EP0363375B1 - Dispositif de coulee continue - Google Patents
Dispositif de coulee continue Download PDFInfo
- Publication number
- EP0363375B1 EP0363375B1 EP88903813A EP88903813A EP0363375B1 EP 0363375 B1 EP0363375 B1 EP 0363375B1 EP 88903813 A EP88903813 A EP 88903813A EP 88903813 A EP88903813 A EP 88903813A EP 0363375 B1 EP0363375 B1 EP 0363375B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cooling
- continuous casting
- primary
- cooler
- casting apparatus
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000009749 continuous casting Methods 0.000 title claims abstract description 43
- 239000000463 material Substances 0.000 claims abstract description 13
- 239000002826 coolant Substances 0.000 claims abstract description 5
- 238000001816 cooling Methods 0.000 claims description 70
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 15
- 238000005266 casting Methods 0.000 claims description 15
- 229910002804 graphite Inorganic materials 0.000 claims description 15
- 239000010439 graphite Substances 0.000 claims description 15
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 7
- 229910010293 ceramic material Inorganic materials 0.000 claims description 6
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 6
- 230000001105 regulatory effect Effects 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 4
- 229910052582 BN Inorganic materials 0.000 claims description 2
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims description 2
- 230000035939 shock Effects 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 238000005259 measurement Methods 0.000 claims 1
- 206010008531 Chills Diseases 0.000 abstract 6
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
- 239000000155 melt Substances 0.000 description 9
- 150000001247 metal acetylides Chemical class 0.000 description 4
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910000881 Cu alloy Inorganic materials 0.000 description 2
- 230000004323 axial length Effects 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 238000005219 brazing Methods 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- -1 nadium Chemical compound 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/04—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
- B22D11/045—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds for horizontal casting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/04—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
- B22D11/045—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds for horizontal casting
- B22D11/047—Means for joining tundish to mould
Definitions
- the invention relates to a continuous casting device according to the preamble of claim 1.
- Conventional continuous casting devices consist of a mold which is made from a graphite tube or at least has a graphite layer on its inner surface.
- a mold which is made from a graphite tube or at least has a graphite layer on its inner surface.
- conventional molds are usually designed to protrude into the melting chamber.
- this basically has the disadvantage in terms of process technology that considerable amounts of heat are withdrawn from the furnace and, above all, from the material to be cast, which then have to flow off to the surrounding cooler via the mold wall, the one from the EP has nevertheless -A-0158898 known continuous casting device very proven.
- this known continuous casting device has the essential advantage, which is decisive in comparison with other known devices, that the cooling mold is made of a casting material which is made in the Shrink fit surrounds the cast-in cooling pipe and the spiral cooling pipe surrounding the cooling pipe and through which the coolant medium flows.
- a two-part mold has also become known, for example, from DE-A-2058051 and from DE-U1-1854884.
- the mold is divided in two in the longitudinal direction, whereby in the first-mentioned publication the cooling device following the introductory part is divided into two different zones, which differ in the use of different materials on the inner cooling central tube.
- the much larger and longer part of the cooling central tube is also made of graphite in this prior art, which is why the disadvantages mentioned above exist and occur here.
- a continuous casting mold with a primary and a secondary cooler is also from "Soviet Invention Illustrated", Section CH, Week K46, December 28, 1983 Derwent Publications Ltd. (London, (GB) - Summary No. 819305, Class M22 & SU-A-990,411, January 23, 1983 (D1).
- this two-part mold is not suitable for practical operation in many respects due to the conically overlapping arrangement between the primary and secondary coolers and because of the changing inner diameter from the primary to the secondary mold.
- due to the overlapping conical arrangement of the primary and secondary coolers a large heat flow is already caused in the primary cooler.
- a two-part continuous casting mold can also be found in GB-A-1227312, in which the secondary cooler consists of copper or a copper alloy, ie a harder material than graphite.
- Primary and secondary coolers in this case comprise a cooling device in the form of a plurality of cooling tubes lying transversely to the longitudinal direction of the mold.
- the present invention for the first time creates a continuous casting device in which particularly favorable continuous casting properties can be achieved due to the relatively small axial length of the primary cooler with a comparatively large inner diameter in cooperation with the secondary cooler.
- the secondary cooler which has a much greater axial length, enables optimized, controlled cooling of the continuous casting while avoiding graphite for the cooling central tube.
- the use of a cooling coil known per se is just as important as the feature known from EP-A-0158898, in particular, that the central tube, like the cooling coil, is encapsulated by the metal of the heat sink in a shrink fit. This is the only way to achieve the absolutely necessary heat transfer coefficients.
- the tubular feed part anchored to the crucible can extend as far as the secondary cooler, the extremely short primary cooler only surrounding the lower section of the tubular feed part immediately adjacent to the secondary cooler.
- This front feed part can consist of good heat-conducting, high-quality graphite which is not soluble in the melt. Due to this short length, the graphite costs for this wearing part are kept extremely low.
- the wall temperature of this short primary cooler can be regulated so high that it completely solidifies over the entire length of the strand without any noticeable shrinkage taking place.
- this has the advantage that sufficient hot metal always flows into the short hot feed part of the cooling device and the gases released during the solidification and dissolved in the melt can escape in countercurrent without the metal temperature of the melt and, associated therewith, its gas content disadvantageously to have to lift high.
- the larger part of the cooling mold, namely the secondary cooler, is designed as a reusable component. It proves to be particularly advantageous here that the use of graphite can be dispensed with in the continuous casting device according to the invention in this secondary cooler, which accounts for the largest part of the longitudinal extent. This saves extreme costs and also ensures that the secondary cooler is continuously reused.
- a carbide compound in particular silicon carbide, is particularly suitable for the cooling central tube in the secondary cooler.
- this mold is extremely light and therefore easy to handle.
- the continuous casting device according to the invention With the continuous casting device according to the invention, the casting performance can also be increased by more than 30% compared to conventional continuous casting devices.
- the continuous casting device according to the invention is suitable for both horizontal and vertical operation. Above all, it can be used for a continuous continuous casting process, although it is of course also suitable for discontinuous operation. It is precisely here that the particular advantages of the invention are shown by the use of a highly wear-resistant, highly heat-conducting, thermo-shock-resistant and at the same time extremely hard, polishable material such as ceramic material for the inner cooling central tube, which can often be used without otherwise having to rework the inner surface of the casting mold. The otherwise considerable wear of graphite molds during discontinuous continuous casting is obviously avoided here.
- FIG. 1 denotes the bottom and side walls of a holding furnace in which there is a melt 3.
- a feed part 5 of the continuous casting device is provided so as to protrude, the opening of which is provided in a known manner with an insert 7 made of refractory material which is not soluble in the melt and has passages 9.
- the end of the feed part 5 opposite the insert 7 in the continuous casting direction is fitted in a conical or cylindrical seat of a primary cooling 11 in the manner of a cooling ring. 13 with thermal insulation is designated, which sits between the furnace wall 1 and the primary cooler 11 designed as a cooling ring.
- the cooling itself takes place through a cooling spiral 15 provided in the primary cooler 11.
- the amount of cooling water required for cooling is adjusted accordingly by a control valve 19 arranged in the inflow line 17 for the cooling spiral 15, which is regulated and controlled in a known manner by the temperature of the exiting heated cooling water via a thermal sensor 23 arranged in the outlet pipe 21.
- the primary cooling 11 designed as a cooling ring sits with only a small longitudinal extension at the end of the feed part 5 directly in front of the subsequent secondary cooler 25.
- a favorable ratio of the length of this cooled primary or feed part 5, which is pressed into the surrounding metal cooler, to the inner diameter the tubular feed part 5 is less than 60: 100; 50: 100, 40: 100 or 35: 100.
- the mentioned inner diameter of the tubular feed part 5 corresponds to the outer diameter of the casting strand taking into account the shrinkage factor.
- the material for the feed part 5 is generally high-quality graphite which is a good heat conductor and is not soluble in the melt.
- the use of e.g. Boron nitride Due to the relative shortness of the cooled feed part 5, the temperature in the foremost part of the feed part 5 protruding into the crucible is only approximately 60 ° to 110 ° C. less than the temperature range of the melt 3. This realizes the advantage that the melt is little Heat is removed.
- the extreme ratio of the short length of the primary cooler to its diameter results in a high ⁇ T of at least 550 ° C. to 600 ° C. at the inlet of the primary cooler 11 and less than 200 ° C. at the end of the cooler, especially when entering the primary cooler.
- the wall temperature on the short primary cooler is still so high that in this front primary cooler a complete edge rigidity over the entire strand circumference occurs, but no noticeable shrinkage.
- the cooling disc 11 is designed in the manner of a flat cone. It consists of highly thermally conductive metal or a likewise highly thermally conductive metal alloy, e.g. Copper or copper with e.g. 0.5 to 0.7% Si with 1% to 1.2% Ni, i.e. a hardenable, heat-resistant Cu alloy. Discarding this primary cooling disk 11 is almost impossible due to its special, compact shape.
- the cast-in cooling spirals 15 eliminate the need for expensive machining of cooling channels, as in the case of traditional coolers. Likewise, the welding or brazing otherwise required is not required.
- the primary cooler 11 is followed by the secondary cooler 25, the inner cooling central tube 27 of which consists of highly thermally conductive ceramic material.
- the cooling central tube 27 is surrounded by the actual cooler made of highly thermally conductive metal, such as aluminum or an aluminum lining, which are joint-tight to the feed part 5 by means of a snug fit 31 and anchor bolts 33, but are easily detachably connected.
- the cooling tubes 17 and 21 of the primary cooling circuit are guided in axial alignment through the cooler 25 such that they pass into the cooling spirals 15 in the primary cooler 11.
- the cooling coil 35 of the secondary cooler 25 like the inner cooling central tube 27, which is made of ceramic material, is connected in a heat-conducting manner by the metal of the cooler 25 which is shrinking around both.
- the temperature of the secondary cooler 25 is regulated by a further thermal sensor 39 located in the outlet pipe 37, which controls the control valve 41 in the feed pipe 43 of the secondary cooler 25.
- thermocouple 45 with a thermocouple is designated, which is installed between the inner wall of the cooler 25 and the ceramic central cooling tube 27 just behind the transition of the supply part 5 to the secondary cooler 25.
- This thermocouple 45 influences the casting speed, ie the strand transport and its speed, in such a way that it is ensured that the edge rigidity of the casting strand in the feed part 5 is completed.
- FIG. 47 denotes the position of the phase boundary immediately after the end of the pull period, while line 49 shows the solidification front moved back towards the furnace during the stop period.
- thermocouple 45 effects the regulation of the pull-off speed, for which purpose the thermocouple 45 controls a sensor designated 51 in the drawing, to limit the phase limit at the level of the connection or shortly before the connection between the feed part 5 and the secondary cooler 25.
- the thermocouple shows 45 an increasing temperature above a set value as a result of the displacement of a phase boundary, the casting speed is reduced via the transmitter 51, as a result of which the temperature measured again at the thermocouple 45 drops.
- the production of the secondary cooler by simultaneously casting around the inner ceramic cooling central tube 27 and the cooling spiral 35 is particularly cost-saving and efficient. After pouring, the inner cooling central tube 27 forms a firm, non-detachable shrink connection with the surrounding metal of the secondary cooler 25, the inner cooling surface of which no longer has to be machined.
- FIG. 2 A further exemplary embodiment of the invention is explained below with reference to FIG. 2, in which the same components as in FIG. 1 are provided with corresponding reference symbols.
- the exemplary embodiment according to FIG. 2 relates to a vertical continuous casting device, in particular for heavy metal alloys.
- the entire furnace can be protected here by additional floor insulation 61, 63 being a floor plate.
- the feed part is let into the furnace bottom 1 by means of a fitting piece 65.
- the fitting 65 lies on the cooling ring-like primary cooler 11 or on the insulation 13 provided there.
- 67 denotes a hollow casting mandrel, preferably made of graphite, which is precisely in by means of a graphite plug 69 and a centering 71 the middle of the feed part 5 is held.
- the plug 70 made of refractory cement prevents direct heat flow from the melt to the casting mandrel and prevents possible leakages of melt through the thread 73 into the interior of the casting strand 75.
- Ceramic materials are particularly suitable for the central cooling pipe.
- Carbides or carbide compounds are particularly recommended.
- boron and silicon carbides are considered as covalent carbides, which are hard, difficult to melt and chemically inert.
- Most metallic carbides are non-stoichiometric compounds of an alloy character. They are resistant to acids, usually harder than the pure metal components and conduct the electrical current.
- Carbides of chromium, tungsten, hafnium, molybdenum, nadium, niobium, tantalum and titanium are technically important.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Continuous Casting (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
- Handcart (AREA)
- Vehicle Body Suspensions (AREA)
- Body Structure For Vehicles (AREA)
Claims (10)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT88903813T ATE66840T1 (de) | 1987-04-28 | 1988-04-27 | Stranggiessvorrichtung. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19873714139 DE3714139A1 (de) | 1987-04-28 | 1987-04-28 | Stranggiessvorrichtung |
| DE3714139 | 1987-04-28 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0363375A1 EP0363375A1 (fr) | 1990-04-18 |
| EP0363375B1 true EP0363375B1 (fr) | 1991-09-04 |
Family
ID=6326432
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP88903813A Expired - Lifetime EP0363375B1 (fr) | 1987-04-28 | 1988-04-27 | Dispositif de coulee continue |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5027881A (fr) |
| EP (1) | EP0363375B1 (fr) |
| AT (1) | ATE66840T1 (fr) |
| AU (1) | AU640342B2 (fr) |
| CA (1) | CA1327111C (fr) |
| DE (2) | DE3714139A1 (fr) |
| NZ (1) | NZ224397A (fr) |
| WO (1) | WO1988008344A1 (fr) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100331152B1 (ko) * | 1999-06-28 | 2002-04-01 | 황해웅 | 무산소동이나 특수합금동의 일체형 수평연속주조 설비 및 탈산·정제방법 |
| AU2001280541A1 (en) | 2000-07-17 | 2002-01-30 | Consolidated Engineering Company, Inc. | Methods and apparatus for utilization of chills for castings |
| AU2003250533A1 (en) * | 2002-07-22 | 2004-02-09 | Showa Denko K.K. | Continuous cast aluminum alloy rod and production method and apparatus thereof |
| WO2011049698A2 (fr) | 2009-10-19 | 2011-04-28 | Micropyretics Heaters International, Inc. | Dispositifs de protection électrique d'énergie verte propre pour des matériaux |
| EP3088101A4 (fr) * | 2013-12-23 | 2017-08-09 | Shigin, Victor Victorovich | Procédé de coulage et de laminage combinés d'alliages de cuivre à partir de rebuts de cuivre |
| CN104057039A (zh) * | 2014-06-19 | 2014-09-24 | 无锡隆达金属材料有限公司 | 热冷组合型水平连铸专用内冷式封炉压板 |
| KR102222896B1 (ko) * | 2019-08-02 | 2021-03-03 | 권상철 | 연속 주조용 냉각튜브 어셈블리 및 이를 포함하는 연속 주조용 냉각 장치 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2169893A (en) * | 1937-11-01 | 1939-08-15 | Chase Brass & Copper Co | Cooling means for continuous casting apparatus |
| GB1227312A (fr) * | 1967-02-06 | 1971-04-07 | ||
| AT287215B (de) * | 1968-01-09 | 1971-01-11 | Boehler & Co Ag Geb | Verfahren und Vorrichtung zum Elektroschlackenumschmelzen von Metallen, insbesondere von Stählen |
| US3730251A (en) * | 1971-06-21 | 1973-05-01 | Gen Motors Corp | Method of continuous casting |
| GB1431729A (en) * | 1973-08-04 | 1976-04-14 | Hitachi Shipbuilding Eng Co | Copper alloy and mould produced therefrom |
| CH568113A5 (fr) * | 1974-05-15 | 1975-10-31 | Concast Ag | |
| CH577352A5 (fr) * | 1975-02-28 | 1976-07-15 | Concast Ag | |
| SU950490A1 (ru) * | 1981-01-28 | 1982-08-15 | Липецкий Филиал Всесоюзного Проектно-Технологического Института Литейного Производства | Кристаллизатор дл непрерывного лить полых заготовок |
| DE3578045D1 (de) * | 1984-04-13 | 1990-07-12 | Hans Horst | Stranggiessvorrichtung und verfahren zu deren herstellung. |
| US4669529A (en) * | 1984-12-03 | 1987-06-02 | Egon Evertz | Continuous casting mould |
| US4774996A (en) * | 1986-09-29 | 1988-10-04 | Steel Casting Engineering, Ltd. | Moving plate continuous casting aftercooler |
| US4789021A (en) * | 1986-09-29 | 1988-12-06 | Steel Casting Engineering, Ltd. | Short mold for continuous casting |
-
1987
- 1987-04-28 DE DE19873714139 patent/DE3714139A1/de not_active Withdrawn
-
1988
- 1988-04-27 WO PCT/EP1988/000351 patent/WO1988008344A1/fr not_active Ceased
- 1988-04-27 NZ NZ224397A patent/NZ224397A/xx unknown
- 1988-04-27 EP EP88903813A patent/EP0363375B1/fr not_active Expired - Lifetime
- 1988-04-27 AT AT88903813T patent/ATE66840T1/de not_active IP Right Cessation
- 1988-04-27 AU AU17062/88A patent/AU640342B2/en not_active Ceased
- 1988-04-27 DE DE8888903813T patent/DE3864686D1/de not_active Expired - Lifetime
-
1989
- 1989-09-29 CA CA000615288A patent/CA1327111C/fr not_active Expired - Fee Related
-
1990
- 1990-12-17 US US07/629,079 patent/US5027881A/en not_active Expired - Fee Related
Non-Patent Citations (1)
| Title |
|---|
| Soviet Inventions Illustrated, Section CH, week K46, 28 December 1983, Derwent Publications Ltd, London (GB), abstract no. 819305, Class M22 & SU,A,990411 (Don Poly) 23 January 1983 * |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0363375A1 (fr) | 1990-04-18 |
| AU1706288A (en) | 1988-12-02 |
| DE3864686D1 (de) | 1991-10-10 |
| DE3714139A1 (de) | 1987-10-22 |
| CA1327111C (fr) | 1994-02-22 |
| AU640342B2 (en) | 1993-08-26 |
| WO1988008344A1 (fr) | 1988-11-03 |
| ATE66840T1 (de) | 1991-09-15 |
| US5027881A (en) | 1991-07-02 |
| NZ224397A (en) | 1991-01-29 |
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