EP0383787A1 - Produit anti-insecte - Google Patents
Produit anti-insecteInfo
- Publication number
- EP0383787A1 EP0383787A1 EP19880908725 EP88908725A EP0383787A1 EP 0383787 A1 EP0383787 A1 EP 0383787A1 EP 19880908725 EP19880908725 EP 19880908725 EP 88908725 A EP88908725 A EP 88908725A EP 0383787 A1 EP0383787 A1 EP 0383787A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- wipe according
- active agent
- solvent
- wax
- indicator dye
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000077 insect repellent Substances 0.000 title claims description 12
- 239000000758 substrate Substances 0.000 claims abstract description 23
- 239000013543 active substance Substances 0.000 claims abstract description 22
- 239000000203 mixture Substances 0.000 claims description 15
- MMOXZBCLCQITDF-UHFFFAOYSA-N N,N-diethyl-m-toluamide Chemical compound CCN(CC)C(=O)C1=CC=CC(C)=C1 MMOXZBCLCQITDF-UHFFFAOYSA-N 0.000 claims description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 239000002904 solvent Substances 0.000 claims description 9
- -1 polyethylene Polymers 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 4
- SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 claims description 4
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 claims description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- 239000004745 nonwoven fabric Substances 0.000 claims description 4
- 229920001155 polypropylene Polymers 0.000 claims description 4
- FHNINJWBTRXEBC-UHFFFAOYSA-N Sudan III Chemical compound OC1=CC=C2C=CC=CC2=C1N=NC(C=C1)=CC=C1N=NC1=CC=CC=C1 FHNINJWBTRXEBC-UHFFFAOYSA-N 0.000 claims description 3
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 claims description 3
- 229960001826 dimethylphthalate Drugs 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 238000011282 treatment Methods 0.000 claims description 3
- 239000002759 woven fabric Substances 0.000 claims description 3
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 claims description 2
- RWLALWYNXFYRGW-UHFFFAOYSA-N 2-Ethyl-1,3-hexanediol Chemical compound CCCC(O)C(CC)CO RWLALWYNXFYRGW-UHFFFAOYSA-N 0.000 claims description 2
- DSKYSDCYIODJPC-UHFFFAOYSA-N 2-butyl-2-ethylpropane-1,3-diol Chemical compound CCCCC(CC)(CO)CO DSKYSDCYIODJPC-UHFFFAOYSA-N 0.000 claims description 2
- AAIBYZBZXNWTPP-UHFFFAOYSA-N 2-phenylcyclohexan-1-ol Chemical compound OC1CCCCC1C1=CC=CC=C1 AAIBYZBZXNWTPP-UHFFFAOYSA-N 0.000 claims description 2
- GUOVYFDMGDEHNM-UHFFFAOYSA-N 4-methyl-2-[(2-methylphenyl)diazenyl]phenol Chemical compound CC1=CC=C(O)C(N=NC=2C(=CC=CC=2)C)=C1 GUOVYFDMGDEHNM-UHFFFAOYSA-N 0.000 claims description 2
- XTJFFFGAUHQWII-UHFFFAOYSA-N Dibutyl adipate Chemical compound CCCCOC(=O)CCCCC(=O)OCCCC XTJFFFGAUHQWII-UHFFFAOYSA-N 0.000 claims description 2
- YUXIBTJKHLUKBD-UHFFFAOYSA-N Dibutyl succinate Chemical compound CCCCOC(=O)CCC(=O)OCCCC YUXIBTJKHLUKBD-UHFFFAOYSA-N 0.000 claims description 2
- NPGIHFRTRXVWOY-UHFFFAOYSA-N Oil red O Chemical compound Cc1ccc(C)c(c1)N=Nc1cc(C)c(cc1C)N=Nc1c(O)ccc2ccccc12 NPGIHFRTRXVWOY-UHFFFAOYSA-N 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims description 2
- YCUVUDODLRLVIC-UHFFFAOYSA-N Sudan black B Chemical compound C1=CC(=C23)NC(C)(C)NC2=CC=CC3=C1N=NC(C1=CC=CC=C11)=CC=C1N=NC1=CC=CC=C1 YCUVUDODLRLVIC-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 239000005667 attractant Substances 0.000 claims description 2
- WURBFLDFSFBTLW-UHFFFAOYSA-N benzil Chemical compound C=1C=CC=CC=1C(=O)C(=O)C1=CC=CC=C1 WURBFLDFSFBTLW-UHFFFAOYSA-N 0.000 claims description 2
- 229960002903 benzyl benzoate Drugs 0.000 claims description 2
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 claims description 2
- 239000003139 biocide Substances 0.000 claims description 2
- 235000000484 citronellol Nutrition 0.000 claims description 2
- 238000005260 corrosion Methods 0.000 claims description 2
- 230000007797 corrosion Effects 0.000 claims description 2
- 239000002537 cosmetic Substances 0.000 claims description 2
- 239000003241 dermatological agent Substances 0.000 claims description 2
- 229940000033 dermatological agent Drugs 0.000 claims description 2
- 229940100539 dibutyl adipate Drugs 0.000 claims description 2
- VGQLNJWOULYVFV-SPJNRGJMSA-N dimethylcarbate Chemical compound C1[C@H]2C=C[C@@H]1[C@H](C(=O)OC)[C@@H]2C(=O)OC VGQLNJWOULYVFV-SPJNRGJMSA-N 0.000 claims description 2
- 229960004118 dimethylcarbate Drugs 0.000 claims description 2
- UKZQEOHHLOYJLY-UHFFFAOYSA-M ethyl eosin Chemical compound [K+].CCOC(=O)C1=CC=CC=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C([O-])=C(Br)C=C21 UKZQEOHHLOYJLY-UHFFFAOYSA-M 0.000 claims description 2
- 239000000417 fungicide Substances 0.000 claims description 2
- 239000004009 herbicide Substances 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 239000003112 inhibitor Substances 0.000 claims description 2
- 239000002917 insecticide Substances 0.000 claims description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- ZWDZJRRQSXLOQR-UHFFFAOYSA-N n-butyl-n-phenylacetamide Chemical compound CCCCN(C(C)=O)C1=CC=CC=C1 ZWDZJRRQSXLOQR-UHFFFAOYSA-N 0.000 claims description 2
- VKWNTWQXVLKCSG-UHFFFAOYSA-N n-ethyl-1-[(4-phenyldiazenylphenyl)diazenyl]naphthalen-2-amine Chemical compound CCNC1=CC=C2C=CC=CC2=C1N=NC(C=C1)=CC=C1N=NC1=CC=CC=C1 VKWNTWQXVLKCSG-UHFFFAOYSA-N 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 229920001451 polypropylene glycol Polymers 0.000 claims description 2
- UZCDZCKZKAMXMC-UHFFFAOYSA-N propyl 4-(diethylamino)-4-oxobutanoate Chemical compound CCCOC(=O)CCC(=O)N(CC)CC UZCDZCKZKAMXMC-UHFFFAOYSA-N 0.000 claims description 2
- TVRGPOFMYCMNRB-UHFFFAOYSA-N quinizarine green ss Chemical compound C1=CC(C)=CC=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=CC=C(C)C=C1 TVRGPOFMYCMNRB-UHFFFAOYSA-N 0.000 claims description 2
- 239000003128 rodenticide Substances 0.000 claims description 2
- 239000002481 rotproofing Substances 0.000 claims description 2
- RCTGMCJBQGBLKT-PAMTUDGESA-N scarlet red Chemical compound CC1=CC=CC=C1\N=N\C(C=C1C)=CC=C1\N=N\C1=C(O)C=CC2=CC=CC=C12 RCTGMCJBQGBLKT-PAMTUDGESA-N 0.000 claims description 2
- 229920002994 synthetic fiber Polymers 0.000 claims description 2
- 230000000063 preceeding effect Effects 0.000 claims 2
- 239000004480 active ingredient Substances 0.000 claims 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 239000004744 fabric Substances 0.000 abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
- 239000001993 wax Substances 0.000 description 14
- 238000009472 formulation Methods 0.000 description 7
- 229920000297 Rayon Polymers 0.000 description 4
- 229960001673 diethyltoluamide Drugs 0.000 description 4
- 241001465754 Metazoa Species 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000002415 cerumenolytic agent Substances 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 235000013365 dairy product Nutrition 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- IITCWRFYJWUUPC-UHFFFAOYSA-N dipropyl pyridine-2,5-dicarboxylate Chemical compound CCCOC(=O)C1=CC=C(C(=O)OCCC)N=C1 IITCWRFYJWUUPC-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229940057838 polyethylene glycol 4000 Drugs 0.000 description 1
- 229940093429 polyethylene glycol 6000 Drugs 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 229940099373 sudan iii Drugs 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0208—Tissues; Wipes; Patches
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/02—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings containing insect repellants
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/45—Colour indicators, e.g. pH- or Redox indicators
Definitions
- the present invention addresses itself to the need to indicate the remaining presence of useful levels of water-insoluble active agents on flexible substrates such as wipes, pads, cloths, sponges, sponge-cloth, mats, clothing, head-bands, mittens, gloves of woven and nonwoven fabrics, other fibrous materials, animal skin products (e.g. leather) and animal furs. Further, the present invention covers such articles comprising a substrate, a water insoluble active agent, and a visual indicator of the continuing presence or conversely of the depletion of said active agent, which may be a chemical substance, mixture or formulation.
- the present invention covers substrates having applied thereto, as active agent, insect repellent compositions which may usefully be transferred to inanimate surfaces, human hair or skin, or animal skin, hair, or fur.
- insect repellent compositions which may usefully be transferred to inanimate surfaces, human hair or skin, or animal skin, hair, or fur.
- the invention is not limited to insect repellent as active agents. Any chemical agent which could usefully be transferred to a surface, to modify the manner in which the surface interacts with its environment could be used for instance insecticides, herbicides, fungicides, rodenticides, biocides, timber treatment agents, rot proofing agents, corrosion inhibitors, cosmetics, dermatological agents, polish, pheromome attractants or combinations thereof.
- a wipe comprising a flexible substrate, to at least a portion of which has been applied a water-insoluble active agent which can be transferred to a surface by wiping and an indicator dye which becomes transferred to the surface along with the active agent, thus giving a visible indication of depletion of the active agent.
- active agent has been applied to the substrate as a first step, and the indicator dye in a subsequent step.
- the indicator dye is preferably applied in conjunction with a substance in which the dye is soluble but in which the active agent is at least partially insoluble. That substance is preferably a wax.
- the indicator dye and the wax are applied in the form of a solution at a temperature above ambient temperature, the solvent being such that the wax is at least partially insoluble in it at ambient temperature. That solvent is preferably more of the active agent that was already applied in the first step.
- a flexible substrate such as a cloth, wipe, sponge pad or other form of substrate, preferably a woven or nonwoven textile or fabric to which has been applied, uniformly or otherwise, an agent comprising an active substantially water insoluble component which component may be in formulation with other materials and may be in aqueous emulsion or dispersion at its time of application to the substrate.
- an indicator system which comprises one or more components which are at least partially insoluble, and preferably are substantially insoluble, in the active component at normal ambient temperatures: along with the dye or pigment, which may be soluble or insoluble in the active component.
- the said indicator is capable of application in a discreet and clearly delineated form, such as stripes, patterns, images or logos, and will maintain this distinct format subsequent to production and throughout the proper storage of the product. However, upon usage of the product the indicator will fade, blur, or otherwise start to disappear as it is transferred to the requisite surface along with the active component, e.g. when an insect repellent wipe is rubbed on the skin.
- flexible substrates used in this invention are preferably woven or nonwoven fabrics composed of natural or synthetic fibres, particularly cellulosic fibres such as viscose, or petrochemical derived polymers such as polyethylene, polypropylene, polyamides, polyesters.
- insect repellent agent is chosen from among those chemicals known to have the relevant properties of safety in use combined with repellent properties.
- the following are examples benzil, benzyl benzoate, 2,3,4,5-bis(butyl-2-ene)-tetrahydrofurfural, butoxypolypropylene glycol, N-butylacetanilide, n-butyl 6,6-dimethyl-5,6-dihydro-1,4-pyrone-2-carboxylate, dibutyl adipate, dibutyl phthalate, di-n-butyl succinate, N,N-diethyl-m-toluamide, dimethyl carbate (cis-dimethyl bicyclo[2.2.1]-5-heptene-2,3-dicarboxylate), dimethyl phthalate, 2-ethyl-2-butyl-1,3-propanediol, 2-ethyl-1,3-hexanediol, di-n
- the insect repellent agent is N,N-diethyl-m-toluamide either alone or in combination with other insect repellent agents.
- This material is preferably but not of necessity applied to the substrate in the form of a simple aqueous emulsion.
- a suitable emulsifier is a linear alcohol mixed ethoxylate propoxylate block copolymer.
- the indicator system is preferably prepared in the form of a liquid made by dissolving a wax in a solvent, which solvent may be the active chemical, e.g. diethyl toluamide, or may be some other solvent.
- the wax may be a natural or synthetic hydrocarbon wax, a wax acid, ester, partially saponified wax, or polyethylene or polypropylene glycol, or a mixture thereof. It is preferred that the wax has a melting point of above 50°C.
- a small amount of a waxsoluble dye such as Waxoline Blue, Solvent Green 3, Solvent Yellow 12, Solvent Red 19, 23, 24, 27 or 45, Solvent Black 3 is added to the wax and co-solvent.
- an insoluble pigment such as Ultramarine may be utilisted.
- Viscose polypropylene nonwoven fabric 50 gram per square metre
- N,N-diethyl-m-toluamide (insect repellent agent) dispersed in water with the aid of a nonionic wetting agent, e.g. linear alcohol ethoxylate
- the impregnant is then applied to the fabric to give a loading ofbetween 2.5 and 50% by weight of Diethyl toluamide, but preferably between 10 and 25%.
- the indicator formulation made up as follows:
- An especially preferred indicator dye formulation would be:
- This indicator formulation is applied in stripes or some other format to the impregnated and dried substrate, such that a proportion of the substrate having been impregnated receives the indicator.
- Example 3 SUBSTRATE Viscose polypropylene nonwoven.
- This formulation is suitable for direct application of the DEET as neat raw material followed by gravure or flexographic printing of the indicator component.
- the ratio of components in..the indicator system may be varied depending on the particular product characteristics required.
- a typical formulation would be 3 PARTS DEET to 1 PART equal proportions of the two waxes, with a final pigment concentration of between 5 and 20% by weight of the indicator composition.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Veterinary Medicine (AREA)
- Textile Engineering (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Biochemistry (AREA)
- Environmental Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Toxicology (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Microbiology (AREA)
- Dermatology (AREA)
- Agronomy & Crop Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Biomedical Technology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
L'invention concerne une pièce de tissu comprenant un substrat souple, sur au moins une partie duquel on a appliqué un agent actif insoluble dans l'eau, et pouvant être transféré sur une surface par frottement, ainsi qu'un colorant indicateur transféré sur la surface en même temps que l'agent actif, donnant ainsi une indication d'épuisement visible de l'agent actif. L'agent actif étant notamment un produit anti-insecte.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8724646 | 1987-10-21 | ||
| GB8724646A GB2211092A (en) | 1987-10-21 | 1987-10-21 | Wipe incorporating an indicator dye |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP0383787A1 true EP0383787A1 (fr) | 1990-08-29 |
Family
ID=10625663
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19880908725 Withdrawn EP0383787A1 (fr) | 1987-10-21 | 1988-10-10 | Produit anti-insecte |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0383787A1 (fr) |
| AU (1) | AU611228B2 (fr) |
| GB (1) | GB2211092A (fr) |
| WO (1) | WO1989003639A1 (fr) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6103644A (en) | 1993-12-22 | 2000-08-15 | Nordico Marketing Development, Inc. | Impregnated matrix and method for making same |
| US6338855B1 (en) | 1996-10-25 | 2002-01-15 | The Procter & Gamble Company | Cleansing articles for skin and/or hair which also deposit skin care actives |
| US5972361A (en) * | 1996-10-25 | 1999-10-26 | The Procter & Gamble Company | Cleansing products |
| CN1146399C (zh) * | 1996-10-25 | 2004-04-21 | 普罗克特和甘保尔公司 | 清洁产品 |
| US6063397A (en) * | 1996-10-25 | 2000-05-16 | The Procter & Gamble Company | Disposable cleansing products for hair and skin |
| US5854145A (en) * | 1997-05-14 | 1998-12-29 | Cortec Corporation | Corrosion inhibitor solution applicator |
| US6132746A (en) * | 1997-05-22 | 2000-10-17 | The Procter & Gamble Company | Cleansing products with improved moisturization |
| US6280757B1 (en) | 1997-05-22 | 2001-08-28 | The Procter & Gamble Company | Cleansing articles for skin or hair |
| US5951991A (en) * | 1997-05-22 | 1999-09-14 | The Procter & Gamble Company | Cleansing products with improved moisturization |
| ES2143372B1 (es) * | 1997-07-10 | 2000-12-01 | Pubill Marcos Guasch | Sistema para el control de la limpieza e higiene en hosteleria, hospitales y otros establecimientos, y prendas y trapos utilizados en dicho sistema. |
| AU748441B2 (en) | 1997-09-05 | 2002-06-06 | Procter & Gamble Company, The | Cleansing and conditioning products for skin or hair with improved deposition of conditioning ingredients |
| KR100481563B1 (ko) * | 1997-09-12 | 2005-04-08 | 더 프록터 앤드 갬블 캄파니 | 피부 또는 모발용 세정 및 컨디셔닝 제품 |
| WO2001048303A2 (fr) | 1999-12-28 | 2001-07-05 | Kimberly-Clark Worldwide, Inc. | Chiffon contenant un agent antimicrobien a liberation controlee |
| EP1241973B1 (fr) | 1999-12-28 | 2007-04-11 | Kimberly-Clark Worldwide, Inc. | Systeme indicateur dependant de l'utilisation pour des articles absorbants |
| CA2393525C (fr) | 1999-12-28 | 2010-09-14 | Kimberly-Clark Worldwide, Inc. | Chiffon antimicrobien a liberation controlee pour surfaces dures |
| AUPQ747900A0 (en) * | 2000-05-12 | 2000-06-08 | Novapharm Research (Australia) Pty Ltd | Biocidal cloth |
| US7115551B2 (en) | 2002-06-07 | 2006-10-03 | The Procter & Gamble Company | Cleansing articles for skin or hair |
| GB0320351D0 (en) * | 2003-08-29 | 2003-10-01 | Yates Donald H | A preparation against flying insects that bite |
| DE102004024199A1 (de) * | 2004-05-13 | 2005-12-01 | Beiersdorf Ag | Kosmetische oder dermatologische getränkte Tücher |
| JP2013503123A (ja) * | 2009-08-26 | 2013-01-31 | ビーエーエスエフ ソシエタス・ヨーロピア | １，３−ジオール類の殺生物剤としての使用 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3818533A (en) * | 1969-07-18 | 1974-06-25 | Alustikin Prod Inc | Treated paper and non-woven material for wiping surfaces and method therefor |
| GB2007096B (en) * | 1977-09-27 | 1982-09-02 | Exterma Germ Prod | Method of indicating the presence of an impregnant |
| US4248597A (en) * | 1978-12-12 | 1981-02-03 | Akzona Incorporated | Time watch or depletion indicator for removable substances |
| JPS6172701A (ja) * | 1984-09-17 | 1986-04-14 | Osaka Seiyaku:Kk | 防虫能表示器兼用防虫材 |
| GB8518736D0 (en) * | 1985-07-24 | 1985-08-29 | Fibre Treatments Ltd | Impregnated substrate |
| GB2180752A (en) * | 1985-09-24 | 1987-04-08 | Tk Ind Supplies | Bactericidal shields for telephone handsets |
-
1987
- 1987-10-21 GB GB8724646A patent/GB2211092A/en not_active Withdrawn
-
1988
- 1988-10-10 WO PCT/GB1988/000841 patent/WO1989003639A1/fr not_active Ceased
- 1988-10-10 EP EP19880908725 patent/EP0383787A1/fr not_active Withdrawn
- 1988-10-10 AU AU25372/88A patent/AU611228B2/en not_active Expired - Fee Related
Non-Patent Citations (1)
| Title |
|---|
| See references of WO8903639A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| WO1989003639A1 (fr) | 1989-05-05 |
| GB8724646D0 (en) | 1987-11-25 |
| GB2211092A (en) | 1989-06-28 |
| AU611228B2 (en) | 1991-06-06 |
| AU2537288A (en) | 1989-05-23 |
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