EP0323532A1 - Cleaning agent for textile surfaces, especially for the cleaning of textile upholstery - Google Patents
Cleaning agent for textile surfaces, especially for the cleaning of textile upholstery Download PDFInfo
- Publication number
- EP0323532A1 EP0323532A1 EP88100009A EP88100009A EP0323532A1 EP 0323532 A1 EP0323532 A1 EP 0323532A1 EP 88100009 A EP88100009 A EP 88100009A EP 88100009 A EP88100009 A EP 88100009A EP 0323532 A1 EP0323532 A1 EP 0323532A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- approx
- cleaning
- active substance
- textile
- cleaning agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 14
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 9
- 239000004753 textile Substances 0.000 title claims abstract description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002245 particle Substances 0.000 claims abstract description 9
- 239000013543 active substance Substances 0.000 claims abstract description 8
- 239000006260 foam Substances 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims abstract description 4
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 4
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 claims description 4
- 240000000731 Fagus sylvatica Species 0.000 claims description 2
- 235000010099 Fagus sylvatica Nutrition 0.000 claims description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 229920002678 cellulose Polymers 0.000 claims 1
- 239000001913 cellulose Substances 0.000 claims 1
- 229920005610 lignin Polymers 0.000 claims 1
- 239000000401 methanolic extract Substances 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 239000003380 propellant Substances 0.000 abstract description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 1
- 239000004202 carbamide Substances 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- DNEHKUCSURWDGO-UHFFFAOYSA-N aluminum sodium Chemical compound [Na].[Al] DNEHKUCSURWDGO-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 3
- 239000004639 urea-formaldehyde foam Substances 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000004604 Blowing Agent Substances 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- OKSRBEMKUSZPOX-UHFFFAOYSA-N aluminum;sodium;silicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])([O-])[O-] OKSRBEMKUSZPOX-UHFFFAOYSA-N 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0031—Carpet, upholstery, fur or leather cleansers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0043—For use with aerosol devices
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
Definitions
- the invention relates to a cleaning agent according to the preamble of the main claim.
- the object of the present invention is to construct a generic cleaning agent without sacrificing any advantages in use so that it can be sprayed without a propellant component, for example by spraying with a hand pump as a liquid / air mixture. It was found that if there is a problem here that the actual cleaning effect sodium aluminum silicate is no longer suitable to be distributed sufficiently finely if the previously known blowing agent component is missing. In this case, as has been found, also the difficulty of keeping the sodium-aluminum-silicate in sufficient fine distribution already in the storage can while avoiding settling on the bottom in such an order of magnitude that even shaking does not bring about sufficient dispersion homogeneity as is necessary for spraying with a spray pump.
- the subclaim represents an advantageous further development with regard to the special average values of the cellulose powder to be used.
- composition of the cleaning agent according to the invention is given below in the embodiment found for optimal: 1. Very fine native bleached beech sulfite cellulose powder with the average value specified in claim 2. 5.00% by weight 2nd water 70.65% by weight 3rd Surfactant (Ubatol * VTR 317) 5.00% by weight 4th Defoamer (Baysilon * E) 0.20% by weight 5. Fragrance (Kobofleur * 0/239632) 0.05% by weight 6. Isopropanol 10.00% by weight 7. Basoform * V 500 2.00% by weight 8th. ammonia 0.10% by weight 9. Urea-formaldehyde foam for upholstery snow 7.00% by weight (* registered trademark)
- the residual moisture content of the carrier materials should preferably be less than 10 percent by weight.
- the moisture determined must be deducted from the water content of the recipe when the product is manufactured.
- the density of the urea-formaldehyde foam before comminution (dry) is in the range of 50 plus / minus 2.5 kg per cbm, measured on the block.
- the bulk density of the foam is preferably in the range of 150 plus / minus 20 g / l.
- the bulk density of the cellulose powder is between 240 and 280 gr / l.
- the grain spectrum of the urea-formaldehyde foam is optimal as follows: 100% smaller 0.125 mm 90% smaller 0.071 mm
- the grain spectrum of the cellus brine powder can range from 0.05 mm to 0.001 mm, average particle size at 20 my.
- the pH value of the cleaning active substance must be 7-9. This is achieved by buffering using the ammonia component.
- the density of the cleaning active substance at 20 degrees C should be about 1.031 plus / minus 0.005 gr / cm3.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Die Erfindung betrifft ein Reinigungsmittel gemäß Gattungsbegriff des Hauptanspruches.The invention relates to a cleaning agent according to the preamble of the main claim.
Entsprechende Mittel sind vorbekannt durch die EP-PS 086 968. Nachteilig an diesen Lösungen ist gemäß jüngeren Erkenntnissen die für die Versprühbarkeit notwendige Treibmittelkomponente. Vorteilhaft an dieser vorbekannten Lösung ist andererseits die optimale Eignung des Reinigungsmittels, z.B. mit Hilfe eines Staubsaugers oder dergleichen nach Vollzug der Reinigungswirkung von der textilen Fläche wieder entfernt zu werden, was bei dem vorbekannten Mittel daraus resultiert, daß die dort im Reinigungsmittel enthaltenen Harnstoff-Formaldehyd-Harz-Schaumstoffteilchen der entsprechenden Gattung Korngröße usw. Über einen gewissen "Huckepack-Effekt- dafür sorgen, daß man auch das vordergründig ausschließlich die Reinigung vollziehende Natrium-Aluminiumsilikat mit dem Staubsauger (oder dergleichen) entfernen kann, und zwar deshalb, weil sich diese Aluminium-Silikat-Partikelchen an die äußerst leicht, Z.B. im Luftstrom aufzunehmenden Harnstoff-Formaldehyd-Harz-Schaumstoffteilchen anlagern.Corresponding agents are already known from EP-PS 086 968. According to recent knowledge, the disadvantage of these solutions is the propellant component necessary for sprayability. Another advantage of this known solution is the optimal suitability of the cleaning agent, e.g. with the help of a vacuum cleaner or the like to be removed from the textile surface after completion of the cleaning action, which in the case of the known agent results from the fact that the urea-formaldehyde resin foam particles of the corresponding genus therein contained in the cleaning agent, etc. Over a certain " Piggyback effect - ensure that the sodium aluminum silicate, which is primarily used for cleaning, can also be removed with a vacuum cleaner (or the like), because these aluminum silicate particles adhere to the extremely easy, for example, airflow Add urea-formaldehyde resin foam particles.
Aufgabe der vorliegenden Erfindung ist es, ein gattungsgemäßes Reinigungsmittel ohne Einbuße an Verwendungsvorteilen so aufzubauen, daß es unter Verzicht auf eine Treibmittelkomponente versprühbar ist, bspw. durch Versprühen mittels einer Handpumpe als Flüssigkeits/Luftgemisch. Dabei wurde gefunden, daß sich in sofern hier eine Problemstellung ergibt, als daß den eigentlichen Reinigungseffekt vollziehende Natrium-Aluminium-Silikat dann nicht mehr geeignet ist, genügend fein verteilt zu werden, wenn die vorbekannte Treibmittelkomponente fehlt. In diesem Falle tritt, wie gefunden wurde, auch die Schwierigkeit auf, das Natrium-Aluminium-Silikat schon in der Vorratsdose in genügender Feinverteilung zu behalten unter Vermeidung eines bodenseitigen Absetzens in derartiger Größenordnung, daß selbst ein Schütteln keine so ausreichende Dispersionshomogenität bringt, wie sie für das Versprühen mit einer Spraypumpe notwendig ist.The object of the present invention is to construct a generic cleaning agent without sacrificing any advantages in use so that it can be sprayed without a propellant component, for example by spraying with a hand pump as a liquid / air mixture. It was found that if there is a problem here that the actual cleaning effect sodium aluminum silicate is no longer suitable to be distributed sufficiently finely if the previously known blowing agent component is missing. In this case, as has been found, also the difficulty of keeping the sodium-aluminum-silicate in sufficient fine distribution already in the storage can while avoiding settling on the bottom in such an order of magnitude that even shaking does not bring about sufficient dispersion homogeneity as is necessary for spraying with a spray pump.
Gelöst ist die erwähnte Aufgabenstellung durch die im Kennzeichen des Hauptanspruches angegebene Auswahl eines Cellulose-Pulvers der Korngröße kleiner 50 My als Reinigungswirksubstanz.The above-mentioned problem is solved by the selection of a cellulose powder with a grain size of less than 50 microns as the cleaning active substance, as indicated in the characterizing part of the main claim.
Es wurde gefunden, daß bei Auswahl dieses Cellulose Pulver als Ersatz für das beim Stand der Technik verwendete Natrium-Aluminium-Silikat einerseits die Versprühbarkeit mittels einer normalen Pumpe, gegebenenfalls Handpumpe, als Flüssigkeitsluftgemisch möglich ist, andererseits aber auch bezüglich dieses Cellulosepulvers der gleiche im Stand der Technik die erheblichen Vorteile bringende "Anlagerungs-Huckepack-Effekt" zum Harnstoff-Formaldehyd-Harz-Schaumstoffteilchen stattfindet. Sowohl die gleichmäßige Verteilung auf dem textilen Reinigungsobjekt als auch das spätere Entfernen Z.B. mittels eines Staubsaugers, sind also in gleichem Maße optiomal möglich, andererseits findet trotz Fehlen der Treibmittelkomponente auch kein so weitgehendes Absetzen in der Vorratsdose statt, daß selbst nach längerem Lagern nicht ein kurzzeitiges Schütteln die notwendige Homogenität der gesamten zu versprühenden Dispersion bringt.It has been found that when this cellulose powder is selected as a replacement for the sodium aluminum silicate used in the prior art, on the one hand sprayability by means of a normal pump, if appropriate a hand pump, as a liquid / air mixture is possible, but on the other hand the same in the state with regard to this cellulose powder the technology brings the significant advantages "attachment piggyback effect" to the urea-formaldehyde resin foam particles. Both the even distribution on the textile cleaning object and the subsequent removal e.g. by means of a vacuum cleaner, are equally possible to the same extent, on the other hand, despite the absence of the propellant component, there is no such extensive settling in the storage container that even after prolonged storage, brief shaking does not bring the necessary homogeneity of the entire dispersion to be sprayed.
Der Unteranspruch stellt eine vorteilhafte Weiterbildung dar im Hinblick auf die speziellen Durchschnittswerte des zu verwendenden Cellulosepulvers.The subclaim represents an advantageous further development with regard to the special average values of the cellulose powder to be used.
Nachstehend ist die Zusammensetzung des erfindungsgemäßen Reinigungsmittels in der für optimal gefundenen Ausführungsform angegeben:
Die Restfeuchtigkeit der Trägermaterialien soll vorzugsweise kleiner 10 Gewichtsprozent betragen. Die ermittelte Feuchtigkeit ist bei der Herstellung des Produktes vom Wassergehalt der Rezeptur abzuziehen.The residual moisture content of the carrier materials should preferably be less than 10 percent by weight. The moisture determined must be deducted from the water content of the recipe when the product is manufactured.
Das Raumgewicht des Harnstoff-Formaldehyd-Schaumstoffes liegt vor der Zerkleinerung (trocken) im Bereich von 50 plus/minus 2,5 kg pro cbm, am Block gemessen. Das Schüttgewicht des Schaumstoffes liegt vorzugsweise im Bereich von 150 plus/minus 20 g/l. Das Schüttgewicht des Cellulosepulvers liegt zwischen 240 und 280 gr/l. Das Kornspektrum des Harnstoff-Formaldehyd-Schaumes ist optimal wie folgt:
Das Kornspektrum des Cellusolepulvers kann etwa von 0,05 mm bis 0,001 mm reichen, mittlere Teilchengröße bei 20 My. Der ph-Wert der Reinigungs-Wirksubstanz muß bei 7 - 9 liegen. Erreicht wird dieses durch Pufferung mittels der Ammoniak-Komponente. Die Dichte der Reinigungswirkstubstanz bei 20 Grad C soll etwa 1,031 plus/minus 0,005 gr/cm3 betragen.The grain spectrum of the cellus brine powder can range from 0.05 mm to 0.001 mm, average particle size at 20 my. The pH value of the cleaning active substance must be 7-9. This is achieved by buffering using the ammonia component. The density of the cleaning active substance at 20 degrees C should be about 1.031 plus / minus 0.005 gr / cm3.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP88100009A EP0323532A1 (en) | 1988-01-04 | 1988-01-04 | Cleaning agent for textile surfaces, especially for the cleaning of textile upholstery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP88100009A EP0323532A1 (en) | 1988-01-04 | 1988-01-04 | Cleaning agent for textile surfaces, especially for the cleaning of textile upholstery |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP0323532A1 true EP0323532A1 (en) | 1989-07-12 |
Family
ID=8198623
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP88100009A Withdrawn EP0323532A1 (en) | 1988-01-04 | 1988-01-04 | Cleaning agent for textile surfaces, especially for the cleaning of textile upholstery |
Country Status (1)
| Country | Link |
|---|---|
| EP (1) | EP0323532A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2253364A3 (en) * | 2009-05-18 | 2011-04-06 | Wacker Chemie AG | Silicone antifoam particles |
| WO2015150124A1 (en) * | 2014-03-31 | 2015-10-08 | Henkel Ag & Co. Kgaa | Liquid detergent containing polymers for increasing the fragrance performance |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2732011A1 (en) * | 1977-07-15 | 1979-02-01 | Vorwerk Co Interholding | CLEANING AGENT FOR TEXTILE SURFACES BASED ON UREA-FORMALDEHYDE RESIN FOAM |
| GB2112013A (en) * | 1981-10-16 | 1983-07-13 | Fuji Kasei Co Ltd | Powdered cleaning composition |
| EP0086968A1 (en) * | 1982-02-20 | 1983-08-31 | Vorwerk & Co. Interholding GmbH | Aerosol cleaning agent |
| EP0178566A2 (en) * | 1984-10-13 | 1986-04-23 | Henkel Kommanditgesellschaft auf Aktien | Carpet-cleaning composition |
-
1988
- 1988-01-04 EP EP88100009A patent/EP0323532A1/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2732011A1 (en) * | 1977-07-15 | 1979-02-01 | Vorwerk Co Interholding | CLEANING AGENT FOR TEXTILE SURFACES BASED ON UREA-FORMALDEHYDE RESIN FOAM |
| GB2112013A (en) * | 1981-10-16 | 1983-07-13 | Fuji Kasei Co Ltd | Powdered cleaning composition |
| EP0086968A1 (en) * | 1982-02-20 | 1983-08-31 | Vorwerk & Co. Interholding GmbH | Aerosol cleaning agent |
| EP0178566A2 (en) * | 1984-10-13 | 1986-04-23 | Henkel Kommanditgesellschaft auf Aktien | Carpet-cleaning composition |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2253364A3 (en) * | 2009-05-18 | 2011-04-06 | Wacker Chemie AG | Silicone antifoam particles |
| US8461221B2 (en) | 2009-05-18 | 2013-06-11 | Wacker Chemie Ag | Silicone antifoam particles |
| WO2015150124A1 (en) * | 2014-03-31 | 2015-10-08 | Henkel Ag & Co. Kgaa | Liquid detergent containing polymers for increasing the fragrance performance |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| 17P | Request for examination filed |
Effective date: 19890403 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH DE ES FR GB GR IT LI LU NL SE |
|
| 17Q | First examination report despatched |
Effective date: 19901030 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN WITHDRAWN |
|
| 18W | Application withdrawn |
Withdrawal date: 19910708 |
|
| R18W | Application withdrawn (corrected) |
Effective date: 19910708 |