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EP0114591A1 - Procédé de fabrication de canons - Google Patents

Procédé de fabrication de canons Download PDF

Info

Publication number
EP0114591A1
EP0114591A1 EP83890232A EP83890232A EP0114591A1 EP 0114591 A1 EP0114591 A1 EP 0114591A1 EP 83890232 A EP83890232 A EP 83890232A EP 83890232 A EP83890232 A EP 83890232A EP 0114591 A1 EP0114591 A1 EP 0114591A1
Authority
EP
European Patent Office
Prior art keywords
tube
alloy
jacket tube
resistant
liner
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP83890232A
Other languages
German (de)
English (en)
Other versions
EP0114591B1 (fr
Inventor
Manfred Gstettner
Bruno Dipl.-Ing. Hribernik
Alexander Kohnhauser
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Voest-Alpine Stahl AG Te Linz Ad
Original Assignee
Vereinigte Edelstahlwerke AG
Voestalpine Stahl GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=3567024&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0114591(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Vereinigte Edelstahlwerke AG, Voestalpine Stahl GmbH filed Critical Vereinigte Edelstahlwerke AG
Publication of EP0114591A1 publication Critical patent/EP0114591A1/fr
Application granted granted Critical
Publication of EP0114591B1 publication Critical patent/EP0114591B1/fr
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/12Both compacting and sintering
    • B22F3/1208Containers or coating used therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F7/00Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
    • B22F7/06Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools
    • B22F7/062Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools involving the connection or repairing of preformed parts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F7/00Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
    • B22F7/06Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools
    • B22F7/08Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools with one or more parts not made from powder
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41WEAPONS
    • F41AFUNCTIONAL FEATURES OR DETAILS COMMON TO BOTH SMALLARMS AND ORDNANCE, e.g. CANNONS; MOUNTINGS FOR SMALLARMS OR ORDNANCE
    • F41A21/00Barrels; Gun tubes; Muzzle attachments; Barrel mounting means
    • F41A21/02Composite barrels, i.e. barrels having multiple layers, e.g. of different materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00Supplementary information concerning processes or compositions relating to powder metallurgy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12014All metal or with adjacent metals having metal particles
    • Y10T428/12028Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, etc.]
    • Y10T428/12063Nonparticulate metal component
    • Y10T428/12097Nonparticulate component encloses particles

Definitions

  • the invention relates to a method for producing gun barrels, which have a core barrel and at least one jacket barrel made of different metallic materials.
  • Gun barrels are subject to two completely different stresses: on the one hand, the explosion of the propellant charge of a projectile creates a high pressure inside the barrel, which the gun barrel must be able to withstand, and on the other hand the projectile is driven through the barrel at high speed, thereby stabilizing the bullet trajectory the projectile is rotated by the cables in the gun barrel, which creates an extreme abrasive load on the barrel interior.
  • these two loads place different demands on the material.
  • One way to meet these different requirements is to provide a correspondingly large dimensioning of the weapon barrel, which means that the mobility of the weapons suffers and an extremely high amount of material is required.
  • a method for the manufacture of gun barrels has already become known, wherein a core tube is fitted into a tubular casing.
  • the disadvantage of this method is that particularly precise machining of both the inner hollow of the casing tube and the outer casing of the core tube is required.
  • damage to the inner tube such as that caused by cracks, which can be attributed to the pressure load, a significant change in the caliber can occur, which can result in the gun barrel being destroyed by a projectile.
  • the present invention has set itself the goal of providing a method for producing gun barrels that are suitable for guns as well as handguns and handguns that have a core barrel and at least one jacket barrel made of different metallic materials, which allows a to produce a particularly light and resistant weapon barrel.
  • the method according to the invention for the manufacture of weapon tubes which have a core tube and at least one jacket tube made of different metallic materials, consists essentially in the fact that in a sleeve tube, which is optionally arranged in a capsule tube, made of a tough alloy, e.g.
  • a weapon barrel manufactured according to this method has the advantage that it takes into account both the high pressure and the abrasive stresses in a particularly favorable manner, a particularly advantageous combination of a melt metallurgical
  • the central hollow area is filled with a filler, preferably made of an easily machinable material, e.g. Free cutting steel, so an unnecessary loss of the complex metal powder can be saved, while at the same time particularly easy mechanical processing can take place.
  • a filler preferably made of an easily machinable material, e.g. Free cutting steel
  • the manipulation can be very easily carried out because the G-e weight of the composite body can be kept particularly low.
  • the composite body is subjected to a hot deformation, in particular forging, with a deformation of at least 1.3 times, in particular at least 2 times, before it is mechanically processed into a weapon barrel, a particularly homogeneous structure of the core tube portion obtained by powder metallurgy can be achieved, with a longer service life of the Gun barrel enters.
  • Is as zähfestes material is titanium or a Titanle g IE coding is used, a particularly low-weight weapon barrel may be generated.
  • a cobalt-based alloy is used as the highly wear-resistant alloy for gun barrels for guns or the like with a particularly elongated weft track,
  • a nickel-based alloy is used as the material for filling the casing tube.
  • a cladding tube which has a coating of an adhesion promoter, e.g. Nickel or the like.
  • a composite metal tube part was produced by using X40CrMoV51 (with 0.38% C, 1.1% Si, 0.38% Mn, 5.20% Cr, 1.30% Mo and 1.2% V, rest essentially iron) of the dimension: 46 mm outer diameter, 15 mm wall thickness and 650 mm length, a rod of the same length made of free - cutting steel - inserted centrally and in the remaining cavity a metal powder made of a heat-resistant nickel-based alloy with the composition 0 , 12% C, 20.0% Cr, 18.1% Co, 2.5% Ti, 1.5% Al, 1.5% Fe, the rest essentially nickel.
  • the tube ends were sealed gas-tight by welding circular sheet metal washers onto the jacket tube and the hot isostatic pressing process was carried out at 1080 ° C. and a gas pressure of 1100 bar for 3 hours.
  • the central core made of free-cutting steel was completely drilled out and then the further mechanical processing was carried out to produce the trains and to complete the barrel.
  • a sleeve tube made of an alloy of the following composition in wt .-% C 0.33, Si 0.28, Mn 0.50, Cr 3.0, Mo 1.2, V 0.27 and remainder iron with an outer diameter of 60 mm and an inner diameter of 40 mm and a length of 800 mm.
  • the hollow cylindrical intermediate space was coated with a powder of a cobalt-based alloy with the following composition in% by weight C 0.17, Si 0.35, Mn 0.65, Cr 28.0, Mo'5.6, Ni max. 0.5, Co 66.0 and Fe max. 0.5 filled, a density of 6.5 g / cm 3 was achieved by shaking. Degassing was carried out at 350 ° C., whereupon an upper cover with a suction opening was welded onto the capsule tube. Then it was evacuated and the suction opening was closed. The encapsulated body was hot-isostatically pressed for 3 hours in an argon atmosphere at 1150 ° C. and at a pressure of 1000 bar.
  • This composite body was then forged on a long forging machine to an outer diameter of approximately 35 mm, which corresponds to approximately three times the deformation.
  • solution annealing was carried out at 1100 ° C for one hour, after which a barrel for a heavy machine gun was made by mechanical processing and cold forging the trains.
  • a cylindrical rod made of free-cutting steel with an outside diameter of 45 mm and a length of 900 mm was inserted in the center of the casing tube.
  • the hollow cylindrical space was filled with a powder of a cobalt-based alloy with the following composition in% by weight C 0.17, Si 0.35, Mn 0.65, Cr 28.0, Mo 5.5, Ni max. 0.5, Co 66.0 and Fe max. 0.5 filled, a density of 6.7 g / cm 3 was achieved by shaking. Degassing was carried out at 340 ° C., whereupon an upper cover with a suction opening was welded on. The mixture was then evacuated and hot-isostatically pressed in accordance with Example 2. The composite body thus obtained was forged on a long forging machine to a diameter of 105 mm or 35 mm or 23 mm and a length of 3500 mm, which corresponds to a fourfold deformation.
  • the further processing was carried out analogously to Example 2, except that a tensile strength of 900-1100 N / m 2 was set by tempering the jacket tube.
  • the tube obtained had a caliber of 1 "and was used for a rapid-fire cannon.
  • a casing tube made of TiA16V4 with an outer diameter of 210 mm and an inner diameter of 160 mm and a length of 900 mm was introduced into a capsule tube provided with a base.
  • a core rod made of free-cutting steel with a diameter of 45 mm and a length of 900 mm was then introduced into this casing tube.
  • the intermediate space was filled with a powder of the following composition in% by weight C 0.34, Cr 1.2, Mo 0.2, A1 0.95, the rest Fe. It was compressed to 70% of the density.
  • the procedure was then as in Example 3 and the composite body was forged to a diameter of 105 mm or 35 mm and a length of 3500 mm, which corresponds to a fourfold deformation.
  • This composite was a hour at 940 ° C de heated and then cooled in oil and tempered at 520 ° C for four hours. After processing, the inner surface was nitrided in a manner known per se to a depth of 0.3 to 0.4 mm.
  • the sleeve tube can also be welded directly to the lids, since there is no pressure on the powder in the radial direction due to the material thickness. of the cladding tube can occur.
  • the core can also be formed by a hollow cylinder, in which case, which is particularly suitable for larger calibers, forging can be carried out using a mandrel.

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Materials Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Forging (AREA)
  • Powder Metallurgy (AREA)
  • Pressure Welding/Diffusion-Bonding (AREA)
  • Glass Compositions (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)
  • Semiconductor Lasers (AREA)
  • Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Coating With Molten Metal (AREA)
EP83890232A 1982-12-23 1983-12-22 Procédé de fabrication de canons Expired EP0114591B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AT4679/82 1982-12-23
AT467982 1982-12-23

Publications (2)

Publication Number Publication Date
EP0114591A1 true EP0114591A1 (fr) 1984-08-01
EP0114591B1 EP0114591B1 (fr) 1988-03-30

Family

ID=3567024

Family Applications (3)

Application Number Title Priority Date Filing Date
EP83890232A Expired EP0114591B1 (fr) 1982-12-23 1983-12-22 Procédé de fabrication de canons
EP83890233A Expired EP0114592B1 (fr) 1982-12-23 1983-12-22 Procédé de transformation de métaux à l'aide de filières
EP83890234A Withdrawn EP0114593A1 (fr) 1982-12-23 1983-12-22 Procédé de fabrication d'un cylindre creux pour machines de transformation des plastiques

Family Applications After (2)

Application Number Title Priority Date Filing Date
EP83890233A Expired EP0114592B1 (fr) 1982-12-23 1983-12-22 Procédé de transformation de métaux à l'aide de filières
EP83890234A Withdrawn EP0114593A1 (fr) 1982-12-23 1983-12-22 Procédé de fabrication d'un cylindre creux pour machines de transformation des plastiques

Country Status (6)

Country Link
US (1) US4747225A (fr)
EP (3) EP0114591B1 (fr)
AT (2) ATE33218T1 (fr)
DE (2) DE3376100D1 (fr)
ES (2) ES528315A0 (fr)
GR (2) GR79748B (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0220800A1 (fr) * 1985-10-17 1987-05-06 Crucible Materials Corporation Procédé de la métallurgie des poudres pour produire un produit tubulaire
EP0151103A3 (en) * 1984-01-24 1988-01-20 Vereinigte Edelstahlwerke Aktiengesellschaft (Vew) Manufacturing method for elements of force, especially torque transmission
EP0602877A1 (fr) * 1992-12-14 1994-06-22 General Electric Company Tube de canon composite ayant plusieurs couches
RU2167742C2 (ru) * 1999-03-31 2001-05-27 Курский государственный технический университет Способ армирования металлических изделий твердосплавным слоем

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3881923T2 (de) * 1987-03-25 1994-01-27 Nippon Steel Corp Verfahren zur Herstellung von beschichteten Metallrohre.
AT391105B (de) * 1988-10-07 1990-08-27 Boehler Gmbh Vormaterial fuer die erzeugung von verbundwerkstoffen
US5277228A (en) * 1990-11-02 1994-01-11 Usui Kokusai Sangyo Kaisha Limited Welded pipe with excellent corrosion resistance inner surface
US5290507A (en) * 1991-02-19 1994-03-01 Runkle Joseph C Method for making tool steel with high thermal fatigue resistance
US5357842A (en) * 1993-07-09 1994-10-25 Reynolds Charles E Recoil reducing device
US6218026B1 (en) 1995-06-07 2001-04-17 Allison Engine Company Lightweight high stiffness member and manufacturing method thereof
US5724643A (en) * 1995-06-07 1998-03-03 Allison Engine Company, Inc. Lightweight high stiffness shaft and manufacturing method thereof
US5856631A (en) * 1995-11-20 1999-01-05 Nitinol Technologies, Inc. Gun barrel
DE19834394A1 (de) * 1998-07-30 2000-02-03 Rheinmetall W & M Gmbh Waffenrohr mit einer verschleißmindernden Hartchromschicht
SE516130C2 (sv) * 1999-03-15 2001-11-19 Damasteel Ab Ämne för metallprodukt, förfarande för framställning av metallprodukt samt metallprodukt
DE19926246A1 (de) * 1999-06-09 2000-12-14 Rheinmetall W & M Gmbh Verfahren zur Innenbeschichtung eines Waffenrohres
US6594936B1 (en) * 2002-10-03 2003-07-22 Gary Sniezak Method for lining a gun barrel
US20040226211A1 (en) * 2003-05-16 2004-11-18 Ra Brands. L.L.C. Composite receiver for firearms
US20040244254A1 (en) * 2003-06-09 2004-12-09 Barfield Christopher A.. Firearm safety device
US7922065B2 (en) 2004-08-02 2011-04-12 Ati Properties, Inc. Corrosion resistant fluid conducting parts, methods of making corrosion resistant fluid conducting parts and equipment and parts replacement methods utilizing corrosion resistant fluid conducting parts
US7963202B1 (en) * 2005-09-21 2011-06-21 The United States Of America As Represented By The Secretary Of The Army Superalloy mortar tube
US7921590B2 (en) * 2006-02-23 2011-04-12 Strum, Ruger & Company, Inc. Composite firearm barrel reinforcement
US20100236122A1 (en) * 2006-07-26 2010-09-23 Fonte Matthew V Flowforming Gun Barrels and Similar Tubular Devices
EP2046524A4 (fr) * 2006-08-01 2016-05-25 Afl Telecommunications Llc Tubes métalliques encastrés pourvus d'un raccord de compression et leur procédé de fabrication
US8910409B1 (en) 2010-02-09 2014-12-16 Ati Properties, Inc. System and method of producing autofrettage in tubular components using a flowforming process
US8869443B2 (en) 2011-03-02 2014-10-28 Ati Properties, Inc. Composite gun barrel with outer sleeve made from shape memory alloy to dampen firing vibrations
US10118259B1 (en) 2012-12-11 2018-11-06 Ati Properties Llc Corrosion resistant bimetallic tube manufactured by a two-step process
US9279633B2 (en) 2014-01-21 2016-03-08 Richard R. Hayes Multi-caliber weapon
US9796057B2 (en) * 2015-01-15 2017-10-24 Saeilo Enterprises, Inc. Gun barrel assembly
SE2300011A1 (sv) * 2023-02-09 2024-08-10 Bae Systems Bofors Ab Eldrör
SE2400064A1 (sv) * 2024-05-28 2025-11-11 Bae Systems Bofors Ab Eldrör samt metod för tillverkning av eldrörsegment

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3753704A (en) * 1967-04-14 1973-08-21 Int Nickel Co Production of clad metal articles
DE2504032A1 (de) * 1974-01-31 1975-08-07 Nippon Musical Instruments Mfg Verfahren zur herstellung von metallverbundstoffen
DE2514565A1 (de) * 1975-04-03 1976-10-14 Uralsky Nii Trubnoj Promy Verfahren zur herstellung von rohrerzeugnissen
DE2855155A1 (de) * 1977-12-22 1979-06-28 United Technologies Corp Verfahren zum herstellen eines fluidgekuehlten bedampfungstargets
DE3114659A1 (de) * 1980-04-10 1982-01-28 Cameron Iron Works, Inc., Houston, Tex. Verfahren zum auskleiden der hohlraeume in einem bauteil, beispielsweise einem ventil, sowie ausgekleidetes bauteil
US4327154A (en) * 1977-08-18 1982-04-27 Motoren- Und Turbinen-Union Muenchen Gmbh High-strength components of complex geometric shape and method for their manufacture

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US930927A (en) * 1906-03-19 1909-08-10 Robert H Berkstresser Gun-barrel and process of producing the same.
US2372202A (en) * 1940-05-08 1945-03-27 Mallory & Co Inc P R Bearing
US2636849A (en) * 1946-12-13 1953-04-28 Us Sec War Method of electroforming gun barrels and liners
US2977666A (en) * 1954-12-29 1961-04-04 Porter H Brace Method of making gun liner elements
US3112553A (en) * 1960-06-08 1963-12-03 William H Safranek Electroforming of gun liners
US3261121A (en) * 1961-10-13 1966-07-19 Joseph R Eves Gun barrel with explosively welded liner
US4016008A (en) * 1975-07-31 1977-04-05 The International Nickel Company, Inc. Clad metal tubes
US4426248A (en) * 1983-05-20 1984-01-17 The United States Of America As Represented By The Secretary Of The Army Process for coating rifle tubes

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3753704A (en) * 1967-04-14 1973-08-21 Int Nickel Co Production of clad metal articles
DE2504032A1 (de) * 1974-01-31 1975-08-07 Nippon Musical Instruments Mfg Verfahren zur herstellung von metallverbundstoffen
DE2514565A1 (de) * 1975-04-03 1976-10-14 Uralsky Nii Trubnoj Promy Verfahren zur herstellung von rohrerzeugnissen
US4327154A (en) * 1977-08-18 1982-04-27 Motoren- Und Turbinen-Union Muenchen Gmbh High-strength components of complex geometric shape and method for their manufacture
DE2855155A1 (de) * 1977-12-22 1979-06-28 United Technologies Corp Verfahren zum herstellen eines fluidgekuehlten bedampfungstargets
DE3114659A1 (de) * 1980-04-10 1982-01-28 Cameron Iron Works, Inc., Houston, Tex. Verfahren zum auskleiden der hohlraeume in einem bauteil, beispielsweise einem ventil, sowie ausgekleidetes bauteil

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0151103A3 (en) * 1984-01-24 1988-01-20 Vereinigte Edelstahlwerke Aktiengesellschaft (Vew) Manufacturing method for elements of force, especially torque transmission
EP0220800A1 (fr) * 1985-10-17 1987-05-06 Crucible Materials Corporation Procédé de la métallurgie des poudres pour produire un produit tubulaire
EP0602877A1 (fr) * 1992-12-14 1994-06-22 General Electric Company Tube de canon composite ayant plusieurs couches
TR28217A (tr) * 1992-12-14 1996-02-29 Gen Electric Cok-tabakali kompozit top namlusu.
RU2167742C2 (ru) * 1999-03-31 2001-05-27 Курский государственный технический университет Способ армирования металлических изделий твердосплавным слоем

Also Published As

Publication number Publication date
DE3376101D1 (en) 1988-05-05
EP0114593A1 (fr) 1984-08-01
EP0114591B1 (fr) 1988-03-30
US4747225A (en) 1988-05-31
ES8501657A1 (es) 1984-12-01
ATE33219T1 (de) 1988-04-15
ES8501658A1 (es) 1984-12-01
EP0114592B1 (fr) 1988-03-30
ES528315A0 (es) 1984-12-01
ES528317A0 (es) 1984-12-01
EP0114592A1 (fr) 1984-08-01
GR81355B (fr) 1984-12-11
GR79748B (fr) 1984-10-31
ATE33218T1 (de) 1988-04-15
DE3376100D1 (en) 1988-05-05

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