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EP0108925B1 - Agent de lubrification fibreux pour matériau textile - Google Patents

Agent de lubrification fibreux pour matériau textile Download PDF

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Publication number
EP0108925B1
EP0108925B1 EP83110079A EP83110079A EP0108925B1 EP 0108925 B1 EP0108925 B1 EP 0108925B1 EP 83110079 A EP83110079 A EP 83110079A EP 83110079 A EP83110079 A EP 83110079A EP 0108925 B1 EP0108925 B1 EP 0108925B1
Authority
EP
European Patent Office
Prior art keywords
weight
alkyl
acid
ethylene oxide
cotton
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP83110079A
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German (de)
English (en)
Other versions
EP0108925A3 (en
EP0108925A2 (fr
Inventor
Manfred Petzold
Peter Waltenberger
Rudolf Dr. Veitenhansl
Claudia Haak
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to AT83110079T priority Critical patent/ATE31435T1/de
Publication of EP0108925A2 publication Critical patent/EP0108925A2/fr
Publication of EP0108925A3 publication Critical patent/EP0108925A3/de
Application granted granted Critical
Publication of EP0108925B1 publication Critical patent/EP0108925B1/fr
Expired legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D06M2101/08—Esters or ethers of cellulose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/10—Animal fibres
    • D06M2101/12—Keratin fibres or silk
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions

Definitions

  • a known method for improving the smoothness of textile fiber material is the so-called dry waxing.
  • the yarn to be treated is passed over solid paraffin during winding.
  • the thread absorbs an amount of paraffin which depends on the type of paraffin, the contact pressure and the material speed.
  • DE-A-26 21 881 describes agents based on aqueous paraffin dispersions which are suitable for treating a wide variety of textile fiber materials, such as cellulose, wool, synthetic fiber material or mixtures thereof, and which give this material the smoothness required for further processing and good grip .
  • Wet waxing agents of the type described in DE-A-26 21 881 do not always process yarns of cotton or of cotton / synthetic fibers without additional hard waxing.
  • the object of the invention is therefore the development of smoothing agents in the form of aqueous dispersions which are suitable for treating a wide variety of textile fiber materials, such as cellulose, wool, synthetic fiber material, or mixtures thereof.
  • smoothing agents are storage-stable, aqueous, cationic dispersions, the specific substantivity of which enables application in particular in the exhaust process.
  • Suitable polyethylenes (I) are anoxidized types with saponification numbers of 40-80 and acid numbers of 25-60, which are derived from low molecular weight polyethylenes (so-called polyethylene waxes).
  • the densities of the oxidized polyethylenes are above 0.94 g / cm 3 , preferably between 0.98 and 1.00 g / cm 3 , the molecular weights are 3,000-8,000. It has been shown that only with such polyethylene waxes are satisfactory effects can be achieved in the sense of the invention.
  • Emulsifiers of the formula (11) are obtained from fatty amines having 12 to 22 carbon atoms, preferably 16 to 18 carbon atoms, by reaction with 2 to 20 moles of ethylene oxide or with ethylene oxide and propylene oxide, preferably 2 to 10 moles of alkylene oxide, for. B. the adduct of technical stearylamine with 10 mol EO.
  • the lower carboxylic acids (III) are used for salt formation with the fatty acid amidopolyamines or for neutralizing other basic constituents of the composition and should advantageously be used in an amount such that the pH of the product is about 4-5.
  • acetic acid and glycolic acid are suitable.
  • Paraffins (IV) used are preferably those in the melting range 50-60 ° C.
  • Suitable fatty acid esters (V) are, in particular, methyl or ethyl or isostridecyl palmitate or stearic acid.
  • esters or partial esters of ethylene glycol, propylene glycol, glycerol, pentaerythritol, trimethylolpropane, 2,2'-dimethyl-1,3-dioxypropane or sorbitan, e.g. B. palmitic or stearic monoglyceride can be used.
  • the fatty acid amidopolyamines (VI) are preferably obtained from saturated fatty acids or fatty acid mixtures having 16-22 carbon atoms with polyalkylene polyamines, such as diethylenetriamine, triethylene tetramine or tetraethylene pentamine, the reaction taking place in such a molar ratio that at least one amine nitrogen atom capable of salt formation is retained.
  • polyalkylene polyamines such as diethylenetriamine, triethylene tetramine or tetraethylene pentamine
  • An example is the reaction product of 2 moles of stearic acid with 1 mole of diethylenetriamine.
  • the fatty acid amidopolyamines are in the form of their salts with lower carboxylic acids or hydroxycarboxylic acids with 1 to 4 carbon atoms, e.g. B. acetic acid or glycolic acid.
  • Suitable quaternary ammonium salts are, for example, lauryl trimethyl ammonium chloride, dodecyl benzyl trimethyl ammonium methosulfate, distearyl dimethyl ammonium chloride or 1-ethyl-1-hydroxyethyl-2-heptadecenyl imidazolinium ethyl sulfate.
  • the smoothing agents also contain 0-5% by weight, preferably 0.5-1.5% by weight, of an ethylene oxide adduct of straight- or branched-chain, saturated or unsaturated higher alcohols with 9-22, preferably 16-18C- Atoms, e.g. B. the adduct of 20 moles of ethylene oxide with 1 mole of oleyl alcohol, or of alkylphenol with 12-20 C atoms, for. B. the adduct of 10 moles of ethylene oxide with nonylphenol, or with higher fatty acids with 10 - 22 carbon atoms, or mixtures of these adducts (VII).
  • the ethylene oxide content of the adducts should be 35-85% by weight.
  • the ethylene oxide adducts with higher alcohols and alkylphenols are preferred.
  • Particularly suitable silicones (VIII) are dimethylpolysiloxanes with a viscosity of 350-30,000 cSt, preferably 10,000-20,000 cSt, but also nonionically or anionically modified dimethylpolysiloxanes.
  • Protective colloids (IX) are preferably methyl cellulose, hydroxyethyl cellulose, glue, polyvinyl alcohol or gum arabic.
  • composition is supplemented with water (X) to 100% by weight and converted into a stable dispersion, which can be done in the usual manner by stirring, if appropriate at elevated temperatures and using Stirrers, dispersers, homogenizers, etc. can be done. Distilled or demineralized water is preferably used.
  • the smoothing agents claimed according to the invention can be used to finish textile fiber materials such as cotton, wool, rayon, polyacrylonitrile; Polyester; Polyamide, triacetate, polyethylene, polypropylene and mixtures thereof, preferably cotton, wool and their mixtures with polyester or polyacrylonitrile can be used.
  • the textile fiber materials are in the form of flakes, slats, yarn, knitted fabrics, fabrics or nonwovens, preferably yarn, knitted fabrics and fabrics.
  • the material can be raw white, bleached or colored.
  • the smoothing agents can be applied in customary equipment, such as dyeing equipment for packages, strands or muffs, on the reel runner or on jet dyeing equipment.
  • the extraction process from an aqueous liquor is preferably carried out at a liquor ratio of 1: 8 to 1:40 and a liquor pH of 2-8, at 25-80 ° C., the concentration being 0.2-3.0, preferably 0, 2-2.5 wt .-% of smoothing agent, based on the weight of the goods.
  • the finishing can take place in the presence of electrolytes, such as Na acetate, Na sulfate, Na chloride etc.
  • the smoothing agents can also be experienced in a so-called forced application, such as. B. in the foulard or in the lisseuse, brought to the textile material.
  • the padding process is carried out at a concentration of 2-10 g / 1, preferably 4-7 g / I, calculated on 100% active ingredient content, it also being possible to use high-quality finishing agents, such as anti-crease or anti-shrinkage finishing agents.
  • the textile materials equipped according to the invention have a soft, supple and elegant handle, which is why an additional application of finishing agents is not necessary.
  • the smoothness values are significantly lower in comparison to other known wet waxing agents, in particular in the case of cotton and cotton blends, and have a high degree of uniformity, which enables perfect processing into knitted fabrics (for knitting and knitting). This effect occurs especially under normal drying conditions. There is no additional hard waxing.
  • the knitted fabrics and knitted fabrics produced according to the invention show good and calm stitch patterns.
  • the needle penetration forces of woven and knitted goods show unusually low values. This applies both to goods treated exclusively with the smoothing agents according to the invention and to goods which are equipped with a customary synthetic resin finish.
  • the substantivity of the smoothing agents is very good and leads to a high liquor yield.
  • the thermal stability of the smoothing agent is very high, so that in the usual drying processes neither smoke nor deposits in the dryer occur.
  • the smoothing agents of the formulations (A) - (C) and (D) - (E) are stable dispersions that can be mixed with water in any ratio.
  • Pure cotton yarn was dyed on a cross-wound HT dyeing machine with indanthrene dyes.
  • the aftertreatment was carried out on a fresh bath, liquor ratio 1:10, acetic acid, pH 5.0.
  • the smoothing agents (A) - (C) and the comparative additives (D) and (E) were applied with a 0.6% active ingredient over a period of 20 minutes at 45 ° C.
  • the coils were then suctioned off on the apparatus and dried on a pressure dryer.
  • the sewing needle penetration forces were measured on a Pfaff double lockstitch high-performance high-speed sewing machine, type 483 with built-in penetration force transducer, at 4000 stitches / min.
  • the mean values from 50 individual punctures are shown in the table.
  • Cotton knitwear was refined on the padder using 60 g / l of a reactant resin (Stabitex FRD®) and 6.0 d / 1 magnesium chloride as a catalyst. Drying and condensation took place on the stenter. 8.0 g / 1 smoothing agent or comparative rinse aid, based on 100% active substance, was added to the liquors, in particular to improve the sewability, but also to adjust the soft feel.
  • a reactant resin Stitex FRD®
  • 6.0 d / 1 magnesium chloride as a catalyst. Drying and condensation took place on the stenter.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)
  • Storage Of Web-Like Or Filamentary Materials (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)

Claims (4)

1. Agents de lissage pour matériel en fibres textiles, caractérisés par la composition suivante:
(I) 10- 30 % en poids de polyéthylène ayant subi un commenncement d'ohydation, avec un poids moléculaire moyen de 3000 à 8000, une densité de plus de 0,94 jusqu'à 1.01, un indice d'acide de 25 à 60 et un incide de saponification de 40 à 80;
(II) 3-10% en poids d'un émulsifiant cationique comme celui obtenu par addition de 2 à 20 moles d'oxyde d'éthylène et/ou d'oxyde de propylène sur une alcoylamine ayant 10 à 22 atomes de carbone;
(III) 1 - 5 % en poids d'un acide carboxylique ou d'un acide hydroxycarboxylique inférieur ayant 1 à 4 atomes de carbone;
(IV) 0 - 10 % d'un poids de paraffine ayant un intervalle de fusion de 40 - 70° C;
(V) 0 - 8% en poids d'un ester d'acide gras au départ de 1 mole d'acide gras ayant 10 à 22 atomes de carbone et d'un alcool mono- ou polyvalent ayant 1 à 20 atomes de carbone;
(VI) 0 à 10 % en poids d'un amidopolyamine d'acide gras de formule générale:
Figure imgb0008
où -OCR1 est un radical acyle gras ayant 14 à 22 atomes de carbone, m = 2 - 6, n - 1 - 3, o = 1 - 3, ou bien d'un composé d'ammonium quaternaire de formule:
Figure imgb0009
R1 = alcoyle en C10-C22
R2 =alcoyle en C1-C22
R3=alcoyle en C2-C22
R4=alcoyle en C1-C4
A=anion formateur de sel

ou d'un sel d'alcoylimidazolinium ayant un radical alcoyle comportant 12 à 20 atomes de carbone;
(VII) 0 - 5 % en poids d'un produit d'addition d'oxyde d'éthylène sur des alcools supérieurs ayant 8 à 22 atomes de carbone ou sur des alcoylphénols ayant 12 à 20 atomes de carbone ou sur des acides gras supérieurs ayant 10 à 22 atomes de carbone;
(VIII) 0 - 3 % en poids d'une dispersion de diméthylpolysiloxane à environ 30 % de substance active;
(IX) 0 - 1 % en poids d'un colloide protecteur;
(X) le restant étant de l'eau pour compléter à 100 % en poids.
2. Agents de lissage selon la revendication 1, caractérisés en ce que les polyéthylènes oxydés possèdent des densités de 0,98 à 1,00 g/cm3.
3. Utilisation des agents de lissage selon les revendications 1 et 2 pour l'avivage de filés, de tricots ou de tissus en coton ou en des mélanges de coton-fibre synthétique.
EP83110079A 1982-10-16 1983-10-08 Agent de lubrification fibreux pour matériau textile Expired EP0108925B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT83110079T ATE31435T1 (de) 1982-10-16 1983-10-08 Glaettemittel fuer textilfasermaterial.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19823238395 DE3238395A1 (de) 1982-10-16 1982-10-16 Glaettemittel fuer textilfasermaterial
DE3238395 1982-10-16

Publications (3)

Publication Number Publication Date
EP0108925A2 EP0108925A2 (fr) 1984-05-23
EP0108925A3 EP0108925A3 (en) 1986-02-05
EP0108925B1 true EP0108925B1 (fr) 1987-12-16

Family

ID=6175886

Family Applications (1)

Application Number Title Priority Date Filing Date
EP83110079A Expired EP0108925B1 (fr) 1982-10-16 1983-10-08 Agent de lubrification fibreux pour matériau textile

Country Status (7)

Country Link
US (1) US4474668A (fr)
EP (1) EP0108925B1 (fr)
AT (1) ATE31435T1 (fr)
DE (2) DE3238395A1 (fr)
ES (1) ES8506123A1 (fr)
TR (1) TR22324A (fr)
ZA (1) ZA837671B (fr)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8400899D0 (en) * 1984-01-13 1984-02-15 Procter & Gamble Granular detergent compositions
FR2565609B1 (fr) * 1984-06-08 1989-02-17 Sandoz Sa Nouvelles dispersions aqueuses de cires destinees au finissage des substrats textiles
DE3734931A1 (de) * 1987-10-15 1989-05-03 Henkel Kgaa Mittel zum glaetten von textilfasermaterialien
DE3809928A1 (de) * 1988-03-24 1989-10-05 Henkel Kgaa Ziehfaehige textilhilfsmittel fuer polyesterhaltige fasermaterialien
US5051250A (en) * 1989-06-21 1991-09-24 Colgate-Palmolive Company Fiber conditioning compositions containing solubilized poly-lower alkylene
AU640382B2 (en) 1989-11-07 1993-08-26 Colgate-Palmolive Company, The Fiber conditioning compositions containing solubilized poly-lower alkylene
ES2109144B1 (es) * 1994-10-28 1998-08-16 Productes Del Latex S A Composicion para el recubrimiento de articulos de goma o latex.
US5830843A (en) * 1996-01-31 1998-11-03 The Procter & Gamble Company Fabric care compositions including dispersible polyolefin and method for using same
US5728673A (en) * 1996-01-31 1998-03-17 The Procter & Gamble Company Process for making a fluid, stable liquid fabric softening composition including dispersible polyolefin
US5789373A (en) * 1996-01-31 1998-08-04 Baker; Ellen Schmidt Laundry additive compositions including dispersible polyolefin
US5972497A (en) * 1996-10-09 1999-10-26 Fiberco, Inc. Ester lubricants as hydrophobic fiber finishes
EP0905301A1 (fr) * 1997-09-02 1999-03-31 Chimitex S.A.R.L. Agent encollant pour un système d'encollage à basse température
DE10204808A1 (de) * 2002-02-06 2003-08-14 Cognis Deutschland Gmbh Verwendung von ethoxylierten Fettsäuren als Glättemittel für synthetische und natürliche Fasern
RU2222653C1 (ru) * 2002-05-28 2004-01-27 Ивановский государственный химико-технологический университет Состав для обработки текстильных волокон и пряжи
CN113445318A (zh) * 2021-07-28 2021-09-28 沂水祥腾化工有限公司 一种纺织用纱线平滑剂及其制备方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE549558A (fr) * 1955-07-15
US3155537A (en) * 1959-02-24 1964-11-03 Du Pont Rope finish
FR1298562A (fr) * 1960-07-05 1962-07-13 Argus Chem Compositions d'hydrofugation, produits et procédés pour les préparer
SE328665B (fr) * 1966-04-18 1970-09-21 Kanegafuchi Spinning Co Ltd
DE2502155C2 (de) * 1974-01-22 1985-01-03 Toyobo Co., Ltd., Osaka Spinnölpräparate
DE2733493C2 (de) * 1976-05-17 1986-11-13 Henkel KGaA, 4000 Düsseldorf Glättemittel für Textilfasermaterial
DE2621881C2 (de) * 1976-05-17 1985-10-31 Henkel KGaA, 4000 Düsseldorf Glättemittel für Textilfasermaterial

Also Published As

Publication number Publication date
DE3238395A1 (de) 1984-04-19
ZA837671B (en) 1984-08-29
DE3374952D1 (en) 1988-01-28
US4474668A (en) 1984-10-02
ES526490A0 (es) 1985-06-16
TR22324A (tr) 1987-02-10
EP0108925A3 (en) 1986-02-05
ATE31435T1 (de) 1988-01-15
ES8506123A1 (es) 1985-06-16
EP0108925A2 (fr) 1984-05-23

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