[go: up one dir, main page]

EP0422196B1 - Process and installation for producing a lining on the internal walls of a metallurgical vessel - Google Patents

Process and installation for producing a lining on the internal walls of a metallurgical vessel Download PDF

Info

Publication number
EP0422196B1
EP0422196B1 EP90907161A EP90907161A EP0422196B1 EP 0422196 B1 EP0422196 B1 EP 0422196B1 EP 90907161 A EP90907161 A EP 90907161A EP 90907161 A EP90907161 A EP 90907161A EP 0422196 B1 EP0422196 B1 EP 0422196B1
Authority
EP
European Patent Office
Prior art keywords
vessel
mixture
metallurgical vessel
binder
lining
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP90907161A
Other languages
German (de)
French (fr)
Other versions
EP0422196A1 (en
Inventor
Jean-Charles Daussan
Gérad DAUSSAN
André Daussan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Daussan SAS
Original Assignee
Daussan SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Daussan SAS filed Critical Daussan SAS
Priority to AT90907161T priority Critical patent/ATE100364T1/en
Publication of EP0422196A1 publication Critical patent/EP0422196A1/en
Application granted granted Critical
Publication of EP0422196B1 publication Critical patent/EP0422196B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D41/00Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
    • B22D41/02Linings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D41/00Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
    • B22D41/02Linings
    • B22D41/023Apparatus used for making or repairing linings

Definitions

  • the present invention relates to a method for producing a coating on the interior walls of a metallurgical container intended to receive liquid metal.
  • the present invention also relates to an installation for implementing the above method.
  • patent application EP-A-0 289 480 on which the preambles of claims 1 and 9 are based.
  • This patent application describes a device allowing the economic implementation of a process known as "guniting”. He therefore teaches projection under pressure, using a lance, of a pasty and curable aqueous mixture. Such a method makes it possible to project with a certain speed the particles already deposited and promotes the compactness and therefore the resistance of the coating thus obtained. It is however necessary to heat this coating to dry it.
  • a template is placed inside a metallurgical container, a material composed of refractory particles and a thermosetting binder is pneumatically projected between the template and the interior walls of the container. leaving the template in place to cause the binder to harden, finally we remove the template.
  • the sprayed material contains an inorganic compound containing water of crystallization.
  • the material of the aforementioned type is compacted between the template and the interior walls of the container, either by tamping, or by vibration or impact.
  • heating the material through the template represents a certain energy consumption and additional time to immobilize the metallurgical container.
  • the object of the present invention is to remedy the drawbacks of known methods and to propose a method which is simple, rapid and economical to use, and which is particularly well suited to producing the wear coating of a metallurgical container.
  • the object of the present invention is also to propose an installation for the implementation of said method.
  • the newly spread material forms with the material deposited previously a monolithic coating which adheres to the wall on which it is spread.
  • the installation of the coating can therefore be carried out very quickly, without the aid of a template, and without the need for compaction of the material.
  • the material deposited being substantially dry, no drying is necessary, and, when the quality of the cast steel does not require the departure of the water of crystallization and / or certain gases which the coating may contain, the metallurgical container is therefore practically immediately returned to the operating circuit, which allows a very rapid rotation rate thereof.
  • the method makes it possible to deposit a layer of determined thickness: if a consumable layer is deposited on a partially worn permanent coating, it is possible to follow the external surface thereof and to avoid any unnecessary excess of material.
  • the coating obtained is refractory insulator.
  • this installation makes it possible, in most cases, without a template, to coat a coating which does not require any drying before putting the container back into service, and the newly spread material forms with the material already in place a monolithic block. which adheres to the wall.
  • the installation according to the invention is suitable for coating the interior walls of a ladle 1 whose casing 2, provided with ears 3, is internally lined with a coating permanent refractory 4, made of shaped bricks or refractory concrete.
  • This permanent refractory coating 4 must be covered with a wear coating 5 deposited on the bottom and the inner side walls of the ladle 1 and intended to be in contact with the liquid metal.
  • the ladle 1 is placed on a tilting support (not shown) known per se.
  • This support tilting can receive the pocket 1 in the position shown in dashes in the figure, in which the bottom of the pocket 1 is substantially horizontal.
  • the support can also tilt the pocket 1 into the position shown in solid lines, in which the lowest part of the interior wall of the pocket is substantially horizontal and turned upwards.
  • the tilting support comprises means, known in themselves and shown diagrammatically by rollers 6, 7, 8, for rotating the pocket 1 around its axis X, X ', in this tilted position, as shown diagrammatically by the arrows 9.
  • the installation comprises means for preparing or receiving and conveying a substantially dry material intended to be spread to form the wear coating 5.
  • these means consist of two hoppers 10a, 10b, mounted on a frame 11 and adapted to receive, in bags (not shown) or by a conveyor, for example a conveyor belt (not shown ), the substantially dry mixture to be deposited.
  • these hoppers 10a, 10b can be alternately closed and pressurized with compressed air for the pneumatic transport of the material by a flexible pipe 12 to a cyclonic separator 13 which separates the material to be deposited from the air of transport.
  • the material can thus be conveyed without pressure by simple gravity in a flexible pipe 14 to the discharge point 15 which can be provided with a valve (not shown).
  • the cyclonic separator 13 and the flexible pipe 14 are carried by a robot 16.
  • the robot 16 has a substantially vertical barrel 17, which can rotate around its axis by relative to a fixed base 18 and driven in rotation in one direction or the other, as indicated by arrow 19, by a motor 20.
  • a substantially horizontal arm 21 carried by the barrel 17 can move vertically (arrow 22) along the barrel 17 under the action of a motor 23.
  • the cyclonic separator 13 is carried by the arm 21.
  • a second substantially horizontal arm 24 is articulated at one of its ends at the end of the arm 21 and can pivot in a horizontal plane around the end of the arm 21 (arrow 25) under the action of a motor 26.
  • the other end of the arm 24 supports a substantially vertical mast 27 which can move vertically (arrow 28) under the action of a first motor 29, and which can rotate around its axis (arrow 30) under the action of 'a second motor 31.
  • the mast 27 is extended downwards by a part 27a which extends obliquely and which ends in a substantially vertical part 27b.
  • the flexible pipe 14 is hung along the mast 27, the discharge point 15 of this pipe being adjacent to the lower end of the part 27b of the mast 27.
  • the diameter of this flexible pipe 14 is sufficient to allow satisfactory flow of the material by gravity without risk of clogging.
  • the robot 16 also includes means, not shown, for coordinating the arrival of the material, the movements of the elements which compose it and the movements of the pocket on the tilting support.
  • the installation according to the invention comprises a tilting support 32 capable of pivoting about an axis 33 relative to a fixed frame 34 under the action of a pivoting cylinder 35.
  • the tilting support 32 carries a turntable 36 capable of rotating relative to the support 32 under the action of a motor 37 by any known means symbolized by balls 38.
  • the turntable 36 is intended to receive a pocket casting 1 fixed on the turntable 36 by means of clamps 39 actuated by a jack 40, so as to rotate the pocket 1 around its axis X, X '(arrow 41).
  • the lowest part of the interior wall of the pocket 1 is substantially horizontal.
  • the material to be spread is stored in a hopper 42, which has for example a conical shape, inside which rotates a mixing screw 43 driven by a motor not shown. At the lower part of the hopper 42, the material falls into a conveyor screw 44 at the discharge end 45 from which the material is deposited on the inside wall of the bag 1.
  • the screw 44 is shown mounted on a jack 46 which allows it to be fitted onto the lower part of the hopper 42 and to separate it from the latter, this lower part of the hopper then being closed by a valve not shown.
  • the hopper 42 and the conveyor screw 44 are mounted on a carriage 47 movable along the arrow 47a in the axial direction of the screw 44 to allow the material to be spread along a generator of the interior wall of the pocket 1.
  • the carriage 47 is itself mounted on a chassis 48 which is for example movable in the direction perpendicular to the direction of movement of the carriage 47.
  • the assembly forms a robot 49 equipped with means not shown to coordinate the arrival of the material with the movements from pocket 1 and those of the carriage 47.
  • the bottom 4a of the pocket can be coated in a similar manner to that described with reference to FIG. 1, this bottom being in a horizontal position and the coating material being poured onto this bottom, for example by means a tubular chute movable over the entire surface of said bottom.
  • a continuous casting distributor 50 is mounted on a tilting frame 51 of any known type near, for example, the robot 16 with articulated arms described above in reference to figure 1.
  • the distributor 50 is shown in Figure 3 in the inverted position which allows to drop the wear coating used and "wolves" of metal and / or slag attached to it, for example in a waste bin not represented.
  • the distributor 50 is shown in Figure 4A in the normal position of use; the horizontal arms 21 and 24 are deployed and the mast 27 is oriented so as to allow the coating to be formed on the bottom 52 of the distributor 50.
  • the flexible pipe 14 is not shown for the sake of clarity of the drawing.
  • the distributor 50 is shown in Figure 4B in the tilted position to the left of the figure, in which the longitudinal side wall 53 is substantially in a horizontal position: the bent portion 27a can thus penetrate inside the distributor to spread the material over the entire surface of the wall 53 and thus form the covering 55.
  • the distributor 50 is tilted to the right and the articulated arm 24 is deployed so as to allow the deposition of the material on the wall 54 and the formation of the coating 55.
  • the material constituting the coating wear 5, 55 is a substantially dry material comprising a mixture of refractory particles and a binder of the thermosetting type or equivalent, the composition and the particle size of the mixture of refractory particles being such that this mixture sintered in contact with the liquid metal.
  • this material is intended to be spread over the interior walls of a metallurgical container which are initially at a temperature sufficient to be able to heat the material deposited thereon to a temperature allowing the softening and setting of the binder of the thermosetting type. or equivalent and the formation of a monolithic coating which adheres to these interior walls of the container 1, 50.
  • Refractory particles can be chosen, for example, from the group comprising magnesian, silico-magnesian, silico-aluminous, aluminous, siliceous particles, calcium carbonate, lime, dolomite, carbon, chromium oxide, zircon, and mixtures thereof. These particles can be in the form of grains, powders and / or fibers.
  • thermosetting type or equivalent for example, from the group comprising natural and synthetic thermosetting resins such as for example phenol-formaldehyde resins, urea-formaldehyde resins, polyvinyl resins, etc., mineral binders of the thermosetting type or equivalent softening with heat such as for example sodium silicate (which dissolves around 70 ° C), metasilicate, etc., organic binders and / or agglutinants such as for example starch, starch, stearate , carboxymethylcellulose, etc., and mixtures of these compounds.
  • natural and synthetic thermosetting resins such as for example phenol-formaldehyde resins, urea-formaldehyde resins, polyvinyl resins, etc.
  • mineral binders of the thermosetting type or equivalent softening with heat such as for example sodium silicate (which dissolves around 70 ° C), metasilicate, etc.
  • organic binders and / or agglutinants such as for example
  • the refractory particles can be simply mixed with particles of the binder of the thermosetting type.
  • the particles refractories can be embedded in the binder, for example if very hygroscopic particles such as dolomite particles are used which tend to absorb moisture.
  • the widespread mixture is preferably refractory insulator, and is made up of particles whose particle size is studied so as to give the coating in place after sintering in contact with the liquid metal a total porosity greater than 45%: this insulating nature of the coating limits cooling.
  • liquid metal in contact with the walls of the metallurgical container which makes it possible to dispense with preheating the walls of the container before use without risk of solidification of metal in contact with them.
  • the widespread mixture can have a general composition of the following type: Refractory particles in grains and / or powders: 80 to 100% Organic and / or mineral fibers: 0 to 10% Binder: 0 to 10%
  • compositions of mixtures of different characters can thus be given as nonlimiting examples, in which the binder appears in the section "loss on ignition”:
  • the permanent internal coating can thus be at a temperature ranging from approximately 250 ° C. to approximately 400 ° C.: it is thus possible to refill a container shortly after its use.
  • a container whose walls are cold is to be refilled, one begins by reheating them to the required temperature with any known means, for example a gas burner or an infrared ramp.
  • Some walls may not be accessible by the means described above and are coated in any known manner, automatically or manually.
  • the pouring orifice of the container is temporarily closed during the deposition of the coating.
  • the binder softens and becomes sticky, which makes it possible to stick the material to the interior walls and to form on them a monolithic coating with the material already in square. It is thus possible to quickly move the container and even to tilt it nearly 180 ° to coat a wall opposite to that already coated without the risk of dropping the coating already in place.
  • the means used for storing, transporting and spreading the coating material may be different from those described: it is for example possible to use, instead of the hoppers 10 alternately pressurized, a barrel type spraying machine suitable for conveying pulverulent materials which may contain fibers, and more generally any set of known means of transport and handling capable of conveying the material to be spread over the entire wall or part of the interior wall to be coated. Any device making it possible to separate the material to be spread from the compressed transport air can be used in place of the cyclonic separator 13.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Furnace Housings, Linings, Walls, And Ceilings (AREA)
  • Details Of Rigid Or Semi-Rigid Containers (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Casting Support Devices, Ladles, And Melt Control Thereby (AREA)

Abstract

A metallurgical vessel (1) to be lined, whose internal walls are relatively hot, is placed on a suitable support. The support is tilted and the metallurgical vessel (1) brought successively into several different positions in each of which an internal wall or part of an internal wall of the vessel is essentially horizontal and facing upward. In each of said positions, at least one layer of essentially dry material consisting of a mixture of refractory particles and a thermosetting binder or equivalent is spread oversaid internal wall or part of an internal wall. The composition and particle size of the mixture of refractory particles are such that the mixture sinters on contact with the molten metal. This material is spread so as to form a substantially uniform layer, the initial temperature of the internal walls of the vessel being sufficient to heat the material spread on them to a temperature at which the thermosetting binder or equivalent softens and sets and to form a monolithic lining (5) which adheres to the internal walls of the vessel.

Description

La présente invention concerne un procédé pour réaliser un revêtement sur les parois intérieures d'un récipient métallurgique destiné à recevoir du métal liquide.The present invention relates to a method for producing a coating on the interior walls of a metallurgical container intended to receive liquid metal.

La présente invention concerne également une installation pour la mise en oeuvre du procédé précité.The present invention also relates to an installation for implementing the above method.

On connaît plusieurs procédés pour réaliser un revêtement sur les parois intérieures d'un récipient métallurgique.Several methods are known for producing a coating on the interior walls of a metallurgical container.

On connaît ainsi, par exemple, selon le brevet français 2 393 637 de la demanderesse, un procédé dans lequel on applique à l'intérieur d'un récipient métallurgique, tel qu'un répartiteur de coulée, par moulage, damage ou projection à la truelle ou pneumatique ou autre, un mélange aqueux et pâteux durcissable renfermant des particules inorganiques, éventuellement des fibres, un liant organique et/ou inorganique. Le mélange de particules fritte au contact du métal liquide, ce qui assure la cohésion du revêtement.There is thus known, for example, according to French patent 2,393,637 of the applicant, a process in which one applies inside a metallurgical container, such as a tundish, by molding, tamping or spraying with trowel or pneumatic or other, a curable aqueous and pasty mixture containing inorganic particles, optionally fibers, an organic and / or inorganic binder. The mixture of particles sintered in contact with the liquid metal, which ensures the cohesion of the coating.

On connaît aussi la demande de brevet EP - A - 0 289 480, sur lequel les préambules des revendications 1 et 9 sont basés. Cette demande de brevet décrit un dispositif permettant la mise en oeuvre économique d'un procédé dit de "gunitage". Il enseigne donc la projection sous pression, à l'aide d'une lance, d'un mélange aqueux pâteux et durcissable. Une telle méthode permet de projeter avec une certaine vitesse les particules déjà déposées et favorise la compacité et donc la résistance du revêtement ainsi obtenu. Il est nécessaire par contre de chauffer ce revêtement pour le sécher.Also known is patent application EP-A-0 289 480, on which the preambles of claims 1 and 9 are based. This patent application describes a device allowing the economic implementation of a process known as "guniting". He therefore teaches projection under pressure, using a lance, of a pasty and curable aqueous mixture. Such a method makes it possible to project with a certain speed the particles already deposited and promotes the compactness and therefore the resistance of the coating thus obtained. It is however necessary to heat this coating to dry it.

On connaît également, selon les demandes de brevet français 2 585 273, 2 613 256 ou 2 619 323 au nom de la demanderesse, un procédé suivant lequel on applique à l'intérieur du récipient métallurgique, au moins deux couches de compositions différentes appliquées chacune par projection d'un mélange aqueux et pâteux durcissable du type précité.Also known, according to French patent applications 2 585 273, 2 613 256 or 2 619 323 in the name of the applicant, a process according to which one applies to the interior of the metallurgical container, at least two layers of different compositions each applied by spraying a curable aqueous and pasty mixture of the aforementioned type.

Ces procédés, qui donnent par ailleurs toute satisfaction aux utilisateurs, présentent toutefois un inconvénient : il est nécessaire d'éliminer par séchage au moins toute l'eau d'humidification utilisée pour la formation du ou des mélange(s) aqueux, ce qui implique un temps d'immobilisation et une dépense d'énergie qui ne sont pas négligeables.These methods, which moreover give all satisfaction to the users, have however a drawback: it is necessary to remove by drying at least all the humidification water used for the formation of the aqueous mixture (s), which implies non-negligible downtime and energy expenditure.

On connaît également un procédé selon lequel on place un gabarit à l'intérieur d'un récipient métallurgique, on projette pneumatiquement entre le gabarit et les parois intérieures du récipient un matériau composé de particules réfractaires et d'un liant thermodurcissable, puis on chauffe en laissant le gabarit en place pour provoquer le durcissement du liant, enfin on enlève le gabarit. Le matériau projeté contient un composé inorganique contenant de l'eau de cristallisation.There is also known a method according to which a template is placed inside a metallurgical container, a material composed of refractory particles and a thermosetting binder is pneumatically projected between the template and the interior walls of the container. leaving the template in place to cause the binder to harden, finally we remove the template. The sprayed material contains an inorganic compound containing water of crystallization.

Selon d'autres procédés connus nécessitant l'emploi d'un gabarit, le matériau du type précité est compacté entre le gabarit et les parois intérieures du récipient, soit par damage, soit par vibration ou par chocs.According to other known methods requiring the use of a template, the material of the aforementioned type is compacted between the template and the interior walls of the container, either by tamping, or by vibration or impact.

On connaît, par le demande de brevet EP - A - 0 105 795, un procédé et une installation pour le moulage d'un revêtement réfractaire entre un moule et les parois du récipient à protéger. Ce document enseigne d'utiliser un béton réfractaire ou agrégat contenant un liant chimique ou hydraulique assurant la prise du revêtement. L'agrégat est un mélange produit réfractaire et eau, qui est de préférence soit aspiré soit injecté sous pression par une pompe. Il est donc nécessaire de sécher le revêtement après sa formation. La chaleur emmaganisée par le récipient participe à ce séchage. Ce document recommande également de projeter les particules avec une certaine vitesse pour faciliter leur ancrage dans celles déjà déposées. Enfin, il faut laisser le moule en place le temps nécessaire à la prise du revêtement.There is known from patent application EP-A-0 105 795 a method and an installation for molding a refractory lining between a mold and the walls of the container to be protected. This document teaches to use a refractory or aggregate concrete containing a chemical or hydraulic binder ensuring the setting of the coating. The aggregate is a mixture of refractory product and water, which is preferably either aspirated or injected under pressure by a pump. It is therefore necessary to dry the coating after its formation. The heat stored in the container contributes to this drying. This document also recommends projecting the particles with a certain speed to facilitate their anchoring in those already deposited. Finally, leave the mold in place for the time necessary for the coating to set.

L'utilisation d'un gabarit, qui dans certains cas doit être laissé en place, est toujours une cause de perte de temps et une source de dépenses par les manutentions et les réglages qu'elle nécessite.The use of a template, which in some cases must be left in place, is always a cause of loss of time and a source of expense by the handling and adjustments it requires.

De plus, le chauffage du matériau à travers le gabarit représente une certaine consommation d'énergie et un temps complémentaire d'immobilisation du récipient métallurgique.In addition, heating the material through the template represents a certain energy consumption and additional time to immobilize the metallurgical container.

Enfin, si l'on dépose le matériau sur un revêtement permanent de protection déjà usé, l'utilisation d'un gabarit qui impose un profil extérieur constant du revêtement entraîne la mise en place d'une couche de matériau d'épaisseur plus grande que celle nécessaire, ce qui provoque une consommation excessive et inutile de ce matériau.Finally, if the material is deposited on a permanent protective coating already worn, the use of a template which imposes a constant external profile of the coating results in the establishment of a layer of material of thickness greater than that necessary, which causes excessive and unnecessary consumption of this material.

Le but de la présente invention est de remédier aux inconvénients des procédés connus et de proposer un procédé qui soit d'utilisation simple, rapide et économique, et qui soit particulièrement bien adapté à la réalisation du revêtement d'usure d'un récipient métallurgique.The object of the present invention is to remedy the drawbacks of known methods and to propose a method which is simple, rapid and economical to use, and which is particularly well suited to producing the wear coating of a metallurgical container.

Le but de la présente invention est également de proposer une installation pour la mise en oeuvre dudit procédé.The object of the present invention is also to propose an installation for the implementation of said method.

Suivant l'invention, le procédé pour réaliser un revêtement sur les parois intérieures d'un récipient métallurgique destiné à recevoir du métal liquide est caractérisé en ce qu'il comporte les étapes suivantes :

  • a) on place sur un support approprié un récipient métallurgique dont les parois intérieures à revêtir sont portées à une température déterminée ;
  • b) on fait basculer le support et on amène le récipient métallurgique successivement dans plusieurs positions différentes dans chacune desquelles une paroi ou une partie de paroi intérieure du récipient est sensiblement horizontale et tournée vers le haut ;
  • c) dans chacune des positions précitées, on répand sur ladite paroi ou partie de paroi intérieure au moins une couche d'un matériau sensiblement sec comprenant un mélange de particules réfractaires et un liant du type thermodurcissable ou équivalent, la composition et la granulométrie du mélange de particules réfractaires étant telles que ce mélange fritte au contact du métal liquide, et on étale ce matériau de manière à constituer une couche sensiblement régulière ;
  • d) les parois intérieures du récipient étant initialement à ladite température déterminée, cette température étant suffisante pour pouvoir chauffer le matériau déposé sur celles-ci à une température permettant le ramollissement et la prise du liant du type thermodurcissable ou équivalent et de former ainsi un revêtement monolithique qui adhère aux parois intérieures du récipient.
According to the invention, the method for producing a coating on the interior walls of a metallurgical container intended to receive liquid metal is characterized in that it comprises the following steps:
  • a) a metallurgical container is placed on an appropriate support, the internal walls to be coated are brought to a determined temperature;
  • b) the support is tilted and the metallurgical container is brought successively to several different positions in each of which an inner wall or part of the container wall is substantially horizontal and turned upwards;
  • c) in each of the aforementioned positions, at least one layer of a substantially dry material comprising a mixture of refractory particles and a binder of the thermosetting type or equivalent, is spread over said wall or part of the interior wall, the composition and the particle size of the mixture refractory particles being such that this mixture sintered in contact with the liquid metal, and this material is spread so as to constitute a substantially regular layer;
  • d) the interior walls of the container being initially at said determined temperature, this temperature being sufficient to be able to heat the material deposited thereon to a temperature allowing the softening and setting of the binder of the thermosetting type or equivalent and thus to form a coating monolithic which adheres to the interior walls of the container.

On peut ainsi utiliser un matériau sensiblement sec sans avoir à le mélanger à de l'eau pour former un mélange aqueux, puis à sécher le revêtement en place pour éliminer cette eau.It is thus possible to use a substantially dry material without having to mix it with water to form an aqueous mixture, then to dry the coating in place to remove this water.

Etant donné que les parois et le fond du récipient sont initialement à une température suffisante pour pouvoir chauffer le revêtement déposé à une température permettant de provoquer le ramollissement et la prise du liant du type thermodurcissable, le matériau nouvellement répandu forme avec le matériau déposé précédemment un revêtement monolithique qui adhère à la paroi sur laquelle il est répandu.Since the walls and bottom of the container are initially at a temperature sufficient to be able to heat the coating deposited at a temperature making it possible to cause the softening and the setting of the binder of the thermosetting type, the newly spread material forms with the material deposited previously a monolithic coating which adheres to the wall on which it is spread.

Dès que la paroi ou partie de paroi à revêtir a été revêtue, il est donc possible de modifier la position du récipient métallurgique pour revêtir une autre paroi ou partie de paroi, voire même de retourner de 180° le récipient pour revêtir la paroi opposée à celle revêtue, sans risquer de décoller de celle-ci le revêtement déposé, ou de faire tomber des particules réfractaires non encore liées à celui-ci.As soon as the wall or part of the wall to be coated has been coated, it is therefore possible to modify the position of the metallurgical container to coat another wall or part of the wall, or even to turn the container 180 ° to coat the wall opposite to the coated one, without risking to take off from it the deposited coating, or to drop refractory particles not yet linked to it.

La mise en place du revêtement peut donc être effectuée très rapidement, sans l'aide d'un gabarit, et sans besoin d'un compactage du matériau.The installation of the coating can therefore be carried out very quickly, without the aid of a template, and without the need for compaction of the material.

Par ailleurs, le matériau déposé étant sensiblement sec, aucun séchage n'est nécessaire, et, lorsque la qualité de l'acier coulé ne nécessite pas le départ de l'eau de cristallisation et/ou de certains gaz que peut contenir le revêtement, le récipient métallurgique est donc pratiquement immédiatement remis dans le circuit d'utilisation, ce qui autorise un rythme de rotation très rapide de celui-ci.Furthermore, the material deposited being substantially dry, no drying is necessary, and, when the quality of the cast steel does not require the departure of the water of crystallization and / or certain gases which the coating may contain, the metallurgical container is therefore practically immediately returned to the operating circuit, which allows a very rapid rotation rate thereof.

En outre, le procédé permet de déposer une couche d'épaisseur déterminée : si on dépose une couche consommable sur un revêtement permanent partiellement usé, il est possible de suivre la surface extérieure de celui-ci et d'éviter tout excès inutile de matériau.In addition, the method makes it possible to deposit a layer of determined thickness: if a consumable layer is deposited on a partially worn permanent coating, it is possible to follow the external surface thereof and to avoid any unnecessary excess of material.

Selon une version préférée de l'invention, le revêtement obtenu est isolant réfractaire.According to a preferred version of the invention, the coating obtained is refractory insulator.

On peut donc utiliser, dans la plupart des cas, le récipient métallurgique sans aucun préchauffage préalable sans risque que du métal liquide refroidi au contact des parois ne se fige contre celles-ci, et faire ainsi l'économie du temps et des calories nécessaires pour ce préchauffage.It is therefore possible, in most cases, to use the metallurgical vessel without any preheating without risk that liquid metal cooled in contact with the walls will freeze against them, and thus save the time and calories required for this preheating.

Selon un autre aspect de la présente invention, l'installation pour réaliser un revêtement sur les parois intérieures d'un récipient métallurgique destiné à recevoir un métal liquide, par la mise en oeuvre du procédé précité, est caractérisée en ce qu'elle comprend :

  • des moyens pour préparer ou recevoir un matériau sensiblement sec comprenant un mélange de particules réfractaires et un liant du type thermodurcissable ou équivalent, la composition et la granulométrie du mélange de particules étant telles que ce mélange fritte au contact du métal liquide ;
  • des moyens formant support pour recevoir un récipient métallurgique dont les parois intérieures sont relativement chaudes ;
  • des moyens pour faire basculer le support et pour amener le récipient métallurgique successivement dans plusieurs positions différentes dans chacune desquelles une paroi ou une partie de paroi intérieure du récipient est sensiblement horizontale et tournée vers le haut ;
  • des moyens pour, dans chacune des positions précitées, répandre sur ladite paroi ou partie de paroi intérieure au moins une couche dudit matériau sensiblement sec, et étaler ce matériau de manière à constituer une couche sensiblement régulière.
According to another aspect of the present invention, the installation for producing a coating on the interior walls of a metallurgical container intended to receive a liquid metal, by the implementation of the aforementioned method, is characterized in that it comprises:
  • means for preparing or receiving a substantially dry material comprising a mixture of refractory particles and a binder of the thermosetting type or equivalent, the composition and particle size of the mixture of particles being such that this mixture sintered in contact with the liquid metal;
  • support means for receiving a metallurgical container whose inner walls are relatively hot;
  • means for tilting the support and for bringing the metallurgical container successively into several different positions in each of which an inner wall or part of the container wall is substantially horizontal and turned upwards;
  • means for, in each of the aforementioned positions, spreading on said wall or interior wall part at least one layer of said substantially dry material, and spreading this material so as to constitute a substantially regular layer.

Comme indiqué ci-dessus, cette installation permet de réaliser, dans la plupart des cas, sans gabarit un revêtement qui ne nécessite aucun séchage avant la remise en service du récipient, et le matériau nouvellement répandu forme avec le matériau déjà en place un bloc monolithique qui adhère à la paroi.As indicated above, this installation makes it possible, in most cases, without a template, to coat a coating which does not require any drying before putting the container back into service, and the newly spread material forms with the material already in place a monolithic block. which adheres to the wall.

D'autres caractéristiques et avantages de l'invention apparaîtront encore dans la description détaillée ci-après.Other characteristics and advantages of the invention will become apparent in the detailed description below.

Aux dessins annexés, donnés à titre d'exemples non limitatifs :

  • la figure 1 est un schéma avec arrachement d'une installation selon un premier mode de réalisation de l'invention et comprenant un robot pour revêtir une poche de coulée ;
  • la figure 2 est un schéma, partiellement en coupe, d'une installation selon un autre mode de réalisation de l'invention pour revêtir une poche de coulée ;
  • la figure 3 est une vue schématique partielle en coupe transversale d'un répartiteur de coulée continue placé dans un basculeur près du robot de la figure 1, le basculeur étant dans la position retournée ;
  • les figures 4A, 4B et 4C sont des vues semblables à la figure 3, le répartiteur étant respectivement en position normale, en position basculée vers la gauche et en position basculée vers la droite, pour le dépôt du revêtement respectivement sur le fond et sur l'une et l'autre des deux parois latérales longitudinales.
In the appended drawings, given by way of nonlimiting examples:
  • Figure 1 is a cutaway diagram of an installation according to a first embodiment of the invention and comprising a robot for coating a ladle;
  • Figure 2 is a diagram, partially in section, of an installation according to another embodiment of the invention for coating a ladle;
  • Figure 3 is a partial schematic view in cross section of a continuous casting distributor placed in a rocker near the robot of Figure 1, the rocker being in the inverted position;
  • Figures 4A, 4B and 4C are views similar to Figure 3, the distributor being respectively in the normal position, in the tilted position to the left and in the tilted position to the right, for depositing the coating respectively on the bottom and on the one and the other of the two longitudinal side walls.

Dans la réalisation représentée à la figure 1, l'installation conforme à l'invention est adaptée à revêtir les parois intérieures d'une poche de coulée 1 dont l'enveloppe 2, munie d'oreilles 3, est garnie intérieurement d'un revêtement réfractaire permanent 4, réalisé en briques de forme ou en béton réfractaire.In the embodiment shown in Figure 1, the installation according to the invention is suitable for coating the interior walls of a ladle 1 whose casing 2, provided with ears 3, is internally lined with a coating permanent refractory 4, made of shaped bricks or refractory concrete.

Ce revêtement réfractaire permanent 4 doit être recouvert d'un revêtement d'usure 5 déposé sur le fond et les parois latérales intérieures de la poche de coulée 1 et destiné à être en contact avec le métal liquide.This permanent refractory coating 4 must be covered with a wear coating 5 deposited on the bottom and the inner side walls of the ladle 1 and intended to be in contact with the liquid metal.

La poche de coulée 1 est placée sur un support basculant (non représenté) connu en soi. Ce support basculant peut recevoir la poche 1 dans la position représentée en tirets à la figure, dans laquelle le fond de la poche 1 est sensiblement horizontal. Le support peut aussi basculer la poche 1 dans la position représentée en traits pleins, dans laquelle la partie la plus basse de la paroi intérieure de la poche est sensiblement horizontale et tournée vers le haut.The ladle 1 is placed on a tilting support (not shown) known per se. This support tilting can receive the pocket 1 in the position shown in dashes in the figure, in which the bottom of the pocket 1 is substantially horizontal. The support can also tilt the pocket 1 into the position shown in solid lines, in which the lowest part of the interior wall of the pocket is substantially horizontal and turned upwards.

Le support basculant comporte des moyens, connus en eux-mêmes et schématisés par des galets 6, 7, 8, pour faire tourner la poche 1 autour de son axe X, X', dans cette position basculée, comme schématisé par les flèches 9.The tilting support comprises means, known in themselves and shown diagrammatically by rollers 6, 7, 8, for rotating the pocket 1 around its axis X, X ', in this tilted position, as shown diagrammatically by the arrows 9.

L'installation comprend des moyens pour préparer ou recevoir et acheminer un matériau sensiblement sec destiné à être répandu pour former le revêtement d'usure 5.The installation comprises means for preparing or receiving and conveying a substantially dry material intended to be spread to form the wear coating 5.

Dans l'exemple schématisé à la figure, ces moyens consistent en deux trémies 10a, 10b, montées sur un châssis 11 et adaptées à recevoir, dans des sacs (non représentés) ou par un transporteur, par exemple un transporteur à bande (non représenté), le mélange sensiblement sec à déposer. De façon connue, ces trémies 10a, 10b peuvent être alternativement fermées et mises sous pression d'air comprimé pour le transport pneumatique du matériau par une canalisation souple 12 jusqu'à un séparateur cyclonique 13 qui sépare le matériau à déposer de l'air de transport. Le matériau peut ainsi être acheminé sans pression par simple gravité dans une canalisation souple 14 jusqu'au point de déversement 15 qui peut être muni d'un clapet (non représenté).In the example shown schematically in the figure, these means consist of two hoppers 10a, 10b, mounted on a frame 11 and adapted to receive, in bags (not shown) or by a conveyor, for example a conveyor belt (not shown ), the substantially dry mixture to be deposited. In known manner, these hoppers 10a, 10b can be alternately closed and pressurized with compressed air for the pneumatic transport of the material by a flexible pipe 12 to a cyclonic separator 13 which separates the material to be deposited from the air of transport. The material can thus be conveyed without pressure by simple gravity in a flexible pipe 14 to the discharge point 15 which can be provided with a valve (not shown).

Dans l'exemple représenté, le séparateur cyclonique 13 et la canalisation souple 14 sont portés par un robot 16.In the example shown, the cyclonic separator 13 and the flexible pipe 14 are carried by a robot 16.

Le robot 16 comporte un fût 17 sensiblement vertical, mobile en rotation autour de son axe par rapport à une base fixe 18 et entraîné en rotation dans un sens ou dans l'autre, comme indiqué par la flèche 19, par un moteur 20.The robot 16 has a substantially vertical barrel 17, which can rotate around its axis by relative to a fixed base 18 and driven in rotation in one direction or the other, as indicated by arrow 19, by a motor 20.

Un bras sensiblement horizontal 21 porté par le fût 17 peut se déplacer verticalement (flèche 22) le long du fût 17 sous l'action d'un moteur 23. Le séparateur cyclonique 13 est porté par le bras 21.A substantially horizontal arm 21 carried by the barrel 17 can move vertically (arrow 22) along the barrel 17 under the action of a motor 23. The cyclonic separator 13 is carried by the arm 21.

Un second bras sensiblement horizontal 24 est articulé à une de ses extrémités à l'extrémité du bras 21 et peut pivoter dans un plan horizontal autour de l'extrémité du bras 21 (flèche 25) sous l'action d'un moteur 26.A second substantially horizontal arm 24 is articulated at one of its ends at the end of the arm 21 and can pivot in a horizontal plane around the end of the arm 21 (arrow 25) under the action of a motor 26.

L'autre extrémité du bras 24 supporte un mât 27 sensiblement vertical qui peut se déplacer verticalement (flèche 28) sous l'action d'un premier moteur 29, et qui peut tourner autour de son axe (flèche 30) sous l'action d'un second moteur 31.The other end of the arm 24 supports a substantially vertical mast 27 which can move vertically (arrow 28) under the action of a first motor 29, and which can rotate around its axis (arrow 30) under the action of 'a second motor 31.

Le mât 27 se prolonge vers le bas par une partie 27a qui s'étend obliquement et qui se termine par une partie 27b sensiblement verticale. La canalisation souple 14 est accrochée le long du mât 27, le point de déversement 15 de cette canalisation étant adjacent à l'extrémité inférieure de la partie 27b du mât 27. Le diamètre de cette canalisation souple 14 est suffisant pour permettre un écoulement satisfaisant du matériau par gravité sans risque de bouchage.The mast 27 is extended downwards by a part 27a which extends obliquely and which ends in a substantially vertical part 27b. The flexible pipe 14 is hung along the mast 27, the discharge point 15 of this pipe being adjacent to the lower end of the part 27b of the mast 27. The diameter of this flexible pipe 14 is sufficient to allow satisfactory flow of the material by gravity without risk of clogging.

Le robot 16 comprend également des moyens non représentés pour coordonner l'arrivée du matériau, les mouvements des éléments qui le composent et les mouvements de la poche sur le support basculant.The robot 16 also includes means, not shown, for coordinating the arrival of the material, the movements of the elements which compose it and the movements of the pocket on the tilting support.

Dans la réalisation schématisée à la figure 2, l'installation conforme à l'invention comporte un support basculant 32 susceptible de pivoter autour d'un axe 33 par rapport à un bâti fixe 34 sous l'action d'un vérin de pivotement 35.In the embodiment shown diagrammatically in FIG. 2, the installation according to the invention comprises a tilting support 32 capable of pivoting about an axis 33 relative to a fixed frame 34 under the action of a pivoting cylinder 35.

Le support basculant 32 porte un plateau tournant 36 susceptible de tourner par rapport au support 32 sous l'action d'un moteur 37 par l'intermédiaire de moyens connus quelconques symbolisés par des billes 38. Le plateau tournant 36 est destiné à recevoir une poche de coulée 1 fixée sur le plateau tournant 36 par l'intermédiaire de pinces 39 actionnées par un vérin 40, de façon à faire tourner la poche 1 autour de son axe X, X' (flèche 41).The tilting support 32 carries a turntable 36 capable of rotating relative to the support 32 under the action of a motor 37 by any known means symbolized by balls 38. The turntable 36 is intended to receive a pocket casting 1 fixed on the turntable 36 by means of clamps 39 actuated by a jack 40, so as to rotate the pocket 1 around its axis X, X '(arrow 41).

Dans la position basculée du support 32, représentée à la figure, la partie la plus basse de la paroi intérieure de la poche 1 est sensiblement horizontale.In the tilted position of the support 32, shown in the figure, the lowest part of the interior wall of the pocket 1 is substantially horizontal.

Le matériau à répandre est stocké dans une trémie 42, qui a par exemple une forme conique, à l'intérieur de laquelle tourne une vis mélangeuse 43 entraînée par un moteur non représenté. A la partie inférieure de la trémie 42, le matériau tombe dans une vis transporteuse 44 à l'extrémité de déversement 45 de laquelle le matériau est déposé sur la paroi intérieure de la poche 1.The material to be spread is stored in a hopper 42, which has for example a conical shape, inside which rotates a mixing screw 43 driven by a motor not shown. At the lower part of the hopper 42, the material falls into a conveyor screw 44 at the discharge end 45 from which the material is deposited on the inside wall of the bag 1.

La vis 44 est représentée montée sur un vérin 46 qui permet de l'emboîter sur la partie inférieure de la trémie 42 et de la désolidariser de celle-ci, cette partie inférieure de la trémie étant alors obturée par un clapet non représenté.The screw 44 is shown mounted on a jack 46 which allows it to be fitted onto the lower part of the hopper 42 and to separate it from the latter, this lower part of the hopper then being closed by a valve not shown.

La trémie 42 et la vis transporteuse 44 sont montées sur un chariot 47 mobile selon la flèche 47a dans la direction axiale de la vis 44 pour permettre de répandre le matériau le long d'une génératrice de la paroi intérieure de la poche 1. Le chariot 47 est lui-même monté sur un châssis 48 qui est par exemple mobile dans la direction perpendiculaire à la direction du déplacement du chariot 47. L'ensemble forme un robot 49 équipé de moyens non représentés pour coordonner l'arrivée du matériau avec les mouvements de la poche 1 et ceux du chariot 47. Le fond 4a de la poche peut être revêtu d'une manière analogue à celle décrite en référence à la figure 1, ce fond étant en position horizontale et le matériau du revêtement étant déversé sur ce fond par exemple au moyen d'une goulotte tubulaire mobile sur toute la surface dudit fond.The hopper 42 and the conveyor screw 44 are mounted on a carriage 47 movable along the arrow 47a in the axial direction of the screw 44 to allow the material to be spread along a generator of the interior wall of the pocket 1. The carriage 47 is itself mounted on a chassis 48 which is for example movable in the direction perpendicular to the direction of movement of the carriage 47. The assembly forms a robot 49 equipped with means not shown to coordinate the arrival of the material with the movements from pocket 1 and those of the carriage 47. The bottom 4a of the pocket can be coated in a similar manner to that described with reference to FIG. 1, this bottom being in a horizontal position and the coating material being poured onto this bottom, for example by means a tubular chute movable over the entire surface of said bottom.

Dans la réalisation schématisée aux figures 3, 4A, 4B et 4C, un répartiteur de coulée continue 50 est monté sur un châssis basculant 51 d'un type connu quelconque à proximité, par exemple, du robot 16 à bras articulés décrit ci-dessus en référence à la figure 1.In the embodiment shown diagrammatically in FIGS. 3, 4A, 4B and 4C, a continuous casting distributor 50 is mounted on a tilting frame 51 of any known type near, for example, the robot 16 with articulated arms described above in reference to figure 1.

Le répartiteur 50 est représenté à la figure 3 dans la position renversée qui permet de faire tomber le revêtement d'usure utilisé et des "loups" de métal et/ou de scorie accrochés à celui-ci, par exemple dans une benne à déchets non représentée.The distributor 50 is shown in Figure 3 in the inverted position which allows to drop the wear coating used and "wolves" of metal and / or slag attached to it, for example in a waste bin not represented.

Le répartiteur 50 est représenté à la figure 4A dans la position normale d'utilisation ; les bras horizontaux 21 et 24 sont déployés et le mât 27 est orienté de manière à permettre de former le revêtement sur le fond 52 du répartiteur 50. La canalisation souple 14 n'est pas représentée par souci de clarté du dessin.The distributor 50 is shown in Figure 4A in the normal position of use; the horizontal arms 21 and 24 are deployed and the mast 27 is oriented so as to allow the coating to be formed on the bottom 52 of the distributor 50. The flexible pipe 14 is not shown for the sake of clarity of the drawing.

Le répartiteur 50 est représenté à la figure 4B dans la position basculée vers la gauche de la figure, dans laquelle la paroi latérale longitudinale 53 se trouve sensiblement en position horizontale : la partie coudée 27a peut ainsi pénétrer à l'intérieur du répartiteur pour répandre le matériau sur toute la surface de la paroi 53 et former ainsi le revêtement 55.The distributor 50 is shown in Figure 4B in the tilted position to the left of the figure, in which the longitudinal side wall 53 is substantially in a horizontal position: the bent portion 27a can thus penetrate inside the distributor to spread the material over the entire surface of the wall 53 and thus form the covering 55.

De même, à la figure 4C, le répartiteur 50 est basculé vers la droite et le bras articulé 24 est déployé de manière à permettre le dépôt du matériau sur la paroi 54 et la formation du revêtement 55.Similarly, in FIG. 4C, the distributor 50 is tilted to the right and the articulated arm 24 is deployed so as to allow the deposition of the material on the wall 54 and the formation of the coating 55.

Quels que soient le récipient métallurgique et l'installation utilisés pour la mise en oeuvre de l'invention, le matériau constituant le revêtement d'usure 5, 55, est un matériau sensiblement sec comprenant un mélange de particules réfractaires et un liant du type thermodurcissable ou équivalent, la composition et la granulométrie du mélange de particules réfractaires étant telles que ce mélange fritte au contact du métal liquide.Whatever the metallurgical container and the installation used for the implementation of the invention, the material constituting the coating wear 5, 55, is a substantially dry material comprising a mixture of refractory particles and a binder of the thermosetting type or equivalent, the composition and the particle size of the mixture of refractory particles being such that this mixture sintered in contact with the liquid metal.

Par ailleurs, ce matériau est destiné à être répandu sur les parois intérieures d'un récipient métallurgique qui sont initialement à une température suffisante pour pouvoir chauffer le matériau déposé sur celles-ci à une température permettant le ramollissement et la prise du liant du type thermodurcissable ou équivalent et la formation d'un revêtement monolithique qui adhère à ces parois intérieures du récipient 1, 50.Furthermore, this material is intended to be spread over the interior walls of a metallurgical container which are initially at a temperature sufficient to be able to heat the material deposited thereon to a temperature allowing the softening and setting of the binder of the thermosetting type. or equivalent and the formation of a monolithic coating which adheres to these interior walls of the container 1, 50.

On peut choisir les particules réfractaires, par exemple, dans le groupe comprenant les particules magnésiennes, silico-magnésiennes, silico-alumineuses, alumineuses, siliceuses, le carbonate de calcium, la chaux, la dolomie, le carbone, l'oxyde de chrome, le zircon, et leurs mélanges. Ces particules peuvent être sous forme de grains, de poudres et/ou de fibres.Refractory particles can be chosen, for example, from the group comprising magnesian, silico-magnesian, silico-aluminous, aluminous, siliceous particles, calcium carbonate, lime, dolomite, carbon, chromium oxide, zircon, and mixtures thereof. These particles can be in the form of grains, powders and / or fibers.

On peut choisir le liant du type thermodurcissable ou équivalent, par exemple, dans le groupe comprenant les résines thermodurcissables naturelles et synthétiques telles que par exemple les résines phénol-formol, les résines urée-formaldéhyde, les résines polyvinyliques, etc., des liants minéraux du type thermodurcissable ou équivalent ramollissant à la chaleur tels que par exemple silicate de soude (qui se dissout aux environs de 70°C), métasilicate, etc., des liants organiques et/ou des agglutinants tels que par exemple amidon, fécule, stéarate, carboxyméthycellulose, etc., et les mélanges de ces composés.One can choose the binder of the thermosetting type or equivalent, for example, from the group comprising natural and synthetic thermosetting resins such as for example phenol-formaldehyde resins, urea-formaldehyde resins, polyvinyl resins, etc., mineral binders of the thermosetting type or equivalent softening with heat such as for example sodium silicate (which dissolves around 70 ° C), metasilicate, etc., organic binders and / or agglutinants such as for example starch, starch, stearate , carboxymethylcellulose, etc., and mixtures of these compounds.

Les particules réfractaires peuvent être simplement mélangées à des particules du liant du type thermodurcissable. Dans certains cas, les particules réfractaires peuvent être enrobées dans le liant, par exemple si on utilise des particules très hygroscopiques telles que des particules de dolomie qui ont tendance à absorber l'humidité.The refractory particles can be simply mixed with particles of the binder of the thermosetting type. In some cases, the particles refractories can be embedded in the binder, for example if very hygroscopic particles such as dolomite particles are used which tend to absorb moisture.

Le mélange répandu est de préférence isolant réfractaire, et est constitué de particules dont la granulométrie est étudiée de manière à donner au revêtement en place après frittage au contact du métal liquide une porosité totale supérieure à 45% : ce caractère isolant du revêtement limite le refroidissement du métal liquide au contact des parois du récipient métallurgique, ce qui permet de se dispenser de préchauffer les parois du récipient avant utilisation sans risque de solidification de métal au contact de celles-ci.The widespread mixture is preferably refractory insulator, and is made up of particles whose particle size is studied so as to give the coating in place after sintering in contact with the liquid metal a total porosity greater than 45%: this insulating nature of the coating limits cooling. liquid metal in contact with the walls of the metallurgical container, which makes it possible to dispense with preheating the walls of the container before use without risk of solidification of metal in contact with them.

Le mélange répandu peut avoir une composition générale du type suivant :
   Particules réfractaires en grains et/ou en poudres :   80 à 100%
   Fibres organiques et/ou minérales :   0 à 10%
   Liant :   0 à 10%
The widespread mixture can have a general composition of the following type:
Refractory particles in grains and / or powders: 80 to 100%
Organic and / or mineral fibers: 0 to 10%
Binder: 0 to 10%

On peut ainsi donner à titre d'exemples non limitatifs les compositions suivantes de mélanges de caractères différents, dans lesquelles le liant apparaît dans la rubrique "perte au feu" :The following compositions of mixtures of different characters can thus be given as nonlimiting examples, in which the binder appears in the section "loss on ignition":

Matériau isolant réfractaire siliceuxSiliceous refractory insulating material

SiO₂ :If:
80 à 96%80 to 96%
Al₂O₃ :Al₂O₃:
6 à 0%6 to 0%
Perte au feu :Fire loss :
0,5 à 8%0.5 to 8%
Sels alcalins :Alkaline salts:
0 à 5%0 to 5%
Matériau isolant réfractaire magnésienMagnesian refractory insulating material

MgOMgO
: 68 à 83,5%: 68 to 83.5%
Cr₂O₃Cr₂O₃
: 8 à 0 %: 8 to 0%
ChamotteChamotte
: 4 à 0 %: 4 to 0%
Al₂O₃Al₂O₃
: 2,8 à 0 %: 2.8 to 0%
SiO₂If
: 0 à 8 %: 0 to 8%
Oxyde de ferIron oxide
: 0,2 à 8 %: 0.2 to 8%
Sels alcalinsAlkaline salts
: 5 à 0 %: 5 to 0%
Perte au feuFire loss
: 8 à 0,5%: 8 to 0.5%
Matériau isolant réfractaire épurantPurifying refractory insulating material

SiO₂If
: 0 à 6 %: 0 to 6%
Al₂O₃Al₂O₃
: 5 à 0 %: 5 to 0%
CaOCaO
: 20 à 80 %: 20 to 80%
MgOMgO
: 80 à 20 %: 80 to 20%
Oxyde de ferIron oxide
: 0,8 à 8 %: 0.8 to 8%
BB
: 0 à 4 %: 0 to 4%
Perte au feuFire loss
: 0,5 à 4 %: 0.5 to 4%

La mise en oeuvre du procédé de l'invention en utilisant l'une ou l'autre des installations décrites ci-dessus est extrêmement simple :

  • a) on place sur un support approprié un récipient métallurgique 1, 50, dont les parois intérieures à revêtir sont relativement chaudes ;
  • b) on fait basculer le support et on amène le récipient métallurgique 1, 50, successivement dans plusieurs positions différentes dans chacune desquelles une paroi ou une partie de paroi intérieure du récipient est sensiblement horizontale et tournée vers le haut ;
  • c) dans chacune des positions précitées, on répand sur ladite paroi ou partie de paroi intérieure, au moins une couche d'un matériau sensiblement sec comprenant un mélange de particules réfractaires et un liant du type thermodurcissable ou équivalent, la composition et la granulométrie du mélange de particules réfractaires étant telles que ce mélange fritte au contact du métal liquide, et on étale ce matériau de manière à constituer une couche sensiblement régulière ;
  • d) les parois intérieures du récipient étant initialement à une température suffisante pour pouvoir chauffer le matériau déposé sur celles-ci à une température permettant la prise du liant de type thermodurcissable ou équivalent et la formation d'un revêtement monolithique 5, 55 qui adhére aux parois intérieures du récipient.
The implementation of the process of the invention using one or the other of the installations described above is extremely simple:
  • a) a metallurgical container 1, 50 is placed on a suitable support, the internal walls to be coated are relatively hot;
  • b) tilting the support and bringing the metallurgical container 1, 50, successively in several different positions in each of which an inner wall or part of the container wall is substantially horizontal and turned upwards;
  • c) in each of the aforementioned positions, the said wall or part of the interior wall is spread over the at least one layer of a substantially dry material comprising a mixture of refractory particles and a binder of the thermosetting type or equivalent, the composition and the particle size of the mixture of refractory particles being such that this mixture sintered in contact with the liquid metal, and this material so as to constitute a substantially regular layer;
  • d) the internal walls of the container being initially at a temperature sufficient to be able to heat the material deposited thereon to a temperature allowing the setting of the binder of thermosetting type or equivalent and the formation of a monolithic coating 5, 55 which adheres to inner walls of the container.

Le revêtement intérieur permanent peut ainsi être à une température allant de 250°C environ à 400°C environ : il est ainsi possible de regarnir un récipient peu de temps après son utilisation.The permanent internal coating can thus be at a temperature ranging from approximately 250 ° C. to approximately 400 ° C.: it is thus possible to refill a container shortly after its use.

Si on doit regarnir un récipient dont les parois sont froides, on commence par réchauffer celles-ci jusqu'à la température requise avec des moyens connus quelconques, par exemple un brûleur à gaz ou une rampe à infra-rouges.If a container whose walls are cold is to be refilled, one begins by reheating them to the required temperature with any known means, for example a gas burner or an infrared ramp.

Certaines parois peuvent ne pas être accessibles aux moyens décrits ci-dessus et sont revêtues d'une manière connue quelconque, automatiquement ou manuellement.Some walls may not be accessible by the means described above and are coated in any known manner, automatically or manually.

Ainsi, par exemple, dans le cas d'un récipient métallurgique allongé tel qu'un répartiteur de coulée continue, il n'est pas aisé d'amener les parois latérales transversales en position horizontale pour pouvoir déposer le matériau du revêtement.Thus, for example, in the case of an elongated metallurgical container such as a continuous casting distributor, it is not easy to bring the transverse side walls in a horizontal position in order to be able to deposit the coating material.

Il est plus simple de mettre en place un petit gabarit partiel, provisoire ou sacrifié, et de déposer le matériau du revêtement entre ce gabarit et la paroi intérieure à revêtir. On peut également, en variante, préparer et mettre en place un panneau de revêtement préformé réalisé dans le même matériau.It is easier to set up a small partial template, temporary or sacrificed, and to deposit the coating material between this template and the interior wall to be coated. Alternatively, prepare and install a preformed covering panel made of the same material.

On peut évidemment prévoir de répandre un revêtement composé de deux ou plusieurs couches de compositions et caractéristiques différentes appliquées successivement, et d'étaler par exemple contre le revêtement permanent une couche qui ne fritte pas ou ne fritte que faiblement de façon à faciliter la séparation du revêtement d'usure après utilisation sans risque d'accrochage sur le revêtement permanent.It is obviously possible to provide for spreading a coating composed of two or more layers of different compositions and characteristics applied successively, and to spread, for example against the permanent coating, a layer which does not sinter or sinter only slightly so as to facilitate the separation of the wear coating after use without risk of snagging on the permanent coating.

Dans tous les cas, l'orifice de coulée du récipient est provisoirement obturé pendant le dépôt du revêtement.In all cases, the pouring orifice of the container is temporarily closed during the deposition of the coating.

Etant donné la température des parois intérieures du récipient, dès que le matériau est répandu, le liant se ramollit et devient collant, ce qui permet de coller le matériau aux parois intérieures et de former sur celles-ci un revêtement monolithique avec le matériau déjà en place. Il est ainsi possible de déplacer rapidement le récipient et même de le basculer de près de 180° pour revêtir une paroi opposée à celle déjà revêtue sans risque de faire tomber le revêtement déjà en place.Given the temperature of the interior walls of the container, as soon as the material is spread, the binder softens and becomes sticky, which makes it possible to stick the material to the interior walls and to form on them a monolithic coating with the material already in square. It is thus possible to quickly move the container and even to tilt it nearly 180 ° to coat a wall opposite to that already coated without the risk of dropping the coating already in place.

On peut donc supprimer l'étape de chauffage du gabarit des procédés connus décrits plus haut. Le matériau étant sensiblement sec, il est également inutile, dans la plupart des cas, de procéder au séchage nécessaire avec les procédés utilisant des mélanges aqueux. Par contre, si la qualité de l'acier coulé nécessite l'élimination de l'eau de cristallisation et/ou de gaz nuisibles susceptibles de se dégager au contact du métal liquide, il reste nécessaire de chauffer le revêtement pour éliminer cette eau et ces gaz.It is therefore possible to omit the heating step from the template of the known methods described above. The material being substantially dry, it is also unnecessary, in most cases, to carry out the necessary drying with the methods using aqueous mixtures. On the other hand, if the quality of the cast steel requires the elimination of the water of crystallization and / or harmful gases likely to be released on contact with the liquid metal, it remains necessary to heat the coating in order to eliminate this water and these gas.

Ultérieurement, quand on verse du métal liquide dans le récipient revêtu comme décrit ci-dessus, on sait que le liant disparaît rapidement, mais la cohésion du revêtement en place est assurée par le frittage du matériau en contact avec le métal liquide.Subsequently, when liquid metal is poured into the coated container as described above, it is known that the binder disappears quickly, but the cohesion of the coating in place is ensured by sintering the material in contact with the liquid metal.

On comprendra de ce qui précède que le procédé et l'installation conformes à l'invention concernent tout particulièrement les récipients métallurgiques de transvasement tels que poches de coulée, cuves à scories, répartiteurs de coulée continue.It will be understood from the above that the method and the installation in accordance with the invention relate in particular to metallurgical transfer containers such as ladles, slag tanks, continuous casting distributors.

Bien entendu, l'invention n'est pas limitée aux modes de réalisation que l'on vient de décrire, et on peut apporter à ceux-ci de nombreux changements et modifications sans sortir du domaine de l'invention.Of course, the invention is not limited to the embodiments which have just been described, and many changes and modifications can be made to them without departing from the scope of the invention.

Ainsi, les moyens utilisés pour stocker, transporter et répandre le matériau du revêtement peuvent être différents de ceux décrits : on peut par exemple utiliser, à la place des trémies 10 mises alternativement sous pression, une machine à projeter du type à barillet adaptée à véhiculer des matières pulvérulentes pouvant contenir des fibres, et de manière plus générale tout ensemble de moyens connus de transport et de manutention capable d'acheminer le matériau à répandre sur toute la paroi ou partie de paroi intérieure à revêtir. On peut utiliser à la place du séparateur cyclonique 13 tout appareil permettant de séparer le matériau à répandre de l'air comprimé de transport. On peut également utiliser toute combinaison de transporteurs, vis transporteuses, goulottes ou canalisations souples pour diriger le produit, et monter ces appareils sur divers types de chariots et châssis permettant de déplacer l'orifice de déversement du produit sur toute la paroi ou partie de paroi intérieure à revêtir.Thus, the means used for storing, transporting and spreading the coating material may be different from those described: it is for example possible to use, instead of the hoppers 10 alternately pressurized, a barrel type spraying machine suitable for conveying pulverulent materials which may contain fibers, and more generally any set of known means of transport and handling capable of conveying the material to be spread over the entire wall or part of the interior wall to be coated. Any device making it possible to separate the material to be spread from the compressed transport air can be used in place of the cyclonic separator 13. One can also use any combination of conveyors, conveyor screws, troughs or flexible pipes to direct the product, and mount these devices on various types of trolleys and chassis making it possible to move the product discharge orifice over the entire wall or part of the wall. interior to be coated.

On peut également utiliser un robot 16 d'un autre type que celui décrit, par exemple un robot dont la base soit mobile en translation dans la direction de l'axe longitudinal d'un répartiteur de coulée continue, ou un robot comportant un portique à la place des bras articulés décrits.One can also use a robot 16 of another type than that described, for example a robot whose base is movable in translation in the direction of the longitudinal axis of a continuous casting distributor, or a robot comprising a gantry to the place of the articulated arms described.

On peut également utiliser le procédé et l'installation conformes à l'invention pour former le revêtement réfractaire permanent de protection d'un récipient métallurgique, la composition et la granulométrie du mélange de particules utilisé étant adaptées à une telle utilisation.It is also possible to use the method and the installation in accordance with the invention to form the permanent refractory coating for protecting a metallurgical container, the composition and the particle size of the mixture of particles used being suitable for such use.

Claims (13)

  1. A process for producing a lining (5, 55) on the inside walls of a metallurgical vessel (1, 50) intended to receive liquid metal, characterised in that it comprises the following steps:
    a) a metallurgical vessel (1, 50), whose inside walls for lining are brought to a given temperature, is placed on a suitable support;
    b) the support is rocked and the metallurgical vessel (1, 50) is successively brought into a number of different positions, in each of which an inside wall part or wall of the vessel (1, 50) is substantially horizontal and facing upwards;
    c) in each of the said positions there is spread over said substantially horizontal inside wall part or wall at least one layer of a substantially dry material comprising a mixture of refractory particles and a binder of the thermosetting type or the like, the composition and the particle size of the mixture of refractory particles being such that said mixture sinters on contact with the liquid metal, and said metal is spread out so as to form a substantially uniform layer;
    d) the inside walls of the vessel initially being at said given temperature, which temperature is sufficient to be able to heat the material deposited thereon to a temperature allowing softening and setting of the binder of the thermosetting type or the like and the formation of a monolithic lining (5, 55) which adheres to the inside walls of the vessel (1, 50).
  2. A process according to claim 1, characterised in that there is applied to some small walls which cannot be placed in a substantially horizontal position, the same material either in the form of preformed panels or by using suitable partial templates behind which the material is spread.
  3. A process according to claim 1 or 2, characterised in that two or more layers of different compositions and characteristics are applied successively.
  4. A process according to any one of claims 1 to 3, characterised in that the refractory particles are selected from the group comprising magnesia, silico-magnesia, silico-alumina, alumina, and silica based particles, calcium carbonate, lime, dolomite, carbon, chromium oxide, zirconium, and their mixtures.
  5. A process according to any one of claims 1 to 4, characterised in that the binder of the thermosetting type or the like is selected from the group comprising natural and synthetic thermosetting resins such as, for example, phenol-formaldehyde resins, urea-formaldehyde resins, polyvinyl resins, etc., mineral binders of the thermosetting type or the like softening under heat and thus becoming adhesive, such as, for example, sodium silicate, metasilicate, etc., organic binders or agglutinants, such as, for example, starch, potato starch, stearate, carboxymethylcellulose, etc, and mixtures of these compounds.
  6. A process according to any one of claims 1 to 5, characterised in that the refractory particles are mixed with particles of binder of the thermosetting type or the like.
  7. A process according to any one of claims 1 to 5, characterised in that the refractory particles are coated with the binder of the thermosetting type or the like.
  8. A process according to any one of the preceding claims, characterised in that the lining obtained is a refractory insulant.
  9. An installation for making a lining (5, 55) on the inside walls of a metallurgical vessel (1, 50) adapted to receive a liquid metal, by the practice of the process according to any one of claims 1 to 8, characterised in that it comprises:
    - means for preparing or receiving a substantially dry material comprising a mixture of refractory particles and a binder of the thermosetting type or the like, the composition and the particle size of the mixture of particles being such that said mixture sinters on contact with the liquid metal;
    - means acting as a support to receive a metallurgical vessel (1, 50) whose inside walls are relatively hot;
    - means for rocking the support and bringing the metallurgical vessel (1, 50) successively into a number of different positions in each of which an inside wall part or wall of the vessel is substantially horizontal and facing upwards;
    - means for spreading on said inside wall part or wall, in each of the said positions, at least one layer of said substantially dry material and spreading said material in such manner as to form a substantially uniform layer.
  10. An installation according to claim 9, characterised in that the support means are adapted to assume a turned-over position in which the metallurgical vessel is turned over through 180° with respect to its normal position of use.
  11. An installation according to claim 9 or 10, the metallurgical vessel being an elongate continuous casting distributor, characterised in that the distributor support is adapted to rock the distributor at least about a horizontal axis parallel to its longitudinal axis in both directions.
  12. An installation according to claim 9 or 10, the metallurgical vessel being a casting ladle, characterised in that it comprises means for rocking the ladle about a horizontal axis into a position in which the lowest part of the inside side wall of the ladle is substantially horizontal, and means for turning the ladle over about its axis in that position.
  13. An installation according to any one of claims 9 to 12, characterised in that it comprises a robot comprising means for spreading the lining material over the substantially horizontal inside wall part and means for co-ordinating the arrival and spreading of the material with the movements of the metallurgical vessel (1, 50).
EP90907161A 1989-04-26 1990-04-25 Process and installation for producing a lining on the internal walls of a metallurgical vessel Expired - Lifetime EP0422196B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT90907161T ATE100364T1 (en) 1989-04-26 1990-04-25 METHOD AND DEVICE FOR MAKING A LINING ON THE INTERIOR SURFACES OF A METALLURGICAL VESSEL.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8905528A FR2646367B1 (en) 1989-04-26 1989-04-26 METHOD AND INSTALLATION FOR REALIZING A COATING ON THE INTERIOR WALLS OF A METALLURGICAL CONTAINER
FR8905528 1989-04-26

Publications (2)

Publication Number Publication Date
EP0422196A1 EP0422196A1 (en) 1991-04-17
EP0422196B1 true EP0422196B1 (en) 1994-01-19

Family

ID=9381146

Family Applications (1)

Application Number Title Priority Date Filing Date
EP90907161A Expired - Lifetime EP0422196B1 (en) 1989-04-26 1990-04-25 Process and installation for producing a lining on the internal walls of a metallurgical vessel

Country Status (12)

Country Link
US (1) US5160692A (en)
EP (1) EP0422196B1 (en)
KR (1) KR940003901B1 (en)
AU (1) AU627585B2 (en)
BR (1) BR9006724A (en)
CA (1) CA2030787A1 (en)
CS (1) CS203890A3 (en)
DE (1) DE69006158T2 (en)
ES (1) ES2048492T3 (en)
FR (1) FR2646367B1 (en)
HU (1) HUT56750A (en)
WO (1) WO1990012666A1 (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT399464B (en) * 1992-03-05 1995-05-26 Veitsch Radex Ag DEVICE FOR TREATING AND FEEDING A MONOLITHIC CERAMIC MASS INTO A METALLURGICAL MELTING VESSEL
KR100360976B1 (en) * 1993-12-13 2003-03-03 민테크인터내쇼날인코포레이티드 Spray Melting Furnace Repair System
FR2728185A1 (en) 1994-12-19 1996-06-21 Daussan & Co METHOD FOR APPLYING TO THE INNER SIDES OF A METALLURGICAL CONTAINER A PROTECTIVE COATING COMPRISING AT LEAST TWO LAYERS
FR2732915B1 (en) * 1995-04-14 1997-06-13 Daussan & Co PROCESS FOR APPLYING A PROTECTIVE COATING WITH AT LEAST TWO LAYERS INSIDE A METALLURGICAL CONTAINER
US5885510A (en) * 1997-02-07 1999-03-23 Alcoa Chemie Gmbh Methods of making refractory bodies
US6165926A (en) * 1998-06-24 2000-12-26 Alcoa Chemie Gmbh Castable refractory composition and methods of making refractory bodies
US6268018B1 (en) * 1999-02-09 2001-07-31 Harbison-Walker Refractories Company Method of applying a non-slumping pumpable castable high purity silica composition
KR100484539B1 (en) * 2002-08-01 2005-05-17 주식회사 포스렉 Coating Agent for Slag Pot
CN100453211C (en) * 2007-06-22 2009-01-21 河北理工大学 A preparation method of tundish dry working lining
CN101858694B (en) * 2010-06-22 2011-11-16 武汉科技大学 Die used for molding prefabricated furnace liner of induction furnace
KR101526440B1 (en) * 2013-11-08 2015-06-05 주식회사 포스코 pot and method for manufacturing the pot

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3637412A (en) * 1968-09-16 1972-01-25 Combustion Eng Ladle lining refractory
CA1016962A (en) * 1973-01-04 1977-09-06 Crawford B. Murton Applying a refractory lining on hot metallurgical containments
FR2533492B1 (en) * 1982-09-29 1986-06-13 Gilson Jacques METHOD AND INSTALLATION FOR MOLDING A REFRACTORY COATING OF A CONTAINER FOR LIQUID METAL
US4696455A (en) * 1984-10-30 1987-09-29 Consolidated Ceramic Products, Inc. Zircon and MgO preheatable insulating refractory liners and methods of use thereof
FR2585273B1 (en) * 1985-07-24 1988-05-13 Daussan & Co COATING FOR PROTECTING THE INTERIOR OF A METALLURGICAL CONTAINER AND METHOD FOR PRODUCING THE SAME
BE1000516A6 (en) * 1987-04-30 1989-01-10 Centre Rech Metallurgique Device for submit a protective coating on the inner wall of a metallurgical container.

Also Published As

Publication number Publication date
ES2048492T3 (en) 1994-03-16
DE69006158D1 (en) 1994-03-03
CA2030787A1 (en) 1990-10-27
AU627585B2 (en) 1992-08-27
FR2646367A1 (en) 1990-11-02
HU904258D0 (en) 1991-07-29
KR940003901B1 (en) 1994-05-09
CS203890A3 (en) 1992-11-18
FR2646367B1 (en) 1994-04-01
BR9006724A (en) 1991-08-06
DE69006158T2 (en) 1994-05-05
EP0422196A1 (en) 1991-04-17
KR920700082A (en) 1992-02-19
WO1990012666A1 (en) 1990-11-01
AU5657690A (en) 1990-11-16
US5160692A (en) 1992-11-03
HUT56750A (en) 1991-10-28

Similar Documents

Publication Publication Date Title
EP0422196B1 (en) Process and installation for producing a lining on the internal walls of a metallurgical vessel
EP0214882B1 (en) Protective lining for the interior of a metallurgical vessel, and process for making the lining
US4489022A (en) Forming coherent refractory masses
US3917110A (en) Stopper rod having fibrous protective sleeve
NO820397L (en) CORE FOR BLADE FORMATION OF THE LINES IN A MOLD OF METAL CONTAINER, LINING METHOD BY REVERSING THE CORE CORE, AND LINING COMPOSITION FOR USE BY THIS METHOD
WO1992020479A1 (en) Process for applying on the inner surfaces of a metallurgical vessel a protective coating comprising at least two layers, and protective coating so obtained
GB2154228A (en) Composition of matter for use in forming refractory masses in situ
JPH09316819A (en) Joint seal machine for new/old pavement boundary line on paved road
WO1992000157A1 (en) Method for coating the inside of a metallurgical container with a protective coating having at least two layers, and protective coating thereby obtained
US2663920A (en) Hot top cover
BE820783A (en) PROCESS FOR APPLYING REFRACTORY PADDING IN METALLURGIC CONTAINERS
US5511762A (en) Consumable form with degradable lining
CN110257586B (en) Slag bucket and processing method thereof
JPS6018625B2 (en) Stamp material for molten metal containers
RU2383412C2 (en) Method of fabrication of wearable layer of refractory lining in casting ladles and casting moulds, also wearable layer of refractory lining fabricated by this method
JPH0245111B2 (en)
KR900009216B1 (en) Lining for protecting the interior of a metallurgical vessel and a method for forming said lining
KR100840267B1 (en) Blast furnace repair method
MC591A1 (en) Method and apparatus for the application of monolithic coatings
JPH0339782B2 (en)
JP3004270B1 (en) Heat insulating material for molten metal and method for producing the same
BE835396Q (en) IMPROVEMENTS PROVIDED TO DISTRIBUTORS FILLED WITH REFRACTORY
FR2717720A1 (en) Coating for protecting the interior of a metallurgical container, device and method for applying this coating.
JPH0356825B2 (en)
JP2587827Y2 (en) Converter tap tap

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 19901211

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES GB IT LI LU NL SE

17Q First examination report despatched

Effective date: 19920806

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH DE DK ES GB IT LI LU NL SE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Effective date: 19940119

REF Corresponds to:

Ref document number: 100364

Country of ref document: AT

Date of ref document: 19940215

Kind code of ref document: T

ITF It: translation for a ep patent filed
GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

Effective date: 19940124

REF Corresponds to:

Ref document number: 69006158

Country of ref document: DE

Date of ref document: 19940303

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2048492

Country of ref document: ES

Kind code of ref document: T3

EPTA Lu: last paid annual fee
PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed
EAL Se: european patent in force in sweden

Ref document number: 90907161.5

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 19960401

Year of fee payment: 7

Ref country code: LU

Payment date: 19960401

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 19960411

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: AT

Payment date: 19960416

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 19960424

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 19960430

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CH

Payment date: 19960502

Year of fee payment: 7

Ref country code: BE

Payment date: 19960502

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 19960626

Year of fee payment: 7

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19970425

Ref country code: GB

Effective date: 19970425

Ref country code: AT

Effective date: 19970425

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Effective date: 19970426

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19970426

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19970430

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19970430

Ref country code: BE

Effective date: 19970430

BERE Be: lapsed

Owner name: DAUSSAN ET CIE

Effective date: 19970430

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Effective date: 19971101

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 19970425

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19980101

NLV4 Nl: lapsed or anulled due to non-payment of the annual fee

Effective date: 19971101

EUG Se: european patent has lapsed

Ref document number: 90907161.5

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 19990405

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20050425