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EP0348380A1 - Utilisation d'un alliage à base de fer pour la fabrication de pièces frittées, présentant une haute résistance à la corrosion, une haute résistance à l'usure ainsi qu'une haute tenacité et résistance à la compression et destinées, en particulier, au travail des matières synthétiques - Google Patents

Utilisation d'un alliage à base de fer pour la fabrication de pièces frittées, présentant une haute résistance à la corrosion, une haute résistance à l'usure ainsi qu'une haute tenacité et résistance à la compression et destinées, en particulier, au travail des matières synthétiques Download PDF

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Publication number
EP0348380A1
EP0348380A1 EP89890163A EP89890163A EP0348380A1 EP 0348380 A1 EP0348380 A1 EP 0348380A1 EP 89890163 A EP89890163 A EP 89890163A EP 89890163 A EP89890163 A EP 89890163A EP 0348380 A1 EP0348380 A1 EP 0348380A1
Authority
EP
European Patent Office
Prior art keywords
max
iron
content
alloy according
carbides
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP89890163A
Other languages
German (de)
English (en)
Other versions
EP0348380B2 (fr
EP0348380B1 (fr
Inventor
Alfred Dr. Kulmburg
Johann Dipl.-Ing. Stamberger
Hubert Dipl.-Ing. Lenger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Boehler Edelstahl alpha Edelstahl Gmbh boehle GmbH
Boehler GmbH Germany
Original Assignee
Boehler GmbH
Boehler GmbH Germany
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=3516903&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0348380(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Boehler GmbH, Boehler GmbH Germany filed Critical Boehler GmbH
Publication of EP0348380A1 publication Critical patent/EP0348380A1/fr
Application granted granted Critical
Publication of EP0348380B1 publication Critical patent/EP0348380B1/fr
Publication of EP0348380B2 publication Critical patent/EP0348380B2/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/02Making ferrous alloys by powder metallurgy
    • C22C33/0257Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements
    • C22C33/0278Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5%
    • C22C33/0285Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5% with Cr, Co, or Ni having a minimum content higher than 5%

Definitions

  • the invention relates to the use of an iron-based alloy with a special composition as a material for the powder metallurgical production of parts with high corrosion resistance, high wear resistance and high toughness and pressure resistance, preferably for plastic molds, machine parts and tools for non-cutting shaping.
  • a material for the powder metallurgical production of parts with high corrosion resistance, high wear resistance and high toughness and pressure resistance preferably for plastic molds, machine parts and tools for non-cutting shaping.
  • shaping parts are exposed to chemical and abrasive stresses at the same time, these parts having to have high material toughness, high compressive strength and special material homogeneity due to the mechanical stresses.
  • Such requirements are placed, for example, on materials that are used in devices for pressing fiber-reinforced or filler-containing plastics. Austenitic steels or chrome steels with a chromium content of approx.
  • alloys according to DIN material no. are used for mechanical components such as screws etc. and also for forming and pressing tools, which are particularly exposed to corrosive stresses. 1.4528. Although such materials have sufficient corrosion resistance, the wear behavior is usually unsatisfactory in practical operation. In order to improve or increase the wear resistance and hardness of the steel, attempts have also been made by higher carbon contents to increase the carbide content of the alloy. These steels, for example alloys according to DIN material no. 1.2080 and material no. 1.2379, with a carbon content of approx. 2% and a chromium content of approx.
  • the object of the invention is to avoid the above disadvantages and, in particular, to create materials which can be used advantageously for the plastics processing industry and which, due to a special composition when using certain manufacturing processes, provide high corrosion resistance, high wear resistance and high pressure resistance have good toughness properties.
  • the invention therefore relates to the use of an iron-based alloy with a composition in% by weight.
  • the alloy proportions in% by weight chrome 18.0 - 25.0 molybdenum 0.6 - 1.7 tungsten 0.5 - 1.5 Vanadium 3.5 - 5.6 nitrogen 0.03-0.1 niobium up to 5.0 titanium up to 5.0 boron to 0.03
  • the material has a niobium content of 0.2 to 3.0 and / or a titanium content of 0.2 to 3.5 and / or a boron content of 0.001 to 0.002. It is particularly preferred if the value is formed from (% Cr - 13) + 4.4x (% V - 3) + 2x (% Nb) + 4.2x (Ti) is at least 10.0.
  • the parts which are manufactured from the alloy according to the invention or from the material according to the invention by a powder metallurgical manufacturing process must have a chromium concentration in all parts of the matrix of at least 13 after hardening and tempering.
  • the alloy according to the invention from a minimum value, which takes into account the concentrations and the respective effect with the mutual influence of the carbide-forming elements chromium, vanadium, niobium and titanium, and which in particular determines the wear resistance of the material, in certain narrow Limits set carbon contents and when using powder metallurgical manufacturing processes, materials that have high corrosion resistance, high wear resistance, high pressure resistance and high toughness and are advantageous, especially for the construction of plastic molds, can be used, the hardened and tempered state of the Chromium content in all areas of the matrix and the proportion as well as the composition and the grain size of the carbides can be adjusted according to the invention.
  • Silicon as a deoxidizing agent influences the composition of the oxides and, in small concentrations, can be advantageous for good polishability from Le manufactured parts. Levels above 1% by weight, however, have an adverse effect on the solidification behavior and, if appropriate, on the conversion processes during the heat treatment. Manganese contents of up to 1% by weight may be important for sulfur contents of up to 0.03% by weight in order to bind the sulfur as sulfide and thereby improve the toughness of the material. Phosphorus has an embrittling effect and should be present in the steel as low as possible, but below 0.03% by weight. Chromium acts as an alloying element which, from a content of approx. 13% by weight in the matrix, makes the material resistant to corrosion.
  • chromium is a carbide former that can also form M23C6 carbides with carbon in certain carbon activities and in the presence of molybdenum and vanadium in addition to M7C3 carbides. It is therefore important that the steel contains at least 16% by weight of chromium, but at most contains 29% by weight of chromium, because higher chromium concentrations lead to embrittlement of the material. Molybdenum in a content of 0.4 to 2.5 wt .-% and tungsten in a content of 0.3 to 2.0 wt .-% cause an increase in secondary hardness in the heat treatment by the formation of fine carbides and are used to adjust the carbon activity Alloy important.
  • Vanadium as a strong carbide former, causes the formation of MC carbides, especially at levels above 0.7 to 3% by weight. Higher contents, in particular over 10%, lead to an improvement in wear resistance, but the toughness of the parts deteriorates considerably. Titanium up to 5% by weight improves the wear resistance of the material, in particular through MC carbide formation. Due to nitride formation, nitrogen contents from 0.01% have a grain-refining effect or prevent grain growth during annealing at high temperatures tures, whereby a decrease in the toughness of the alloy is avoided. Furthermore, wear resistance can be improved by nitrogen concentrations up to 0.18%.
  • Aluminum can be alloyed as an element with a high affinity for oxygen and a high affinity for nitrogen in concentrations of up to 1% by weight to adjust the low oxygen content of the steel and to avoid grain growth, whereby advantageous effects on the conversion behavior and the toughness of the material can also be achieved. It was also found that a minimum value of the alloy, formed from the concentrations of the carbide- and nitride-forming elements chromium, tungsten, niobium, titanium and certain action factors of these elements is required for the setting of the desired mechanical properties of the part, by increasing this Worth an improvement in wear resistance and compressive strength with a slight decrease in toughness.
  • the carbon content is set within narrow limits depending on the contents and on certain operating parameters of the carbide-forming elements in the steel in order to obtain the desired properties of the parts.
  • MC carbides are formed for matrix hardening and to obtain high compressive strength M7C3, M23C6 and M6C carbides and for setting high wear resistance, but on the other hand there is a chromium content of greater than 13% required for corrosion resistance in all areas of the matrix.
  • Powder-metallurgical production of the parts is essential because this significantly improves their isotropy of the properties of the material and the grain size of the precipitates or intermetallic phases can be kept small.
  • Carbides with grain sizes over 14 ⁇ m significantly impair the mechanical properties, in particular the bending strength of the parts.
  • the powder can be produced using all suitable processes, in particular using gas atomization processes, after which, if appropriate, compacting is carried out by hot-isostatic pressing and / or by hot-working the powder in suitable casings.
  • the wear behavior of the part was tested in the grinding wheel test, in which a steel disc rotates in a corundum-water mixture, against which the sample is pressed.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Powder Metallurgy (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Mounting, Exchange, And Manufacturing Of Dies (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
EP89890163A 1988-06-21 1989-06-14 Utilisation d'un alliage à base de fer pour la fabrication de pièces frittées, présentant une haute résistance à la corrosion, une haute résistance à l'usure ainsi qu'une haute tenacité et résistance à la compression et destinées, en particulier, au travail des matières synthétiques Expired - Lifetime EP0348380B2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AT0159988A AT393642B (de) 1988-06-21 1988-06-21 Verwendung einer eisenbasislegierung zur pulvermetallurgischen herstellung von teilen mit hoher korrosionsbestaendigkeit, hoher verschleissfestigkeit sowie hoher zaehigkeit und druckfestigkeit, insbesondere fuer die kunststoffverarbeitung
AT1599/88 1988-06-21

Publications (3)

Publication Number Publication Date
EP0348380A1 true EP0348380A1 (fr) 1989-12-27
EP0348380B1 EP0348380B1 (fr) 1992-11-19
EP0348380B2 EP0348380B2 (fr) 1996-04-17

Family

ID=3516903

Family Applications (1)

Application Number Title Priority Date Filing Date
EP89890163A Expired - Lifetime EP0348380B2 (fr) 1988-06-21 1989-06-14 Utilisation d'un alliage à base de fer pour la fabrication de pièces frittées, présentant une haute résistance à la corrosion, une haute résistance à l'usure ainsi qu'une haute tenacité et résistance à la compression et destinées, en particulier, au travail des matières synthétiques

Country Status (8)

Country Link
EP (1) EP0348380B2 (fr)
JP (1) JP2583451B2 (fr)
AT (2) AT393642B (fr)
AU (1) AU615756B2 (fr)
DE (1) DE58902742D1 (fr)
ES (1) ES2052971T5 (fr)
PT (1) PT90925B (fr)
ZA (1) ZA894703B (fr)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0378925A1 (fr) * 1988-12-27 1990-07-25 Daido Tokushuko Kabushiki Kaisha Poudre d'acier pour outil de travail à froid
GB2298869A (en) * 1995-03-10 1996-09-18 Powdrex Ltd Stainless steel powders and articles produced therefrom by powder metallurgy
EP0721995A3 (fr) * 1995-01-16 1996-11-27 Boehler Edelstahl Utilisation d'un alliage ferreux pour la fabrication de formes pour la transformation des matières plastiques
US5679908A (en) * 1995-11-08 1997-10-21 Crucible Materials Corporation Corrosion resistant, high vanadium, powder metallurgy tool steel articles with improved metal to metal wear resistance and a method for producing the same
WO2000073527A1 (fr) * 1999-05-28 2000-12-07 Edelstahl Witten-Krefeld Gmbh Acier compacte par pulverisation, son procede de fabrication et materiau composite
WO2003069004A1 (fr) * 2002-02-15 2003-08-21 Uddeholm Tooling Aktiebolag Acier d'outillage riche en carbure et en chrome, fabrique selon les techniques de la metallurgie des poudres, et outil fait de cet alliage
RU2283888C2 (ru) * 2001-11-13 2006-09-20 Фундасьон Инасмет Изготовление продукта из конструкционных металлических материалов, армированных карбидами
WO2006112912A1 (fr) * 2005-04-18 2006-10-26 Wilson Tool International Inc. Poinçons et matrices solides et resistants a l'usure, formes d'acier ecroui issu de la metallurgie des poudres
AT501794A1 (de) * 2005-04-26 2006-11-15 Boehler Edelstahl Kunststoffform
US7442338B2 (en) 2001-11-13 2008-10-28 Fundacion Inasmet Product manufacture in structural metallic materials reinforced with carbides
WO2011115547A1 (fr) * 2010-03-17 2011-09-22 Uddeholms Ab Procédé de fabrication d'une plaque d'usure pour guide de lame de scie à ruban, plaque d'usure de ce type, et utilisation d'un matériau en acier pour la production de la plaque d'usure
EP3428300A1 (fr) * 2017-07-10 2019-01-16 Saar-Pulvermetall GmbH Rouleau pour un dispositif moulin et / ou presse, en particulier un rouleau de pressage pour une presse de fabrication de pellets et procédé de fabrication de rouleau
CN111850427A (zh) * 2020-06-07 2020-10-30 江苏钢银智能制造有限公司 一种合金钢材料及其钢板材加工铸造工艺

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5900560A (en) * 1995-11-08 1999-05-04 Crucible Materials Corporation Corrosion resistant, high vanadium, powder metallurgy tool steel articles with improved metal to metal wear resistance and method for producing the same
CN103060700B (zh) * 2013-01-07 2014-12-31 北京工业大学 硼化物颗粒强化Fe-Cr-Al复合材料及其制造方法
CN104878298B (zh) * 2015-05-15 2017-05-03 安泰科技股份有限公司 粉末冶金耐磨损耐腐蚀合金
WO2021007209A1 (fr) 2019-07-09 2021-01-14 Oerlikon Metco (Us) Inc. Alliages à base de fer conçus pour être dotés d'une résistance à l'usure et à la corrosion
JP2022182485A (ja) * 2021-05-28 2022-12-08 山陽特殊製鋼株式会社 耐食性に優れた工具鋼

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1313981A (en) * 1970-08-28 1973-04-18 Hoeganaes Ab High alloy steel powders and their consolidation into homogeneous tool steel
LU81268A1 (de) * 1978-09-20 1979-09-10 Crucible Inc Pulvermetallurgischer stahlartikel mit hohem vanadiumcarbidgehalt
EP0271238A2 (fr) * 1986-12-11 1988-06-15 Crucible Materials Corporation Articles en un alliage résistant à l'usure et à la corrosion

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2204886C3 (de) * 1972-02-02 1979-11-22 Gfe Gesellschaft Fuer Elektrometallurgie Mbh, 4000 Duesseldorf Verfahren zur pulvermetallurgischen Herstellung von Schnellarbeitsstahl-Formkörpern
SE446277B (sv) * 1985-01-16 1986-08-25 Kloster Speedsteel Ab Vanadinhaltigt verktygsstal framstellt av metallpulver och sett vid dess framstellning

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1313981A (en) * 1970-08-28 1973-04-18 Hoeganaes Ab High alloy steel powders and their consolidation into homogeneous tool steel
LU81268A1 (de) * 1978-09-20 1979-09-10 Crucible Inc Pulvermetallurgischer stahlartikel mit hohem vanadiumcarbidgehalt
EP0271238A2 (fr) * 1986-12-11 1988-06-15 Crucible Materials Corporation Articles en un alliage résistant à l'usure et à la corrosion

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0378925A1 (fr) * 1988-12-27 1990-07-25 Daido Tokushuko Kabushiki Kaisha Poudre d'acier pour outil de travail à froid
EP0721995A3 (fr) * 1995-01-16 1996-11-27 Boehler Edelstahl Utilisation d'un alliage ferreux pour la fabrication de formes pour la transformation des matières plastiques
GB2298869A (en) * 1995-03-10 1996-09-18 Powdrex Ltd Stainless steel powders and articles produced therefrom by powder metallurgy
GB2298869B (en) * 1995-03-10 1999-03-03 Powdrex Ltd Stainless steel powders and articles produced therefrom by powder metallurgy
US5679908A (en) * 1995-11-08 1997-10-21 Crucible Materials Corporation Corrosion resistant, high vanadium, powder metallurgy tool steel articles with improved metal to metal wear resistance and a method for producing the same
US5936169A (en) * 1995-11-08 1999-08-10 Crucible Materials Corporation Corrosion resistant, high vanadium, powder metallurgy tool steel articles with improved metal to metal wear resistance and a method for producing the same
WO2000073527A1 (fr) * 1999-05-28 2000-12-07 Edelstahl Witten-Krefeld Gmbh Acier compacte par pulverisation, son procede de fabrication et materiau composite
RU2283888C2 (ru) * 2001-11-13 2006-09-20 Фундасьон Инасмет Изготовление продукта из конструкционных металлических материалов, армированных карбидами
US7442338B2 (en) 2001-11-13 2008-10-28 Fundacion Inasmet Product manufacture in structural metallic materials reinforced with carbides
WO2003069004A1 (fr) * 2002-02-15 2003-08-21 Uddeholm Tooling Aktiebolag Acier d'outillage riche en carbure et en chrome, fabrique selon les techniques de la metallurgie des poudres, et outil fait de cet alliage
WO2006112912A1 (fr) * 2005-04-18 2006-10-26 Wilson Tool International Inc. Poinçons et matrices solides et resistants a l'usure, formes d'acier ecroui issu de la metallurgie des poudres
AT501794A1 (de) * 2005-04-26 2006-11-15 Boehler Edelstahl Kunststoffform
AT501794B1 (de) * 2005-04-26 2008-06-15 Boehler Edelstahl Kunststoffform
WO2011115547A1 (fr) * 2010-03-17 2011-09-22 Uddeholms Ab Procédé de fabrication d'une plaque d'usure pour guide de lame de scie à ruban, plaque d'usure de ce type, et utilisation d'un matériau en acier pour la production de la plaque d'usure
CN102905831A (zh) * 2010-03-17 2013-01-30 尤迪霍尔姆斯有限责任公司 用于制备带锯条导向装置的垫磨片的方法,这样的垫磨片,以及钢材用于制备所述垫磨片的用途
EP3428300A1 (fr) * 2017-07-10 2019-01-16 Saar-Pulvermetall GmbH Rouleau pour un dispositif moulin et / ou presse, en particulier un rouleau de pressage pour une presse de fabrication de pellets et procédé de fabrication de rouleau
CN111850427A (zh) * 2020-06-07 2020-10-30 江苏钢银智能制造有限公司 一种合金钢材料及其钢板材加工铸造工艺

Also Published As

Publication number Publication date
PT90925A (pt) 1989-12-29
ATE82595T1 (de) 1992-12-15
ATA159988A (de) 1991-05-15
AU615756B2 (en) 1991-10-10
DE58902742D1 (de) 1992-12-24
ZA894703B (en) 1992-01-29
AU3666289A (en) 1990-01-25
ES2052971T5 (es) 1996-10-01
ES2052971T3 (es) 1994-07-16
JP2583451B2 (ja) 1997-02-19
PT90925B (pt) 1997-10-31
EP0348380B2 (fr) 1996-04-17
AT393642B (de) 1991-11-25
JPH0277556A (ja) 1990-03-16
EP0348380B1 (fr) 1992-11-19

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