Classifications

• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/38—Products with no well-defined composition, e.g. natural products
  • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
  • C11D3/38663—Stabilised liquid enzyme compositions

Definitions

• the present invention relates to enzymatic detergent compositions with improved enzyme-storage stability. More particularly, the invention relates to a detergent composition which contains a bleaching agent, in addition to the enzymes, with improved enzyme-storage stability.
• German Patent Application 3321082 laid open to public inspection on 15 December 1983, to improve the storage stability of sodium percarbonate in a detergent composition by coating the sodium percarbonate with a coating which contains a borate, such as sodium tetraborate (either the anhydrous salt or the different hydrates thereof), sodium octaborate, sodium pentaborate and sodium metaborate.
• a borate such as sodium tetraborate (either the anhydrous salt or the different hydrates thereof), sodium octaborate, sodium pentaborate and sodium metaborate.
• the sodium metaborate-dihydrate and -tetrahydrate are preferred.
• compositions may also contain enzymes and it is stated that such enzyme-containing detergent composi- tons have an improved enzyme-storage stability.
• the present invention therefore relates to an enzymatic detergent composition which comprises a peroxy-type bleaching agent other than an alkali metal percarbonate, and enzymes, the storage stability of which is improved by the inclusion in the composition of an alkali metal metaborate.
• the first essential ingredient is a bleaching agent of the peroxy-type other than alkali metal percarbonate.
• peroxy-type bleaching agents are alkali metal persulphates, -perphosphates, -perborates, alkali metal and alkaline earth metal salts of organic peracids, such as perphthalic acid, mono- and diperoxy azelaic acid, peroxy acetic acid, diperdodecane dioic acid and so on.
• the preferred peroxy-type bleaching agents are those which have, under the same storage conditions, a better storage stability in terms of available oxygen than percarbonate.
• a particularly preferred bleaching agent is sodium perborate, both in its tetrahydrate as well as in its monohydrate form.
• the amount of peroxy-type bleaching agent in the compositions of the invention ranges from 1-40%, preferably 3-35%, and particularly preferably from 5-30% by weight.
• the compositions of the invention may in this respect also contain bleach precursors, such as tetraacetyl ethylene diamine, tetraacetyl glycoluril, glucose pentaacetate and so on, to provide with the peroxy-type bleaching agent for a low temperature bleaching detergent composition.
• bleach precursors such as tetraacetyl ethylene diamine, tetraacetyl glycoluril, glucose pentaacetate and so on, to provide with the peroxy-type bleaching agent for a low temperature bleaching detergent composition.
• the second essential ingredient is the alkali metal metaborate.
• Typical suitable examples thereof are sodium and potassium metaborate, either anhydrous or in its various hydrate forms, e.g. K-metaborate. 1.5 aq, Na- metaborate. 2 aq. and . 4 aq.
• the alkali metal metaborate can be added in powdered form to the compositions of the invention or can be affixed to the surface of the peroxy-type bleaching agent when the latter is used in a particulate form.
• a potassium salt having a lower equilibrium humidity than the particulate peroxy-type bleaching agent, followed by a treatment with sodium metaborate.
• Typical examples of a suitable potassium salt is potassium metaborate. Both the potassium salts and the sodium metaborate are affixed to the particulate peroxy-type bleaching agent in the dry, powdered form.
• metaborate-forming substances which react with the peroxy-type bleaching agent, e.g. dimethyl sulfoxide.
• the alkali metal metaborate is present in the composition in an amount ranging from 0.1 % to 50 %, preferably 0.2 to 30%, and particularly preferably 0.5 to 20% by weight
• the third essential ingredient in the compositions of the invention is an enzyme.
• Typical examples of enzymes which can be used according to the invention are proteases, amylases, lipases and cellulases as they are usually proposed in the detergent art for inclusion in detergent compositions.
• proteolytic enzymes are the sub- tilisins which are obtained from particular strains of B. subtilis and B. licheniformis, such as the commercially available Maxatase ⁇ (ex Gist-Brocades N.V., Delft, Holland) and Alcalase e (ex Novo Industri A/S, Copenhagen, Denmark).
• Particularly suitable are proteases obtained from a strain of Bacillus having maximum activity in the pH-range of 8-12, developed and sold by Novo Industri A/S under the registered trade-names Esperase ® and Savinase 0. The preparation of such enzymes is described in British Patent Specification 1 ,243,784.
• amylolytic enzymes are commercially available amylases, such as Maxamyl (ex Gist-Brocades) and Termamyl ® (ex Novo Industri A/S). Amylases as described in British Patent Specification 1,296,839 are also suitable.
• Typical examples of commercial lipolytic enzymes are e.g. Lipase YL, Amano CE, Wallerstein AW, Lipase MY, and typical examples of cellulolytic enzymes are cellulases ex Humiscola insolens as described in German Patent Application 3,117,250.
• the benefits of the present invention are especially pronounced in amylase-containing formulations.
• the amount of enzymes present in the compositions of the invention is dictated by the activity of the enzyme preparation used. The higher this activity, the lower the level of enzymes required. In general the amount will vary between 0.001 and 10% by weight, and for most practical purposes between 0.1 and 5% by weight of the composition.
• compositions of the present invention can furthermore contain other ingredients commonly encountered in bleaching and detergent compositions.
• they may comprise one or more surfactants in an amount of up to 60%, such as soaps, anionic, nonionic, cationic and/or amphoteric synthetic detergents.
• they may comprise one or more inorganic and/or organic builder salts, such as the condensed phosphates, silicates, carbonates, nitrilotriacetates and so on, in amounts up to 60% by weight.
• the benefits of the present invention are particularly pronounced in formulations which contain a phosphate builder salt.
• other optional ingredients include soil- suspending agents, hydrotropes, corrosion inhibitors, dyes, perfumes, optical brighteners, suds-depressants, germicides, anti-tarnishing agents, other enzyme stabilizers, softening agents, sequestering agents, such as the amino polyphosphonic acids, clays and so on.
• a typical formulation for use in machine dishwashing may contain from 20-50% of sodium tripolyphosphate, 2-20% sodium silicate, 0-50% sodium carbonate, 5-25% sodium perborate, amylase plus protease up to 4%, TAED up to 10%, and amino polyphosphonic acid up to 1 %.
• compositions of the present invention can be prepared in any suitable particulate form, such as powders, granules, tablets, flakes, ribbons, noodles and the like, and they can be used for fabric washing, hard surface cleaning, dishwashing and general purpose cleaning.
• Termamyl is an amylase according to British Patent 1.296,839, sold by Novo Industri AS. These products were stored under the conditions as given in the Table below and the residual enzymatic activity (REA) was determined at the end of the storage period. The results were as follows : REA (expressed as % of initial activity) after
• SP 227 is a cellulase as described in German Patent Application 3,117,250, manufactured by NOVO Industri AS, and Savinase is a protease as described in British Patent 1,243,784, manufactured by NOVO Industri AS.
• compositions were prepared by dry mixing:
• compositions were prepared consisting of 2.1% Termamyl, 10% sodium perborate tetrahydrate, alkali metal metaborate as specified in the Table below, and sodium tripolyphosphate up to 100%.
• the residual enzymatic activity after x days' storage in open containers at 37°C/70% RH was as follows :
• Granulated sodium perborate (73.92 kg) was mixed in a Lodige mixer at 20°C for one hour with powdered potassium metaborate.1.5 H 2 0 (2.94 kg). The metaborate melted within the surface of the perborate granules, causing a fluidized surface thereon. Subsequently, powdered dry sodium metaborate (7.14 kg) was added to the mixer, which adhered to the fluidized surface and restored the free- flowing character of the granulate. After sieving and collecting the particles with a diameter of more than 230 micrometer, 79.5 kg of a granulate containing up to 87.3% sodium perborate were obtained.
• Formulations were made with this granulate, with or without separately added dry sodium disilicate, and these formulations were compared with the same formulations but without the metaborate.
• the formulations had the following compositions:

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• Chemical & Material Sciences (AREA)
• Life Sciences & Earth Sciences (AREA)
• Engineering & Computer Science (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Oil, Petroleum & Natural Gas (AREA)
• Wood Science & Technology (AREA)
• Organic Chemistry (AREA)
• Detergent Compositions (AREA)

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• 1984
  • 1984-10-02 GB GB848424812A patent/GB8424812D0/en active Pending
• 1985
  • 1985-09-25 EP EP85201534A patent/EP0181651A3/fr not_active Withdrawn
  • 1985-09-26 CA CA000491582A patent/CA1247025A/fr not_active Expired
  • 1985-09-30 ZA ZA857543A patent/ZA857543B/xx unknown
  • 1985-09-30 AU AU48107/85A patent/AU576629B2/en not_active Ceased
  • 1985-09-30 BR BR8504806A patent/BR8504806A/pt unknown
  • 1985-09-30 JP JP60217756A patent/JPS62116696A/ja active Granted

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