EP0265443A1 - Ameliorations apportees a des produits du tabac - Google Patents
Ameliorations apportees a des produits du tabacInfo
- Publication number
- EP0265443A1 EP0265443A1 EP19870900190 EP87900190A EP0265443A1 EP 0265443 A1 EP0265443 A1 EP 0265443A1 EP 19870900190 EP19870900190 EP 19870900190 EP 87900190 A EP87900190 A EP 87900190A EP 0265443 A1 EP0265443 A1 EP 0265443A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- tobacco
- zinc
- tobacco products
- iron
- ferric oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 235000019505 tobacco product Nutrition 0.000 title claims abstract description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 16
- 241000208125 Nicotiana Species 0.000 claims abstract description 10
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims abstract description 10
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000011787 zinc oxide Substances 0.000 claims abstract description 8
- 235000019504 cigarettes Nutrition 0.000 claims abstract description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- 229910052742 iron Inorganic materials 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 4
- 150000003752 zinc compounds Chemical class 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 235000019506 cigar Nutrition 0.000 claims 1
- 150000002506 iron compounds Chemical class 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052799 carbon Inorganic materials 0.000 abstract description 4
- 150000001875 compounds Chemical class 0.000 abstract description 4
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 4
- 206010013911 Dysgeusia Diseases 0.000 abstract description 2
- 230000000711 cancerogenic effect Effects 0.000 abstract 2
- 231100000315 carcinogenic Toxicity 0.000 abstract 2
- 230000000694 effects Effects 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 230000000391 smoking effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 206010058467 Lung neoplasm malignant Diseases 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 201000005202 lung cancer Diseases 0.000 description 1
- 208000020816 lung neoplasm Diseases 0.000 description 1
- 229960002715 nicotine Drugs 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
Definitions
- the present invention relates to tobacco products.
- the present invention seeks to provide an improved form of tobacco product.
- tobacco used herein includes not only tobacco but also other substances and tobacco-like substances which may be smoked.
- the present invention provides a mixture comprising tobacco and at least one substance selected from iron and zinc compounds of the type that are reduced to iron or zinc respectively on exposure to high temperatures.
- ferric oxide Under the conditions existing in the combustion area of a tobacco product which is being smoked, such as a cigarette, incorporating for example ferric oxide in particulate form, the ferric oxide is reduced to iron. In this state immediately after reduction the iron is pure and highly reactive, dissociating water vapour into hydrogen and oxygen and also causing the preferential combination of nitrogen with hydrogen, rather than with oxygen and carbon, to form ammonia in trace quantities which vapourise. Thus the combination of nitrogen and carbon to form, for example, pyridenes is reduced if not eliminated.
- the use alternatively or additionally of zinc oxide produces a similar effect and increases the nicotine yield in the resulting smoke.
- ferric oxide and/or zinc oxide also has the unexpected effect of removing the less desirable "taste” or "after taste” aspects of the tobacco products.
- ferric oxide and/or zince oxide are required and, since this compound is an inert, non-toxic, naturally occuring compound which is available in considerable quantities the addition of ferric oxide and/or zinc oxide does not in itself promote any harmful after effects.
- the most effective way of mixing the zinc oxide in ferric oxide with tobacco is to form the zinc oxide or ferric oxide in solution in e.g. water and spray the solution onto the tobacco. As the tobacco dries, the zinc oxide or ferric oxide is left as a deposit on the tobacco.
Landscapes
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture Of Tobacco Products (AREA)
Abstract
La consommmation des produits du tabac, tels que les cigarettes, engendre des composés carcinogènes constitués d'azote et de carbone. L'addition de petites quantités d'oxyde de zinc et d'oxyde ferrique au tabac permet de réduire ou d'éliminer ces composés carcinogènes et présente aussi l'avantage d'éliminer "l'après-goût" vicié associé aux cigarettes.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8609603 | 1986-04-19 | ||
| GB868609603A GB8609603D0 (en) | 1986-04-19 | 1986-04-19 | Tobacco products |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP0265443A1 true EP0265443A1 (fr) | 1988-05-04 |
Family
ID=10596494
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19870900190 Withdrawn EP0265443A1 (fr) | 1986-04-19 | 1986-12-08 | Ameliorations apportees a des produits du tabac |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0265443A1 (fr) |
| AU (1) | AU6771987A (fr) |
| GB (1) | GB8609603D0 (fr) |
| WO (1) | WO1987006104A1 (fr) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20000047148A (ko) * | 1998-12-30 | 2000-07-25 | 최상구 | 황토분을 첨가한 담배와 그 제조방법 |
| US7011096B2 (en) | 2001-08-31 | 2006-03-14 | Philip Morris Usa Inc. | Oxidant/catalyst nanoparticles to reduce carbon monoxide in the mainstream smoke of a cigarette |
| US20040025895A1 (en) * | 2001-08-31 | 2004-02-12 | Ping Li | Oxidant/catalyst nanoparticles to reduce tobacco smoke constituents such as carbon monoxide |
| US6769437B2 (en) * | 2002-04-08 | 2004-08-03 | Philip Morris Incorporated | Use of oxyhydroxide compounds for reducing carbon monoxide in the mainstream smoke of a cigarette |
| CN1324999C (zh) * | 2002-04-12 | 2007-07-11 | 菲利普莫里斯生产公司 | 降低香烟烟雾中一氧化碳和一氧化氮数量的纳米颗粒添加剂 |
| US6782892B2 (en) | 2002-08-30 | 2004-08-31 | Philip Morris Usa Inc. | Manganese oxide mixtures in nanoparticle form to lower the amount of carbon monoxide and/or nitric oxide in the mainstream smoke of a cigarette |
| US9107452B2 (en) | 2003-06-13 | 2015-08-18 | Philip Morris Usa Inc. | Catalyst to reduce carbon monoxide in the mainstream smoke of a cigarette |
| US7152609B2 (en) | 2003-06-13 | 2006-12-26 | Philip Morris Usa Inc. | Catalyst to reduce carbon monoxide and nitric oxide from the mainstream smoke of a cigarette |
| EA008260B1 (ru) | 2003-06-13 | 2007-04-27 | Филип Моррис Продактс С.А. | Сигаретная обертка с напечатанным катализатором |
| US7165553B2 (en) | 2003-06-13 | 2007-01-23 | Philip Morris Usa Inc. | Nanoscale catalyst particles/aluminosilicate to reduce carbon monoxide in the mainstream smoke of a cigarette |
| US7243658B2 (en) | 2003-06-13 | 2007-07-17 | Philip Morris Usa Inc. | Nanoscale composite catalyst to reduce carbon monoxide in the mainstream smoke of a cigarette |
| US7028694B2 (en) | 2003-08-22 | 2006-04-18 | Philip Morris Usa Inc. | Method for dispersing powder materials in a cigarette rod |
| US7950400B2 (en) | 2003-10-27 | 2011-05-31 | Philip Morris Usa Inc. | Tobacco cut filler including metal oxide supported particles |
| US7677254B2 (en) | 2003-10-27 | 2010-03-16 | Philip Morris Usa Inc. | Reduction of carbon monoxide and nitric oxide in smoking articles using iron oxynitride |
| US8006703B2 (en) | 2003-10-27 | 2011-08-30 | Philip Morris Usa Inc. | In situ synthesis of composite nanoscale particles |
| US7712471B2 (en) | 2003-10-27 | 2010-05-11 | Philip Morris Usa Inc. | Methods for forming transition metal oxide clusters and smoking articles comprising transition metal oxide clusters |
| US7509961B2 (en) | 2003-10-27 | 2009-03-31 | Philip Morris Usa Inc. | Cigarettes and cigarette components containing nanostructured fibril materials |
| US7640936B2 (en) | 2003-10-27 | 2010-01-05 | Philip Morris Usa Inc. | Preparation of mixed metal oxide catalysts from nanoscale particles |
| US8701681B2 (en) | 2003-10-27 | 2014-04-22 | Philip Morris Usa Inc. | Use of oxyhydroxide compounds in cigarette paper for reducing carbon monoxide in the mainstream smoke of a cigarette |
| US7934510B2 (en) | 2003-10-27 | 2011-05-03 | Philip Morris Usa Inc. | Cigarette wrapper with nanoparticle spinel ferrite catalyst and methods of making same |
| US7878211B2 (en) | 2005-02-04 | 2011-02-01 | Philip Morris Usa Inc. | Tobacco powder supported catalyst particles |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE537734C (de) * | 1929-03-27 | 1931-11-06 | Wendt S Cigarrenfabriken Akt G | Verfahren zur Entfernung des Nikotins aus Tabakrauch |
| US3720214A (en) * | 1970-12-03 | 1973-03-13 | Liggett & Myers Inc | Smoking composition |
| ZA723458B (en) * | 1971-06-11 | 1973-03-28 | British American Tobacco Co | Improvements relating to reconstituted-tobacco smoking materials |
| DE2525276A1 (de) * | 1975-06-06 | 1977-01-13 | Brasec Gmbh Chemisch Physikali | Verfahren zur entgiftung von tabak |
-
1986
- 1986-04-19 GB GB868609603A patent/GB8609603D0/en active Pending
- 1986-12-08 AU AU67719/87A patent/AU6771987A/en not_active Abandoned
- 1986-12-08 WO PCT/GB1986/000749 patent/WO1987006104A1/fr not_active Ceased
- 1986-12-08 EP EP19870900190 patent/EP0265443A1/fr not_active Withdrawn
Non-Patent Citations (1)
| Title |
|---|
| See references of WO8706104A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| AU6771987A (en) | 1987-11-09 |
| WO1987006104A1 (fr) | 1987-10-22 |
| GB8609603D0 (en) | 1986-05-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH DE FR GB IT LI LU NL SE |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
| 18D | Application deemed to be withdrawn |
Effective date: 19880122 |