[go: up one dir, main page]

EP0376954A1 - Procede de fabrication d'un revetement protecteur et/ou decoratif a couches multiples et compositions de revetement delayables dans l'eau - Google Patents

Procede de fabrication d'un revetement protecteur et/ou decoratif a couches multiples et compositions de revetement delayables dans l'eau

Info

Publication number
EP0376954A1
EP0376954A1 EP88905824A EP88905824A EP0376954A1 EP 0376954 A1 EP0376954 A1 EP 0376954A1 EP 88905824 A EP88905824 A EP 88905824A EP 88905824 A EP88905824 A EP 88905824A EP 0376954 A1 EP0376954 A1 EP 0376954A1
Authority
EP
European Patent Office
Prior art keywords
water
component
weight
polymer microparticles
thinnable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP88905824A
Other languages
German (de)
English (en)
Inventor
Bodo Müller
Eric Martin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Farben und Fasern AG
Original Assignee
BASF Lacke und Farben AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF Lacke und Farben AG filed Critical BASF Lacke und Farben AG
Publication of EP0376954A1 publication Critical patent/EP0376954A1/fr
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/52—Two layers
    • B05D7/53—Base coat plus clear coat type
    • B05D7/532—Base coat plus clear coat type the two layers being cured or baked together, i.e. wet on wet
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/06—Polyurethanes from polyesters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02—Emulsion paints including aerosols
    • C09D5/024—Emulsion paints including aerosols characterised by the additives

Definitions

  • the invention relates to a method for producing a multilayer, protective and / or decorative coating on a substrate surface, in which
  • a pseudoplastic and / or thixotropic water-dilutable base coating composition is applied as the base coating composition, this base coating composition comprising water, optionally organic solvents, a water-dilutable binder, crosslinked polymer microparticles with a diameter of 0.01 to 10 ⁇ m, Contains pigment particles and a thickener,
  • Multicoat paint systems are preferably applied by the so-called "base coat / clear coat” process, i.e. 5
  • a pigmented basecoat is pre-painted and after a short flash-off time without a baking step (wet-on-wet process), overcoated with clear coat. Then the base coat and clear coat are baked together.
  • EP-A-38127 discloses a process for the production of multilayer coatings of the base coat / clear coat type, in which aqueous base coating compositions are used which contain stably dispersed crosslinked polymer microparticles and have a pseudoplastic or thixotropic character .
  • EP-A-38127 preferably uses polymer microparticles made from crosslinked polyacrylates.
  • polymer microparticles made from crosslinked polycondensates such as e.g. cross-linked polyester microparticles can be used.
  • the problem underlying the present invention is to provide a new method according to the preamble of the first claim. This new method is intended to overcome or reduce the problems of the prior art described above. 0
  • the base coating composition 0.1 to 4.0% by weight, preferably 1.0 to 2.0% by weight, based on the binder solid, xanthan and 5 to 80 5% by weight, preferably 30 to 70% by weight, particularly preferably 40 to 60% by weight, based on the binder solid, contains crosslinked polymer microparticles, the crosslinked polymer microparticles being obtainable, by 0
  • the component (B) from one or more optionally blocked polyisocyanate compound (s) l and the component (A) and / or (B) has a sufficient number of ionic groups to form a stable dispersion and at least part of the component (A) and / or (B) has more than two hydroxyl groups - or possibly blocked isocyanate groups per molecule and
  • the advantages achieved by the invention are to be seen essentially in the fact that the crosslinked polymer microparticles used according to the invention are simple. - Can be adjusted to the special requirements of the aqueous base coating compositions and that no incompatibility symptoms occur when incorporated into aqueous base coating compositions, particularly those which contain a mixture of a melamine resin and a polyester resin as a binder.
  • xanthan as a thickening agent surprisingly does not adversely affect the sensitivity to moisture, the adhesion properties or the metallic effect of the films obtained. Rather, the use of xanthan allows the application of basecoats
  • the first step of the method according to the invention consists in the application of a pseudoplastic and / or thixotropic, water-dilutable base coating composition.
  • the base coating compositions used according to the invention contain water as liquid diluent, which may also contain organic solvents.
  • the proportion of organic solvents is kept as low as possible.
  • solvents which may be present in water are heterocyclic, aliphatic or aromatic hydrocarbons, mono- or polyhydric alcohols, ethers, glycol ethers, esters, amides and ketones, e.g. N-methylpyrrolidone, dirnethylformamide, toluene, xylene,
  • the base coating compositions used according to the invention can in principle contain all water-thinnable binders and mixtures of these binders suitable for the purpose in question.
  • Water-thinnable binders are understood to mean all binder constituents excluding the crosslinked polymer microparticles.
  • the solid binder refers to the sum of water-thinnable binders and crosslinked polymer microparticles.
  • water-dilutable binders examples include water-dilutable melamine resins, water-dilutable polyester resins, water-dilutable polyacrylate resins, water-dilutable polyethers and water-dilutable polyurethane resins.
  • Water-dilutable melamine resins are known per se and are used on a larger scale. These are generally etherified melamine-formaldehyde condensation products. Apart from the degree of condensation, which should be as low as possible, their water solubility depends on the etherification component, only the lowest members of the alkanol or ethylene glycol monoether series giving water-soluble condensates. Methanol etherified melamine resins are of greatest importance. If solubilizers are used, butanol-etherified melamine resins can also be dispersed in the aqueous phase.
  • Transetherification products of highly etherified formaldehyde condensates with oxycarboxylic acids are water-soluble via their carboxyl group after neutralization and can be contained in the base coating compositions used according to the invention.
  • Hydroxyl group-bearing polyester resins are preferably used as water-dilutable polyester resins.
  • the polyester resins used according to the invention preferably contain carboxylate groups as the olubilizing groups
  • Polyester resins of the type described above are known per se and can be prepared by reacting polyvalent polyols with polycarboxylic acids or polycarbonic anhydrides. Polyester resins with an average functionality per molecule of 2.5 to 10 and with an average degree of condensation per molecule of 10 to 25 are preferably used. The degree of condensation indicates the sum of the monomer units in the chain of the polymer molecule.
  • the polyester resins used preferably have an acid number of at most 30 and a hydroxyl number of at most 150.
  • Preferred acid components for the synthesis of the polyester resins are aliphatic, cycloaliphatic saturated or unsaturated and / or aromatic polybasic carboxylic acids, preferably di-, tri- and tetracarboxylic acids with 2 to 14, preferably 4 to 12 C atoms per molecule or their derivatives capable of esterification (for example anhydrides or esters), for example Phthalic anhydride, isophthalic acid, terephthalic acid, tetrahydro- and hexahydrophthalic anhydride, endomethylene tetrahydrophthalic acid, succinic acid, glutaric acid, sebacic acid, azelaic acid, trimellitic acid and trimellitic acid anhydride, pyromellitic acid and maleic acid fumaric acid anhydride.
  • Phthalic anhydride is the most common acid component.
  • the polyester resins should not contain more than 20 mol%, based on the condensed-in polycarboxylic acid residues,
  • Preferred polyols for the synthesis of the polyesters are aliphatic, cycloaliphatic and / or araliphatic alcohols having 1 to 15, preferably 2 to 6, carbon atoms and 1 to 6, preferably 1 to 4, OH-bonded OH atoms Groups per molecule, for example glycols such as ethylene glycol, 1,2-and 1,3-propanediol, 1,2-butanediol, 1,3 and 1,4, 2-ethylpropanediol-1, 3,2-ethylhexanediol-1, 3, neopentyl glycol, 2,2-trimethylpentanediol-1, 3, hexanediol-1,6, cyclohexanediol-1, and -1,4, 1,2- and 1,4-bis (hyd ⁇ o - methyl-) c clohexane, adipic acid bis (ethylene glycol ester); Ether alcohols such as di- and tri
  • polyester resins which can be used according to the invention can also be modified with monocarboxylic acid and monoalcohols.
  • monocarboxylic acids are saturated or unsaturated fatty acids, benzoic acid, p-tert-butylbenzoic acid, hexahydrobenzoic acid and abietic acid.
  • monoalcohols examples include methanol, propanol, cyclohexanol, 2-ethylhexanol and benzyl alcohol.
  • Preferred polyacrylate resins are obtained by copolymerizing vinyl or vinylidene monomers, such as, for example, styrene, ⁇ -methylstyrene, o- or p-chlorostyrene, o-, m- or p-methylstyrene, p-tert-butylstyrene, (Meth) acrylic acid, (meth) acrylonitrile, acrylic and methacrylic acid alkyl esters with 1 to 8 carbon atoms in the alcohol component, for example ethyl acrylate, methyl acrylate, n- or iso-propyl acrylate, n-butyl acrylate, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, isooctyl acrylate, tert-butyl acrylate, methyl methacrylate, ethyl methacrylate, n- or iso-propyl me
  • (Meth) acrylic acid amide vinyl esters of alkane monocarboxylic acids with 2 to 5 carbon atoms such as vinyl acetate or vinyl propionate or mixtures of the monomers mentioned, N-methoxymethyl (eth) acrylic acid amide.
  • Preferred monomers are styrene and (meth) acrylic acid alkyl esters with 1 to 8 carbon atoms in the alcohol component, the esterification product of fatty acid and hydroxyalkyl acrylates and mixtures thereof.
  • Linear or branched poly (oxypropylene) glycols with an average molecular weight of 400 to 1000, preferably 600 to 900, are mentioned as examples of water-dilutable polyethers.
  • Preferred water-dilutable polyurethane resins are the polyurethane resins disclosed in DE-0S-3545618 and US Pat. No. 4,423,179.
  • Base coating compositions which contain, as water-dilutable binder, a mixture of a water-dilutable melamine resin and a water-dilutable polyester resin are very particularly preferably used.
  • Particularly preferred basecoat compositions are obtained when the proportion of melamine resin, based on the proportion of the crosslinked polymer used in the invention, 1 to 80 wt .-%, preferably 30 to 70 wt .-%, by weight and when the weight ratio Melamin ⁇ resin to polyester resin Is 2: 1 to 1: 4.
  • the base coating compositions used according to the invention can also contain blocked polyisocyanates as crosslinking agents.
  • the base coating compositions used in the process according to the invention preferably contain 2 to 15% by weight, particularly preferably 5 to 13% by weight, of water-dilutable binder constituents.
  • Water-thinnable binder components are understood to mean all binder components except the crosslinked polymer microparticles used according to the invention.
  • the base coating compositions used in the process according to the invention contain crosslinked polymer microparticles which can be obtained by
  • component (B) consists of one or more optionally blocked polyisocyanate compound (s) and component (A) and / or (B) has a sufficient number of ionic groups to form a stable dispersion and at least one Part of component (A) and / or (B) contains more than two hydroxyl or optionally blocked isocyanate groups per molecule and
  • the dispersion thus obtained is then heated to such an extent that components (A) and (B) are converted into crosslinked polymer microparticles.
  • the polymer microparticles used according to the invention preferably have a diameter which is less than 1 ⁇ m, particularly preferably between 0.05 and 0.2 ⁇ m.
  • the particle size of the crosslinked polymer microparticles can be influenced by simple means (for example via the amount of the ionic groups contained in the starting component (A) or (B)).
  • the network structure of the particles can be influenced by the targeted incorporation of certain chain segments.
  • polymer microparticles can be optimally matched to the components contained in the base coating compositions, in particular the binder components, using simple means. This advantage is particularly important for base coating compositions that
  • microparticles of acrylic polymers it has proven to be advantageous to also add microparticles of acrylic polymers to the coating compositions according to the invention in addition to the polymer microparticles described above.
  • the first step in the preparation of the polymer microparticles used according to the invention consists in providing a mixture of components (A) and (B), care being taken that component (A) and / or
  • component (B) over a sufficient number of ionic groups to form a stable dispersion preferably Has carboxylate groups and which contains at least part of component (A) and / or (B) more than two hydroxyl or isocyanate groups per molecule.
  • stable dispersion means dispersions in which the dispersed particles coagulate to a larger extent only after application and release of the dispersing medium.
  • Groups other stabilizing groups e.g. Polyoxyalkylene groups to be incorporated into component (A) and / or (B).
  • anionic stabilization preferably via carboxylate groups, being preferred.
  • the average person skilled in the art can determine the optimum concentration of ionic groups in component (A) and / or (B) for the formation of a stable dispersion with the aid of simple routine examinations.
  • concentration of ionic groups generally required to form a stable dispersion is between 0.01 and 2 milliequivalents per gram of component (A) and / or (B).
  • the groups capable of salt formation are neutralized with the aid of bases or acids, preferably shortly before the dispersion or during the dispersion of the mixture consisting of components (A) and (B) in the aqueous dispersion medium.
  • Particularly suitable groups for salt formation are carboxyl and sul on acid groups. These groups are preferably neutralized with a tertiary amine.
  • the content of ionic groups or the degree of neutralization of the groups suitable for salt formation is an important parameter by means of which the size of the crosslinked polymer microparticles that are formed can be controlled.
  • Component (A) consists of one or more polyester polyol containing at least two hydroxyl groups.
  • polyester polyols are, in particular, the reaction products of polyvalent polyols with polycarboxylic acids or polycarboxylic acid anhydrides which are known per se in polyurethane chemistry.
  • Suitable polyols for the production of the polyester polyols are e.g. Ethylene glycol, propanediol 1,2 and 1,3, butanediol 1,3 and 1,4, the isomeric pentanediols, hexanediols or octanediols, e.g.
  • the polycarboxylic acids suitable for the production of the polyester polyols consist primarily of low molecular weight polycarboxylic acids or their anhydrides with 2 to 18 carbon atoms in the molecule.
  • Di- and tricarboxylic acids are preferably used.
  • Suitable acids are, for example, oxalic acid, succinic acid, fumaric acid, phthalic acid, isophthalic acid, terephthalic acid, tetrahydrophthalic acid, hexahydrophthalic acid, adipic acid,fuginic acid, sebacic acid, maleic acid, glutaric acid, Hexachloroheptic dicarboxylic acid, tetrachlorophthalic acid and trimellitic acid.
  • these acids their anhydrides, if they exist, can also be used.
  • Polyester polyols which have been prepared by polymerizing lactones can also be used as component (A).
  • polyester polyols the molecules of which each carry on average one carboxylate group and at least two, preferably more than two, hydroxyl groups.
  • (B) components which are free from ionic groups are preferably used.
  • the (A) component is preferably selected so that it can be stably dispersed alone in the aqueous medium.
  • the connections between the structure of polyester polyols (acid number, molecular weight %) and their dispersing behavior are well known to the average person skilled in the art, and with the aid of a few less preliminary tests he can select the polyester polyol component which is optimal for solving the respective problem.
  • polyester polyols used as the (A) component It is also possible to add further compounds which contain groups reactive toward isocyanate groups to the polyester polyols used as the (A) component. Care must be taken care that the mixture formed from the components in the aqueous medium remains stably dispersible and that having the gewünsch ⁇ te size of these dispersants L sion formed crosslinked polymer.
  • polyisocyanate compounds are used whose isocyanate groups are at least partially present in blocked form.
  • Examples include: trimethylene diisocyanate, tetramethylene diisocyanate, pentamethylene diisocyanate, hexamethylene diisocyanate, ethylethylene diisocyanate, 2,3-dimethylethylene diisocyanate, 1-methyltrimethylene diisocyanate, 1,3-cyclopentylene diisocyanate, 1,4-cyclohexylene diisocyanate, 1,2-cyclo - Hexylene diisocyanate, 1 s 3-phenylene diisocyanate, 1,4-phenylene diisocyanate, 2,4-tolylene diisocyanate, 2,6-tolylene diisocyanate, 4,4-biphenylene diisocyanate, 1,5-naphthylene diisocyanate, 1,4-naphthylene diisocyanate, l-isocyanatomethyl -5-isocyanato-1,3,3-trimethylcyclohexane etc.
  • prepolymers containing isocyanate groups as polyisocyanate components.
  • very particularly preferred blocking agents are the diesters of malonic acid with C 1 -C 8 -alkanols such as methanol, ethanol, N-propanol, N-butanol, isobutanol, N-hexanol,
  • N-octanol or isooctanol with cycloaliphatic alcohols, such as cyclopentanol or cyclohexanol, and also with araliphatic alcohols, such as benzyl alcohol or 2-phenylethanol.
  • cycloaliphatic alcohols such as cyclopentanol or cyclohexanol
  • araliphatic alcohols such as benzyl alcohol or 2-phenylethanol.
  • the malonic acid diethyl ester is used as a particularly preferred blocking agent.
  • Polyisocyanate components whose isocyanate groups are bonded to (cyclo) aliphatic radicals are preferably used.
  • Polyisocyanate compounds containing isocyanate groups bound to aromatic groups are due to Their high reactivity with water can only be used in exceptional cases (for example as part of component (B)).
  • the Crosslinking density of the resulting polymer microparticles can be influenced.
  • the crosslink density in turn correlates with the swelling behavior of the polymer microparticles.
  • the swelling behavior of the polymer microparticles can also be controlled via the chemical nature of components (A) or (B) (incorporation of more or less hydrophilic molecular segments; incorporation of more or less rigid molecular parts).
  • Particularly preferred mixtures of components (A) and (B) consist of polyester polyols, the molecules of which each carry an average of one carboxyl group and at least 3 hydroxyl groups, and triisocyanate compounds, the isocyanate groups of which are attached to (cyclo) aliphatic radicals and, if appropriate, at least are partially blocked with malonic acid di-ester, preferably diethyl malonic acid.
  • the mixture consisting of components (A) and (B) can be dispersed in bulk in the aqueous dispersion medium.
  • Disperse solution or dispersion in the aqueous dispersion medium it is advantageous to dissolve or disperse components (A) and (B) in a water-miscible organic solvent which is inert to isocyanate groups and preferably boils below 100 ° C., and then dissolves them 1 Disperse solution or dispersion in the aqueous dispersion medium.
  • a solvent or dispersant for the mixture consisting of components (A) and (B) all are water-miscible and opposite
  • organic solvents which are inert to isocyanate groups can be used.
  • Organic solvents with a boiling point below 100 ° C. are advantageously used. Particularly good results can be obtained with acetone and methyl ethyl ketone.
  • the aqueous dispersing medium in which the mixture of (A) and (B) is dispersed consists of water which can also contain organic solvents.
  • a stable aqueous dispersion which consists of particles whose size 20 can be influenced by targeted variation of the parameters discussed above.
  • the dispersion obtained is then heated to such an extent (in general at 60 to 95 ° C.) that components (A) and (B) are converted into crosslinked polymer microparticles.
  • the organic solvent used to disperse or dissolve the mixture consisting of components (A) and (B) can, before the reaction of components (A) and (B), at a temperature which is below that for formation
  • the polymer microparticles used according to the invention are very particularly preferably produced by 1 (1) a mixture of components (A) and (B) is dispersed in an aqueous medium, wherein
  • Component (B) made of polyisocyanate compounds, which preferably blocks more than two isocyanate groups bonded to (cyclo) aliphatic radicals
  • 10 can be, contains, and and the mixture of components (A) and (B) in a water-miscible, boiling at 100 ° C, inert to isocyanate groups, preferably acetone and / or
  • crosslinked polymer microparticles containing aqueous dispersions obtained in this way can be easily incorporated into the aqueous base coating compositions used according to the invention.
  • the base coating compositions used according to the invention preferably contain 2 to 15% by weight, particularly preferably 5 to 13% by weight, of crosslinked polymer microparticles of the type described above. Based on the binder solids
  • the proportion of crosslinked polymer microparticles in the body is 5 to 80% by weight, preferably 30 to 70% by weight, particularly preferably 40 to 60% by weight.
  • binder solids is the total proportion of - - water-dilutable. Understand binders and cross-linked polymer microparticles. In other words, the “binder solid” is obtained by adding the proportion of water-diluted cash binder and the proportion of crosslinked polymer microparticles.
  • the binder solid of the base coating compositions used according to the invention is preferably 5 to 30% by weight, particularly preferably 10 to 25% by weight.
  • the base coating compositions used according to the invention can contain all pigments suitable for the basecoat / clearcoat process.
  • pigments suitable for the basecoat / clearcoat process examples include titanium dioxide, graphite, carbon black, phthalocyanine blue, chromium oxide, perylene tetracarboximides and the like. called.
  • the base coating compositions used according to the invention very particularly preferably contain metal platelet pigments, particularly preferably aluminum platelets, as pigments.
  • the metallic flake pigments can also be used together with color pigments. In this case, the type and amount of color pigments are chosen so that the desired metallic effect is not suppressed.
  • the base coating compositions used according to the invention can also, instead of or in combination with metallic flake pigments, other effect pigments, such as contain mica flakes coated with metal oxides (so-called Mica).
  • the metal flake pigment content of the base coating composition used according to the invention is - based on the binder solid - up to 25% by weight, preferably 12 to 18% by weight.
  • the base coating compositions used according to the invention contain 0.1 to 4.0% by weight, preferably 1.0 27
  • Xanthan is a generally known thickener which is also used in aqueous coating compositions, in particular latex paints.
  • aqueous coating compositions in particular latex paints.
  • Xanthan is a highly polymeric heteropolysaccharide (molecular weight about 2 million) separated from the bacterial strain Xanthomonas ca pestris with the following structure:
  • the base coating compositions according to the invention can also contain other conventional additives such as fillers, plasticizers, stabilizers, wetting agents, dispersing agents, and the like.
  • a suitable transparent top layer composition After application of the base coating compositions, after a short flash-off time without a baking step, a suitable transparent top layer composition is applied. Conventional solvent-based clearcoats, water-dilutable clearcoats or powder clearcoats can be applied.
  • the invention also relates to water-thinnable coating compositions which are suitable for producing the base layer of two-coat coatings of the basecoat / clearcoat type and which comprise water, optionally organic solvents, a water-thinnable binder, crosslinked polymer microparticles with a diameter of 0.01 to 10 , um, pigment particles and a thickener, characterized in that they 0.1 to 4.0 wt .-%, preferably 1.0 to 2.0 wt .-%, based on the binder solid, xanthan and 5 to 80% by weight, preferably 30 to 70% by weight, particularly preferably 40 to 60% by weight, based on the binder solid, contains crosslinked polymer microparticles, the crosslinked polymer microparticles being obtainable by:
  • - Component (A) consists of one or more polyester polyol (s) containing at least two hydroxyl groups and - Component (B) consists of one or more optionally blocked polyisocyanate compounds) and component (A) and / or (B) has one to form a stable dispersion ausrei ⁇ sponding number of ionic groups and at least part has - ⁇ r component (a) and / or (B) contains more than two hydroxyl or optionally blocked isocyanate groups per molecule and
  • the substrates to be coated are, in particular, pretreated metal substrates; non-pretreated metals and any other substrates, such as e.g. Wood, plastics, etc., are coated with a multi-layer, protective and / or decorative coating using the base coating compositions according to the invention.
  • the dispersion has a solids content of 35% by weight.
  • the dispersion prepared in this way is heated to 90 ° C. within 1 hour.
  • the viscosity begins to increase about 2 hours after the temperature of 90 ° C. has been reached. In the course of a further 2 hours, as much water is always added as is necessary for thorough mixing. A total of 7285 parts of water are added so that the solids content of the dispersion 5 drops to 15% by weight.
  • the dispersion obtained in this way is adjusted to a pH of 7.3 using a 10% strength aqueous solution of dimethylethanolamine. Viscosity, measured in a DIN 4 cup: 25 seconds. Measurements with a Haake RV 100 0 rotary viscometer show that the dispersion has a high degree of structural viscosity (pseudoplasticity).
  • a base coating composition with the following composition is produced according to generally known methods:
  • the metallic basecoat obtained has a pH value of 7.7 and a viscosity which can no longer be measured in a DIN 4 cup. Despite the high viscosity, the basecoat can be used e.g. due to the highly pseudoplastic plastic flow behavior, e.g. easy to apply by pneumatic atomization. 5
  • This basecoat was used to apply two-coat metallic effect paints using the usual wet-on-wet method 27 manufactured. These coatings showed an excellent metallic effect and a very good clear coat level.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

Un procédé sert à produire un laquage à couches mutiples du type ''base coat/clear coat'' (couche de base/couche transparente) au moyen d'une composition de revêtement de base délayable dans l'eau. La composition de revêtement de base contient entre 0,1 et 4,0 % en poids, par rapport au liant solide, de xanthane, et entre 5 et 80 % en poids, par rapport au liant solide, de microparticules polymères réticulées composées de polyols de polyester et de polyisocyanates.
EP88905824A 1987-07-31 1988-07-11 Procede de fabrication d'un revetement protecteur et/ou decoratif a couches multiples et compositions de revetement delayables dans l'eau Pending EP0376954A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3725371 1987-07-31
DE19873725371 DE3725371A1 (de) 1987-07-31 1987-07-31 Verfahren zur herstellung eines mehrschichtigen schuetzenden und/oder dekorativen ueberzugs und wasserverduennbare beschichtungszusammensetzungen

Publications (1)

Publication Number Publication Date
EP0376954A1 true EP0376954A1 (fr) 1990-07-11

Family

ID=6332770

Family Applications (2)

Application Number Title Priority Date Filing Date
EP88905824A Pending EP0376954A1 (fr) 1987-07-31 1988-07-11 Procede de fabrication d'un revetement protecteur et/ou decoratif a couches multiples et compositions de revetement delayables dans l'eau
EP88111048A Expired - Lifetime EP0301300B1 (fr) 1987-07-31 1988-07-11 Procédé de préparation d'un revêtement multicouche protecteur et/ou décoratif et compositions de revêtement diluables à l'eau

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP88111048A Expired - Lifetime EP0301300B1 (fr) 1987-07-31 1988-07-11 Procédé de préparation d'un revêtement multicouche protecteur et/ou décoratif et compositions de revêtement diluables à l'eau

Country Status (5)

Country Link
EP (2) EP0376954A1 (fr)
AT (1) ATE67693T1 (fr)
DE (2) DE3725371A1 (fr)
ES (1) ES2026971T3 (fr)
WO (1) WO1989000891A1 (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5667847A (en) * 1987-07-31 1997-09-16 Basf Lacke+Farben Aktiengesellschaft Process for the production of a multicoat protective and/or decorative coating and water-dilutable coating compositions
DE3832142A1 (de) * 1988-09-22 1990-04-12 Basf Lacke & Farben Verfahren zur herstellung eines mehrschichtigen, schuetzenden und/oder dekorativen ueberzugs und wasserverduennbare beschichtungszusammensetzungen
GB9217211D0 (en) * 1992-08-13 1992-09-23 Courtaulds Coatings Holdings Segregating water-borne coating systems
ES2110321T3 (es) * 1994-04-30 1998-02-01 Wacker Chemie Gmbh Producto de revestimiento acuoso y proceso para la preparacion de revestimientos barnizados multicapa cuya sensacion de color depende del angulo de observacion.
EP2169011A1 (fr) * 2008-09-24 2010-03-31 Looser Holding AG Epaississant pour dispersions polymères pouvant se fritter ou fondre

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3210051A1 (de) * 1982-03-19 1983-09-29 Basf Farben + Fasern Ag, 2000 Hamburg Wasserverduennbares ueberzugsmittel zur herstellung der basisschicht eines mehrschichtueberzuges

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO8900891A1 *

Also Published As

Publication number Publication date
EP0301300A1 (fr) 1989-02-01
WO1989000891A1 (fr) 1989-02-09
EP0301300B1 (fr) 1991-09-25
ATE67693T1 (de) 1991-10-15
DE3865141D1 (de) 1991-10-31
DE3725371A1 (de) 1989-02-09
ES2026971T3 (es) 1992-05-16

Similar Documents

Publication Publication Date Title
EP0234362B1 (fr) Dispersions aqueuses de particules de polymères réticulées, procédé pour la préparation de ces dispersions et les compositions de revêtement contenant ces dispersions
EP0234361B2 (fr) Dispersions aqueuses de particules de polymères réticulées, procédé pour la préparation de ces dispersions et les compositions de revêtement contenant ces dispersions
EP0036975B1 (fr) Procédé de fabrication de vernissages à effet métallique et objets plans présentant des vernissages multi-couches à effet métallique résistant aux intempéries
EP1135424B1 (fr) Agent de revetement constitue d'au moins trois composants, son procede de production et son utilisation
EP0339433B1 (fr) Laques au four diluables à l'eau et leur utilisation comme charge et peinture de fond contre l'écaillage ainsi qu'un procédé pour le revêtement de carrosseries d'automobiles
WO1992015405A1 (fr) Procede de production d'un revetement de vernis multicouche protecteur et/ou decoratif
EP0879255B1 (fr) Liants pour peintures a base de polyurethane
DE19904317A1 (de) Aus mindestens vier Komponenten bestehendes Beschichtungsmittel, Verfahren zu seiner Herstellung sowie seine Verwendung
DE3201749C2 (fr)
EP0505469B2 (fr) Procede de fabrication d'un revetement multicouche de protection et/ou de decoration
DE19730890C2 (de) Verfahren zur Herstellung mehrschichtiger Überzüge und mit diesen beschichtete Substrate
DE3739332C2 (fr)
DE4028386A1 (de) Verfahren zur herstellung eines mehrschichtigen schuetzenden und/oder dekorativen ueberzugs und wasserverduennbare beschichtungszusammensetzungen
EP0301300B1 (fr) Procédé de préparation d'un revêtement multicouche protecteur et/ou décoratif et compositions de revêtement diluables à l'eau
EP0302240B1 (fr) Procédé de préparation d'un revêtement multicouche protecteur et/ou décoratif et compositions de revêtement diluables à l'eau
WO2007054289A2 (fr) Dispersions de poudre aqueuses durcissables par polymerisation radicalaire, procede pour leur production et leur utilisation
DE3832142C2 (fr)
EP0882102B1 (fr) Procede de production, en plusieurs etapes, d'agents de revetement aqueux pour la mise en peinture d'habitacles de vehicules
EP0560783B1 (fr) Enduit a teneur elevee en matieres solides, son procede de production et son utilisation comme email et comme couche de fond dans des applications industrielles
DE3828051C3 (de) Verfahren zur Herstellung von lagerstabilen, wasserverdünnbaren Überzugsmitteln und Verwendung

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE

17P Request for examination filed

Effective date: 19891201

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH DE FR GB IT LI NL SE

XX Miscellaneous (additional remarks)

Free format text: VERFAHREN ABGESCHLOSSEN INFOLGE VERBINDUNG MIT 88111048.0/0301300 (EUROPAEISCHE ANMELDENUMMER/VEROEFFENTLICHUNGSNUMMER) VOM 01.02.91.