EP0119082B1 - Unsaturated vapor high pressure sodium lamp including getter - Google Patents
Unsaturated vapor high pressure sodium lamp including getter Download PDFInfo
- Publication number
- EP0119082B1 EP0119082B1 EP84301610A EP84301610A EP0119082B1 EP 0119082 B1 EP0119082 B1 EP 0119082B1 EP 84301610 A EP84301610 A EP 84301610A EP 84301610 A EP84301610 A EP 84301610A EP 0119082 B1 EP0119082 B1 EP 0119082B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- arc tube
- oxygen
- sodium
- envelope
- getter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 title claims description 28
- 229910052708 sodium Inorganic materials 0.000 title claims description 28
- 239000011734 sodium Substances 0.000 title claims description 28
- 239000000919 ceramic Substances 0.000 claims description 20
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 10
- 229910052753 mercury Inorganic materials 0.000 claims description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 239000000758 substrate Substances 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 239000004411 aluminium Substances 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims description 3
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 claims description 2
- 229910000497 Amalgam Inorganic materials 0.000 claims description 2
- 229910052684 Cerium Inorganic materials 0.000 claims description 2
- 229910052776 Thorium Inorganic materials 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- 229910052746 lanthanum Inorganic materials 0.000 claims description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 229910052706 scandium Inorganic materials 0.000 claims description 2
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 229910052727 yttrium Inorganic materials 0.000 claims description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 1
- 238000010891 electric arc Methods 0.000 claims 1
- 229910052735 hafnium Inorganic materials 0.000 claims 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims 1
- 239000000463 material Substances 0.000 description 9
- 238000005247 gettering Methods 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 239000004020 conductor Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- DNXNYEBMOSARMM-UHFFFAOYSA-N alumane;zirconium Chemical compound [AlH3].[Zr] DNXNYEBMOSARMM-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910001092 metal group alloy Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 238000001275 scanning Auger electron spectroscopy Methods 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/02—Details
- H01J61/24—Means for obtaining or maintaining the desired pressure within the vessel
- H01J61/26—Means for absorbing or adsorbing gas, e.g. by gettering; Means for preventing blackening of the envelope
Definitions
- This invention relates to unsaturated vapor high pressure sodium lamps and more particularly to the mounting of getters within the arc tube of an unsaturated vapor high pressure sodium lamp.
- High pressure sodium vapor discharge lamps comprising a getter are also known from US-A-3 485 313 and US-A-3 953 755.
- the above-described technique has been employed with varying amounts of success, it has been found that the results do leave something to be desired. More specifically, it has been found that intimate contact between the tubular ceramic envelope of the arc tube and the oxygen-absorbing getter therein tends to cause an undesired darkening of the ceramic envelope in the area of contact with the getter material. Although the exact cause of this darkening condition of the ceramic envelope is not thoroughly understood, it is believed that a chemical reduction takes place between the getter and the aluminium envelope whereat contact therebetween is effected.
- An object of the present invention is to provide an improved high pressure sodium lamp. Another object of the invention is to enhance the arc tube of an unsaturated vapor high pressure sodium lamp. A further object of the invention is the structure of an unsaturated vapor high pressure sodium lamp.
- an arc tube having a tubular ceramic envelope with an electrode sealed into each end of the envelope, a dosing of sodium, mercury and rare gas within the envelope and an oxygen-absorbing getter attached to at least one of the electrodes within the ceramic envelope.
- Fig. 1 illustrates an unsaturated vapor high pressure sodium lamp having a hermetically sealed and evacuated glass envelope 5 formed to fit into an ordinary screw- type base member 7.
- a glass stem member 9 is sealed to the envelope 5 and projects therein. Electrical conductors, 11 and 13 respectively, are sealed into and pass through the stem member 9 to provide electrical connections from the interior to the exterior of the glass envelope.
- An electrically conductive support member 15 is affixed to one of the electrical conductors 11 and has a pair of crossbars 17 and 19 affixed thereto at either end. Also, a plurality of springlike members 21 are affixed to the support member 15 and formed for contact with the glass envelope 5. Moreover, a pair of getters 23 and 25 are attached to the support member 15 and serve to insure the integrity of the evacuated envelope 5.
- This arc tube 27 Disposed within the glass envelope 5 and supported by the crossbars 17 and 19 is an arc tube 27.
- This arc tube preferably of a material such as polycrystalline alumina for example, includes an electrode 29 and 31 at either end thereof.
- One electrode 29 is affixed to and supported by the crossbar 17 while the other electrode 31 is insulatingly supported by the other crossbar 19, but electrically connected to the electrical conductor 13 passing through the stem member 9.
- Heat conserving elements 33 may be wrapped about the arc tube 27 at each end thereof in the vicinity of the electrodes 29 and 31 in order to reduce the heat differential thereat from the center of the arc tube 27.
- a getter 37 is disposed within the arc tube 27 of Fig. 1
- an electrode member 39 is sealed into an apertured ceramic 41 which is, in turn, sealed into the end of a tubular ceramic envelope of an arc tube.
- the opposite end of the tubular ceramic envelope is sealed in substantially the same manner.
- the electrode member 39 includes a shank portion 43 which has a substantially circularly- wound cathode portion 45 telescoped thereover and affixed thereto, as by welding for example. Also affixed to the shank portion 43 intermediate the cathode portion 45 and the apertured ceramic 41 is the getter 37.
- the getter 37 is in the form of a suitable substrate 47, such as nickel plated iron, and a gettering material 49, such as zirconium- aluminum powder, is sintered thereto. Thereafter, the substrate 47 is affixed to or telescoped over the shank portion 43 of the electrode member 39.
- a preferred gettering material is a zirconium-aluminum alloy known as ST-101, available from SAES Getters, Milan, Italy, other metals are equally applicable.
- metal alloys selected from the metal group consisting of aluminum, titanium, scandium, cerium, lanthanum, thorium, zirconium, yttrium and other rare earth oxides are suitable gettering materials for the above-described configurations.
- a small tab containing a gettering material could be affixed to the electrode or alternatively, the getter material could be applied to the wound cathode portion 45 of the electrode member 39.
- other configurations of a similar nature are appropriate to the structure so long as the gettering material is separated from the ceramic envelope of the arc tube.
Landscapes
- Vessels And Coating Films For Discharge Lamps (AREA)
- Common Detailed Techniques For Electron Tubes Or Discharge Tubes (AREA)
- Discharge Lamp (AREA)
Description
- This invention relates to unsaturated vapor high pressure sodium lamps and more particularly to the mounting of getters within the arc tube of an unsaturated vapor high pressure sodium lamp.
- In the field of high pressure sodium lamps, it is a common practice to provide an arc tube fill which includes a large amount of sodium and mercury in order to compensate for the undesired sodium losses encountered: These excess amount of sodium and mercury result in an amalgam at the coolest points of the arc tube which is normally adjacent the electrodes at the ends of the arc tube. As a result, undesired variations in source voltage, color rendition and numerous other characteristics are encountered.
- In an effort to eliminate or at least reduce some undesired effects, it has long been known that a lamp wherein the amount of sodium and mercury employed is only that which will become totally vaporized would provide the desired result. In other words, a high pressure sodium lamp of the unsaturated vapor type wherein sodium and mercury are introduced in only such an amount as to become totally vaporized is a highly desirable structure insofar as efficiency, cost of manufacture and enhanced lighting capability are concerned, see document US-A-4075530.
- Also, it has long been recognized that a principal cause of undesired sodium loss in high pressure sodium lamps is the presence of oxygen in the gas fill of the arc tube. One known attempt to alleviate this undesired loss of sodium due to the presence of oxygen is set forth in a concurrently filed Application EP-A-0 123 397. Therein, a getter in the form of a metal or metal alloy is located within an elongated ceramic arc tube with the metal oxides of the getter having a free energy of formation per mole of oxygen greater than that of sodium oxide. In effect, the getter reacts with free oxygen to inhibit the formation of compounds containing sodium and oxygen.
- High pressure sodium vapor discharge lamps comprising a getter are also known from US-A-3 485 313 and US-A-3 953 755. Although the above-described technique has been employed with varying amounts of success, it has been found that the results do leave something to be desired. More specifically, it has been found that intimate contact between the tubular ceramic envelope of the arc tube and the oxygen-absorbing getter therein tends to cause an undesired darkening of the ceramic envelope in the area of contact with the getter material. Although the exact cause of this darkening condition of the ceramic envelope is not thoroughly understood, it is believed that a chemical reduction takes place between the getter and the aluminium envelope whereat contact therebetween is effected.
- An object of the present invention is to provide an improved high pressure sodium lamp. Another object of the invention is to enhance the arc tube of an unsaturated vapor high pressure sodium lamp. A further object of the invention is the structure of an unsaturated vapor high pressure sodium lamp.
- These and other objects, advantages and capabilities are achieved in one aspect of the invention by an arc tube having a tubular ceramic envelope with an electrode sealed into each end of the envelope, a dosing of sodium, mercury and rare gas within the envelope and an oxygen-absorbing getter attached to at least one of the electrodes within the ceramic envelope.
- The invention is illustrated by way of example in the accompanying drawings, in which:
- Fig. 1 is an elevation of a preferred form of unsaturated vapor high pressure sodium lamp; and
- Fig. 2 is an exploded sectional view of an electrode formed for enclosure within a ceramic envelope and having an oxygen-absorbing getter affixed thereto.
- For a better understanding of the present invention, together with other and further objects, advantages and capabilities thereof, reference is made to the following disclosure and appended Claims in conjunction with the accompanying drawings.
- Referring to the drawings, Fig. 1 illustrates an unsaturated vapor high pressure sodium lamp having a hermetically sealed and evacuated
glass envelope 5 formed to fit into an ordinary screw-type base member 7. A glass stem member 9 is sealed to theenvelope 5 and projects therein. Electrical conductors, 11 and 13 respectively, are sealed into and pass through the stem member 9 to provide electrical connections from the interior to the exterior of the glass envelope. - An electrically
conductive support member 15 is affixed to one of the electrical conductors 11 and has a pair ofcrossbars 17 and 19 affixed thereto at either end. Also, a plurality ofspringlike members 21 are affixed to thesupport member 15 and formed for contact with theglass envelope 5. Moreover, a pair of 23 and 25 are attached to thegetters support member 15 and serve to insure the integrity of the evacuatedenvelope 5. - Disposed within the
glass envelope 5 and supported by thecrossbars 17 and 19 is anarc tube 27. This arc tube, preferably of a material such as polycrystalline alumina for example, includes an 29 and 31 at either end thereof. Oneelectrode electrode 29 is affixed to and supported by thecrossbar 17 while theother electrode 31 is insulatingly supported by the other crossbar 19, but electrically connected to theelectrical conductor 13 passing through the stem member 9.Heat conserving elements 33 may be wrapped about thearc tube 27 at each end thereof in the vicinity of the 29 and 31 in order to reduce the heat differential thereat from the center of theelectrodes arc tube 27. - Referring more specifically to Fig. 2 wherein a
getter 37 is disposed within thearc tube 27 of Fig. 1, anelectrode member 39 is sealed into an apertured ceramic 41 which is, in turn, sealed into the end of a tubular ceramic envelope of an arc tube. Similarly, the opposite end of the tubular ceramic envelope is sealed in substantially the same manner. - The
electrode member 39 includes ashank portion 43 which has a substantially circularly-wound cathode portion 45 telescoped thereover and affixed thereto, as by welding for example. Also affixed to theshank portion 43 intermediate thecathode portion 45 and the apertured ceramic 41 is thegetter 37. - Preferably, the
getter 37 is in the form of asuitable substrate 47, such as nickel plated iron, and a getteringmaterial 49, such as zirconium- aluminum powder, is sintered thereto. Thereafter, thesubstrate 47 is affixed to or telescoped over theshank portion 43 of theelectrode member 39. Although a preferred gettering material is a zirconium-aluminum alloy known as ST-101, available from SAES Getters, Milan, Italy, other metals are equally applicable. For example, metal alloys selected from the metal group consisting of aluminum, titanium, scandium, cerium, lanthanum, thorium, zirconium, yttrium and other rare earth oxides are suitable gettering materials for the above-described configurations. - Additionally, alternative methods of containing a getter material within the ceramic envelope of the arc tube and separated therefrom are appropriate. For example, a small tab containing a gettering material could be affixed to the electrode or alternatively, the getter material could be applied to the
wound cathode portion 45 of theelectrode member 39. Obviously, other configurations of a similar nature are appropriate to the structure so long as the gettering material is separated from the ceramic envelope of the arc tube.
Claims (9)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US47389783A | 1983-03-10 | 1983-03-10 | |
| US473897 | 1983-03-10 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0119082A2 EP0119082A2 (en) | 1984-09-19 |
| EP0119082A3 EP0119082A3 (en) | 1985-06-19 |
| EP0119082B1 true EP0119082B1 (en) | 1988-12-28 |
Family
ID=23881474
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP84301610A Expired EP0119082B1 (en) | 1983-03-10 | 1984-03-09 | Unsaturated vapor high pressure sodium lamp including getter |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0119082B1 (en) |
| JP (1) | JPS59169051A (en) |
| AU (1) | AU578602B2 (en) |
| CA (1) | CA1222274A (en) |
| DE (1) | DE3475853D1 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8623296D0 (en) * | 1986-09-27 | 1986-10-29 | Emi Plc Thorn | Hydrogen getter |
| US5434472A (en) * | 1992-04-15 | 1995-07-18 | United States Philips Corporation | High-pressure sodium discharge lamp with getter |
| DE4325679A1 (en) * | 1993-07-30 | 1995-02-02 | Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh | Electric lamp with halogen filling |
| US20070096649A1 (en) * | 2005-10-28 | 2007-05-03 | Roels Timothy J | Electrode-mounted getter |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3485343A (en) * | 1967-08-28 | 1969-12-23 | Gen Electric | Oxygen getter for high pressure sodium vapor lamp |
| US4075530A (en) * | 1976-04-21 | 1978-02-21 | Japan Storage Battery Company Limited | High pressure sodium vapor lamp of unsaturated vapor pressure type |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1211176A (en) * | 1967-02-16 | 1970-11-04 | Gen Electric | High-pressure sodium vapor lamp |
| US3453477A (en) * | 1967-02-16 | 1969-07-01 | Gen Electric | Alumina-ceramic sodium vapor lamp |
| NL7315641A (en) * | 1973-11-15 | 1975-05-20 | Philips Nv | HIGH PRESSURE GAS DISCHARGE LAMP. |
| NL7611137A (en) * | 1976-10-08 | 1978-04-11 | Philips Nv | HIGH PRESSURE DISCHARGE LAMP. |
| CA1214196A (en) * | 1983-02-14 | 1986-11-18 | Jack M. Strok | Color rendition high pressure sodium arc tubes having an oxygen getter |
-
1984
- 1984-03-06 CA CA000448955A patent/CA1222274A/en not_active Expired
- 1984-03-09 AU AU25477/84A patent/AU578602B2/en not_active Ceased
- 1984-03-09 EP EP84301610A patent/EP0119082B1/en not_active Expired
- 1984-03-09 JP JP59044158A patent/JPS59169051A/en active Pending
- 1984-03-09 DE DE8484301610T patent/DE3475853D1/en not_active Expired
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3485343A (en) * | 1967-08-28 | 1969-12-23 | Gen Electric | Oxygen getter for high pressure sodium vapor lamp |
| US4075530A (en) * | 1976-04-21 | 1978-02-21 | Japan Storage Battery Company Limited | High pressure sodium vapor lamp of unsaturated vapor pressure type |
Also Published As
| Publication number | Publication date |
|---|---|
| AU578602B2 (en) | 1988-11-03 |
| CA1222274A (en) | 1987-05-26 |
| JPS59169051A (en) | 1984-09-22 |
| EP0119082A2 (en) | 1984-09-19 |
| EP0119082A3 (en) | 1985-06-19 |
| DE3475853D1 (en) | 1989-02-02 |
| AU2547784A (en) | 1984-09-13 |
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