Classifications

• • G—PHYSICS
  • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
  • G21C—NUCLEAR REACTORS
  • G21C3/00—Reactor fuel elements and their assemblies; Selection of substances for use as reactor fuel elements
  • G21C3/42—Selection of substances for use as reactor fuel
  • G21C3/58—Solid reactor fuel Pellets made of fissile material
  • G21C3/62—Ceramic fuel
• • C—CHEMISTRY; METALLURGY
  • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
  • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
  • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
  • C04B35/51—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on compounds of actinides
• • G—PHYSICS
  • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
  • G21C—NUCLEAR REACTORS
  • G21C3/00—Reactor fuel elements and their assemblies; Selection of substances for use as reactor fuel elements
  • G21C3/42—Selection of substances for use as reactor fuel
  • G21C3/58—Solid reactor fuel Pellets made of fissile material
  • G21C3/62—Ceramic fuel
  • G21C3/623—Oxide fuels
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
  • Y02E30/00—Energy generation of nuclear origin
  • Y02E30/30—Nuclear fission reactors

Definitions

• the present invention concerns the fabrication of pellets, in particular nuclear fuel pellets comprising uranium dioxide or a mixture of uranium and plutonium dioxides.
• pellets basically involves the pressing of powder into green pellets which are then sintered to a required density.
• the powder feed to the pelleting presses must have good pour qualities such that it will flow freely and evenly into the press dies. To achieve good pour qualities it is accepted practice to granulate the powder using either a binder or binderless technique.
• the binder technique involves the addition of a proprietary organic binding agent to the powder.
• the powder is slurried with solvent and binder, the slurry is spray-dried to dispel solvent and granules are discharged and classified on vibratory screens.
• powder mixing with binder and solvent can be achieved in a dough-­mixer, which can also be used to dispel solvent during the mixing process.
• powder is pre-compacted into briquettes which are then fractured, sieved and conditioned to produce granules for subsequent pelleting operations.
• the initial step in both the binder and binderless techniques can involve attrition of the powder feed, conveniently by ball milling. This step serves to break down the powder and in the case where the feed is a mixture of different powders to achieve homogenisation.
• a lubricant such as zinc stearate, can be introduced into the mill, preferably before the introduction of the powder or powders, in order the prevent compaction within the mill.
• the fabrication of pellets by a binderless technique comprises subjecting dry powder or a mixture of powders to attrition to increase the packing density thereof, thereafter and without pre-compaction and granulation conditioning the treated powder or mixture such that it is capable of free flow and pressing the free-flowing powder or mixture into green pellets having a required density.
• the invention omits the pre-compaction and granulation stages from the existing binderless route for pellet production and for convenience can be termed the "short binderless route".
• Attrition by ball milling can be performed in a rolling polypropylene mill pot using hardened steel balls at a ball/charge weight ratio of approximately 6/1.
• the balls ranged in diameter from 6 to 19mm.
• the mill was run for a short time interval of about one minute with approximately 0.1% zinc stearate powder before adding the charge.
• precompaction was achieved in a 25 mm die fitted to a 10 ton hydraulic press.
• the precompaction pressure was adjusted to result in a precompact density of about 4.5 g/cc.
• the precompacts were broken and granulated through a stainless steel mesh.
• Conditioning can be achieved by rolling either powder or granules in a cylinder. Conveniently, after conditioning, approximately 0.2% zinc stearate can be added to serve as a lubricant for the subsequent pelletising operation.
• Green pellets were pressed hydraulically in a 9.9mm diameter die. Geometric green densities were measured on the pellets pressed at various pressures in the range 2.36 to 6.30 Te/cm2.
• Green pellets can be sintered in a 4.6% H2-Ar atmosphere using a batch furnace operating at a maximum temperature of 1650°C. The heating rate was 200°C/hour and the normal sintering time at maximum temperature was 6 hours.
• UO2 powder from the milling stage was divided into two batches, batch 1 being processed by the normal binderless route to include precompaction and granulation and batch 2 being processed by the short binderless route.
• batch 1 being processed by the normal binderless route to include precompaction and granulation
• batch 2 being processed by the short binderless route.
• a comparison of the densities of the green and sintered pellets is given in the following table.
• Attritor mill As an alternative to a conventional rolling ball mill it is possible to employ an Attritor mill in which the balls are driven within an upright cylinder or barrel having a rotatable paddle.
• an Attritor mill having a charge of 18Kg hardened stainless steel balls was run at speeds of 120 to 240 rpm (revolutions per minute) with milling times of between 10 and 30 minutes. Results indicate that 10 minutes Attritor milling at 180 rpm yields a powder with very similar tap-density and specific surface area to that achieved by six hours ball milling.

Landscapes

• Engineering & Computer Science (AREA)
• Chemical & Material Sciences (AREA)
• Physics & Mathematics (AREA)
• Ceramic Engineering (AREA)
• Plasma & Fusion (AREA)
• High Energy & Nuclear Physics (AREA)
• General Engineering & Computer Science (AREA)
• Manufacturing & Machinery (AREA)
• Materials Engineering (AREA)
• Structural Engineering (AREA)
• Organic Chemistry (AREA)
• Inorganic Compounds Of Heavy Metals (AREA)
• Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)

Applications Claiming Priority (2)

Publications (3)

Family

ID=10611636

Family Applications (1)

Country Status (4)

Cited By (7)

Families Citing this family (1)

Family Cites Families (11)

• 1987
  • 1987-02-03 GB GB878702371A patent/GB8702371D0/en active Pending
• 1988
  • 1988-01-12 GB GB08800589A patent/GB2200788A/en not_active Withdrawn
  • 1988-01-12 DE DE3851903T patent/DE3851903T2/de not_active Revoked
  • 1988-01-12 EP EP88300215A patent/EP0277708B1/fr not_active Revoked
  • 1988-02-01 JP JP63021819A patent/JP2650938B2/ja not_active Expired - Lifetime

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