EP0336507A1 - Process to compress flat textiles, flat textiles made with this process and their application - Google Patents
Process to compress flat textiles, flat textiles made with this process and their application Download PDFInfo
- Publication number
- EP0336507A1 EP0336507A1 EP89200821A EP89200821A EP0336507A1 EP 0336507 A1 EP0336507 A1 EP 0336507A1 EP 89200821 A EP89200821 A EP 89200821A EP 89200821 A EP89200821 A EP 89200821A EP 0336507 A1 EP0336507 A1 EP 0336507A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- application
- shrinking
- fabric
- polyester
- shrinkage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 25
- 239000004753 textile Substances 0.000 title claims abstract description 9
- 239000004744 fabric Substances 0.000 claims abstract description 25
- 229920000728 polyester Polymers 0.000 claims abstract description 19
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- 230000006835 compression Effects 0.000 abstract description 7
- 238000007906 compression Methods 0.000 abstract description 7
- 239000000463 material Substances 0.000 abstract description 5
- 239000000203 mixture Substances 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 2
- 238000007669 thermal treatment Methods 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 230000000694 effects Effects 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 230000035699 permeability Effects 0.000 description 4
- 239000004952 Polyamide Substances 0.000 description 3
- 238000010411 cooking Methods 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000009941 weaving Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 2
- -1 polyethylene terephthalate Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 210000001519 tissue Anatomy 0.000 description 2
- 238000004873 anchoring Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000002635 electroconvulsive therapy Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000009998 heat setting Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 210000001724 microfibril Anatomy 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 238000009997 thermal pre-treatment Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
- D04B1/18—Other fabrics or articles characterised primarily by the use of particular thread materials elastic threads
- D04B1/20—Other fabrics or articles characterised primarily by the use of particular thread materials elastic threads crimped threads
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
- D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/30—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the fibres or filaments
- D03D15/33—Ultrafine fibres, e.g. microfibres or nanofibres
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/567—Shapes or effects upon shrinkage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63H—MARINE PROPULSION OR STEERING
- B63H9/00—Marine propulsion provided directly by wind power
- B63H9/04—Marine propulsion provided directly by wind power using sails or like wind-catching surfaces
- B63H9/06—Types of sail; Constructional features of sails; Arrangements thereof on vessels
- B63H9/067—Sails characterised by their construction or manufacturing process
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/08—Physical properties foamed
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2507/00—Sport; Military
- D10B2507/04—Sails
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2507/00—Sport; Military
- D10B2507/06—Parachutes
Definitions
- the invention relates to a method for compressing textile fabrics in the longitudinal and / or transverse direction from polyester yarns, a part made of high-shrinking polyester filament and a part made of normal-shrinking polyester filament being processed to form a flat article, and a flat article produced by the process and its application.
- GB-A-985451 discloses textile articles made of a shrunk and an unshrunk polyester filament, the resulting fabrics have an undesirable crepe effect for a dense sheet.
- the permeability to water, water vapor and gases can be reduced by compacting textile fabrics, in particular fabrics. Dense fabrics are water-repellent. A good tissue density is an essential prerequisite for Inletts
- a method is known (EP 0 092 938) which works with extremely fine fibers in the range from 0.001 to 0.8 denier made of polyester and polyamide, the polyamide component being swelled first and then shrinking by means of a swelling agent.
- the shrinking polyester filament is a cold-drawn polyester POY with a cooking shrinkage of at least 20%.
- the thermal treatment of the fabric takes place without tension between 60 and 200 ° C in a gaseous or liquid environment. A temperature range of 80 to 180 ° C has proven to be the most appropriate. In a preferred procedure, the fabric is shock-treated in water from 95 to 98 ° C.
- the method according to the invention has the advantage, among other things, that the yarn allows the manufacturer of the fabric to be processed more easily. For example, in order to achieve the highest possible weft density, it is not necessary to work with a correspondingly high warp tension, which can cause thread breaks. The compression takes place without a building effect.
- Both cold and hot drawn polyester threads are made from the same polymer.
- a cold-drawn polyester POY is to be understood as a thread which contains at least 90% by weight of polyethylene terephthalate and which has been spun at a speed of approximately 3100 m / min and then drawn below the glass transition point.
- the cold-drawn polyester POY threads used have a cooking shrinkage of 20 to 60%, preferably 30 to 50%, based on the starting length of the thread.
- Warm-drawn polyester is to be understood to mean all threads which have been produced either by the split process or by the continue process, contain at least 90% by weight of polyethylene terephthalate and have been drawn above the glass transition point. All of these threads have a cooking shrinkage ⁇ 20%.
- the compacted fabric consists of cold-drawn and warm-drawn polyester threads.
- the cold drawn threads can be used in the warp and / or in the weft. Depending on the compression in the weft or warp direction.
- the fabric is subjected to stress-free thermal shock treatment in a known manner, which results in compression by shrinking the cold-drawn threads.
- the fabrics mentioned here can also contain other fibers in addition to polyester filament yarns.
- the shrinkage along and / or across is at least 10%, preferably 20 to 30%, based on the initial dimensions.
- Such a shrinkage causes a density which reduces the air and water permeability to such an extent that chemical treatment, for example in the form of a coating or impregnation, can even be dispensed with under certain circumstances.
- Woven goods are to be understood in particular as canvas, parachutes and inlets, which are for this Intended use must have optimal air and water tightness or permeability.
- Warp material Variant A + B PA66, dtex 235 f 34 t Shot material: variant A PES, high shrink yarn dtex 167 f 30 Z, Variant B PES, normal shrink yarn dtex 167 f 30 Z Binding: canvas
- Variations A + B have the same warp and weft thread numbers when raw.
- the fabric is washed without tension and in a shock-like manner at 70 to 98 ° C and then dyed and heat-set. This process has increased the number of warp threads in variant A by 32.5% and in variant B by 10%.
- Pollen rail L2 Variant A + B PES, dtex 84 f 36
- Basic guide rail L1 variant A PES, shrinkable yarn dtex 78 f 24 Z
- Variant B PES normal shrink yarn dtex 76 f 22
- Binding L1: Tricot, L2: Poltechnische
- Variations A + B have the same number of stitches (rods / cm, rows / cm) in the raw state.
- the pile mesh fabric is washed as tension-free and shock-like as possible at 70 to 98 ° C and then dyed and heat-set.
- the compression is over 30% in the transverse direction with variant A, i.e. the width increase is over 30%, based on the initial width.
- Variant B only shrinks about 10%.
- the pile goods are characterized by a good look and a closed surface and also have a good pile position.
- Pole chain PES, dtex 167 f 72 x2 shrunk
- Base fabric warp PES, high shrink yarn, dtex 150 f 48 x2 Shot PES, dtex 167 f 72 x2 shrunk
- Binding double velvet, canvas
- a fabric is produced on the double plush hover that has identical warp and weft thread numbers compared to a reference pattern.
- the shrinking warp yarn In order not to trigger the shrinking effect prematurely, the shrinking warp yarn must not be exposed to any thermal pretreatment (e.g. warm sizing) before the weaving process.
- the process according to the invention has the advantage that, depending on the conditions of the material and equipment parameters, the 30 to 60% boiling shrinkage of the cold-drawn POY polyester yarns can be transferred to the fabric to a greater or lesser extent, i.e. a shrinkage of length and / or lengthways of 15% and more, based on the starting dimension of the fabric, can be achieved.
- the method according to the invention also makes weaving more economical. It can be woven with a lower number of weft threads, which results in better weaving and thus a higher network effect.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Nanotechnology (AREA)
- Treatment Of Fiber Materials (AREA)
- Woven Fabrics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Description
Die Erfindung betrifft ein Verfahren zum Verdichten von textilen Flächengebilden in Längs- und/oder Querrichtung aus Polyestergarnen, wobei ein Teil aus hochschrumpfenden Polyesterfilament und ein Teil aus normalschrumpfenden Polyesterfilament zu einem Flächengebilde verarbeitet werden sowie ein Flachengebilde, hergestellt nach dem Verfahren und dessen Anwendung.The invention relates to a method for compressing textile fabrics in the longitudinal and / or transverse direction from polyester yarns, a part made of high-shrinking polyester filament and a part made of normal-shrinking polyester filament being processed to form a flat article, and a flat article produced by the process and its application.
Aus der GB-A-985451 sind zwar textile Artikel aus einem geschrumpften und einem ungeschrumpften Polyesterfilament bekannt, die resultierenden Gewebe weisen jedoch einen für ein dichtes Flächengebilde unerwünschten Crêpe-Effekt auf.Although GB-A-985451 discloses textile articles made of a shrunk and an unshrunk polyester filament, the resulting fabrics have an undesirable crepe effect for a dense sheet.
Durch Verdichten von textilen Flächengebilden, insbesondere von Geweben, kann die Durchlässigkeit für Wasser, Wasserdampf und Gase reduziert werden. Dichte Gewebe wirken wasserabstossend. Für Inletts ist für deren Gebrauch eine gute Gewebedichte eine unabdingbare VoraussetzungThe permeability to water, water vapor and gases can be reduced by compacting textile fabrics, in particular fabrics. Dense fabrics are water-repellent. A good tissue density is an essential prerequisite for Inletts
Es wurden verschiedene Verfahren zum Verdichten von Geweben vorgeschlagen, welche sich die Kompressibilität von Kompositfasern, bestehend aus Polyester und Polyamid Mikrofibrillen zu Nutze machen. Die Einzelfibrillen weisen dabei einen Titer von weniger als 0,5 denier (=0,55 dtex) auf.Various methods of compressing tissues have been proposed that improve the compressibility of Use composite fibers consisting of polyester and polyamide microfibrils. The individual fibrils have a titer of less than 0.5 denier (= 0.55 dtex).
Es ist ein Verfahren bekannt (EP 0 092 938), das mit extrem feinen Fasern im Bereich von 0,001 bis 0,8 denier aus Polyester und Polyamid arbeitet, wobei die Polyamidkomponente mittels eines Quellmittels zuerst zum Quellen und anschliessend zum Schrumpfen gebracht wird.A method is known (EP 0 092 938) which works with extremely fine fibers in the range from 0.001 to 0.8 denier made of polyester and polyamide, the polyamide component being swelled first and then shrinking by means of a swelling agent.
Schon die Herstellung der extrem feinen Kompositfasern mit der erforderlichen Wasserbeständigkeit und Festigkeit ist problematisch und auf mehreren Wegen versucht worden. Hinzu kommt die Zugabe von Quellmitteln die in ihrer Toxizität weitere Einschränkungen in der Anwendung erforderlich machen.Even the production of the extremely fine composite fibers with the required water resistance and strength is problematic and attempts have been made in several ways. Added to this is the addition of swelling agents, which make further restrictions in use necessary in their toxicity.
Allen bekannten Verfahren gemeinsam ist die Verwendung von Garnmischungen bzw. Filamentmischungen, welche aus unterschiedlichen Rohstoffen hergestellt sind. Das hat den Nachteil, dass eine Vielzahl von unterschiedlichen Polymeren zur Verarbeitung gelangt und eine aufwendige analytische Qualitätskontrolle erforderlich ist. Auch sind bei unterschiedlichen Polymeren unterschiedliche Spinntechniken einzusetzen.Common to all known processes is the use of yarn blends or filament blends which are produced from different raw materials. This has the disadvantage that a large number of different polymers are processed and complex analytical quality control is required. Different spinning techniques can also be used with different polymers.
Es besteht schon lange das Bedürfnis aus einem einheitlichen Rohstoff, welcher leicht und preiswert zugänglich ist, ein ebenes textiles Flächengebilde herzustellen, welches auf einfache Weise so verdichtet werden kann, dass seine Durchlässigkeit für Wasser und Luft gering ist. Es besteht aber auch das Bedürfnis die Spinntechnik resp. Strecktechnik weitgehend zu vereinfachen, um zu einem wirtschaftlichen Verfahren zu gelangen.There has long been a need to produce a flat textile fabric from a uniform raw material, which is easily and inexpensively accessible, and which can be compacted in a simple manner so that its permeability to water and air is low. But there is also a need for spinning technology, respectively. To largely simplify stretching technology in order to arrive at an economical process.
Die Aufgabe wird erfindungsgemäss dadurch gelöst, dass das hochschrumpfende Polyesterfilament ein kaltverstrecktes Polyester-POY mit einem Kochschrumpf von wenigstens 20 % ist.The object is achieved according to the invention in that the shrinking polyester filament is a cold-drawn polyester POY with a cooking shrinkage of at least 20%.
Die thermische Behandlung des Flächengebildes erfolgt spannungslos zwischen 60 und 200°C in einer gasförmigen oder flüssigen Umgebung. Dabei hat sich ein Temperaturbereich von 80 bis 180°C als am zweckmässigsten erwiesen. In einer bevorzugten Verfahrensweise wird das Flächengebilde im Wasser von 95 bis 98°C schockartig behandelt.The thermal treatment of the fabric takes place without tension between 60 and 200 ° C in a gaseous or liquid environment. A temperature range of 80 to 180 ° C has proven to be the most appropriate. In a preferred procedure, the fabric is shock-treated in water from 95 to 98 ° C.
Dabei ist darauf zu achten, dass der Hochschrumpffaden während der Verarbeitung zum textilen Flächengebilde nicht gedämpft oder warm geschlichtet oder anderweitig thermisch vorbehandelt werden darf.Care must be taken to ensure that the shrink thread is not steamed or heat-sized or otherwise thermally pretreated during processing into a textile fabric.
Das erfindungsgemässe Verfahren hat unter anderem den Vorteil, dass das Garn dem Hersteller des Flächengebildes eine einfachere Verarbeitung erlaubt. Es muss beispielsweise zum Erreichen einer höchstmöglichen Schussdichte nicht bei entsprechend hoher Kettspannung gearbeitet werden, durch die Fadenbrüche entstehen können. Die Verdichtung erfolgt ohne Bauscheffekt.The method according to the invention has the advantage, among other things, that the yarn allows the manufacturer of the fabric to be processed more easily. For example, in order to achieve the highest possible weft density, it is not necessary to work with a correspondingly high warp tension, which can cause thread breaks. The compression takes place without a building effect.
Aus dem gleichen Polymer werden sowohl kalt wie warmverstreckte Polyesterfäden hergestellt.Both cold and hot drawn polyester threads are made from the same polymer.
Unter einem kaltverstrecktem Polyester-POY ist ein Faden zu verstehen, welcher wenigstens 90 Gew.-% Polyethylenterephthalat enthält und mit einer Geschwindigkeit von etwa 3100 m/min gesponnen und anschliessend unterhalb des Glasumwandlungspunktes verstreckt wurde.A cold-drawn polyester POY is to be understood as a thread which contains at least 90% by weight of polyethylene terephthalate and which has been spun at a speed of approximately 3100 m / min and then drawn below the glass transition point.
Die verwendeten kaltverstreckten Polyester-POY-Fäden weisen einen Kochschrumpf von 20 bis 60 % auf, vorzugsweise 30 bis 50 %, bezogen auf die Ausgangslänge des Fadens.The cold-drawn polyester POY threads used have a cooking shrinkage of 20 to 60%, preferably 30 to 50%, based on the starting length of the thread.
Unter warmverstrecktem Polyester sind alle Fäden zu verstehen, welche entweder im Splitverfahren oder im Continue-Verfahren produziert wurden, wenigstens 90 Gew.-% Polyethylenterephthalat enthalten und oberhalb des Glasumwandlungspunktes verstreckt wurden. Alle diese Fäden haben einen Kochschrumpf <20 %.Warm-drawn polyester is to be understood to mean all threads which have been produced either by the split process or by the continue process, contain at least 90% by weight of polyethylene terephthalate and have been drawn above the glass transition point. All of these threads have a cooking shrinkage <20%.
Das verdichtete Flächengebilde besteht aus kaltverstreckten und warmverstreckten Polyesterfäden. Die kaltverstreckten Fäden können in der Kette und/oder im Schuss eingesetzt werden. Je nachdem erfolgt die Verdichtung in Schuss- oder Kettrichtung. Das Flächengebilde wird in bekannter Weise einer spannungslosen thermischen Schockbehandlung unterzogen, wodurch eine Verdichtung durch Schrumpfen der kaltverstreckten Fäden resultiert.The compacted fabric consists of cold-drawn and warm-drawn polyester threads. The cold drawn threads can be used in the warp and / or in the weft. Depending on the compression in the weft or warp direction. The fabric is subjected to stress-free thermal shock treatment in a known manner, which results in compression by shrinking the cold-drawn threads.
Selbstverständlich können die hier angesprochenen Flächengebilde neben Polyesterfilamentgarnen auch andere Fasern enthalten.Of course, the fabrics mentioned here can also contain other fibers in addition to polyester filament yarns.
Der Warenschrumpf beträgt längs und/oder quer wenigstens 10 %, bevorzugt 20 bis 30 %, bezogen auf die Ausgangsdimensionen. Ein solcher Schrumpf bewirkt eine Dichte, welche die Luft- und Wasserdurchlässigkeit so weit herabsetzt, dass unter Umständen sogar auf eine chemische Behandlung, beispielsweise in Form einer Beschichtung oder Imprägnierung, verzichtet werden kann.The shrinkage along and / or across is at least 10%, preferably 20 to 30%, based on the initial dimensions. Such a shrinkage causes a density which reduces the air and water permeability to such an extent that chemical treatment, for example in the form of a coating or impregnation, can even be dispensed with under certain circumstances.
Die Anwendung des Verfahrens ist besonders vorteilhaft bei der Herstellung von Webwaren, Maschenwaren und Tuftingwaren. Unter Webwaren sind insbesondere Segeltücher, Fallschirme und Inletts zu verstehen, welche für diesen Verwendungszweck eine optimale Luft- und Wasserdichtigkeit bzw. durchlässigkeit aufweisen müssen.The application of the method is particularly advantageous in the manufacture of woven goods, knitwear and tufted goods. Woven goods are to be understood in particular as canvas, parachutes and inlets, which are for this Intended use must have optimal air and water tightness or permeability.
Ein weiteres Anwendungsgebiet ist die Herstellung von verdichteten Polwaren, wo eine gute Verankerung der einzelnen Noppen eine grosse Rolle spielt.Another area of application is the production of compacted pile goods, where good anchoring of the individual knobs plays a major role.
Die Erfindung soll anhand von Beispielen näher beschrieben werden.The invention will be described in more detail by means of examples.
Kettmaterial : Variante A+B
PA66, dtex 235 f 34 Z
Schussmaterial: Variante A
PES, Hochschrumpfgarn dtex 167 f 30 Z,
Variante B
PES, Normalschrumpfgarn dtex 167 f 30 Z
Bindung : LeinwandWarp material: Variant A + B
PA66, dtex 235 f 34 t
Shot material: variant A
PES, high shrink yarn dtex 167 f 30 Z,
Variant B
PES, normal shrink yarn dtex 167 f 30 Z
Binding: canvas
Variante A+B weisen im Rohzustand die gleichen Kett- und Schussfadenzahlen auf.Variations A + B have the same warp and weft thread numbers when raw.
Das Gewebe wird möglichst spannungslos und schockartig bei 70 bis 98°C gewaschen und anschliessend gefärbt und thermofixiert. Durch diesen Vorgang hat sich die Kettfadenzahl bei der Variante A um 32.5 %, bei der Variante B um 10 % erhöht.The fabric is washed without tension and in a shock-like manner at 70 to 98 ° C and then dyed and heat-set. This process has increased the number of warp threads in variant A by 32.5% and in variant B by 10%.
Pollegeschiene L2 : Variante A+B
PES, dtex 84 f 36
Grundlegeschiene L1: Variante A
PES, Hochschrumpfgarn dtex 78 f 24 Z
Variante B
PES, Normalschrumpfgarn dtex 76 f 22 Z
Bindung : L1: Tricot, L2: PollegungPollen rail L2: Variant A + B
PES, dtex 84 f 36
Basic guide rail L1: variant A
PES, shrinkable yarn dtex 78 f 24 Z
Variant B
PES, normal shrink yarn dtex 76 f 22 Z
Binding: L1: Tricot, L2: Pollegung
Variante A+B weisen im Rohzustand die gleichen Maschenzahlen (Stäbchen/cm, Reihen/cm) auf.Variations A + B have the same number of stitches (rods / cm, rows / cm) in the raw state.
Die Polmaschenware wird möglichst spannungslos und schockartig bei 70 bis 98°C gewaschen und anschliessend gefärbt und thermofixiert. Die Verdichtung beträgt über 30 % in Querrichtung bei der Variante A, d.h. der Breiteneinsprung beträgt über 30 %, bezogen auf die Ausgangsbreite. Die Variante B schrumpft nur ca. 10 %.The pile mesh fabric is washed as tension-free and shock-like as possible at 70 to 98 ° C and then dyed and heat-set. The compression is over 30% in the transverse direction with variant A, i.e. the width increase is over 30%, based on the initial width. Variant B only shrinks about 10%.
Die Polware zeichnet sich durch eine gute Optik und eine geschlossene Oberfläche aus und hat ausserdem ein gutes Polstand vermögen.The pile goods are characterized by a good look and a closed surface and also have a good pile position.
Polkette : PES, dtex 167 f 72 x2 geschrumpft
Grundgewebe: Kette PES, Hochschrumpfgarn, dtex 150 f 48 x2
Schuss PES, dtex 167 f 72 x2 geschrumpft
Bindung : Doppelsamt, Leinwand
Pole chain: PES, dtex 167 f 72 x2 shrunk
Base fabric: warp PES, high shrink yarn, dtex 150 f 48 x2
Shot PES, dtex 167 f 72 x2 shrunk
Binding: double velvet, canvas
Auf der Doppelplüschwebmaschine wird ein Gewebe hergestellt, das im Vergleich zu einem Referenzmuster identische Kett- und Schussfadenzahlen aufweist. Um den Schrumpfeffekt nicht vorzeitig auszulösen, darf das hochschrumpfende Kettgarn vor dem Webprozess keiner thermischen Vorbehandlung (z.B. Warmschlichten) ausgesetzt werden.A fabric is produced on the double plush hover that has identical warp and weft thread numbers compared to a reference pattern. In order not to trigger the shrinking effect prematurely, the shrinking warp yarn must not be exposed to any thermal pretreatment (e.g. warm sizing) before the weaving process.
Nach dem möglichst spannungslosen, schockartigen Eintauchen beim Waschvorgang bei 70 bis 98°C und anschliessendem Färben und Thermofixieren wird eine Polware erzielt, die aufgrund der Verdichtung des Grundgewebes eine gegenüber den Referenzmustern höhere Noppenhaftung aufweist. Ausserdem sind das Polstandvermögen und die Optik positiv beeinflusst worden.After the most stress-free, shock-like immersion during the washing process at 70 to 98 ° C and subsequent dyeing and heat setting, a pile fabric is obtained which, due to the compression of the base fabric, has a higher knob adhesion compared to the reference samples. In addition, the pole position and the optics have been positively influenced.
Das erfindungsgemässe Verfahren hat den Vorteil, dass je nach den Bedingungen der stofftechnologischen und ausrüstungstechnischen Parameter der 30 bis 60 %ige Kochschrumpf der kaltverstreckten POY-Polyestergarne mehr oder weniger stark auf das Flächengebilde übertragen werden kann, d.h. es kann ein Warenschrumpf längs und/oder quer von 15 % und mehr, bezogen auf die Ausgangsdimension des Flächengebildes erzielt werden. Je lockerer die Rohgewebeeinstellung gewählt wird, um so höher ist der resultierende Warenschrumpf.The process according to the invention has the advantage that, depending on the conditions of the material and equipment parameters, the 30 to 60% boiling shrinkage of the cold-drawn POY polyester yarns can be transferred to the fabric to a greater or lesser extent, i.e. a shrinkage of length and / or lengthways of 15% and more, based on the starting dimension of the fabric, can be achieved. The looser the raw fabric setting is chosen, the higher the resulting shrinkage.
Durch das erfindungsgemässe Verfahren gelingt es auch wirtschaftlicher zu weben. Es kann bei einer tieferen Schussfadenzahl gewoben werden, wodurch ein besserer Weblauf erreicht und damit ein höherer Netzeffekt erzielt werden kann.The method according to the invention also makes weaving more economical. It can be woven with a lower number of weft threads, which results in better weaving and thus a higher network effect.
Claims (6)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT89200821T ATE78527T1 (en) | 1988-04-06 | 1989-03-30 | PROCESS FOR COMPRESSING TEXTILE SHEET STRUCTURES, SHEET STRUCTURES MANUFACTURED BY THE PROCESS AND ITS APPLICATION. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1266/88 | 1988-04-06 | ||
| CH126688 | 1988-04-06 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0336507A1 true EP0336507A1 (en) | 1989-10-11 |
| EP0336507B1 EP0336507B1 (en) | 1992-07-22 |
| EP0336507B2 EP0336507B2 (en) | 1998-04-15 |
Family
ID=4206373
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP89200821A Expired - Lifetime EP0336507B2 (en) | 1988-04-06 | 1989-03-30 | Process to compress flat textiles, flat textiles made with this process and their application |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0336507B2 (en) |
| AT (1) | ATE78527T1 (en) |
| DE (1) | DE58901863D1 (en) |
| ES (1) | ES2034580T5 (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4000740A1 (en) * | 1990-01-12 | 1991-07-18 | Akzo Gmbh | METHOD FOR PRODUCING A UNPROCESSED AIRBAG WEAVE |
| WO1996016213A1 (en) * | 1994-11-24 | 1996-05-30 | Rhone-Poulenc Setila | Process for fabricating knitted textile surfaces, and textile surfaces obtained thereby |
| NL1000591C2 (en) * | 1995-06-19 | 1996-12-20 | Blydestein Willink N V | Tissue. |
| WO1997019211A1 (en) * | 1995-11-23 | 1997-05-29 | Impak Marketing Limited | Abrading material |
| WO1998057576A1 (en) * | 1997-06-18 | 1998-12-23 | Tytex A/S | A method for manufacturing a mop |
| FR2825104A1 (en) * | 2001-05-22 | 2002-11-29 | North Sails Group Llc | SAIL FABRIC |
| DE10150207A1 (en) * | 2001-10-12 | 2003-05-08 | Inst Textil & Faserforschung | Bulked woven fabric has at least one structured yarn, in the warps and/or wefts, with a differential shrinking characteristic to give a stretched effect component and a shrinkage component and eddied knots at intervals |
| US7309667B2 (en) | 2001-10-12 | 2007-12-18 | Deutsche Institute Fur Textilund Faserforschung Stuttgart | Woven fabric and a method for the production thereof |
| IT201700004581A1 (en) * | 2017-01-17 | 2018-07-17 | Miles S P A | METHOD OF REALIZING A TEXTILE MANUFACTURING, IN PARTICULAR A CLOTHING ACCESSORY, CONTAINING THERMORETRILABLE YARN AND ITS APPAREL ACCESSORY |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0523546B1 (en) * | 1991-07-16 | 1999-03-10 | Akzo Nobel N.V. | Technical woven fabric with adjusted air permeability and high ageing resistance and process for its manufacture |
| DE59406816D1 (en) * | 1993-07-31 | 1998-10-08 | Akzo Nobel Nv | Process for the production of uncoated technical fabrics |
| DK0717133T3 (en) | 1994-12-16 | 2001-04-23 | Hoechst Trevira Gmbh & Co Kg | Hybrid yarn and its shriveled and shriveled, permanently deformable textile material and their manufacture and use |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE549935A (en) * | ||||
| GB985451A (en) * | 1961-06-07 | 1965-03-10 | Rhodiaceta | Improvements relating to textile articles |
| GB1507973A (en) * | 1974-05-15 | 1978-04-19 | Chell F | Knitted fabric |
| DE2757597A1 (en) * | 1977-12-23 | 1979-07-05 | Hoechst Ag | Conveyor belting woven insert - has warps of texturised and non-texturised high tenacity filament yarns to improve bond with cladding mass |
| EP0092938A1 (en) * | 1982-04-26 | 1983-11-02 | Teijin Limited | Process for the preparation of woven fabrics of low air permeability |
-
1989
- 1989-03-30 AT AT89200821T patent/ATE78527T1/en not_active IP Right Cessation
- 1989-03-30 DE DE8989200821T patent/DE58901863D1/en not_active Expired - Lifetime
- 1989-03-30 EP EP89200821A patent/EP0336507B2/en not_active Expired - Lifetime
- 1989-03-30 ES ES89200821T patent/ES2034580T5/en not_active Expired - Lifetime
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE549935A (en) * | ||||
| GB985451A (en) * | 1961-06-07 | 1965-03-10 | Rhodiaceta | Improvements relating to textile articles |
| GB1507973A (en) * | 1974-05-15 | 1978-04-19 | Chell F | Knitted fabric |
| DE2757597A1 (en) * | 1977-12-23 | 1979-07-05 | Hoechst Ag | Conveyor belting woven insert - has warps of texturised and non-texturised high tenacity filament yarns to improve bond with cladding mass |
| EP0092938A1 (en) * | 1982-04-26 | 1983-11-02 | Teijin Limited | Process for the preparation of woven fabrics of low air permeability |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4000740A1 (en) * | 1990-01-12 | 1991-07-18 | Akzo Gmbh | METHOD FOR PRODUCING A UNPROCESSED AIRBAG WEAVE |
| WO1996016213A1 (en) * | 1994-11-24 | 1996-05-30 | Rhone-Poulenc Setila | Process for fabricating knitted textile surfaces, and textile surfaces obtained thereby |
| FR2727438A1 (en) * | 1994-11-24 | 1996-05-31 | Rhone Poulenc Fibres | PROCESS FOR PRODUCING TRICOTED TEXTILE SURFACES AND TEXTILE SURFACES OBTAINED |
| NL1000591C2 (en) * | 1995-06-19 | 1996-12-20 | Blydestein Willink N V | Tissue. |
| WO1997000341A1 (en) * | 1995-06-19 | 1997-01-03 | Blydenstein-Willink N.V. | Fabric |
| US6210506B1 (en) | 1995-11-23 | 2001-04-03 | Impak Marketing Limited | Abrading material |
| WO1997019211A1 (en) * | 1995-11-23 | 1997-05-29 | Impak Marketing Limited | Abrading material |
| CN1061397C (en) * | 1995-11-23 | 2001-01-31 | 伊姆派克销售有限公司 | Abrading material |
| WO1998057576A1 (en) * | 1997-06-18 | 1998-12-23 | Tytex A/S | A method for manufacturing a mop |
| FR2825104A1 (en) * | 2001-05-22 | 2002-11-29 | North Sails Group Llc | SAIL FABRIC |
| DE10150207A1 (en) * | 2001-10-12 | 2003-05-08 | Inst Textil & Faserforschung | Bulked woven fabric has at least one structured yarn, in the warps and/or wefts, with a differential shrinking characteristic to give a stretched effect component and a shrinkage component and eddied knots at intervals |
| US7309667B2 (en) | 2001-10-12 | 2007-12-18 | Deutsche Institute Fur Textilund Faserforschung Stuttgart | Woven fabric and a method for the production thereof |
| IT201700004581A1 (en) * | 2017-01-17 | 2018-07-17 | Miles S P A | METHOD OF REALIZING A TEXTILE MANUFACTURING, IN PARTICULAR A CLOTHING ACCESSORY, CONTAINING THERMORETRILABLE YARN AND ITS APPAREL ACCESSORY |
| WO2018134743A1 (en) * | 2017-01-17 | 2018-07-26 | Miles S.P.A. | Artefact with knitted structure and method of realisation thereof |
| US11643759B2 (en) | 2017-01-17 | 2023-05-09 | Miles S.P.A. | Artifact with knitted structure and method of realization thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| DE58901863D1 (en) | 1992-08-27 |
| EP0336507B1 (en) | 1992-07-22 |
| ES2034580T5 (en) | 1998-11-01 |
| ES2034580T3 (en) | 1993-04-01 |
| ATE78527T1 (en) | 1992-08-15 |
| EP0336507B2 (en) | 1998-04-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69516893T2 (en) | ELASTIC FABRIC | |
| EP1903134B1 (en) | Elastic non-woven fabric and method for its production | |
| EP0336507B2 (en) | Process to compress flat textiles, flat textiles made with this process and their application | |
| DE69101993T2 (en) | Process for the production of cotton mixed warp threads for durable textile materials. | |
| DE2366181C3 (en) | Method for producing pile carpets | |
| DE4408813C1 (en) | Process for making a nonwoven composite and interposed nonwoven composite | |
| DE3521479C1 (en) | Use of a yarn for the production of a deformable surface structure | |
| AT160896B (en) | Textile structures made from condensation polymers and process for their manufacture | |
| EP0301266B1 (en) | Method for continuously sizing and stretching synthetic filaments | |
| DE69925988T2 (en) | METHOD FOR THE TREATMENT OF BULK MATERIAL | |
| DE19720107C2 (en) | Sails and canvas that simulates a woven cloth made from natural fibers | |
| EP0325153B1 (en) | Patterned flat woven polyester yarn textile fabric | |
| DE2523433C2 (en) | Process for improving the properties of fiber materials consisting entirely or partially of natural or regenerated cellulose by treatment with liquid ammonia | |
| DE1760605A1 (en) | Process for producing elastic textiles | |
| DE69801686T2 (en) | Process for producing a stretchable fabric for seat covers | |
| CH497579A (en) | Process for making crepe knitted fabric used in making | |
| DE3025781A1 (en) | Ribbon-yarns for curtain or furnishing fabric - comprising multiple multifilament yarns folded and heat-set in flat form | |
| CH503817A (en) | Elastic fabric prodn | |
| DE2140553C3 (en) | Process for the production of clothing materials from knitted or knitted goods containing polyester | |
| DE2521073A1 (en) | METHOD OF MANUFACTURING AN ELASTIC FABRIC | |
| DE3017951A1 (en) | Raschel knit fabric - has stretch yarn weft for washed fabric to be dried without fixing to give bi-stretch | |
| CH325265A (en) | High voltage electrical switch | |
| DE2924369B1 (en) | Process for producing a roughened warp knitted fabric | |
| AT207355B (en) | Process for the permanent enrichment of any fiber component on the surface or inside of mixed fiber material | |
| DE68916241T2 (en) | Comfortable fabric with great durability. |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH DE ES FR GB IT LI NL SE |
|
| 17P | Request for examination filed |
Effective date: 19900404 |
|
| RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: RHONE-POULENC VISCOSUISSE SA |
|
| 17Q | First examination report despatched |
Effective date: 19910729 |
|
| GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
| AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE CH DE ES FR GB IT LI NL SE |
|
| REF | Corresponds to: |
Ref document number: 78527 Country of ref document: AT Date of ref document: 19920815 Kind code of ref document: T |
|
| REF | Corresponds to: |
Ref document number: 58901863 Country of ref document: DE Date of ref document: 19920827 |
|
| GBT | Gb: translation of ep patent filed (gb section 77(6)(a)/1977) | ||
| ITF | It: translation for a ep patent filed | ||
| ET | Fr: translation filed | ||
| REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2034580 Country of ref document: ES Kind code of ref document: T3 |
|
| PLBI | Opposition filed |
Free format text: ORIGINAL CODE: 0009260 |
|
| 26 | Opposition filed |
Opponent name: HOECHST AKTIENGESELLSCHAFT ZENTRALE PATENTABTEILUN Effective date: 19930421 |
|
| NLR1 | Nl: opposition has been filed with the epo |
Opponent name: HOECHST AKTIENGESELLSCHAFT |
|
| EAL | Se: european patent in force in sweden |
Ref document number: 89200821.0 |
|
| RAP2 | Party data changed (patent owner data changed or rights of a patent transferred) |
Owner name: RHONE-POULENC VISCOSUISSE SA |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: BE Payment date: 19960304 Year of fee payment: 8 Ref country code: AT Payment date: 19960304 Year of fee payment: 8 |
|
| NLT2 | Nl: modifications (of names), taken from the european patent patent bulletin |
Owner name: RHONE-POULENC VISCOSUISSE SA |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AT Effective date: 19970330 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Effective date: 19970331 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CH Payment date: 19970610 Year of fee payment: 9 |
|
| APAC | Appeal dossier modified |
Free format text: ORIGINAL CODE: EPIDOS NOAPO |
|
| BERE | Be: lapsed |
Owner name: S.A. RHONE-POULENC VISCOSUISSE Effective date: 19970331 |
|
| PLAW | Interlocutory decision in opposition |
Free format text: ORIGINAL CODE: EPIDOS IDOP |
|
| PUAH | Patent maintained in amended form |
Free format text: ORIGINAL CODE: 0009272 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: PATENT MAINTAINED AS AMENDED |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: ES Payment date: 19980312 Year of fee payment: 10 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19980331 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19980331 |
|
| 27A | Patent maintained in amended form |
Effective date: 19980415 |
|
| AK | Designated contracting states |
Kind code of ref document: B2 Designated state(s): AT BE CH DE ES FR GB IT LI NL SE |
|
| NLR2 | Nl: decision of opposition | ||
| ITF | It: translation for a ep patent filed | ||
| GBTA | Gb: translation of amended ep patent filed (gb section 77(6)(b)/1977) | ||
| ET3 | Fr: translation filed ** decision concerning opposition | ||
| NLR3 | Nl: receipt of modified translations in the netherlands language after an opposition procedure | ||
| REG | Reference to a national code |
Ref country code: ES Ref legal event code: DC2A Kind code of ref document: T5 Effective date: 19980713 |
|
| NLS | Nl: assignments of ep-patents |
Owner name: RHODIA FILTEC AG |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
| REG | Reference to a national code |
Ref country code: ES Ref legal event code: PC2A |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 19990218 Year of fee payment: 11 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 19990317 Year of fee payment: 11 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 19990322 Year of fee payment: 11 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: SE Payment date: 19990323 Year of fee payment: 11 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 19990409 Year of fee payment: 11 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20000330 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20000331 Ref country code: ES Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20000331 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20001001 |
|
| EUG | Se: european patent has lapsed |
Ref document number: 89200821.0 |
|
| GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20000330 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20001130 |
|
| NLV4 | Nl: lapsed or anulled due to non-payment of the annual fee |
Effective date: 20001001 |
|
| REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20010103 |
|
| REG | Reference to a national code |
Ref country code: ES Ref legal event code: FD2A Effective date: 20011010 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20050330 |
|
| APAH | Appeal reference modified |
Free format text: ORIGINAL CODE: EPIDOSCREFNO |