EP0471392A2 - Composition désodorisante - Google Patents
Composition désodorisante Download PDFInfo
- Publication number
- EP0471392A2 EP0471392A2 EP19910201722 EP91201722A EP0471392A2 EP 0471392 A2 EP0471392 A2 EP 0471392A2 EP 19910201722 EP19910201722 EP 19910201722 EP 91201722 A EP91201722 A EP 91201722A EP 0471392 A2 EP0471392 A2 EP 0471392A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- composition
- deodorant
- composition according
- weight
- zinc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 43
- 239000002781 deodorant agent Substances 0.000 title claims abstract description 23
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 19
- 229920000642 polymer Polymers 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 230000000699 topical effect Effects 0.000 claims abstract description 9
- 150000003839 salts Chemical class 0.000 claims abstract description 7
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 5
- 239000011777 magnesium Substances 0.000 claims abstract description 5
- 239000011701 zinc Substances 0.000 claims abstract description 5
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 5
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical group [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 claims description 6
- 239000011667 zinc carbonate Substances 0.000 claims description 6
- 235000004416 zinc carbonate Nutrition 0.000 claims description 6
- 229910000010 zinc carbonate Inorganic materials 0.000 claims description 6
- 125000004122 cyclic group Chemical group 0.000 claims description 5
- 229920002785 Croscarmellose sodium Polymers 0.000 claims description 4
- 239000002250 absorbent Substances 0.000 claims description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 2
- 230000002745 absorbent Effects 0.000 claims 1
- WEMFUFMJQFVTSW-UHFFFAOYSA-N compositin Natural products CC=C(C)C(=O)OC1CC(O)C2(C)COC3C2C1(C)C1CCC2(C)C(CC=C2C1(C)C3OC(=O)C(C)=CC)c1ccoc1 WEMFUFMJQFVTSW-UHFFFAOYSA-N 0.000 claims 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims 1
- 150000003751 zinc Chemical class 0.000 claims 1
- -1 aluminium chlorhydrate Chemical compound 0.000 description 8
- 239000000047 product Substances 0.000 description 7
- 239000004615 ingredient Substances 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 4
- 239000002304 perfume Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 230000001166 anti-perspirative effect Effects 0.000 description 3
- 239000003213 antiperspirant Substances 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 239000006210 lotion Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- WCOXQTXVACYMLM-UHFFFAOYSA-N 2,3-bis(12-hydroxyoctadecanoyloxy)propyl 12-hydroxyoctadecanoate Chemical compound CCCCCCC(O)CCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCC(O)CCCCCC)COC(=O)CCCCCCCCCCC(O)CCCCCC WCOXQTXVACYMLM-UHFFFAOYSA-N 0.000 description 2
- 229910002016 Aerosil® 200 Inorganic materials 0.000 description 2
- 229920004511 Dow Corning® 200 Fluid Polymers 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
- 229940049964 oleate Drugs 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000003380 propellant Substances 0.000 description 2
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 description 1
- 239000004110 Zinc silicate Substances 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 159000000013 aluminium salts Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000012254 powdered material Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 235000019352 zinc silicate Nutrition 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- 150000003754 zirconium Chemical class 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/27—Zinc; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
Definitions
- the invention relates to deodorant compositions suitable for topical application to human skin, particularly liquid compositions suitable for use with a roll-on dispenser, or solid compositions suitable for use as a cosmetic stick together with a stick holder.
- deodorant and anti-perspirant market is dominated with products based on aluminium or zirconium salts which are intended to prevent, or at least control, perspiration at the skin surface, particularly on the underarm, while simultaneously providing a perceived degree of deodorancy.
- the invention provides a propellant-free deodorant composition suitable for topical application to human skin, which comprises:
- composition according to the invention comprises a deodorant which is chosen from salts or oxides of zinc or magnesium which are insoluble or only sparingly soluble in water.
- Suitable salts or oxides are: zinc oxide zinc carbonate zinc citrate zinc laurate zinc oleate zinc orthophosphate zinc stearate zinc silicate zinc tartrate magnesium oxide magnesium carbonate magnesium fluoride magnesium hydroxide magnesium laurate magnesium myristate magnesium oleate magnesium palmitate magnesium stearate magnesium orthophosphate magnesium pyrophosphate magnesium silicate
- the amount of deodorant present in the composition according to the invention is from 0.5 to 20%, preferably from 1 to 15% by weight of the composition.
- composition according to the invention also comprises a cellulosic polymer having a water absorbing capacity of at least 1.
- water absorbing capacity we mean that the polymer has the ability to absorb an amount of water at least equal to its own weight.
- the cellulosic polymer will have a water absorbing capacity of at least 5, most preferably of at least 10 or even higher.
- cellulosic polymers are cross-linked carboxymethylcelluloses, such as AKUCELL, available from AKZO, and AQUALON available from HERCULES.
- the amount of cellulosic polymer present in the composition according to the invention is from 1 to 50%, preferably from 5 to 30% by weight of the composition.
- composition according to the invention also comprises a linear or cyclic volatile silicone.
- volatile silicones include polydimethyl cyclosiloxane, having a viscosity of less than 5mm2s ⁇ 1, examples of which are DOW CORNING 344 Fluid (tetramer) and DOW CORNING 345 Fluid (pentamer), and volatile hexamethyldisiloxane having a viscosity of not more than 0.65mm2s ⁇ 1, for example DOW CORNING 200 Fluid (0.65mm2s ⁇ 1).
- the preferred volatile silicones are the cyclic forms.
- the amount of volatile silicone present in the composition according to the invention is from 1 to 90%, preferably from 5 to 70% by weight of the composition.
- composition according to the invention can comprise other ingredients, in addition to those already identified, depending on the nature and form of the finished product.
- non-volatile silicones such as a polydimethylsiloxane having a viscosity in excess of 5mm2s ⁇ 1, for example, from 50 to 1000mm2s ⁇ 1, such as DOW CORNING 200 Fluids (standard viscosities 50-1000mm2s ⁇ 1)
- thickeners such as clays, for example Bentone 38
- silica for example Aerosil 200
- skin feel improves such as talc and finely divided polyethylene, an example of which is ACUMIST B18
- cosmetically acceptable vehicles such as anhydrous ethanol and other emollients
- gelling agents such as stearyl alcohol or waxes, for example Castor wax
- perfumes preservatives
- other cosmetic adjuncts conventionally employed in stick, roll-on and spray deodorant products.
- ingredients other than the deodorant, cellulosic polymer and volatile silicone which can optionally be present in the composition according to the invention can conveniently form the balance of the composition, and accordingly can form up to 90%, preferably from 10 to 80% by weight of the composition.
- composition according to the invention can take the form of liquid or solid products, each of which is suited to or adapted for topical application to human skin.
- One convenient form of the composition according to the invention is a solid stick, usually contained in a suitable holder or dispenser to enable it to be applied to the area of the skin, particularly the underarm, where control of perspiration and deodorancy is required.
- composition of the invention is a lotion suitable for inclusion in a roll-on dispenser, fitted with a ball valve, to enable the product to be rolled onto the skin in a manner which is conventional in the art.
- a further example of a composition according to the invention is the liquid composition for dispensing via a finger operated pump-spray or a hand operated squeeze spray to provide for delivery to the skin of a finely divided spray or aerosol, without the use of environmentally unfriendly propellant gases to deliver it.
- the invention also provides for the use of a propellant-free deodorant composition, in accordance with the invention, as herein defined, in perspiration and body malodour control, following topical application to human skin.
- This examples illustrates a deodorant stick product according to the invention.
- the stick had the following formulation: % w/w Volatile silicone - DOW CORNING 345 61.0 Akucell 10.0 Zinc carbonate 6.0 Castor wax 4.0 Stearyl alcohol 16.0 PEG 400 distearate 2.0 Perfume 1.0
- the roll-on lotion for use in a roll-ball applicator, had the following formulation: % w/w Volatile silicone - DOW CORNING 344 + 345 59.95 Akucell 10.0 Zinc carbonate 8.0 Acumist B18* 7.0 Bentone 38 1.0 Aerosil 200 0.55 Silicone 200 fluid 50mm2s ⁇ 1 12.0 Ethanol, anhydrous 0.5 Perfume 1.0 * Finely divided polyethylene powder - particle size 18 ⁇ m.
- This example illustrates a deodorant lotion suitable for dispensing from a hand operated squeeze spray device which is operated without environmentally unfriendly gaseous propellants.
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB909015502A GB9015502D0 (en) | 1990-07-13 | 1990-07-13 | Cosmetic composition |
| GB9015502 | 1990-07-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0471392A2 true EP0471392A2 (fr) | 1992-02-19 |
| EP0471392A3 EP0471392A3 (fr) | 1992-03-11 |
Family
ID=10679088
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19910201722 Withdrawn EP0471392A3 (fr) | 1990-07-13 | 1991-07-04 | Composition désodorisante |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0471392A3 (fr) |
| JP (1) | JPH04230316A (fr) |
| AU (2) | AU638143B2 (fr) |
| BR (2) | BR9102937A (fr) |
| CA (1) | CA2046535A1 (fr) |
| GB (1) | GB9015502D0 (fr) |
| ZA (1) | ZA915454B (fr) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2271716A (en) * | 1992-10-26 | 1994-04-27 | Unilever Plc | Propellant-free deodorant composition |
| EP0676192A3 (fr) * | 1994-02-22 | 1996-08-28 | Curtis Helene Ind Inc | Compositions antiperspirantes déodorantes. |
| WO2003026608A1 (fr) * | 2001-09-26 | 2003-04-03 | The Procter & Gamble Company | Compositions topiques contenant des solides absorbant les liquides et des liquides adhesifs |
| US8147855B2 (en) | 1994-12-21 | 2012-04-03 | Cosmederm Bioscience, Inc. | Methods for inhibiting sensory responses in the skin such as pain and itch using topical product formulations containing strontium |
| WO2012150891A1 (fr) * | 2011-05-02 | 2012-11-08 | Lipidor Ab | Composition destinée à l'administration d'un agent pharmacologiquement ou cosmétiquement actif sur une surface d'un organisme vivant |
| US20230041345A1 (en) * | 2017-06-30 | 2023-02-09 | The Procter & Gamble Company | Antiperspirant and deodorant compositions |
| US11844752B2 (en) | 2017-06-30 | 2023-12-19 | The Procter & Gamble Company | Deodorant compositions |
| US12036301B2 (en) | 2017-06-30 | 2024-07-16 | The Procter & Gamble Company | Deodorant and antiperspirant compositions |
| US12116553B2 (en) | 2016-07-13 | 2024-10-15 | The Procter & Gamble Company | Polypeptide variants |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9015502D0 (en) * | 1990-07-13 | 1990-08-29 | Unilever Plc | Cosmetic composition |
| JP5369674B2 (ja) * | 2008-12-25 | 2013-12-18 | ライオン株式会社 | デオドラント組成物及び複合粒子の製造方法 |
| US9854839B2 (en) | 2012-01-31 | 2018-01-02 | Altria Client Services Llc | Electronic vaping device and method |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PH15735A (en) * | 1979-08-10 | 1983-03-18 | Unilever Nv | Deodorant compositions |
| PH15855A (en) * | 1979-08-10 | 1983-04-13 | Unilever Nv | Deodorant compositions |
| US4863721A (en) * | 1987-05-22 | 1989-09-05 | The Procter & Gamble Company | Reduced stinging antiperspirant compositions |
| GB9015502D0 (en) * | 1990-07-13 | 1990-08-29 | Unilever Plc | Cosmetic composition |
-
1990
- 1990-07-13 GB GB909015502A patent/GB9015502D0/en active Pending
-
1991
- 1991-07-04 EP EP19910201722 patent/EP0471392A3/fr not_active Withdrawn
- 1991-07-09 CA CA002046535A patent/CA2046535A1/fr not_active Abandoned
- 1991-07-10 AU AU80305/91A patent/AU638143B2/en not_active Ceased
- 1991-07-11 JP JP3171344A patent/JPH04230316A/ja active Pending
- 1991-07-11 BR BR919102937A patent/BR9102937A/pt not_active Application Discontinuation
- 1991-07-12 ZA ZA915454A patent/ZA915454B/xx unknown
- 1991-07-24 AU AU81275/91A patent/AU641032B2/en not_active Ceased
- 1991-07-25 BR BR919103183A patent/BR9103183A/pt not_active Application Discontinuation
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2271716A (en) * | 1992-10-26 | 1994-04-27 | Unilever Plc | Propellant-free deodorant composition |
| EP0676192A3 (fr) * | 1994-02-22 | 1996-08-28 | Curtis Helene Ind Inc | Compositions antiperspirantes déodorantes. |
| US8147855B2 (en) | 1994-12-21 | 2012-04-03 | Cosmederm Bioscience, Inc. | Methods for inhibiting sensory responses in the skin such as pain and itch using topical product formulations containing strontium |
| US8449923B2 (en) | 1994-12-21 | 2013-05-28 | Cosmederm Bioscience, Inc. | Methods for inhibiting sensory nerves by topically administering strontium-containing compositions to keratinized skin |
| WO2003026608A1 (fr) * | 2001-09-26 | 2003-04-03 | The Procter & Gamble Company | Compositions topiques contenant des solides absorbant les liquides et des liquides adhesifs |
| WO2012150891A1 (fr) * | 2011-05-02 | 2012-11-08 | Lipidor Ab | Composition destinée à l'administration d'un agent pharmacologiquement ou cosmétiquement actif sur une surface d'un organisme vivant |
| US12116553B2 (en) | 2016-07-13 | 2024-10-15 | The Procter & Gamble Company | Polypeptide variants |
| US20230041345A1 (en) * | 2017-06-30 | 2023-02-09 | The Procter & Gamble Company | Antiperspirant and deodorant compositions |
| US11844752B2 (en) | 2017-06-30 | 2023-12-19 | The Procter & Gamble Company | Deodorant compositions |
| US12036301B2 (en) | 2017-06-30 | 2024-07-16 | The Procter & Gamble Company | Deodorant and antiperspirant compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH04230316A (ja) | 1992-08-19 |
| ZA915454B (en) | 1993-03-31 |
| EP0471392A3 (fr) | 1992-03-11 |
| AU8030591A (en) | 1992-01-16 |
| CA2046535A1 (fr) | 1992-01-14 |
| AU641032B2 (en) | 1993-09-09 |
| AU638143B2 (en) | 1993-06-17 |
| BR9103183A (pt) | 1992-05-05 |
| GB9015502D0 (en) | 1990-08-29 |
| AU8127591A (en) | 1992-01-30 |
| BR9102937A (pt) | 1992-04-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| PUAL | Search report despatched |
Free format text: ORIGINAL CODE: 0009013 |
|
| AK | Designated contracting states |
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|
| 17P | Request for examination filed |
Effective date: 19920127 |
|
| RAP3 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: UNILEVER PLC Owner name: UNILEVER N.V. |
|
| 17Q | First examination report despatched |
Effective date: 19930126 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
| 18D | Application deemed to be withdrawn |
Effective date: 19930806 |