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EP0394324A1 - o-CARBOMETHOXYSULFONYLUREE HERBICIDE - Google Patents

o-CARBOMETHOXYSULFONYLUREE HERBICIDE

Info

Publication number
EP0394324A1
EP0394324A1 EP89900719A EP89900719A EP0394324A1 EP 0394324 A1 EP0394324 A1 EP 0394324A1 EP 89900719 A EP89900719 A EP 89900719A EP 89900719 A EP89900719 A EP 89900719A EP 0394324 A1 EP0394324 A1 EP 0394324A1
Authority
EP
European Patent Office
Prior art keywords
methyl
amino
iii
methoxy
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP89900719A
Other languages
German (de)
English (en)
Inventor
Siew Hoong Chang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of EP0394324A1 publication Critical patent/EP0394324A1/fr
Pending legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals

Definitions

  • This invention pertains to the use of the compound of Formula I and its agriculturally suitable salts for broad spectrum weed control in plantation crops.
  • the compound is methyl 2-[H[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]-sulfonyl]benzoate.
  • Useful formulations of the compound of Formula I can be prepared in conventional ways. They include dusts, granules, pellets, solutions, suspensions, emulsions, wettable powders, emulsifiable concentrates and the like. Many of these may be applied directly.
  • Sprayable formulations can be extended in suitable media and used at spray volumes of from a few liters to several hundred liters per hectare.
  • High strength compositions are primarily used as intermediates for further formulation.
  • the formulations broadly, contain about 0.1% to 99% by weight of active ingredient(s) and at least one of (a) about 0.1% to 20% surfactant(s) and (b) about 1% to 99.9% solid or liquid diluent(s). More specifically, they will contain these ingredients in the following approximate proportions:
  • Active ingredient plus at least one of a Surfactant or a Diluent equals 100 weight percent.
  • Lower or higher levels of active ingredient can, of course, be present depending on the intended use and the physical properties of the compound. Higher ratios of surfactant to active ingredient are sometimes desirable, and are achieved by incorporation into the formulation or by tank mixing.
  • Typical solid diluents are described in Watkins, et al., "Handbook of Insecticide Dust Diluents and Carriers", 2nd Ed * , Dorland Books, Caldwell, New Jersey, but other solids, either mined or manufactured, may be used. The more absorptive diluents are preferred for wettable powders and the denser ones for dusts.
  • Typical liquid diluents and solvents are described in Marsden, “Solvents Guide,” 2nd Ed., Interscience, New York, 1950. Solubility under 0.1% is preferred for suspension concentrates; solution concentrates are preferably stable against phase separation at 0oC.
  • compositions are well known. Solutions are prepared by simply mixing the ingredients. Fine solid compositions are made by blending and, usually, grinding as in a hammer or fluid energy mill. Suspensions are prepared by wet milling (see, for example, Littler, U.S. Patent 3,060,084). Granules and pellets may be made by spraying the active material upon preformed granular carriers or by agglomeration techniques. See
  • the ingredients are blended, coarsely hammermilled and then air-milled to produce particles essentially all below 10 microns in diameter.
  • the product is reblended before packaging.
  • the ingredients are blended, hammer-milled and then moistened with about 12% water.
  • the mixture is extruded as cylinders about 3 mm diameter which are cut to produce pellets about 3 mm long. These may be used directly after drying, or the dried pellets may be crushed to pass a U.S.S. No. 20 sieve (0.84 mm openings).
  • the granules held on a U.S.S. No. 40 sieve (0.42 mm openings) may be packaged for use and the fines recycled.
  • Example 6 The active ingredient is dissolved in the solvent and the solution is sprayed upon dedusted granules in a double cone blender. After spraying of the solution has been completed, the blender is allowed to run for a short period and then the granules are packaged.
  • Example 6 The active ingredient is dissolved in the solvent and the solution is sprayed upon dedusted granules in a double cone blender. After spraying of the solution has been completed, the blender is allowed to run for a short period and then the granules are packaged.
  • Methyl 2-[[[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)- amino]carbonyl]amino]sulfonyl]benzoate 40% polyacrylic acid thickener 0.3% dodecylphenol polyethylene glycol ether 0.5% disodium phosphate 1% monosodium phosphate 0.5% polyvinyl alcohol 1.0% water 56.7%
  • the ingredients are blended and ground together in a sand mill to produce particles essentially all under 5 microns in size.
  • the ingredients are combined and ground together in a sand mill to produce particles essentially all below 5 microns.
  • the product can be used directly, extended with oils, or emulsified in water.
  • the ingredients are blended and ground in a hammer-mill to produce a material essentially all passing a U.S.S. No. 50 screen (0.3 mm opening).
  • the concentrate may be formulated further if necessary.
  • the ingredients are thoroughly blended, coarsely hammer-milled and then air-milled to produce particles essentially all below 10 microns in size.
  • the material is reblended and then packaged.
  • the active ingredient is blended with attapulgite and then passed through a hammer-mill to produce particles substantially all below 200 microns.
  • the ground concentrate is then blended with powdered pyrophyllite until homogeneous.
  • the compound of this invention can be specially formulated with diluents and/or carriers and/or other pesticides for application to plantation crops.
  • the following list exemplifies some of the herbicides suitable for use in mixtures.
  • Common Name Chemical Name dalapon 2,2-dichloropropionic acid diuron 3-(3,4-dichlorophenyl)-1,1-dimethylurea
  • 2,4-DB 4-(2,4-dichlorophenoxy) butyric acid imazapyr- 2-(4-isopropyl-4-methyl-5-oxo-2-imida ⁇ isopropyl- zolin-2-yl)nicotinie acid with iso ⁇ ammonium propyl amine (1:1) picloram 4-amino-3,5,6-trichloropicolinic acid
  • the compound employed in the method of the present invention is an active herbicide for selective broadleaf and grass weed control with safety to plantation crops such as coffee, cocoa, oil palm, rubber, banana, citrus and certain conifers.
  • Compound I can be applied as a preemergence or postemergence treatment using techniques of banding, directed sprays or broadcast applications.
  • the compound of this invention is used at 0.5 to 500 g/ha with a preferred rate range of 1 to 250 g/ha rate.
  • One skilled in the art can select the proper rates for a given situation.
  • the compound of this invention may be used in combination with other pesticides. It is particularly useful in combination with broadleaf herbicides used in plantation crops including: triazine, triazole, uracil, urea, amide, carbamate, bipyridylium, phenoxys, sulfonylurea and imidazolinone types.
  • broadleaf herbicides used in plantation crops including: triazine, triazole, uracil, urea, amide, carbamate, bipyridylium, phenoxys, sulfonylurea and imidazolinone types.
  • the preferred mixture for use in plantation crops includes glyphosate and its agriculturally suitable salts.
  • Test A The herbicidal properties of the subject compound were discovered in field tests conducted as described below. Test A
  • the weed species Calopogonium caerulium (A), Mikania micrantha (B) and Pagpgl ⁇ m coniuoatum (C) ranged in height from 10-20 cm up to mature plants and were sprayed with Compound I or its mixtures with Compounds II and III, dissolved in a nonphytotoxic solvent containing a surfactant.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Un composé de méthyl 2-[[[[(4-méthoxy-6-méthyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]benzoate présente une forte activité herbicide et est particulièrement utile pour éliminer les mauvaises herbes dans des cultures agricoles.
EP89900719A 1987-11-25 1988-11-23 o-CARBOMETHOXYSULFONYLUREE HERBICIDE Pending EP0394324A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12530287A 1987-11-25 1987-11-25
US125302 1987-11-25

Publications (1)

Publication Number Publication Date
EP0394324A1 true EP0394324A1 (fr) 1990-10-31

Family

ID=22419087

Family Applications (1)

Application Number Title Priority Date Filing Date
EP89900719A Pending EP0394324A1 (fr) 1987-11-25 1988-11-23 o-CARBOMETHOXYSULFONYLUREE HERBICIDE

Country Status (7)

Country Link
EP (1) EP0394324A1 (fr)
JP (1) JPH03501479A (fr)
AU (1) AU613136B2 (fr)
BR (1) BR8807812A (fr)
OA (1) OA09626A (fr)
WO (1) WO1989004606A1 (fr)
ZA (1) ZA888856B (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5599769A (en) * 1990-11-13 1997-02-04 Hoechst Aktiengesellschaft Synergistic herbicidal compositions comprising glyphosate or glufosinate in combination with a sulfonylurea herbicide
TW361993B (en) * 1996-02-02 1999-06-21 Nissan Chemical Ind Ltd Herbicidal composition
JP3270819B2 (ja) * 1997-02-13 2002-04-02 北興化学工業株式会社 湛水下水田の直接散布用水性懸濁製剤
CN114403140A (zh) * 2022-01-20 2022-04-29 上海启赟新材料有限公司 一种增稠稳定剂及其制备农药油悬浮剂的方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US438113A (en) * 1890-10-07 Island
DE2419737C3 (de) * 1974-04-24 1978-07-20 Licentia Patent-Verwaltungs-Gmbh, 6000 Frankfurt Vorrichtung zum Vereinzeln von hintereinander auf einem Band befestigten flachen Gegenständen
US4383113A (en) * 1978-05-30 1983-05-10 E. I. Du Pont De Nemours And Company Agricultural sulfonamides
DE2909834A1 (de) * 1979-03-13 1980-09-18 Gao Ges Automation Org Verpackungselement fuer blattgut
DE2926340A1 (de) * 1979-06-29 1981-02-05 Sia Schweizer Schmirgel & Schl Anordnung von schleifblaettern auf unterlagen und dispenser zur aufnahme und abgabe derartig angeordneter schleifblaetter
US4379717A (en) * 1981-02-13 1983-04-12 E. I. Du Pont De Nemours And Company Method of controlling weeds in conifers

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO8904606A1 *

Also Published As

Publication number Publication date
AU613136B2 (en) 1991-07-25
WO1989004606A1 (fr) 1989-06-01
AU2820389A (en) 1989-06-14
BR8807812A (pt) 1990-09-25
JPH03501479A (ja) 1991-04-04
OA09626A (en) 1993-04-30
ZA888856B (en) 1990-07-25

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