EP0198910A1 - Verfahren und vorrichtung zum detektieren von schlacke. - Google Patents
Verfahren und vorrichtung zum detektieren von schlacke.Info
- Publication number
- EP0198910A1 EP0198910A1 EP85905609A EP85905609A EP0198910A1 EP 0198910 A1 EP0198910 A1 EP 0198910A1 EP 85905609 A EP85905609 A EP 85905609A EP 85905609 A EP85905609 A EP 85905609A EP 0198910 A1 EP0198910 A1 EP 0198910A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- coils
- coil
- transmitter
- slag
- measuring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/0025—Adding carbon material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/16—Controlling or regulating processes or operations
- B22D11/18—Controlling or regulating processes or operations for pouring
- B22D11/181—Controlling or regulating processes or operations for pouring responsive to molten metal level or slag level
- B22D11/186—Controlling or regulating processes or operations for pouring responsive to molten metal level or slag level by using electric, magnetic, sonic or ultrasonic means
Definitions
- the invention relates to a method and a device for detecting slag flowing in a flow of a molten metal, in particular in molten steel when pouring from metallurgical vessels.
- the approximate point in time from which slag can drain off is determined.
- the pan is weighed in an empty and full state, so that the respective remaining amount of melt can be determined therefrom.
- the outflow of the slag is determined visually by the operating team after it has been concluded from the display of the balance that the level has dropped to critical values.
- REPLACEMENTB In another method, visual inspection is dispensed with and pouring is stopped when a predetermined fill level is reached in the pan.
- the invention has for its object to arrive at a method with which a small proportion of slag in the flowing melt can be recognized and displayed without having to remove the shielding of the pouring jet or hindering the pouring.
- the temperatures of the melt and the sensor should be monitored continuously.
- the temperature measurements are state of the art. The determination is particularly simple if the ohmic resistances of the coils are used to infer the temperatures of the measuring sensors and from this further the temperature of the melt.
- the heat spread in the system itself can be calculated after the material constants have been determined in the usual way.
- the value of the electrical conductivity which is included in the calculation of the distribution of the slag from the measured values of the voltage spectrum, can be corrected.
- the sensitivity can be increased significantly.
- a further embodiment of the invention provides that a further winding is applied to the transmitter coil of the reference device, into which a current that is variable according to amounts and phase positions is fed in frequency-selectively so that the voltage of the receiver coil for all frequencies becomes zero or approaches zero .
- a further embodiment of the invention provides for a coil arrangement which coaxially surrounds the flow cross section, consisting of two transmitter and receiver coils which maintain a certain radial distance from one another, or to operate a coil arrangement in such a way that the Transmitter and receiver coil axes are arranged in the radial direction around the test object and the transmit coils are located outside the base corners of an isosceles triangle at the same radial distance from the test object, the voltage induced in the receive coil being adjusted to zero for all frequencies by corresponding feeding of the currents into the transmit coils becomes.
- the signals from the measuring coils are preferably measured with the aid of phase-sensitive rectifiers, and the evaluation and adjustment of the bridge circuits is carried out with the aid of a computer or microprocessor.
- a device for carrying out the method according to the invention can be used, for example, in a metallurgical vessel provided with a lining, the transmitter and receiver coils of the measuring sensor being integrated in the lining or in perforated bricks of the vessel.
- both the transmitting and receiving coil and a reference transmitting coil are integrated in the lining or in perforated bricks of the vessel.
- the vessel can be provided with an outflow valve which can be controlled by the measured values determined.
- one or more transmitting and receiving coils can thus be fixed around the flowing pouring jet in such a way that they preferably surround it coaxially.
- the transmitter coils are fed with a current of several frequencies, the voltage induced in the pickup coils being measured in a frequency-selective manner in terms of magnitude and phase position.
- the radial distribution of the electrical conductivity can be used to infer the slag content in the melt.
- a bridge circuit is used to increase the sensitivity, in which a reference arrangement consisting of a transmitting and receiving coil is switched so that the same supply current flows through the transmitter coils, while the receiver coils are switched so that the induced voltages are directed in opposite directions.
- the transmitter coils are fed with currents which contain several frequencies and which are set frequency-selectively against each other in amount and phase position so that the induced voltage in the measuring coil is adjusted to zero for all frequencies. Changes in the electrical conductivity of the test object then lead to a frequency-selective detuning of the zero adjustment of the bridge.
- a slag fraction in the pouring jet can be recognized as follows:
- Slag content in the pouring stream can be recognized.
- Fig. La the mechanical installation of the sensor in a perforated brick of pan or tundish;
- Fig. Lb the mechanical installation of the sensor on the surface of an outlet pipe from pan or tundish
- ERSAT ⁇ B-LAT 3 shows a measuring circuit for three frequencies with compensation winding, in which the measuring bridge is compared with Hi l fe of a compensation current;
- Fig. 4a shows the mechanical structure of a sensor, which consists of two transmitter and a receiver coil, and in which the sensor coils coaxially enclose the flux cross-section of the metal melt;
- 4b shows the mechanical construction of a measuring sensor, which consists of two transmitting and one receiving coil, and in which the measuring sensor coil axes point in the radial direction;
- Fig. La is' a metal lurgi cal vessel with 1, a melt with 2, a transmitter coil with 3, a receiver coil with 4, a pouring jet with 5, an outlet tube with 6, a perforated pipe with 7 and a discharge valve with 16 designated.
- the transmitter coil 3 encloses the pouring jet 5 and generates the primary field.
- the receiving coil 4 is located coaxially within the transmitter coil 3. Both coils 3 and 4 are inserted into the hole 7 and potted.
- Fig. Lb shows an example of how the sensors enclose the outlet tube 6 of the pan and the intermediate vessel.
- Transmitter coil 3 and receiver coil 4 are firmly connected to one another and enclose the outlet pipe 6 coaxially. Transmitter coil 3 and receiver coil 4 are fastened to the outlet pipe 6 in such a way that they can be easily removed and reused when the outlet pipe 6 is changed.
- the reference arrangement consists of a transmitting and receiving coil which are arranged in such a way that an approximately the same induction voltage is generated in the reference receiving coil as in the measuring coil.
- Fig. 2 shows the basic structure of a measuring circuit for three frequencies, in which the transducer and the reference arrangement are operated in a bridge circuit.
- a frequency generator 8 controls a power amplifier 9 with three frequencies, which feeds the series-connected transmission coils 10 of the measuring sensor and a transmission coil 11 of the reference arrangement.
- a receiving coil 10a of the measuring sensor and a receiving coil 11a of the reference arrangement are connected to one another and designed in such a way that the induced voltages are almost compensated for.
- the sum signal is fed via a high-impedance preamplifier 12 to phase-sensitive rectifiers 13, which break down the signal into real and imaginary parts, which are displayed on a corresponding output unit 14.
- Fig. 3 shows the basic structure of a measuring circuit for three frequencies, in which the sensor and the reference arrangement are operated in a bridge circuit and the bridge adjustment is carried out by a compensation current.
- the measuring and reference arrangement is operated as in FIG. 2.
- a compensation winding 15 is applied to the reference coil arrangement, which is operated as a further transmitter coil.
- the signal tapped at the frequency generator 8 is fed frequency-selectively via adjustable phase shifters 16a, 16b, 16c to the power amplifiers 9a, 9b, 9c feeding the compensation winding, the amplification of which can also be changed.
- phase positions and the amounts of the compensation currents are set manually or by a computer or microprocessor 21 so that the sum voltage at the input of the preamplifier 12 is zero for all frequencies. Changes in the conductivity of the measurement object then lead to detuning of the bridge and to a sum signal at the input of the preamplifier 12, from the amounts and phase positions of which the radial distribution of the electrical conductivity of the pouring jet 5 and from this the slag fraction can be determined.
- Fig. 4a shows the basic mechanical structure of a sensor, which consists of two transmitter coils 3, 3a and a receiver coil 4.
- the transmitter coil 3 is thereby coaxially enclosed by the receiver coil 4 at a certain radial distance, the optimum value of which depends on the overall geometry of the sensor, and this in turn is enclosed by the second transmitter spool 3a, which works as a reference coil.
- This coil arrangement is mechanically fixed against one another, preferably cast, and as a whole encloses the pouring jet 5 at a predetermined distance.
- Fig. 4b shows the basic mechanical structure of a sensor, which consists of two transmitter coils 3, 3a and a receiver coil 4.
- the transmitter coils 3, 3a and the receiver coil 4 are arranged in such a way that their axes point in the radial direction and that the transmitter coil 3a is offset by 90 * and the transmitter coil 3 by 180 * with respect to the receiver coil 4.
- Fig. 5 shows the basic structure of a measuring circuit for three frequencies with the coil arrangement according to Fig. 4a or 4b as a sensor.
- a frequency generator 8 controls a power amplifier 9 with three frequencies, which in turn feeds the transmitter coil 3 of the sensor.
- the signal of the frequency generator 8 is simultaneously frequency-selectively supplied via adjustable phase shifters 16a, 16b, 16c to the power amplifiers 9a, 9b, 9c, which feed the transmitter coil 3a of the measuring transducer.
- the voltage induced in the receiving coil 4 of the sensor is fed via a preamplifier 12 to phase-sensitive rectifiers 13, which break down the signal frequency-selectively into real and imaginary parts, which are displayed on a corresponding output unit 14.
- phase positions of the compensation currents in the transmission coil 3a are set by means of the phase shifters 16, 16b, 16c and the amounts by means of the amplification factors of the power amplifiers 9a, 9b, 9c so that the induction voltage at the input of the preamplifier 12 becomes zero for all frequencies.
- Changes in the radial distribution of the electrical conductivity in the test object 5 lead to a detuning of the measuring bridge and to a signal at the input of the preamplifier 12, from whose amounts and phase positions the radial distribution of the electrical conductivity and from this the slag fraction in the pouring jet can be determined.
- the measuring bridge can be adjusted manually or by a microprocessor 21.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Investigating Or Analyzing Materials By The Use Of Magnetic Means (AREA)
- Continuous Casting (AREA)
- Measuring Volume Flow (AREA)
- Geophysics And Detection Of Objects (AREA)
- Furnace Details (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
- Furnace Charging Or Discharging (AREA)
Description
Claims
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT85905609T ATE47062T1 (de) | 1984-10-27 | 1985-10-17 | Verfahren und vorrichtung zum detektieren von schlacke. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3439369 | 1984-10-27 | ||
| DE19843439369 DE3439369A1 (de) | 1984-10-27 | 1984-10-27 | Verfahren und vorrichtung zum detektieren von schlacke |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0198910A1 true EP0198910A1 (de) | 1986-10-29 |
| EP0198910B1 EP0198910B1 (de) | 1989-10-11 |
Family
ID=6248894
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP85905609A Expired EP0198910B1 (de) | 1984-10-27 | 1985-10-17 | Verfahren und vorrichtung zum detektieren von schlacke |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4816758A (de) |
| EP (1) | EP0198910B1 (de) |
| JP (1) | JPH0741402B2 (de) |
| AT (1) | ATE47062T1 (de) |
| CA (1) | CA1270917A (de) |
| DE (2) | DE3439369A1 (de) |
| WO (1) | WO1986002583A1 (de) |
| ZA (1) | ZA858227B (de) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3175939A1 (de) * | 2015-12-01 | 2017-06-07 | Refractory Intellectual Property GmbH & Co. KG | Schiebeverschluss am ausguss eines metallurgischen gefässes |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5023252A (en) * | 1985-12-04 | 1991-06-11 | Conrex Pharmaceutical Corporation | Transdermal and trans-membrane delivery of drugs |
| DE3722795A1 (de) * | 1987-07-10 | 1989-01-19 | Amepa | Vorrichtung zum detektieren von in einem fluss einer metallschmelze mitfliessender schlacke |
| IT1222337B (it) * | 1987-10-21 | 1990-09-05 | Ceda Costruzioni Elettromeccan | Dispositivo per la misura del livello di metallo liquido in un cristallizzatore per lingottiera per colata continua |
| US4810988A (en) * | 1988-06-20 | 1989-03-07 | Westinghouse Electric Corp. | Slag detector transducer coil assembly |
| FI84208C (fi) * | 1989-01-31 | 1991-10-25 | Outokumpu Oy | Foerfarande foer detektering av metallfoeremaol. |
| DE3908199A1 (de) * | 1989-03-14 | 1990-09-27 | Leybold Ag | Vorrichtung zur identifizierung der erstarrungsfront einer schmelze |
| US5232043A (en) * | 1989-03-14 | 1993-08-03 | Leybold Aktiengesellschaft | Device for identifying the solid-liquid interface of a melt |
| US5042700A (en) * | 1989-05-12 | 1991-08-27 | Stopinc Aktiengesellschaft | Process and equipment to determine disturbance variables when pouring molten metal from a container |
| US5157332A (en) * | 1989-10-13 | 1992-10-20 | The Foxboro Company | Three-toroid electrodeless conductivity cell |
| DE4025093A1 (de) * | 1990-08-08 | 1992-02-13 | Schilling Gerhard | Verfahren und schaltung zur induktiven messung der leitfaehigkeit in fluessigkeiten |
| US5237271A (en) * | 1991-05-06 | 1993-08-17 | General Electric Company | Apparatus and method for non-destructive testing using multi-frequency eddy currents |
| US5650117A (en) * | 1995-09-27 | 1997-07-22 | Vesuvius Crucible Company | Slag detecting apparatus and method |
| DE19651535C1 (de) * | 1996-12-11 | 1998-04-30 | Didier Werke Ag | Induktor bei einem Schmelzengefäß |
| US6693443B2 (en) | 1999-04-02 | 2004-02-17 | Worcester Polytechnic Institute | Systems for detecting and measuring inclusions |
| NO326208B1 (no) * | 1999-07-12 | 2008-10-20 | Epsis As | Fremgangsmate og anordning til maling av interfaseniva, samt anvendelse derav |
| ES2230430T3 (es) | 2002-07-25 | 2005-05-01 | Amepa Angewandte Messtechnik Und Prozessautomatisierung Gmbh | Procedimiento y dispositivo para valorar señales de medicion de corriente parasita. |
| US7148678B1 (en) * | 2003-03-26 | 2006-12-12 | Targosz Thomas C | Magnetic taggant system |
| US8269483B2 (en) * | 2003-03-26 | 2012-09-18 | Targosz Thomas C | Magnetic flux tagging for quality construction |
| US7923992B2 (en) * | 2004-03-25 | 2011-04-12 | Targosz Thomas C | Inspection of asphalt during manufacturing |
| EP1486271B1 (de) * | 2003-06-13 | 2008-07-16 | MPC Metal Process Control AB | Verfahren und Vorrichtung zum Erkennen von Schlacken |
| EP1486272B1 (de) * | 2003-06-13 | 2006-03-22 | MPC Metal Process Control AB | Verfahren und Vorrichtung zum Erkennen von Schlacken |
| CN1272628C (zh) * | 2003-09-17 | 2006-08-30 | 姜虹 | 液态金属注流渣含量检测装置 |
| US20050133192A1 (en) * | 2003-12-23 | 2005-06-23 | Meszaros Gregory A. | Tundish control |
| US9250223B2 (en) | 2004-03-25 | 2016-02-02 | Thomas C. Targosz | Method and apparatus for sensing magnetic radiation through tagging |
| US7126343B1 (en) | 2005-07-27 | 2006-10-24 | Ecolab Inc. | Conductivity probe with toroid keeper |
| DE102006056473A1 (de) * | 2006-11-28 | 2008-05-29 | Betriebsforschungsinstitut VDEh - Institut für angewandte Forschung GmbH | Verfahren und Vorrichtung zur Bestimmung des Gehalts von mindestens einer Komponente einer Schlackenschmelze |
| DE102007039435A1 (de) * | 2006-12-15 | 2008-06-19 | Prüftechnik Dieter Busch AG | Vorrichtung und Verfahren zum Erfassen von Partikeln in einer strömenden Flüssigkeit |
| EP2259843B1 (de) * | 2008-03-20 | 2012-08-29 | IMI Intelligent Medical Implants AG | Energieversorgung für ein netzhautimplantat |
| US8482295B2 (en) * | 2009-02-23 | 2013-07-09 | Hatch Ltd. | Electromagnetic bath level measurement for pyrometallurgical furnaces |
| EP2383056B1 (de) * | 2010-04-28 | 2016-11-30 | Nemak Dillingen GmbH | Verfahren und Vorrichtung für eine kontaktlose Metallfühlervorrichtung |
| DE102012019329A1 (de) | 2012-10-02 | 2014-04-03 | Gerd Reime | Verfahren und Sensoreinheit zur Ortung und/oder Erkennung metallischer oder Metall enthaltender Objekte und Materalien |
| DE102015104217A1 (de) * | 2015-03-20 | 2016-09-22 | Endress + Hauser Conducta Gesellschaft für Mess- und Regeltechnik mbH + Co. KG | Messsystem zum Bestimmen der spezifischen elektrischen Leitfähigkeit |
| EP3326735B1 (de) * | 2016-11-29 | 2020-07-22 | Refractory Intellectual Property GmbH & Co. KG | Verfahren sowie eine einrichtung zum detektieren von grössen im ausguss eines metallurgischen gefässes |
| RU2662850C2 (ru) * | 2016-03-09 | 2018-07-31 | Открытое акционерное общество ЕВРАЗ Нижнетагильский металлургический комбинат | Способ обнаружения шлака в потоке расплава металла |
| CN107363252A (zh) * | 2017-08-07 | 2017-11-21 | 河钢股份有限公司邯郸分公司 | 一种提高浇注过程中钢水洁净度的控流装置及方法 |
| CN109848386B (zh) * | 2017-11-30 | 2021-02-05 | 上海梅山钢铁股份有限公司 | 一种连铸断流事故智能判断处置方法 |
| DE102020131685A1 (de) * | 2020-11-30 | 2022-06-02 | Rheinmetall Air Defence Ag | Verfahren zum Befüllen einer Gussformanordnung |
| DE102024103004A1 (de) | 2024-02-02 | 2025-08-07 | Berthold Technologies Gmbh & Co. Kg | Verfahren und System zum Überwachen eines Flusses aufweisend eine Metallschmelze auf Schlacke durch ein Ausgussrohr |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB836723A (en) * | 1956-10-04 | 1960-06-09 | Kelvin & Hughes Ltd | Improvements in or relating to the electromagnetic testing of materials |
| US3229198A (en) * | 1962-09-28 | 1966-01-11 | Hugo L Libby | Eddy current nondestructive testing device for measuring multiple parameter variables of a metal sample |
| DE2722475A1 (de) * | 1976-05-20 | 1977-12-08 | Atomenergi Ab | Spulenanordnung fuer elektromagnetische messungen |
| SE420649B (sv) * | 1976-05-20 | 1981-10-19 | Atomenergi Ab | Anordning for elektromagnetisk metning vid hog temeratur av atmindtone en av storheterna niva, avstand och hastighet i samband med i en behallare, kanal eller liknande innehallet flytande ledande material med mycket ... |
| SE413074B (sv) * | 1976-10-25 | 1980-04-14 | Asea Ab | Forfarande for metning av resistiva spenningsfall vid tappstellen fran metallurgiska behallare |
| SE418996B (sv) * | 1977-09-19 | 1981-07-06 | Atomenergi Ab | Forfarande och anordning for elektromagnetisk storhetsmetning i samband med ett elektriskt ledande material med hog temperatur |
| LU80410A1 (de) * | 1978-10-25 | 1980-05-07 | Arbed | Verfahren zur messung des fuellstandes von metallen in gefaessen,insbesondere in stranggiesskokillen |
| JPS56122656A (en) * | 1980-02-29 | 1981-09-26 | Nippon Kokan Kk <Nkk> | Slag detector |
| JPS5935710B2 (ja) * | 1981-01-20 | 1984-08-30 | 住友金属工業株式会社 | 滓出検出方法 |
| LU83699A1 (de) * | 1981-10-16 | 1983-06-08 | Arbed | Verfahren zum ueberwachen einer stranggiesskokille im betrieb |
| DE3201799C1 (de) * | 1982-01-21 | 1983-08-25 | Fried. Krupp Gmbh, 4300 Essen | Vorrichtung zur Messung der Leitfähigkeit flüssiger Stoffe, insbesondere von Schlacken bei höheren Temperaturen |
| NL8201396A (nl) * | 1982-04-01 | 1983-11-01 | Dow Chemical Nederland | Zilver katalysator en een werkwijze voor de bereiding daarvan. |
| FR2532208A1 (fr) * | 1982-08-24 | 1984-03-02 | Siderurgie Fse Inst Rech | Appareil de detection de l'apparition de laitier dans les jets de coulee |
| JP5916543B2 (ja) | 2012-07-06 | 2016-05-11 | 矢崎総業株式会社 | バスバーの取付構造 |
-
1984
- 1984-10-27 DE DE19843439369 patent/DE3439369A1/de active Granted
-
1985
- 1985-10-17 AT AT85905609T patent/ATE47062T1/de not_active IP Right Cessation
- 1985-10-17 US US06/890,193 patent/US4816758A/en not_active Expired - Lifetime
- 1985-10-17 DE DE8585905609T patent/DE3573545D1/de not_active Expired
- 1985-10-17 JP JP60505242A patent/JPH0741402B2/ja not_active Expired - Lifetime
- 1985-10-17 EP EP85905609A patent/EP0198910B1/de not_active Expired
- 1985-10-17 WO PCT/EP1985/000544 patent/WO1986002583A1/de not_active Ceased
- 1985-10-25 ZA ZA858227A patent/ZA858227B/xx unknown
- 1985-10-28 CA CA000493961A patent/CA1270917A/en not_active Expired - Lifetime
Non-Patent Citations (1)
| Title |
|---|
| See references of WO8602583A1 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3175939A1 (de) * | 2015-12-01 | 2017-06-07 | Refractory Intellectual Property GmbH & Co. KG | Schiebeverschluss am ausguss eines metallurgischen gefässes |
| WO2017093236A1 (de) * | 2015-12-01 | 2017-06-08 | Refractory Intellectual Property Gmbh & Co. Kg | Schiebeverschluss am ausguss eines metallurgischen gefässes |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3439369A1 (de) | 1986-04-30 |
| ZA858227B (en) | 1986-06-25 |
| WO1986002583A1 (fr) | 1986-05-09 |
| CA1270917A (en) | 1990-06-26 |
| DE3573545D1 (en) | 1989-11-16 |
| JPS62500646A (ja) | 1987-03-19 |
| ATE47062T1 (de) | 1989-10-15 |
| DE3439369C2 (de) | 1989-04-13 |
| US4816758A (en) | 1989-03-28 |
| EP0198910B1 (de) | 1989-10-11 |
| JPH0741402B2 (ja) | 1995-05-10 |
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