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EP0391650A3 - Catalyst recovery in the production of alcohols - Google Patents

Catalyst recovery in the production of alcohols Download PDF

Info

Publication number
EP0391650A3
EP0391650A3 EP19900303531 EP90303531A EP0391650A3 EP 0391650 A3 EP0391650 A3 EP 0391650A3 EP 19900303531 EP19900303531 EP 19900303531 EP 90303531 A EP90303531 A EP 90303531A EP 0391650 A3 EP0391650 A3 EP 0391650A3
Authority
EP
European Patent Office
Prior art keywords
alcohols
production
catalyst recovery
carbonyls
cobalt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP19900303531
Other languages
German (de)
French (fr)
Other versions
EP0391650A2 (en
Inventor
Mattheus Derk Olijve
Nicolaas Anthony De Munck
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Publication of EP0391650A2 publication Critical patent/EP0391650A2/en
Publication of EP0391650A3 publication Critical patent/EP0391650A3/en
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/403—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4092—Regeneration or reactivation of catalysts containing metals involving a stripping step, with stripping gas or solvent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12C—BEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
    • C12C11/00—Fermentation processes for beer
    • C12C11/02—Pitching yeast
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Food Science & Technology (AREA)
  • Biochemistry (AREA)
  • Zoology (AREA)
  • Mycology (AREA)
  • Inorganic Chemistry (AREA)
  • Microbiology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

Cobalt is recovered from the oil/water mixed reaction product of an oxonation reaction by converting the cobalt in the oil/water product to carbonyls and absorption of the carbonyls in the residue obtained from the upgrading of the heavy fraction of a hydroformylation reaction.
EP19900303531 1989-04-04 1990-04-02 Catalyst recovery in the production of alcohols Withdrawn EP0391650A3 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB898907577A GB8907577D0 (en) 1989-04-04 1989-04-04 Catalyst recovery in the production of alcohols
GB8907577 1989-04-04

Publications (2)

Publication Number Publication Date
EP0391650A2 EP0391650A2 (en) 1990-10-10
EP0391650A3 true EP0391650A3 (en) 1991-02-27

Family

ID=10654438

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19900303531 Withdrawn EP0391650A3 (en) 1989-04-04 1990-04-02 Catalyst recovery in the production of alcohols

Country Status (9)

Country Link
US (1) US5091599A (en)
EP (1) EP0391650A3 (en)
JP (1) JPH0368458A (en)
CN (1) CN1023112C (en)
AR (1) AR246444A1 (en)
AU (1) AU623758B2 (en)
BR (1) BR9001537A (en)
CA (1) CA2013674A1 (en)
GB (1) GB8907577D0 (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5235112A (en) * 1992-05-29 1993-08-10 Exxon Chemical Patents Inc. Stripper-reactor for volatile cobalt recovery
US5237105A (en) * 1992-05-29 1993-08-17 Exxon Chemical Patents Inc. Method for removing hydroformylation catalyst
US5237104A (en) * 1992-05-29 1993-08-17 Exxon Chemical Patents Inc. Cobalt catalyst recovery using heavy olefin absorbent
US5354908A (en) * 1993-07-16 1994-10-11 Exxon Chemical Patents Inc. Method and system for cobalt absorption in a hydroformylation process
US5457240A (en) * 1994-01-10 1995-10-10 Exxon Chemical Patents, Inc. Use of stripper reactor reflux as an initiator for preforming reaction of cobaltous salts to cobalt carbonyls
US5434318A (en) * 1994-03-23 1995-07-18 Exxon Chemical Patents Inc. Reactivation or regeneration of cobalt preformer catalyst for oxo process
US5410090A (en) * 1994-04-08 1995-04-25 Exxon Chemical Patents Inc. Airless cobalt demetalling in the cobalt flash combination catalyst cycle
ES2158507T3 (en) * 1996-09-20 2001-09-01 Basf Ag PROCEDURE FOR HYDROFORMILATION.
GB0706887D0 (en) * 2007-04-10 2007-05-16 Exxonmobil Chem Patents Inc Cobalt recovery from cobalt catalysed hydroformylation reactions
CN102137834B (en) * 2008-08-29 2013-09-25 埃克森美孚化学专利公司 Offgas cleanup in olefin hydroformylation
RU2424224C2 (en) * 2009-10-01 2011-07-20 Общество с ограниченной ответственностью "Оксохимнефть" Method for introduction and reclamation of cobalt during hydroformylation of propylene
WO2015018710A1 (en) * 2013-08-08 2015-02-12 Basf Se Method for removing cobalt deposits in a high-pressure olefin hydroformylation reactor

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3793437A (en) * 1970-09-14 1974-02-19 Daicel Ltd Process for recovering cobalt carbonyl
GB2055371A (en) * 1979-07-20 1981-03-04 Exxon Research Engineering Co Dual demetalling of oxo products with catalyst recycle
US4400299A (en) * 1981-12-23 1983-08-23 Exxon Research & Engineering Co. Oxidative recovery of cobalt oxo catalysts
EP0183546A1 (en) * 1984-11-30 1986-06-04 Exxon Research And Engineering Company Hydroformylation catalyst removal

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2751403A (en) * 1952-12-31 1956-06-19 Exxon Research Engineering Co Catalyst recovery from alcohol synthesis process
DE1271911B (en) * 1964-04-21 1968-07-04 Maschf Augsburg Nuernberg Ag Stripper mechanism for stripping blocks with an additional device for gripping fallen blocks using the mold holding tongs
US3520937A (en) * 1966-04-05 1970-07-21 Basf Ag Processing oxo reaction mixtures
DE2106244A1 (en) * 1971-02-10 1972-08-17
BE787274A (en) * 1971-08-07 1973-02-07 Basf Ag PROCESS FOR PREPARING ALDEHYDES WITH A PREPONDERING LINEAR STRUCTURE
DE2237373C3 (en) * 1972-07-29 1981-12-10 Basf Ag, 6700 Ludwigshafen Process for the production of predominantly straight-chain aldehydes
DE2451473C2 (en) * 1974-10-30 1983-02-10 Basf Ag, 6700 Ludwigshafen Process for the preparation of formylpropylacetates
US4404119A (en) * 1981-12-23 1983-09-13 Exxon Research & Engineering Co. Process for recovery of cobalt oxo catalysts
GB8430226D0 (en) * 1984-11-30 1985-01-09 Exxon Research Engineering Co Hydroformylation of olefins
GB8430223D0 (en) * 1984-11-30 1985-01-09 Exxon Research Engineering Co Hydroformylation of olefins
EP0185477B1 (en) * 1984-11-30 1991-01-16 Exxon Research And Engineering Company Production of ether/ether-alcohol compositions

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3793437A (en) * 1970-09-14 1974-02-19 Daicel Ltd Process for recovering cobalt carbonyl
GB2055371A (en) * 1979-07-20 1981-03-04 Exxon Research Engineering Co Dual demetalling of oxo products with catalyst recycle
US4400299A (en) * 1981-12-23 1983-08-23 Exxon Research & Engineering Co. Oxidative recovery of cobalt oxo catalysts
EP0183546A1 (en) * 1984-11-30 1986-06-04 Exxon Research And Engineering Company Hydroformylation catalyst removal

Also Published As

Publication number Publication date
JPH0368458A (en) 1991-03-25
CN1046293A (en) 1990-10-24
AU5253090A (en) 1990-10-11
GB8907577D0 (en) 1989-05-17
US5091599A (en) 1992-02-25
BR9001537A (en) 1991-04-23
AU623758B2 (en) 1992-05-21
CN1023112C (en) 1993-12-15
EP0391650A2 (en) 1990-10-10
CA2013674A1 (en) 1990-10-04
AR246444A1 (en) 1994-08-31

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