EP0137540A3 - Process for the electrolytic zinc plating of steel - Google Patents
Process for the electrolytic zinc plating of steel Download PDFInfo
- Publication number
- EP0137540A3 EP0137540A3 EP84201280A EP84201280A EP0137540A3 EP 0137540 A3 EP0137540 A3 EP 0137540A3 EP 84201280 A EP84201280 A EP 84201280A EP 84201280 A EP84201280 A EP 84201280A EP 0137540 A3 EP0137540 A3 EP 0137540A3
- Authority
- EP
- European Patent Office
- Prior art keywords
- acids
- acid
- steel
- oxygenic
- zinc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title abstract 4
- 239000011701 zinc Substances 0.000 title abstract 4
- 229910052725 zinc Inorganic materials 0.000 title abstract 4
- 229910000831 Steel Inorganic materials 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000010959 steel Substances 0.000 title abstract 2
- 238000007747 plating Methods 0.000 title 1
- 239000002253 acid Substances 0.000 abstract 6
- 150000007513 acids Chemical class 0.000 abstract 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 abstract 2
- 239000003792 electrolyte Substances 0.000 abstract 2
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- -1 acids hydride Chemical class 0.000 abstract 1
- HRKQOINLCJTGBK-UHFFFAOYSA-N dihydroxidosulfur Chemical compound OSO HRKQOINLCJTGBK-UHFFFAOYSA-N 0.000 abstract 1
- RMGVZKRVHHSUIM-UHFFFAOYSA-N dithionic acid Chemical compound OS(=O)(=O)S(O)(=O)=O RMGVZKRVHHSUIM-UHFFFAOYSA-N 0.000 abstract 1
- GRWZHXKQBITJKP-UHFFFAOYSA-N dithionous acid Chemical compound OS(=O)S(O)=O GRWZHXKQBITJKP-UHFFFAOYSA-N 0.000 abstract 1
- 238000005246 galvanizing Methods 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 150000002926 oxygen Chemical class 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- 239000011435 rock Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 125000004962 sulfoxyl group Chemical group 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/22—Electroplating: Baths therefor from solutions of zinc
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Electroplating Methods And Accessories (AREA)
- Chemical Treatment Of Metals (AREA)
Abstract
Bei einem Verfahren zur elektrolytischen Verzinkung von Stahl werden schwefelsaure wäßrige Zinkelektrolyte ver wendet, die durch einen Gehalt von ein oder mehreren Sauerstoffsäuren des Schwefels mit der Oxidationszahl von +5 bis +1 gekennzeichnet sind. Derartig erzeugte Zinküber züge ergeben bei dser anschließenden Zinkphosphatierung gleichmäßige stippenfreie Phosphatschichten. Als geeignete Sauerstoffsäuren sind schweflige Säure (H₂SO₃), Sulfoxylsä ure (H₂SO₂), dithionige Säure (H₂S₂O₄) und/oder Thioschwe felsäure (H₂S₂O₃) in Form der Säuren, Salze und Säurean hydride gennant. Die Konzentration der Sauerstoffsäuren im Elektrolyten sollte 0,05 bis 10 g/l, vorzugsweise 0,1 bis 2 g/l, betragen. In a process for the electrolytic galvanizing of Steel, sulfuric acid aqueous zinc electrolytes are used applies by a salary of one or more Oxygenic acids of sulfur with an oxidation number of +5 to +1 are marked. Zinc over produced in this way trains result in the subsequent zinc phosphating even speck-free phosphate layers. As suitable Oxygenic acids are sulfurous acid (H₂SO₃), sulfoxyl acid ure (H₂SO₂), dithionic acid (H₂S₂O₄) and / or thioschwe rock acid (H₂S₂O₃) in the form of acids, salts and acids hydride called. The concentration of oxygen acids in the Electrolytes should 0.05 to 10 g / l, preferably 0.1 to 2 g / l, be.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3335009 | 1983-09-28 | ||
| DE19833335009 DE3335009A1 (en) | 1983-09-28 | 1983-09-28 | METHOD FOR ELECTROLYTIC GALVANIZING STEEL |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0137540A2 EP0137540A2 (en) | 1985-04-17 |
| EP0137540A3 true EP0137540A3 (en) | 1987-05-27 |
Family
ID=6210222
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP84201280A Withdrawn EP0137540A3 (en) | 1983-09-28 | 1984-09-07 | Process for the electrolytic zinc plating of steel |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4547269A (en) |
| EP (1) | EP0137540A3 (en) |
| JP (1) | JPS6092495A (en) |
| DE (1) | DE3335009A1 (en) |
| ES (1) | ES8605872A1 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4663000A (en) * | 1985-07-25 | 1987-05-05 | Kollmorgan Technologies, Corp. | Process for electro-deposition of a ductile strongly adhesive zinc coating for metals |
| IL75974A0 (en) * | 1984-08-16 | 1985-12-31 | Kollmorgen Tech Corp | Electrodeposition composition and process for providing a zn/si/p coating on metal substrates |
| JPS6360290A (en) * | 1986-09-01 | 1988-03-16 | Nippon Parkerizing Co Ltd | Blackening treatment liquid and treatment method for aluminum or its alloy material |
| ES2289521T3 (en) * | 2003-06-05 | 2008-02-01 | Lg Electronics Inc. | DRUM FOR WASHER AND DRYER. |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1380142A (en) * | 1919-11-17 | 1921-05-31 | Eastern Mfg Company | Plating-bath |
| US1607869A (en) * | 1925-06-01 | 1926-11-23 | Us Smelting Refining & Mining | Electrolytic refining of metals |
| US3637475A (en) * | 1968-09-23 | 1972-01-25 | Mini Ind Constructillor | Zinc-plating bath for bright or glossy coating |
| US3850766A (en) * | 1974-03-28 | 1974-11-26 | Sterwin Chem Inc | Electroplating brightener compositions and process |
| SU905335A1 (en) * | 1980-03-03 | 1982-02-15 | За витель Кравцов, Л. Г. Осацкий, В. И. Фоменко, П. В, Топстов, Т. С. Кондратенко и Р. К. Умбвталивва | Zink plating electrolyte solution |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1017981A (en) * | 1911-05-29 | 1912-02-20 | Auguste Arsene Lemetre | Electroplating with zinc. |
| US3713092A (en) * | 1970-10-23 | 1973-01-23 | B Ivenbaum | Air pressure balanced self-contained tire pressure condition signal transmitter |
-
1983
- 1983-09-28 DE DE19833335009 patent/DE3335009A1/en not_active Withdrawn
-
1984
- 1984-09-07 EP EP84201280A patent/EP0137540A3/en not_active Withdrawn
- 1984-09-12 ES ES535855A patent/ES8605872A1/en not_active Expired
- 1984-09-21 US US06/653,504 patent/US4547269A/en not_active Expired - Fee Related
- 1984-09-28 JP JP59203970A patent/JPS6092495A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1380142A (en) * | 1919-11-17 | 1921-05-31 | Eastern Mfg Company | Plating-bath |
| US1607869A (en) * | 1925-06-01 | 1926-11-23 | Us Smelting Refining & Mining | Electrolytic refining of metals |
| US3637475A (en) * | 1968-09-23 | 1972-01-25 | Mini Ind Constructillor | Zinc-plating bath for bright or glossy coating |
| US3850766A (en) * | 1974-03-28 | 1974-11-26 | Sterwin Chem Inc | Electroplating brightener compositions and process |
| SU905335A1 (en) * | 1980-03-03 | 1982-02-15 | За витель Кравцов, Л. Г. Осацкий, В. И. Фоменко, П. В, Топстов, Т. С. Кондратенко и Р. К. Умбвталивва | Zink plating electrolyte solution |
Non-Patent Citations (3)
| Title |
|---|
| H.W. DETTNER et al.: "Handbuch der Galvanotechnik", Band II, Seiten 293-294, Carl Hanser Verlag, M}nchen, DE; * |
| METAL FINISHING ABSTRACTS, Band 24, Nr. 4, Juli/August 1982, Seite 242, Teddington, Middlesex, GB; & SU-A-905 335 (E.E. KRAVTSOV et al.) * |
| THE ELECTROCHEMICAL SOCIETY, Band 80, 1941, Seiten 387-398; E.H. LYONS JR.: "Acid zinc plating" * |
Also Published As
| Publication number | Publication date |
|---|---|
| ES535855A0 (en) | 1985-12-16 |
| ES8605872A1 (en) | 1985-12-16 |
| DE3335009A1 (en) | 1985-04-18 |
| EP0137540A2 (en) | 1985-04-17 |
| JPS6092495A (en) | 1985-05-24 |
| US4547269A (en) | 1985-10-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Designated state(s): AT BE DE FR GB IT LU NL SE |
|
| RTI1 | Title (correction) | ||
| PUAL | Search report despatched |
Free format text: ORIGINAL CODE: 0009013 |
|
| AK | Designated contracting states |
Kind code of ref document: A3 Designated state(s): AT BE DE FR GB IT LU NL SE |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN WITHDRAWN |
|
| 18W | Application withdrawn |
Withdrawal date: 19870711 |
|
| RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: RAUSCH, WERNER, DR. Inventor name: MUELLER, GERHARD |