EP0351125A1 - Apparatus for mixing and dispersing materials - Google Patents
Apparatus for mixing and dispersing materials Download PDFInfo
- Publication number
- EP0351125A1 EP0351125A1 EP89306819A EP89306819A EP0351125A1 EP 0351125 A1 EP0351125 A1 EP 0351125A1 EP 89306819 A EP89306819 A EP 89306819A EP 89306819 A EP89306819 A EP 89306819A EP 0351125 A1 EP0351125 A1 EP 0351125A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- vessel
- rotors
- series
- cage
- shaft
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000463 material Substances 0.000 title abstract description 10
- 238000010008 shearing Methods 0.000 abstract description 8
- 230000001133 acceleration Effects 0.000 abstract description 5
- 230000000694 effects Effects 0.000 description 7
- 239000002904 solvent Substances 0.000 description 5
- 239000011236 particulate material Substances 0.000 description 4
- 239000000049 pigment Substances 0.000 description 3
- 238000010923 batch production Methods 0.000 description 2
- 230000000295 complement effect Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000003605 opacifier Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000002826 coolant Substances 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/05—Stirrers
- B01F27/09—Stirrers characterised by the mounting of the stirrers with respect to the receptacle
- B01F27/091—Stirrers characterised by the mounting of the stirrers with respect to the receptacle with elements co-operating with receptacle wall or bottom, e.g. for scraping the receptacle wall
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/80—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
- B01F27/84—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis with two or more stirrers rotating at different speeds or in opposite directions about the same axis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/80—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
- B01F27/93—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis with rotary discs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/05—Stirrers
- B01F27/11—Stirrers characterised by the configuration of the stirrers
- B01F27/19—Stirrers with two or more mixing elements mounted in sequence on the same axis
- B01F27/191—Stirrers with two or more mixing elements mounted in sequence on the same axis with similar elements
Definitions
- This invention relates to apparatus for mixing and dispensing particulate materials in solvent liquids, especially but not exclusively in the manufacture of paints by incorporating opacifiers and pigments in the solvents
- a successful prior art apparatus comprises a cylindrical vessel having a slow speed rotor with a blade generally of the shape and size of the vessel so as to closely conform to the vessel side wall and which is for maintaining a general mixing or circulating flow in the vessel contents, together with one or more high speed rotor discs for dispersion, which is effected by the shearing forces provided by the acceleration of the material due to the high speed rotor.
- the economic considerations of the mixing and dispersing apparatus include energy input and time taken (which are in general related) but limiting factors include heat evolution which may be deleterious to some materials which are to be mixed as well as representing energy loss.
- the object of the invention is to provide improved apparatus.
- mixing and dispersing apparatus having a main rotor shaft provided with a series of axially spaced rotors of progressively greater effective diameter along the length of the shaft.
- the rotors may be driven at constant speed, or e.g. at variable speeds according to the stage in the mixing and dispersion cycle.
- the stacked rotor assembly of the present invention may be used in a container or vessel arranged for a natural circulation or flow within the vessel or it may be arranged for flow through the vessel, that is to say from an inlet past the rotors to an outlet with continuous flow therethrough, possibly with recirculation via an external passage.
- the vessel may be of generally the same cross sectional shape as the stacked rotor assembly giving the possibility of shearing forces being created by flow between the rotor discs and the vessel wall.
- the stacked rotor assembly is associated with a cage which is generally complementary in shape to the stacked rotors, so that acceleration and shear forces are created between the cage and the rotor tips.
- the cage may be complementary to the vessel shape or not. This also creates the possibility of using a vessel of more complex shape and of arranging for the rotor assembly with or without cage to be movable relative to the vessel so as to operate in different portions of the vessel to different effects at different times.
- the cage is water-cooled.
- Overhung shaft 16 extends generally axially of the vessel from a motor 18 at the top through a seal 20, and carries a series of (in this instance) five rotor discs 22 - 30 which are of progressively larger diameter from the free end towards the motor so that there is a generally similar clearance between the tip of each rotor and the vessel wall.
- the solvents and pigment may be fed through common or separate supply means via inlet 12, and circulated via a passage connecting outlet 14 with inlet 12 or for example solvent can be pumped continuously through the inlet 12 and out of the outlet 40 and from time to time pigments, and opacifiers and the like charged into the vessel at any suitable point.
- the arrangement of Figure 1 can run continuously whilst circulating a single batch, or continuously producing completely mixed and dispersed product.
- the materials are subject to increasing acceleration due to the series of discs of progressively larger diameter, and all of which are inherently driven at the same rotary speed and hence higher tip speed, so that the material is subject to a series of increasing shearing forces at the tips.
- the arrangement is more primarily concerned for batch production and the vessel 101 has a frusto-conical lower portion 30 and a generally cylindrical upper portion 32.
- the stacked rotor assembly carried by shaft 161 is designed to be raised and lowered, i.e. moved in the direction of the arrows AA relative to the vessel.
- the shaft 16 is again overhung, and the vessel is provided with ports 121 and 141 at the bottom and top respectively.
- the vessel may be charged with solvent for example through the port 141 and particulate material may be vacuum induced in the vessel through the port 121. Alternatively and for example, the particulate material may be charged through the port 141.
- FIG. 3 is a further version primarily arranged for batch production like Figure 2 but in this case the stacked rotor set driven by the overdrive shaft 162 is associated with a cage 36 carried by a stationary guide member 38, and the shearing forces applied to the material are due to the flow of the material between the rotor disc peripheries and the cage portions 40.
- the whole assembly of cage and rotors is vertically movable relative to the vessel.
- Figure 3 also shows the use of a slow speed stirring rotor 42 which in this instance is underdriven from shaft 44 via gearbox 46.
- the shaft 44 may be a hollow one providing for vacuum induction of particulate material via the valve 48.
- the cage is cooled, for example water-cooled and coolant may be delivered to the cage via pipes 41,43 extending through a non-rotating sleeve 45 journalling the drive shaft 162.
- coolant may be delivered to the cage via pipes 41,43 extending through a non-rotating sleeve 45 journalling the drive shaft 162.
- the arrangement shown in Figure 4 differs from that in Figure 3 in that the slow speed rotor 421 is overdrive instead of being underdriven.
- the whole rotor assembly may be raised and lowered.
- the effect on the product will be varied by so doing.
- the effect (of raising) will be to reduce the shear forces effect from the lower rotors because of the increased space from the vessel wall, and hence produce a more general stirring effect.
- the arrangement in Figure 5 is generally similar to that in Figure 1 but in this case the arrangement includes a series of fixed baffles 50 interposed between the successive rotors and extending from the container walls towards the shaft. The effect of these is to cause an extended flow path for the whole of the material in flow from the inlet to the outlet so that it reverses direction radially and is subject to shearing forces in flow not only between the rotor tip and the container wall but also between the rotor and each of the baffles.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mixers Of The Rotary Stirring Type (AREA)
Abstract
Mixing and dispersing apparatus shown in Figure 1 has a series of rotors (22, 30) of different diameter carried by and driven by a main rotor shaft (10) and located in a vessel having at a least a portion shape (10) generally complimentary to that of the set of rotors. Material in the vessel which is circulating in the vessel or flowing through the vessel is subject to a series of accelerations and shearing forces in flow between each rotor tip and the vessel wall.
Description
- This invention relates to apparatus for mixing and dispensing particulate materials in solvent liquids, especially but not exclusively in the manufacture of paints by incorporating opacifiers and pigments in the solvents
- A successful prior art apparatus comprises a cylindrical vessel having a slow speed rotor with a blade generally of the shape and size of the vessel so as to closely conform to the vessel side wall and which is for maintaining a general mixing or circulating flow in the vessel contents, together with one or more high speed rotor discs for dispersion, which is effected by the shearing forces provided by the acceleration of the material due to the high speed rotor.
- The economic considerations of the mixing and dispersing apparatus include energy input and time taken (which are in general related) but limiting factors include heat evolution which may be deleterious to some materials which are to be mixed as well as representing energy loss.
- The object of the invention is to provide improved apparatus.
- According to a first broader aspect of the invention, we provide mixing and dispersing apparatus having a main rotor shaft provided with a series of axially spaced rotors of progressively greater effective diameter along the length of the shaft.
- The rotors may be driven at constant speed, or e.g. at variable speeds according to the stage in the mixing and dispersion cycle.
- By these means, in general, it is possible to bring about circulation in the vessel or flow through the vessel without using a slow speed rotor. However a slow speed rotor may also be used in the arrangements of the invention. The series of axially spaced rotors, acting on the vessel contents in its flow within the vessel subjects the material to a series of accelerations and shearing forces, and where the flow is from the smaller diameter rotor to the larger diameter rotor, these shearing forces will be of progressively greater effect. It is believed that this will enable high energy inputs but avoiding problems therefrom.
- The stacked rotor assembly of the present invention may be used in a container or vessel arranged for a natural circulation or flow within the vessel or it may be arranged for flow through the vessel, that is to say from an inlet past the rotors to an outlet with continuous flow therethrough, possibly with recirculation via an external passage.
- The vessel may be of generally the same cross sectional shape as the stacked rotor assembly giving the possibility of shearing forces being created by flow between the rotor discs and the vessel wall.
- Alternatively and according to a feature of the invention, the stacked rotor assembly is associated with a cage which is generally complementary in shape to the stacked rotors, so that acceleration and shear forces are created between the cage and the rotor tips. In this case the cage may be complementary to the vessel shape or not. This also creates the possibility of using a vessel of more complex shape and of arranging for the rotor assembly with or without cage to be movable relative to the vessel so as to operate in different portions of the vessel to different effects at different times. According to an important preferred feature, the cage is water-cooled.
- The invention is further described with reference to the accompanying drawings in which each of the five figures is a diagrammatic elevation of a different embodiment.
- Referring first to Figure 1, the arrangement there comprises a
vessel 10 which is generally conical and has abottom inlet 12 and a top outlet 14.Overhung shaft 16 extends generally axially of the vessel from amotor 18 at the top through aseal 20, and carries a series of (in this instance) five rotor discs 22 - 30 which are of progressively larger diameter from the free end towards the motor so that there is a generally similar clearance between the tip of each rotor and the vessel wall. - The solvents and pigment may be fed through common or separate supply means via
inlet 12, and circulated via a passage connecting outlet 14 withinlet 12 or for example solvent can be pumped continuously through theinlet 12 and out of theoutlet 40 and from time to time pigments, and opacifiers and the like charged into the vessel at any suitable point. In short the arrangement of Figure 1 can run continuously whilst circulating a single batch, or continuously producing completely mixed and dispersed product. - In flow from the
inlet 12 to the outlet 14, the materials are subject to increasing acceleration due to the series of discs of progressively larger diameter, and all of which are inherently driven at the same rotary speed and hence higher tip speed, so that the material is subject to a series of increasing shearing forces at the tips. - In Figure 2, the arrangement is more primarily concerned for batch production and the
vessel 101 has a frusto-conicallower portion 30 and a generally cylindricalupper portion 32. The stacked rotor assembly carried byshaft 161 is designed to be raised and lowered, i.e. moved in the direction of the arrows AA relative to the vessel. Theshaft 16 is again overhung, and the vessel is provided with 121 and 141 at the bottom and top respectively. The vessel may be charged with solvent for example through theports port 141 and particulate material may be vacuum induced in the vessel through theport 121. Alternatively and for example, the particulate material may be charged through theport 141. - The arrangement shown in Figure 3 is a further version primarily arranged for batch production like Figure 2 but in this case the stacked rotor set driven by the
overdrive shaft 162 is associated with acage 36 carried by astationary guide member 38, and the shearing forces applied to the material are due to the flow of the material between the rotor disc peripheries and thecage portions 40. The whole assembly of cage and rotors is vertically movable relative to the vessel. - Figure 3 also shows the use of a slow
speed stirring rotor 42 which in this instance is underdriven fromshaft 44 viagearbox 46. Theshaft 44 may be a hollow one providing for vacuum induction of particulate material via thevalve 48. - Preferably the cage is cooled, for example water-cooled and coolant may be delivered to the cage via
41,43 extending through apipes non-rotating sleeve 45 journalling thedrive shaft 162. The arrangement shown in Figure 4 differs from that in Figure 3 in that the slow speed rotor 421 is overdrive instead of being underdriven. - At least in the case of Figures 2-3 the whole rotor assembly may be raised and lowered. The effect on the product will be varied by so doing. In the case of Figure 2 the effect (of raising) will be to reduce the shear forces effect from the lower rotors because of the increased space from the vessel wall, and hence produce a more general stirring effect.
- The arrangement in Figure 5 is generally similar to that in Figure 1 but in this case the arrangement includes a series of
fixed baffles 50 interposed between the successive rotors and extending from the container walls towards the shaft. The effect of these is to cause an extended flow path for the whole of the material in flow from the inlet to the outlet so that it reverses direction radially and is subject to shearing forces in flow not only between the rotor tip and the container wall but also between the rotor and each of the baffles.
Claims (8)
1. Mixing and dispersing apparatus comprising a vessel and a main rotor shaft provided with a series of axially spaced rotors of progressively greater effective diameter along the length of the shaft.
2. Apparatus as claimed in Claim 1 wherein the vessel comprises a conical portion concentric to the axis of the main rotor shaft.
3. Apparatus as claimed in Claim 2 wherein the vessel has an inlet at the small end of the cone adjacent to the smallest of the series of rotors and an outlet at the large end of the cone adjacent the largest of the series of rotors.
4. Apparatus as claimed in Claim 1 wherein the vessel comprises a cylindrical portion and a conical portion, the said rotor shaft extends axially of the two portions and is displaceable axially to take the set of rotors into and out of the conical portion of the vessel.
5. Apparatus as claimed in Claim 1 wherein a cage surrounds the said series of rotors and the rotors are rotatable relative to said cage.
6. Apparatus as claimed in any proceeding Claim wherein a slow speed rotor comprising one or more blades closely conforming to the wall of the vessel is located between the same and the said series of spaced rotors.
7. Apparatus as claimed in Claim 1 comprising a series of fixed baffles each interposed between two adjacent rotors and mounted on the wall of the vessel and extending towards said shaft.
8. Apparatus as claimed in Claim 5 wherein said cage is water-cooled.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8816890 | 1988-07-15 | ||
| GB888816890A GB8816890D0 (en) | 1988-07-15 | 1988-07-15 | Apparatus for mixing & dispersing materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP0351125A1 true EP0351125A1 (en) | 1990-01-17 |
Family
ID=10640518
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP89306819A Withdrawn EP0351125A1 (en) | 1988-07-15 | 1989-07-05 | Apparatus for mixing and dispersing materials |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0351125A1 (en) |
| DK (1) | DK343389A (en) |
| GB (2) | GB8816890D0 (en) |
| PT (1) | PT91168A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2132725C1 (en) * | 1997-06-24 | 1999-07-10 | Кемеровский технологический институт пищевой промышленности | Centrifugal mixer |
| DE19811112A1 (en) * | 1998-03-13 | 1999-09-16 | Speedform Gmbh | Apparatus and method for mixing a quick-hardening embedding mass for production of molds for metal casting |
| RU2191063C1 (en) * | 2001-01-31 | 2002-10-20 | Кемеровский технологический институт пищевой промышленности | Centrifugal mixer |
| WO2007129340A1 (en) * | 2006-05-10 | 2007-11-15 | Comber S.R.L. | Conical-base drier |
| JP2014223581A (en) * | 2013-05-16 | 2014-12-04 | 株式会社井上製作所 | Low shear type concentric biaxial mixer |
| CN105480655A (en) * | 2015-12-04 | 2016-04-13 | 宜兴天山水泥有限责任公司 | Cement conveying system |
| EP3065552A4 (en) * | 2013-11-08 | 2017-07-26 | Sanso Förvaltning AB | Kneading device |
| KR20200038194A (en) * | 2018-10-02 | 2020-04-10 | 아사다텍코 가부시키가이샤 | Mixing device |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5577675A (en) * | 1995-01-25 | 1996-11-26 | Mitsui Mining Co., Ltd. | Agitating pulverizer |
| US6012473A (en) * | 1998-03-18 | 2000-01-11 | Takehiko Koyama | Fluid mixer and roller cleaner |
| RU2162409C1 (en) * | 1999-07-29 | 2001-01-27 | Яшин Александр Михайлович | Mixer |
| DE102011006636A1 (en) * | 2011-04-01 | 2012-10-04 | Harald Kniele | Pug mill mixer i.e. concrete mixer, for use in construction site for mixing liquid, powdery and/or granular components, has vibrating device coupled to shaft and actuated to simulate shaft for enabling vibration movements |
| JP6725504B2 (en) * | 2015-07-01 | 2020-07-22 | 住友重機械プロセス機器株式会社 | Stirrer |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB378841A (en) * | 1932-02-20 | 1932-08-18 | Albert Henkel | Improvements in and relating to mixing and stirring machines |
| US2163150A (en) * | 1937-08-14 | 1939-06-20 | Sinclair Refining Co | Oil refining apparatus |
| US2315251A (en) * | 1941-06-25 | 1943-03-30 | Edwin G Eppenbach | Combination mixer |
| US3010803A (en) * | 1956-06-21 | 1961-11-28 | Shell Oil Co | Fluid mixer with rotating baffles |
| US3158358A (en) * | 1963-03-11 | 1964-11-24 | Patterson Kelley Co | Materials blending machine |
| US3172609A (en) * | 1960-11-03 | 1965-03-09 | Kaiser Aluminium Chem Corp | Apparatus for disintegrating aggregates of solid material |
| FR1525094A (en) * | 1966-04-18 | 1968-05-17 | Method and device for the preparation of cement and concrete mortar | |
| DE2446975A1 (en) * | 1974-10-02 | 1976-04-15 | Hoechst Ag | Plant for processing viscous or granular materials - e.g. for drying mixing de-odorising degassing, polymerisation |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB270656A (en) * | 1926-05-10 | 1928-02-02 | Societe Chimique Des Usines Du Rhone | |
| GB1037665A (en) * | 1962-08-31 | 1966-08-03 | Unilever Ltd | Mixing device |
| US3268213A (en) * | 1964-06-08 | 1966-08-23 | Charles F Cala | Apparatus for homogenizing glass |
-
1988
- 1988-07-15 GB GB888816890A patent/GB8816890D0/en active Pending
-
1989
- 1989-07-04 GB GB8915294A patent/GB2220585A/en not_active Withdrawn
- 1989-07-05 EP EP89306819A patent/EP0351125A1/en not_active Withdrawn
- 1989-07-11 DK DK343389A patent/DK343389A/en not_active Application Discontinuation
- 1989-07-14 PT PT91168A patent/PT91168A/en not_active Application Discontinuation
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB378841A (en) * | 1932-02-20 | 1932-08-18 | Albert Henkel | Improvements in and relating to mixing and stirring machines |
| US2163150A (en) * | 1937-08-14 | 1939-06-20 | Sinclair Refining Co | Oil refining apparatus |
| US2315251A (en) * | 1941-06-25 | 1943-03-30 | Edwin G Eppenbach | Combination mixer |
| US3010803A (en) * | 1956-06-21 | 1961-11-28 | Shell Oil Co | Fluid mixer with rotating baffles |
| US3172609A (en) * | 1960-11-03 | 1965-03-09 | Kaiser Aluminium Chem Corp | Apparatus for disintegrating aggregates of solid material |
| US3158358A (en) * | 1963-03-11 | 1964-11-24 | Patterson Kelley Co | Materials blending machine |
| FR1525094A (en) * | 1966-04-18 | 1968-05-17 | Method and device for the preparation of cement and concrete mortar | |
| DE2446975A1 (en) * | 1974-10-02 | 1976-04-15 | Hoechst Ag | Plant for processing viscous or granular materials - e.g. for drying mixing de-odorising degassing, polymerisation |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2132725C1 (en) * | 1997-06-24 | 1999-07-10 | Кемеровский технологический институт пищевой промышленности | Centrifugal mixer |
| DE19811112A1 (en) * | 1998-03-13 | 1999-09-16 | Speedform Gmbh | Apparatus and method for mixing a quick-hardening embedding mass for production of molds for metal casting |
| RU2191063C1 (en) * | 2001-01-31 | 2002-10-20 | Кемеровский технологический институт пищевой промышленности | Centrifugal mixer |
| WO2007129340A1 (en) * | 2006-05-10 | 2007-11-15 | Comber S.R.L. | Conical-base drier |
| JP2014223581A (en) * | 2013-05-16 | 2014-12-04 | 株式会社井上製作所 | Low shear type concentric biaxial mixer |
| EP3065552A4 (en) * | 2013-11-08 | 2017-07-26 | Sanso Förvaltning AB | Kneading device |
| US10004238B2 (en) | 2013-11-08 | 2018-06-26 | Sanso Forvaltning Ab | Kneading device for post-working of a product |
| CN105480655A (en) * | 2015-12-04 | 2016-04-13 | 宜兴天山水泥有限责任公司 | Cement conveying system |
| KR20200038194A (en) * | 2018-10-02 | 2020-04-10 | 아사다텍코 가부시키가이샤 | Mixing device |
Also Published As
| Publication number | Publication date |
|---|---|
| GB8915294D0 (en) | 1989-08-23 |
| GB8816890D0 (en) | 1988-08-17 |
| DK343389D0 (en) | 1989-07-11 |
| DK343389A (en) | 1990-01-16 |
| GB2220585A (en) | 1990-01-17 |
| PT91168A (en) | 1990-02-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH DE ES FR GB GR IT LI LU NL SE |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
| 18D | Application deemed to be withdrawn |
Effective date: 19900718 |