus for supplying gasification agent into a low-temperature gasifier
DE102013019655A1 (en) 2013-11-23 2015-05-28 Linde Aktiengesellschaft Container for a low temperature carburetor
DE102013020889A1 (en) 2013-12-11 2015-06-11 Linde Aktiengesellschaft Process and plant for the at least partial gasification of solid, organic feedstock
DE102013020890A1 (en) 2013-12-11 2015-06-11 Linde Aktiengesellschaft Process and plant for the at least partial gasification of solid, organic feedstock
DE102013020792A1 (en) 2013-12-11 2015-06-11 Linde Aktiengesellschaft Process and plant for the gasification of solid, organic feedstock
DE102014016401A1 (en) 2014-11-05 2016-05-12 Linde Aktiengesellschaft Process for using CO2 in syngas production
DE102014016407A1 (en) 2014-11-05 2016-05-12 Linde Aktiengesellschaft Process for the production of synthesis gas
ES2950722T3 (en) * 2019-10-09 2023-10-13 Markus Reissner Procedure and use of a facility for the generation of a gas mixture containing hydrocarbons and hydrogen from plastic

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2261974A1 (en) * 1974-02-21 1975-09-19 Shell Int Research
GB1479257A (en) * 1974-09-23 1977-07-13 Cogas Dev Co Coal gasification
US4229185A (en) * 1975-11-10 1980-10-21 Occidental Petroleum Corporation Process for the gasification of carbonaceous materials
GB2068014A (en) * 1980-01-24 1981-08-05 Tosco Corp Process for the gasification of coal
EP0055840A1 (en) * 1980-12-27 1982-07-14 Forschungszentrum Jülich Gmbh Process and plant for the combustion of organic materials
EP0120397A2 (en) * 1983-03-23 1984-10-03 C. Deilmann AG Device for recovering energy from pyrolysable carbonaceous waste products of variable compositions
WO1990002162A1 (en) * 1988-08-23 1990-03-08 Roessle Gottfried Device and allothermic process for producing a burnable gas from refuse or from refuse together with coal
WO1991004306A1 (en) * 1989-09-20 1991-04-04 American Waste Reduction Corporation Minimization of environmental wastes

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2261974A1 (en) * 1974-02-21 1975-09-19 Shell Int Research
GB1479257A (en) * 1974-09-23 1977-07-13 Cogas Dev Co Coal gasification
US4229185A (en) * 1975-11-10 1980-10-21 Occidental Petroleum Corporation Process for the gasification of carbonaceous materials
GB2068014A (en) * 1980-01-24 1981-08-05 Tosco Corp Process for the gasification of coal
EP0055840A1 (en) * 1980-12-27 1982-07-14 Forschungszentrum Jülich Gmbh Process and plant for the combustion of organic materials
EP0120397A2 (en) * 1983-03-23 1984-10-03 C. Deilmann AG Device for recovering energy from pyrolysable carbonaceous waste products of variable compositions
WO1990002162A1 (en) * 1988-08-23 1990-03-08 Roessle Gottfried Device and allothermic process for producing a burnable gas from refuse or from refuse together with coal
WO1991004306A1 (en) * 1989-09-20 1991-04-04 American Waste Reduction Corporation Minimization of environmental wastes

Also Published As

Publication number Publication date
DE4209549A1 (en) 1993-09-30
EP0563777B1 (en) 1996-05-29
EP0563777A2 (en) 1993-10-06
ATE138679T1 (en) 1996-06-15
DE59302721D1 (en) 1996-07-04

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