EP0201368A1 - Composition de marquage et de dénaturation, particulièrement adaptée au marquage et à la dénaturation de carburants diesel et similaires - Google Patents

Composition de marquage et de dénaturation, particulièrement adaptée au marquage et à la dénaturation de carburants diesel et similaires Download PDF

Info

Publication number: EP0201368A1
Authority: EP; European Patent Office
Prior art keywords: marking; denaturing; anthraquinone; oil; diesel oil
Prior art date: 1985-04-12
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

EP86400642A

Other languages

German (de)

English (en)

Other versions

EP0201368B1 (fr

Inventor

Carlo Prandi

Alberto Osti

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BASF Italia SpA

Original Assignee

PIGMENTI ITALIA SpA

BASF Italia SpA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1985-04-12

Filing date

1986-03-26

Publication date

1986-11-12

1986-03-26 Application filed by PIGMENTI ITALIA SpA, PIGMENTI ITALIA SpA, BASF Italia SpA filed Critical PIGMENTI ITALIA SpA

1986-11-12 Publication of EP0201368A1 publication Critical patent/EP0201368A1/fr

1989-07-19 Application granted granted Critical

1989-07-19 Publication of EP0201368B1 publication Critical patent/EP0201368B1/fr

Status Expired legal-status Critical Current

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/003—Marking, e.g. coloration by addition of pigments
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
- C10L1/1857—Aldehydes; Ketones

Definitions

the Invention relates to a marking and denaturing composition, particularly suitable for marking and denaturing diesel oil and similar oil products.
U.S. patent 4 209 302 discloses the use of naphtylamine derivatives. However, these compounds do not completely satisfy the requirements herein-above, especially because they can easily be extracted from the marked product.
the invention concerns a marking and denaturing composition, particularly suitable for diesel oil and for similar oil products, containing an anthraquinone derivative having the formula: where R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 and R 8 identical or different, represent a hydrogen atom, a halogen atom or an alkyl, cycloalkyl or arylalkyl radical having from 1 to 12 carbon atoms.
Oils products similar to diesel oil are, for example, gasoline, kerosene oil and lamp oil.
anthraquinone derivative to be used as a marker can vary within wide limits and the minimum value merely depends upon the identification test. By using the simple and rapid test described herein-after, concentrations as low as 1 to 3 ppm can be used.
a greater amount is added, in order to obtain in any case a positive result and also to foresee the case where the marked product is diluted at the time the fraud occurs. From a practical point of view, from 1 to 300 ppm (and preferably 3-50 ppm) can be used.
the markers according to the present invention should be prescribed, in particular, when an anthraquinone dye and/or an azoic dye is present; best results are obtained when using said markers or marking compositions in admixture with furfural and/or with other suitable organic solvents, for example xylenes, these xylenes generally acting as a diluent.
Example 1 was repeated, by carrying out the test on the same diesel oil, without any admixture of the marking solution, the final bottom layer was light brown.
Example 6 was repeated while replacing gasoline by lamp oil to be used for the lighting of fishing boats.
the final bottom aqueous layer obtained also presented a deep red color.
Example 1 was repeated while modifying the chemical nature of the marker and its concentration; data and results are on table 1.

Landscapes

Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Emergency Medicine (AREA)
Lubricants (AREA)
Inks, Pencil-Leads, Or Crayons (AREA)

EP86400642A 1985-04-12 1986-03-26 Composition de marquage et de dénaturation, particulièrement adaptée au marquage et à la dénaturation de carburants diesel et similaires Expired EP0201368B1 (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
IT20316/85A IT1200452B (it)	1985-04-12	1985-04-12	Composizione denaturante e marcante,particolarmente adatta per gasolio
IT2031685		1985-04-12

Publications (2)

Publication Number	Publication Date
EP0201368A1 true EP0201368A1 (fr)	1986-11-12
EP0201368B1 EP0201368B1 (fr)	1989-07-19

Family

ID=11165673

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP86400642A Expired EP0201368B1 (fr)	1985-04-12	1986-03-26	Composition de marquage et de dénaturation, particulièrement adaptée au marquage et à la dénaturation de carburants diesel et similaires

Country Status (3)

Country	Link
EP (1)	EP0201368B1 (fr)
DE (1)	DE3664476D1 (fr)
IT (1)	IT1200452B (fr)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP1001003A1 (fr) *	1998-11-09	2000-05-17	Morton International, Inc.	Methode de marquage invisible de produits pétroliers au moyen de colorants visibles
RU2199574C1 (ru) *	2001-06-06	2003-02-27	Институт химии нефти СО РАН	Химический маркер
EP1323811A3 (fr) *	2001-12-20	2003-12-03	Rohm And Haas Company	Procédé de marquage des hydrocarbures avec des anthraquinones
WO2005063942A1 (fr) *	2003-12-23	2005-07-14	Basf Aktiengesellschaft	Concentres d'additifs de carburants et de lubrifiants contenant au moins un derive d'anthrachinone comme matiere de marquage
US6977177B1 (en)	2004-05-26	2005-12-20	Rohm And Haas Company	Method for marking hydrocarbons with substituted anthraquinones
US7157611B2 (en)	2002-07-11	2007-01-02	Rohm And Haas Company	Pyrazinoporphyrazines as markers for liquid hydrocarbons
CN1321965C (zh) *	2005-07-22	2007-06-20	清华大学	蒽醌衍生物的合成方法
US7635596B2 (en)	2004-12-15	2009-12-22	Rohm And Haas Company	Method for monitoring degradation of lubricating oils
US7915048B2 (en)	2003-06-13	2011-03-29	Rohm And Haas Company	Method for marking hydrocarbons with substituted anthraquinones
WO2021110526A1 (fr)	2019-12-03	2021-06-10	Sicpa Holding Sa	Procédé de marquage d'un hydrocarbure de pétrole

Citations (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
BE524604A (fr) *
GB361310A (en) *	1930-06-18	1931-11-18	Howard Ferguson	Improvements in and relating to motor fuels or like combustible liquids
GB851639A (en) *	1958-09-26	1960-10-19	Exxon Research Engineering Co	Improved hydrocarbon oils
US3164449A (en) *	1961-03-01	1965-01-05	Du Pont	Anthraquinone dyes for gasoline
DE2702985C2 (de) *	1977-01-26	1979-02-15	Basf Ag, 6700 Ludwigshafen	Verfahren zur Herstellung von deckenden Pyranthronpigmenten

1985
- 1985-04-12 IT IT20316/85A patent/IT1200452B/it active
1986
- 1986-03-26 EP EP86400642A patent/EP0201368B1/fr not_active Expired
- 1986-03-26 DE DE8686400642T patent/DE3664476D1/de not_active Expired

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
BE524604A (fr) *
GB361310A (en) *	1930-06-18	1931-11-18	Howard Ferguson	Improvements in and relating to motor fuels or like combustible liquids
GB851639A (en) *	1958-09-26	1960-10-19	Exxon Research Engineering Co	Improved hydrocarbon oils
US3164449A (en) *	1961-03-01	1965-01-05	Du Pont	Anthraquinone dyes for gasoline
DE2702985C2 (de) *	1977-01-26	1979-02-15	Basf Ag, 6700 Ludwigshafen	Verfahren zur Herstellung von deckenden Pyranthronpigmenten

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6274381B1 (en)	1998-11-09	2001-08-14	Rohm And Haas Company	Method for invisibly tagging petroleum products using visible dyes
EP1001003A1 (fr) *	1998-11-09	2000-05-17	Morton International, Inc.	Methode de marquage invisible de produits pétroliers au moyen de colorants visibles
RU2199574C1 (ru) *	2001-06-06	2003-02-27	Институт химии нефти СО РАН	Химический маркер
EP1323811A3 (fr) *	2001-12-20	2003-12-03	Rohm And Haas Company	Procédé de marquage des hydrocarbures avec des anthraquinones
US6811575B2 (en)	2001-12-20	2004-11-02	Rohm And Haas Company	Method for marking hydrocarbons with anthraquinones
US7157611B2 (en)	2002-07-11	2007-01-02	Rohm And Haas Company	Pyrazinoporphyrazines as markers for liquid hydrocarbons
US7915048B2 (en)	2003-06-13	2011-03-29	Rohm And Haas Company	Method for marking hydrocarbons with substituted anthraquinones
AU2004309053B2 (en) *	2003-12-23	2010-06-10	Basf Aktiengesellschaft	Power and lubricant additive concentrates containing at least one anthrachinone derivative as a marking substance
WO2005063942A1 (fr) *	2003-12-23	2005-07-14	Basf Aktiengesellschaft	Concentres d'additifs de carburants et de lubrifiants contenant au moins un derive d'anthrachinone comme matiere de marquage
US6977177B1 (en)	2004-05-26	2005-12-20	Rohm And Haas Company	Method for marking hydrocarbons with substituted anthraquinones
US7635596B2 (en)	2004-12-15	2009-12-22	Rohm And Haas Company	Method for monitoring degradation of lubricating oils
CN1321965C (zh) *	2005-07-22	2007-06-20	清华大学	蒽醌衍生物的合成方法
WO2021110526A1 (fr)	2019-12-03	2021-06-10	Sicpa Holding Sa	Procédé de marquage d'un hydrocarbure de pétrole
US12031098B2 (en)	2019-12-03	2024-07-09	Sicpa Holding Sa	Method of marking a petroleum hydrocarbon

Also Published As

Publication number	Publication date
DE3664476D1 (en)	1989-08-24
IT8520316A0 (it)	1985-04-12
EP0201368B1 (fr)	1989-07-19
IT1200452B (it)	1989-01-18

Publication	Publication Date	Title
US4904765A (en)	1990-02-27	Dye mixtures containing an oil-soluble dye and an acid-extractable dye
EP0201368B1 (fr)	1989-07-19	Composition de marquage et de dénaturation, particulièrement adaptée au marquage et à la dénaturation de carburants diesel et similaires
DE69203640T2 (de)	1995-12-21	Unsichtbare Kennzeichen für Petroleum, Verfahren zur Markierung und Verfahren zum Nachweisen.
DE3017653C2 (de)	1984-01-05	Verwendung von Markierungssubstanzen in Mineralölbrennstoffen und Nachweis dieser Markierungssubstanzen
EP0669968A1 (fr)	1995-09-06	Anilines utilisees comme agents de marquage pour des huiles minerales.
DE69614843T2 (de)	2002-04-11	Farblose petroleumsmarkierungsmittel
CN1264803C (zh)	2006-07-19	用于标记或示踪有机产品的芳香酯
US4764474A (en)	1988-08-16	Method for detecting a tagging compound
DE4001662A1 (de)	1991-07-25	Markierte mineraloele sowie verfahren zum markieren von mineraloelen mittels basischer farbstoffe
CN1088742C (zh)	2002-08-07	碱反应性石油燃料标识物的显色剂体系
ZA200305571B (en)	2004-09-13	Method for the marking of mineral oil.
EP0767822A1 (fr)	1997-04-16	Utilisation de leucotriarylmethanes pour marquer des hydrocarbures
EP0736080B1 (fr)	1999-03-31	Utilisation de colorants azoiques pour le marquage d'hydrocarbures et nouveaux colorants azoiques
JP2642081B2 (ja)	1997-08-20	酸抽出性石油燃料マーカー
EP0419976A1 (fr)	1991-04-03	Colorants azoiques dérivés de l'aniline et solubles dans les huiles
US5663386A (en)	1997-09-02	Method for marking mineral oils with amthraquinones
EP0027917B1 (fr)	1984-10-10	Réactif et procédé pour la détermination d'hydrazine
EP0149125B1 (fr)	1989-04-19	Composés de marquage et méthode pour détecter ces composés
AU686838B2 (en)	1998-02-12	Use of benzaldehydes to mark hydrocarbons
CA1098808A (fr)	1981-04-07	Appareil et substance pour le dosage de substances a activite peroxydative
US7956170B2 (en)	2011-06-07	Aromatic-aliphatic azo derivatives particularly as markers for petroleum products, method for synthesizing them, use thereof and derived compositions
EP0310319B1 (fr)	1992-04-15	Utilisation d'alkyl (C1-C4)-phenyl-kétone pour marquer des produits pétroliérs et des solvants organiques
WO1995000606A1 (fr)	1995-01-05	Utilisation d'aminotriarylmethanes pour le marquage d'hydrocarbures, et nouveaux aminotriarylmethanes
JP3117040B2 (ja)	2000-12-11	Ａ重油１０％残留炭素分測定用標準色液列およびこれを使用する測定方法
US3190870A (en)	1965-06-22	Method of preparing colored modified clay

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Date	Code	Title	Description
1986-09-27	PUAI	Public reference made under article 153(3) epc to a published international application that has entered the european phase	Free format text: ORIGINAL CODE: 0009012
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